Citation: Wang Chao, Deng Nan, Wang Lingling, Xu Dingjian, Yao Xiaoquan. Cu-Ag Bimetallic Nanoparticles Catalyzed Addition of Terminal Alkynes to Aldehydes[J]. Chinese Journal of Organic Chemistry, ;2016, 36(5): 1034-1043. doi: 10.6023/cjoc201512018 shu

Cu-Ag Bimetallic Nanoparticles Catalyzed Addition of Terminal Alkynes to Aldehydes

1.
Department of Applied Chemistry, Nanjing University of Aeronautics and Astronautics, Nanjing 210016

Corresponding author: Yao Xiaoquan, yaoxq@nuaa.edu.cn
Received Date: 13 December 2015
Revised Date: 15 January 2016

Fund Project: Project supported by the National Natural Science Foundation of China No.21172107

Figures(2)

A copper-silver nanoparticles-catalyzed addition of terminal alkynes to aldehydes was developed for the synthesis of propargyl alcohols. With the promotion of bipyridine ligand, the bimetallic catalyst showed highly efficient to the reaction under neat condition, and good to excellent yields were achieved for various propargylic alcohols. In this catalytic reaction, a remarkable bimetallic synergistic effect was observed, in which Ag NPs worked as the co-catalyst and improved the catalytic activity of Cu NPs significantly. The nanoparticle catalyst could be recovered and reused effectively, and no obvious reduction on catalytic activity was observed after four recycles. Furthermore, a gram-scale reaction was also carried out successfully.
- Cu-Ag bimetallic nanoparticles,
- co-catalysis,
- the addition of terminal alkynes to aldehydes,
- propargylic alcohols,
- synergistic effect
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1.
沈阳化工大学材料科学与工程学院沈阳 110142