Citation: Cao Jie, Liao Chaoqiang, Yang Ling, Zhang Xuejun. Synthesis and Characterization of the Coumarin-Binuclear Zinc Phthalocyanine Formed by Droxynaphthyl Bridge[J]. Chinese Journal of Organic Chemistry, ;2015, 36(1): 213-217. doi: 10.6023/cjoc201508013 shu

Synthesis and Characterization of the Coumarin-Binuclear Zinc Phthalocyanine Formed by Droxynaphthyl Bridge

1.
College of Science, North University of China, Taiyuan 030051

Corresponding author: Zhang Xuejun, zhangxuejun@nuc.edu.cn
Received Date: 11 August 2015
Revised Date: 2 September 2015

Fund Project: National Natural Science Foundation of China 51272239Shanxi Scholarship Council of China 2015-078National Natural Science Foundation of Shanxi Province 2015011011

Figures(6)

9(10), 16(17), 23(24)-Tris[4-methyl-coumarin-7-yloxy]-2(3)-(1, 5-naphthalene) binuclear zinc phthalocyanine (bi-CPc) based 1, 5-dihydroxynaphthalene, 4-nitro-phthalonitrile, resorcinol, ethyl acetoacetate and zinc acetate on raw material was synthesized. The structures and properties of precursors and bi-CPc were characterized by ¹H NMR, FT-IR, UV-Vis, elemental analysis and thermogravimetric analysis. Results showed that strong π-π^* transition was demonstrated by UV-Vis absorption spectrum of bi-CPc. At the same time, it existed in a form of monomer in solution of N, N-dimethylformamide (DMF) and possessed excellent thermal stability. Redox behavior of bi-CPc was researched by cyclic voltammetry (CV), and energy level of LUMO and HOMO of bi-CPc matched with energy level of nano-TiO₂ after calculating. Through further structural modification, it is expected to use as photosensitive dye with excellent performance for solar cells.
- phthalocyanine,
- binuclear,
- coumarin,
- dye-sensitized solar cells
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沈阳化工大学材料科学与工程学院沈阳 110142