Citation: Kaihui Huang, Dejun Chen, Xin Zhang, Rongchen Shen, Peng Zhang, Difa Xu, Xin Li. Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2024, 40(12): 240702. doi: 10.3866/PKU.WHXB202407020 shu

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production

Kaihui Huang ^1,2 ,
Dejun Chen ² ,
Xin Zhang ^3,, ,
Rongchen Shen ^1,2,, ,
Peng Zhang ^4,, ,
Difa Xu ⁵ ,
Xin Li ^1,2,,

1.
Institute of Biomass Engineering, Key Laboratory of Energy Plants Resource and Utilization, Ministry of Agriculture and Rural Affairs, South China Agricultural University, Guangzhou 510642, China;
2.
Key Laboratory for Biobased Materials and Energy of Ministry of Education, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China;
3.
Hubei Key Lab Low Dimens Optoelect Mat & Devices, Hubei University of Arts and Science, Xiangyang 441053, Hubei Province, China;
4.
State Centre for International Cooperation on Designer Low-Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
5.
Hunan Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha 410022, China

Corresponding author: Xin Zhang, Rongchen Shen, Peng Zhang, Xin Li,
Received Date: 21 July 2024
Revised Date: 18 September 2024
Accepted Date: 19 September 2024

Fund Project: The project was supported from the National Natural Science Foundation of China (22378148, 21975084, 2230082074) and Natural Science Foundation of Guangdong Province (2024A1515012433).

The development of efficient photocatalysts for hydrogen production is crucial in sustainable energy research. In this study, we designed and prepared a Covalent Triazine Framework (CTF)-Cu₂O@NC composite featuring an S-scheme heterojunction structure aimed at enhancing the photocatalytic hydrogen production. The light absorption capacity, electron-hole separation efficiency and H₂-evolution activity of the composite were significantly enhanced due to the synergistic effects of the nitrogen-doped carbon (NC) layer and the S-scheme heterojunction. Structural and photoelectrochemical characterization of the system reveal that the S-scheme heterojunctions not only enhance the separation efficiency of photogenerated carriers but also maintain the strong redox capabilities to further promote the photocatalytic reactions. Moreover, the NC layer could simultaneously reduce the photocorrosion of Cu₂O and promote the electron transfer. Experimental results demonstrate that the CTF-7% Cu₂O@NC composite shows outstanding hydrogen-production performance under visible light, achieving 15645 μmol∙g^-1∙h^-1, significantly surpassing the photocatalytic activity of pure CTF (2673 μmol∙g^-1∙h^-1). This study introduces a novel approach to the development of efficient and innovative photocatalytic materials, strongly supporting the advancement of sustainable hydrogen energy.
- Photocatalytic hydrogen evolution,
- Cu₂O@NC,
- Covalent triazine frameworks (CTF),
- S-scheme heterojunction,
- Nitrogen doped carbon
1. [1]
  (1) Hisatomi, T.; Domen, K. Nat. Catal. 2019, 2, 387. doi:10.1038/s41929-019-0242-6
2. [2]
  (2)
  Zhang, L. J.; Wu, Y. L.; Li, J. K.; Jin, Z. L.; Li, Y. J.; Tsubaki, N. Mater. Today Phys. 2022, 27, 100767. doi:10.1016/j.mtphys.2022.100767
3. [3]
  (3) Liu, H.; Zhang, Y. Y.; Li, D. J.; Li, Y. J.; Jin, Z. L. ACS Appl. Energy Mater. 2022, 5, 2474. doi:10.1021/acsaem.1c03967
4. [4]
  (4) Meng, C.; Huang, M.; Li, Y. Chem. Res. Chin. Univ. 2023, 39, 697. doi:10.1007/s40242-023-3124-z
5. [5]
  (5) Wu, X.; Tan, L.; Chen, G.; Kang, J.; Wang, G. Sci. China. Mater. 2024, 67, 444. doi:10.1007/s40843-023-2755-2
6. [6]
  (6) Qian, Y.; Zhang, F.; Kang, D. J.; Pang, H. Energy Environ. Mater. 2023, 6, e12414. doi:10.1002/eem2.12414
7. [7]
  (7) Wang, P.; Yang, M.; Tang, S. P.; Li, Y. J.; Lin, X.; Zhang, H. Y.; Zhu, Z.; Chen, F. T. J. Alloy. Compd. 2022, 918, 165607. doi:10.1016/j.jallcom.2022.165607
8. [8]
  (8) Wang, X. P., Li, Y. J., Li, T.; Jin, Z. L. Adv. Sustain. Syst. 2023, 7, 2200139. doi:10.1002/adsu.202200139
9. [9]
  (9) Fan, K.; Sun, Y.; Xu, P.; Guo, J.; Li, Z.; Shao, M. Chem. Res. Chin. Univ. 2022, 38, 1185. doi:10.1007/s40242-022-2254-z
10. [10]
  (10) Cai, M.; Wei, Y.; Li, Y.; Li, X.; Wang, S.; Shao, G.; Zhang, P. EcoEnergy 2023, 1, 248. doi:10.1002/ece2.16
11. [11]
  (11) Shen, R.; Liang, G.; Hao, L.; Zhang, P.; Li, X. Adv. Mater. 2023, 35, 2303649. doi:10.1002/adma.202303649
12. [12]
  (12) Zheng, C. Y., Jiang, G. P., Li, Y. J.; Jin, Z. L. J. Alloy. Compd. 2022, 904, 164041. doi:10.1016/j.jallcom.2022.164041.
13. [13]
  (13) Wang, J.; Wang, Z.; Dai, K.; Zhang, J. J. Mater. Sci. Technol. 2023, 165, 187. doi:10.1016/j.jmst.2023.03.067
14. [14]
  (14) Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi:10.1016/j.chempr.2020.06.010
15. [15]
  (15) Wu, X.; Chen, G.; Wang, J.; Li, J.; Wang, G. Acta Phys. -Chim. Sin. 2023, 39, 2212016. doi:10.3866/pku.Whxb202212016
16. [16]
  (16) Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202218688. doi:10.1002/anie.202218688
17. [17]
  (17) Cai, J.; Liu, B.; Zhang, S.; Wang, L.; Wu, Z.; Zhang, J.; Cheng, B. J. Mater. Sci. Technol. 2024, 197, 183. doi:10.1016/j.jmst.2024.02.012
18. [18]
  (18) Fan, Z. B.; Guo, X.; Liu, F. J.; Li, Y. J.; Zhang, L. J.; Jin, Z. L. Appl. Mater. Today 2022, 29, 101637. doi:10.1016/j.apmt.2022.101637.
19. [19]
  (19) Hua, J.; Wang, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi:10.1016/j.jmst.2023.03.003
20. [20]
  (20) He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi:10.1016/S1872-2067(23)64420-1
21. [21]
  (21) Zhu, Z.; Zhang, H. Y.; Teng, Y.; Lin, X.; Li, M.; Li, Y. J. Surf. Interfaces 2023, 41, 103160. doi:10.1016/j.surfin.2023.103160
22. [22]
  (22) Dong, Y.; Ji, P.; Xu, X.; Li, R.; Wang, Y.; Homewood, K. P.; Xia, X.; Gao, Y.; Chen, X. Energy Environ. Mater. 2024, 7, e12643. doi:10.1002/eem2.12643
23. [23]
  (23) Liu, M.; Huang, Q.; Wang, S.; Li, Z.; Li, B.; Jin, S.; Tan, B. Angew. Chem. Int. Ed. 2018, 57, 11968. doi:10.1002/anie.201806664
24. [24]
  (24) He, J.; Wang, X. D.; Jin, S. B.; Liu, Z. Q.; Zhu, M. S. Chin. J. Catal. 2022, 43, 1306. doi:10.1016/s1872-2067(21)63936-0.
25. [25]
  (25) Zhang, G.; Li, X.; Chen, D.; Li, N.; Xu, Q.; Li, H.; Lu, J. Adv. Funct. Mater. 2023, 33, 2308553. doi:10.1002/adfm.202308553.
26. [26]
  (26) Ding, H.; Shen, R.; Huang, K.; Huang, C.; Liang, G.; Zhang, P.; Li, X. Adv. Funct. Mater. 2024, 34, 2400065. doi:10.1002/adfm.202400065.
27. [27]
  (27) Gao, Z.; Jian, Y.; Yang, S.; Xie, Q. J.; McFadzean, C. J. R.; Wei, B. S.; Tang, J. T.; Yuan, J. Y.; Pan, C. Y.; Yu, G. P. Angew. Chem. Int. Ed. 2023, 135, e202304173. doi:10.1002/anie.202304173.
28. [28]
  (28) Liu, R.; Zhao, L.; Liu, B.; Yu, J.; Wang, Y.; Yu, W.; Xin, D.; Fang, C.; Jiang, X.; Hu, R.; et al. Chin. J. Struc. Chem. 2024, 43, 100332. doi:10.1016/j.cjsc.2024.100332
29. [29]
  (29) Zhang, Z. Q.; Wang, H. B.; Li, Y. X.; Xie, M. G.; Li, C. G.; Lu, H. Y.; Peng, Y.; Shi, Z. Chem. Res. Chin. Univ. 2022, 38, 750. doi:10.1007/s40242-022-1504-4
30. [30]
  (30) Huang, K.; Feng, B.; Wen, X.; Hao, L.; Xu, D.; Liang, G.; Shen, R.; Li, X. Chin. J. Struc. Chem. 2023, 42, 100204. doi:10.1016/j.cjsc.2023.100204
31. [31]
  (31) Wan, L.; Zhou, Q.; Wang, X.; Wood, T. E.; Wang, L.; Duchesne, P. N.; Guo, J.; Yan, X.; Xia, M.; Li, Y. F.; et al. Nat. Catal. 2019, 2, 889. doi:10.1038/s41929-019-0338-z
32. [32]
  (32) Han, X.; He, X.; Sun, L.; Han, X.; Zhan, W.; Xu, J.; Wang, X.; Chen, J. ACS Catal. 2018, 8, 3348. doi:10.1021/acscatal.7b04219
33. [33]
  (33) Liu, L.; Yang, W.; Li, Q.; Gao, S.; Shang, J. K. ACS Appl. Mater. Inter. 2014, 6, 5629. doi:10.1021/am500131b
34. [34]
  (34) Wang, K.; Yang, L.; Wang, X.; Guo, L.; Cheng, G.; Zhang, C.; Jin, S.; Tan, B.; Cooper, A. Angew. Chem. Int. Ed. 2017, 56, 14149. doi:10.1002/anie.201708548
35. [35]
  (35) Hao, L.; Ning, J.; Luo, B.; Wang, B.; Zhang, Y.; Tang, Z.; Yang, J.; Thomas, A.; Zhi, L. J. Am. Chem. Soc. 2015, 137, 219. doi:10.1021/ja508693y
36. [36]
  (36) Wang, J.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Struc. Chem. 2023, 42, 100202. doi:10.1016/j.cjsc.2023.100202
37. [37]
  (37) Shen, R.; Li, N.; Qin, C.; Li, X.; Zhang, P.; Li, X.; Tang, J. Adv. Funct. Mater. 2023, 33, 2301463. doi:10.1002/adfm.202301463
38. [38]
  (38) Zhang, M.; Chen, Z.; Wang, Y.; Zhang, J.; Zheng, X.; Rao, D.; Han, X.; Zhong, C.; Hu, W.; Deng, Y. Appl. Catal. B-Environ. 2019, 246, 202. doi:10.1016/j.apcatb.2019.01.042
39. [39]
  (39) Hao, L.; Shen, R.; Huang, C.; Liang, Z.; Li, N.; Zhang, P.; Li, X.; Qin, C.; Li, X. Appl. Catal. B-Environ. 2023, 330, 122581. doi:10.1016/j.apcatb.2023.122581
40. [40]
  (40) Waqas, M. Chem. Res. Chin. Univ. 2024, 40, 529. doi:10.1007/s40242-024-4055-z
41. [41]
  (41) Shen, R.; He, K.; Zhang, A.; Li, N.; Ng, Y. H.; Zhang, P.; Hu, J.; Li, X. Appl. Catal. B-Environ. 2021, 291, 120104. doi:10.1016/j.apcatb.2021.120104
42. [42]
  (42) Guo, L.; Gao, J.; Li, M.; Xie, Y.; Chen, H.; Wang, S.; Li, Z.; Wang, X.; Zhou, W. EcoEnergy 2023, 1, 437. doi:10.1002/ece2.20
43. [43]
  (43) Xu, N.; Liu, Y.; Yang, W.; Tang, J.; Cai, B.; Li, Q.; Sun, J.; Wang, K.; Xu, B.; Zhang, Q. ACS Appl. Energy Mater. 2020, 3, 11939. doi:10.1021/acsaem.0c02102
44. [44]
  (44) Sun, T.; Liang, Y.; Xu, Y. Angew. Chem. Int. Ed. 2022, 61, e202116875. doi:10.1002/anie.202116875
45. [45]
  (45) Gao, S.; Zhang, P.; Huang, G.; Chen, Q.; Bi, J.; Wu, L. ChemSusChem 2021, 14, 3850. doi:10.1002/cssc.202101308
46. [46]
  (46) Xu, Z.; Cui, Y.; Guo, B.; Li, H.-Y.; Li, H.-X. ChemCatChem 2021, 13, 958. doi:10.1002/cctc.202001631
47. [47]
  (47) Feng, T.; Wang, J.; Gao, S.; Feng, C.; Shang, N.; Wang, C.; Li, X. Appl. Surf. Sci. 2019, 469, 431. doi:10.1016/j.apsusc.2018.11.036
48. [48]
  (48) Yu, J.; Sun, X.; Xu, X.; Zhang, C.; He, X. Appl. Catal. B-Environ. 2019, 257, 117935. doi:10.1016/j.apcatb.2019.117935
49. [49]
  (49) Guo, L.; Niu, Y.; Xu, H.; Li, Q.; Razzaque, S.; Huang, Q.; Jin, S.; Tan, B. J. Mater. Chem. A 2018, 6, 19775. doi:10.1039/C8TA07391K
50. [50]
  (50) Chen, C.; Xiong, Y.; Zhong, X.; Lan, P.; Wei, Z.; Pan, H.; Su, P.; Song, Y.; Chen, Y. F.; Nafady, A.; et al. Angew. Chem. Int. Ed. 2022, 61, e202114071. doi:10.1002/anie.202114071
51. [51]
  (51) Kuecken, S.; Acharjya, A.; Zhi, L.; Schwarze, M.; Schomäcker, R.; Thomas, A. Chem. Commun. 2017, 53, 5854. doi:10.1039/C7CC01827D
52. [52]
  (52) Liu, C.; Wang, Y. C.; Yang, Q.; Li, X. Y.; Yi, F.; Liu, K. W.; Cao, H. M.; Wang, C. J.; Yan, H. J. Chem.-A Eur. J. 2021, 27, 13059. doi:10.1002/chem.202101956
53. [53]
  (53) Lan, Z.; Chi, X.; Wu, M.; Zhang, X.; Chen, X.; Zhang, G.; Wang, X. Small 2022, 18, 2200129. doi:10.1002/smll.202200129
54. [54]
  (54) Huang, W.; He, Q.; Hu, Y.; Li, Y. Angew. Chem. Int. Ed. 2019, 131, 8768. doi:10.1002/ange.201900046
55. [55]
  (55) Jiang, Q.; Sun, L.; Bi, J.; Liang, S.; Li, L.; Yu, Y.; Wu, L. ChemSusChem 2018, 11, 1108. doi:10.1002/cssc.201702220
56. [56]
  (56) Xu, N.; Cai, B.; Li, Q.; Liu, Y.; Tang, J.; Wang, K.; Xu, B.; Fan, Y. J. Alloy. Compd. 2021, 871, 159565. doi:10.1016/j.jallcom.2021.159565
57. [57]
  (57) Liu, M.; Yang, K.; Li, Z.; Fan, E.; Fu, H.; Zhang, L.; Zhang, Y.; Zheng, Z. Chem. Commun. 2022, 58, 92. doi:10.1039/d1cc05619k
58. [58]
  (58) Liu, M.; Wang, X.; Liu, J.; Wang, K.; Jin, S.; Tan, B. ACS Appl. Mater. Inter. 2020, 12, 12774. doi:10.1021/acsami.9b21903
59. [59]
  (59) Zhang, S.; Cheng, G.; Guo, L.; Wang, N.; Tan, B.; Jin, S. Angew. Chem. Int. Edit. 2020, 59, 6007. doi:10.1002/anie.201914424
60. [60]
  (60) Meier, C. B.; Clowes, R.; Berardo, E.; Jelfs, K. E.; Zwijnenburg, M. A.; Sprick, R. S.; Cooper, A. I. Chem. Mater. 2019, 31, 8830. doi:10.1021/acs.chemmater.9b02825
61. [61]
  (61) Li, Y.; Tang, Y.; Li, J.; Chang, Y.; Huang, H.; Zhong, C. J. Mater. Sci. 2021, 56, 5772. doi:10.1007/s10853-020-05637-9
62. [62]
  (62) Zheng, L.; Wang, D.; Wu, S.; Jiang, X.; Zhang, J.; Xing, Q.; Zou, J.; Luo, S. J. Mater. Chem. A 2020, 8, 25425. doi:10.1039/D0TA10165F
63. [63]
  (63) Chen, Y.; Huang, G.; Gao, Y.; Chen, Q.; Bi, J. Int. J. Hydrog. Energy 2022, 47, 8739. doi:10.1016/j.ijhydene.2021.12.220
64. [64]
  (64) Liu, J.; Li, X.; Han, C.; Liu, M.; Li, X.; Sun, J.; Shao, C. Energy Environ. Mater. 2023, 6, e12404. doi:10.1002/eem2.12404
65. [65]
  (65) Fu, C.; Li, D.; Zhang, J.; Guo, W.; Yang, H.; Zhao, B.; Chen, Z.; Fu, X.; Liang, Z.; Jiang, L. Chem. Res. Chin. Univ. 2023, 39, 891. doi:10.1007/s40242-023-3182-2
66. [66]
  (66) Zhang, Z.; Xiang, K.; Wang, H.; Li, X.; Zou, J.; Liang, G.; Jiang, J. SusMat 2024, e229. doi:10.1002/sus2.229
67. [67]
  (67) Li, Y.; Li, Y.; Yang, C.; Gan, L. J. Phys. Chem. C 2023, 127, 17732. doi:10.1021/acs.jpcc.3c04031
68. [68]
  (68) Wu, Y.; Lv, H.; Wu, X. Chin. J. Struc. Chem. 2024, 100375. doi:10.1016/j.cjsc.2024.100375
69. [69]
  (69) Yu, K.; He, P.; He, N.; Li, X.; Dong, C.; Jiang, B.; Zou, Y.; Pei, X.; Li, Y.; Ma, L. Sci. China Mater. 2023, 66, 4680. doi:10.1007/s40843-023-2599-9
70. [70]
  (70) Xu, X.; Shao, C.; Zhang, J.; Wang, Z.; Dai, K. Acta Phys. -Chim. Sin. 2024, 40, 2309031. doi:10.3866/PKU.WHXB202309031
71. [71]
  (71) He, H.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K. Adv. Funct. Mater. 2024, 34, 2315426. doi:10.1002/adfm.202315426
72. [72]
  (72) Zhang, H.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2023, 49, 42. doi:10.1016/S1872-2067(23)64444-4
73. [73]
  (73) Yang, T.; Wang, J.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2024, 58, 157. doi:10.1016/S1872-2067(23)64607-8
74. [74]
  (74) Zhang, H.; Shao, C.; Wang, Z.; Zhang, J.; Dai, K. J. Mater. Sci. Technol. 2024, 195, 146. doi:10.1016/j.jmst.2023.11.081
75. [75]
  (75) Xu, Z.; Wu, Y.; Tao, R.; Jin, Z.; Fang, X. Chem. Res. Chin. Univ. 2023, 39, 928. doi:10.1007/s40242-022-2274-8
76. [76]
  (76) Song, P.; Du, J.; Ma, X.; Shi, Y.; Fang, X.; Liu, D.; Wei, S.; Liu, Z.; Cao, Y.; Lin, B.; et al. EcoEnergy 2023, 1, 197. doi:10.1002/ece2.8
77. [77]
  (77) Zhan, H.; Zhou, R.; Liu, K.; Ma, Z.; Wang, P.; Zhan, S.; Zhou, Q. Sci. China Mater. 2024, 67, 1740. doi:10.1007/s40843-024-2900-5
78. [78]
  (78) Zhang, P.; Li, Y.; Zhang, Y.; Hou, R.; Zhang, X.; Xue, C.; Wang, S.; Zhu, B.; Li, N.; Shao, G. Small Methods 2020, 4, 2000214. doi:10.1002/smtd.202000214
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15. [15]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu2O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production

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通讯作者: 陈斌, bchen63@163.com

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production