Citation: Bian Song, Ye Jia-Hai, Fan Zheng, Zhang Wenchao, Wang Leyong. Assembly of Tetraphenylethene Containing Amine and Crown Ether Units and Aggregation-Induced Emission Properties[J]. Chinese Journal of Organic Chemistry, ;2016, 36(4): 855-861. doi: 10.6023/cjoc201510030 shu

Assembly of Tetraphenylethene Containing Amine and Crown Ether Units and Aggregation-Induced Emission Properties

Bian Song ^a ,
Ye Jia-Hai ^a,, ,
Fan Zheng ^a ,
Zhang Wenchao ^a ,
Wang Leyong ^b,,

a.
a. School of Chemical Engineering, Nanjing Univesity of Science and Technology, Nanjing 210094;
b.
b. Laboratory for Supramolecular Chemistry and Dynamic. Materials, School of Chemistry and Chemical Engineering, Nanjing Universty, Nanjing 210093

Corresponding author: Ye Jia-Hai, Wang Leyong,
Received Date: 26 October 2015
Available Online: 9 December 2015

Dibenzo-24-crown-8 (DB24C8) and dibenzylammonium (DBA) are always utilized for the construction of supramolecular assemblies. We reported a new kind supramolecular assembly polymer constructed by M1 which was synthesized from tetraphenylethene (TPE) linked with DB24C8 and DBA through click reaction. The chemical structures of all the compounds were fully characterized by ¹H NMR, ¹³C NMR, and MS. The ¹H NMR titration showed that the supramolecular assembly was successfully constructed in acidic condition. The fluorescent results showed that the assemblies displayed ratio-metric properties with the changes of aggregation-induced emission and monomer-emission, and fluorescence quenching with addition of Pd²⁺.
- tetraphenylethene,
- DB24C8,
- secondary ammonium ion,
- supramolecular polymer,
- aggregations-induced emission
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沈阳化工大学材料科学与工程学院沈阳 110142

Assembly of Tetraphenylethene Containing Amine and Crown Ether Units and Aggregation-Induced Emission Properties

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com