Citation: Jingzhao Cheng, Shiyu Gao, Bei Cheng, Kai Yang, Wang Wang, Shaowen Cao. Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240602. doi: 10.3866/PKU.WHXB202406026 shu

Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution

Jingzhao Cheng ^{1, 2} ,
Shiyu Gao ^{1, 2} ,
Bei Cheng ^{1, 2} ,
Kai Yang ³ ,
Wang Wang ^{1, 2,,} ,
Shaowen Cao ^{1, 2,,}

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
2.
Hubei Technology Innovation Center for Advanced Composites, Wuhan University of Technology, Wuhan 430070, China
3.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

Corresponding author: Wang Wang, doublewang@whut.edu.cn Shaowen Cao, swcao@whut.edu.cn
Received Date: 20 June 2024
Revised Date: 25 July 2024
Accepted Date: 26 July 2024
Available Online: 22 August 2024
Fund Project: the National Key R&D Program of China 2022YFE0114800the National Natural Science Foundation of China 22278324the National Natural Science Foundation of China 52073223the Jiangxi Province "Double Thousand" Talent Training Plan jxsq2023102141

Photocatalytic hydrogen generation through water splitting driven by solar energy is regarded as a highly promising strategy to tackle the challenges of the energy crisis and environmental contamination. Tuning the electronic properties and band structures of photocatalysts is critical to improving the efficiency of charge separation and the activity of hydrogen production. Herein, donor-acceptor modified polymeric carbon nitride (CN)-based copolymers are synthesized via the introduction of 4-amino-1H-imidazole-5-carbonitrile (AICN) into the molecular skeleton of CN. The incorporation of electron donor AICN units can broaden the π-conjugated system and promote the spatial charge separation in the catalysts, thus resulting in enhanced light utilization and improved intramolecular charge carrier transfer rate. As a consequence, the AICN modified CN samples exhibit an increased photocatalytic hydrogen evolution rate, and the optimal photocatalytic activity can reach 3204 μmol·h⁻¹·g⁻¹. This molecular engineering strategy provides an effective avenue to develop high-performance CN-based photocatalysts for hydrogen evolution.
- Polymeric carbon nitride,
- Donor-acceptor,
- Molecular modification,
- Charge separation,
- Hydrogen production
1. [1]
  Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g doi: 10.1039/b800489g
2. [2]
  Nishioka, S.; Osterloh, F. E.; Wang, X.; Mallouk, T. E.; Maeda, K. Nat. Rev. Methods Primers 2023, 3, 42. doi: 10.1038/s43586-023-00226-x doi: 10.1038/s43586-023-00226-x
3. [3]
  Hisatomi, T.; Kubota, J.; Domen, K. Chem. Soc. Rev. 2014, 43, 7520. doi: 10.1039/c3cs60378d doi: 10.1039/c3cs60378d
4. [4]
  Bushmeleva, A. S.; Tafeenko, V. A.; Zakharov, V. N.; Lobova, A. A.; Aslanov, L. A. Struct. Chem. 2019, 30, 425. doi: 10.1007/s11224-018-1187-0 doi: 10.1007/s11224-018-1187-0
5. [5]
  Bie, C.; Wang, L.; Yu, J. Chem 2022, 8, 1567. doi: 10.1016/j.chempr.2022.04.013 doi: 10.1016/j.chempr.2022.04.013
6. [6]
  Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0 doi: 10.1038/238037a0
7. [7]
  Zhang, J.; Le, Y.; Zhang, Y. J. Mater. Sci. Technol. 2023, 142, 121. doi: 10.1016/j.jmst.2022.11.001 doi: 10.1016/j.jmst.2022.11.001
8. [8]
  Bie, C.; Zhu, B.; Wang, L.; Yu, H.; Jiang, C.; Chen, T.; Yu, J. Angew. Chem. Int. Ed. 2022, 61, e202212045. doi: 10.1002/anie.202212045 doi: 10.1002/anie.202212045
9. [9]
  Cai, J.; Liu, B.; Zhang, S.; Wang, L.; Wu, Z.; Zhang, J.; Cheng, B. J. Mater. Sci. Technol. 2024, 197, 183. doi: 10.1016/j.jmst.2024.02.012 doi: 10.1016/j.jmst.2024.02.012
10. [10]
  Zhang, Y.; Zhang, Z. J. Mater. Sci. Technol. 2024, 171, 147. doi: 10.1016/j.jmst.2023.06.048 doi: 10.1016/j.jmst.2023.06.048
11. [11]
  Cao, S.; Zhong, B.; Bie, C.; Cheng, B.; Xu, F. Acta Phys.-Chim.Sin. 2024, 40, 2307016. doi: 10.3866/PKU.WHXB202307016 doi: 10.3866/PKU.WHXB202307016
12. [12]
  He, B.; Xiao, P.; Wan, S.; Zhang, J.; Chen, T.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202313172. doi: 10.1002/anie.202313172 doi: 10.1002/anie.202313172
13. [13]
  Yu, Z.; Guan, C.; Yue, X.; Xiang, Q. Chin. J. Catal. 2023, 50, 361. doi: 10.1016/s1872-2067(23)64448-1 doi: 10.1016/s1872-2067(23)64448-1
14. [14]
  Wang, Y.; Si, W.; Tan, H.; Xie, Z.; Wang, L.; Di, L.; Liang, J.; Hou, F. Sci. China Mater. 2023, 66, 623. doi: 10.1007/s40843-022-2202-3 doi: 10.1007/s40843-022-2202-3
15. [15]
  Zhao, B.; Zhong, W.; Chen, F.; Wang, P.; Bie, C.; Yu, H. Chin. J. Catal. 2023, 52, 127. doi: 10.1016/s1872-2067(23)64491-2 doi: 10.1016/s1872-2067(23)64491-2
16. [16]
  Guo, F.; Hu, B.; Yang, C.; Zhang, J.; Hou, Y.; Wang, X. Adv. Mater. 2021, 33, 2101466. doi: 10.1002/adma.202101466 doi: 10.1002/adma.202101466
17. [17]
  Ghashghaee, M.; Azizi, Z.; Ghambarian, M. Struct. Chem. 2020, 31, 1137. doi: 10.1007/s11224-020-01496-x doi: 10.1007/s11224-020-01496-x
18. [18]
  Jun, Y.; Hong, W.; Antonietti, M.; Thomas, A. Adv. Mater. 2009, 21, 4270. doi: 10.1002/adma.200803500 doi: 10.1002/adma.200803500
19. [19]
  Wan, S.; Xu, J.; Cao, S.; Yu, J. Interdiscip. Mater. 2022, 1, 294. doi: 10.1002/idm2.12024 doi: 10.1002/idm2.12024
20. [20]
  Zhang, R.; Zhang, A.; Cao, Y.; Wang, S.; Dong, F.; Zhou, Y. Chem. Eng. J. 2020, 401, 126028. doi: 10.1016/j.cej.2020.126028 doi: 10.1016/j.cej.2020.126028
21. [21]
  Yu, X.; Su, H.; Zou, J.; Liu, Q.; Wang, L.; Tang, H. Chin. J. Catal. 2022, 43, 421. doi: 10.1016/S1872-2067(21)63849-4 doi: 10.1016/S1872-2067(21)63849-4
22. [22]
  Li, Z.; Yang, Q.; Chen, C.; Zhang, Z.; Fang, X. Chin. J. Catal. 2019, 40, 875. doi: 10.1016/S1872-2067(19)63337-1 doi: 10.1016/S1872-2067(19)63337-1
23. [23]
  Yang, S.; Wang, Q.; Wang, Q.; Li, G.; Zhao, T.; Chen, P.; Liu, F.; Yin, S. J. Mater. Chem. A 2021, 9, 21732. doi: 10.1039/D1TA03813C doi: 10.1039/D1TA03813C
24. [24]
  Fang, Y.; Wang, X. Chem. Commun. 2018, 54, 5674. doi: 10.1039/C8CC02046A doi: 10.1039/C8CC02046A
25. [25]
  Guan, C.; Liao, Y.; Xiang, Q. Sci. China Mater. 2024, 67, 473. doi: 10.1007/s40843-023-2703-0 doi: 10.1007/s40843-023-2703-0
26. [26]
  Chen, D.; Wang, Z.; Fu, J.; Zhang, J.; Dai, K. Sci. China Mater. 2024, 67, 541. doi: 10.1007/s40843-023-2770-8 doi: 10.1007/s40843-023-2770-8
27. [27]
  Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012 doi: 10.1002/anie.201916012
28. [28]
  Zheng, Y.; Yu, Z.; Ou, H.; Asiri, A. M.; Chen, Y.; Wang, X. Adv. Funct. Mater. 2018, 28, 1705407. doi: 10.1002/adfm.201705407 doi: 10.1002/adfm.201705407
29. [29]
  Qin, Z.; Wang, M.; Li, R.; Chen, Y. Sci. China Mater. 2018, 61, 861. doi: 10.1007/s40843-017-9171-9 doi: 10.1007/s40843-017-9171-9
30. [30]
  Wu, X.; Tan, L.; Chen, G.; Kang, J.; Wang, G. Sci. China Mater. 2024, 67, 444. doi: 10.1007/s40843-023-2755-2 doi: 10.1007/s40843-023-2755-2
31. [31]
  Wu, X.; Chen, G.; Wang, J.; Li, J.; Wang, G. Acta Phys.-Chim.Sin. 2023, 39, 2212016. doi: 10.3866/PKU.WHXB202212016 doi: 10.3866/PKU.WHXB202212016
32. [32]
  Chen, Q.; Zhang, Y.; You, E.; Jiang, Q.; Chen, X.; Wang, Y.; Song, Z.; Chang, K.; Xie, Z.; Kuang, Q. Small 2022, 18, 2204924. doi: 10.1002/smll.202204924 doi: 10.1002/smll.202204924
33. [33]
  Li, Z.; Liu, W.; Chen, C.; Ma, T.; Zhang, J.; Wang, Z. Acta Phys.-Chim.Sin. 2023, 39, 2208030. doi: 10.3866/PKU.WHXB202208030 doi: 10.3866/PKU.WHXB202208030
34. [34]
  Li, K.; Wang, L.; Chen, Z.; Yang, X.; Yu, Y.; Zhang, W.; Wang, Y.; Shi, Y.; Loh, K. P.; Xu, Q. Adv. Funct. Mater. 2020, 30, 2070288. doi: 10.1002/adfm.202070288 doi: 10.1002/adfm.202070288
35. [35]
  Yang, C.; Cheng, B.; Xu, J.; Yu, J.; Cao, S. EnergyChem 2024, 6, 100116. doi: 10.1016/j.enchem.2023.100116 doi: 10.1016/j.enchem.2023.100116
36. [36]
  Luo, J.; Liu, Y.; Fan, C.; Tang, L; . Yang, S.; Liu, M.; Wang, M.; Feng, C.; Ouyang, X.; Wang, L.; et al. ACS Catal. 2021, 11, 11440. doi: 10.1021/acscatal.1c03103 doi: 10.1021/acscatal.1c03103
37. [37]
  Yan, F.; Zhang, Y.; Liu, S.; Zou, R.; Ghasemi, J. B.; Li, X. Chin. J. Catal. 2023, 51, 124. doi: 10.1016/s1872-2067(23)64475-4 doi: 10.1016/s1872-2067(23)64475-4
38. [38]
  Cheng, C.; Yu, J.; Xu, D.; Wang, L.; Liang, G.; Zhang, L.; Jaroniec, M. Nat. Commun. 2024, 15, 1313. doi: 10.1038/s41467-024-45604-5 doi: 10.1038/s41467-024-45604-5
39. [39]
  Ou, H.; Chen, X.; Lin, L.; Fang, Y.; Wang, X. Angew. Chem. Int. Ed. 2018, 57, 8729. doi: 10.1002/anie.201803863 doi: 10.1002/anie.201803863
40. [40]
  Xie, Z.; Yang, X.; Zhang, P.; Ke, X.; Yuan, X.; Zhai, L.; Wang, W.; Qin, N.; Cui, C.; Qu, L.; Chen, X. Chin. J. Catal. 2023, 47, 171. doi: 10.1016/S1872-2067(23)64397-9 doi: 10.1016/S1872-2067(23)64397-9
41. [41]
  Yang, C.; Wan, S.; Zhu, B.; Yu, J.; Cao, S. Angew. Chem. Int. Ed. 2022, 61, e202208438. doi: 10.1002/anie.202208438 doi: 10.1002/anie.202208438
42. [42]
  Chen, Y.; Zhang, J.; Zhang, M.; Wang, X. Chem. Sci. 2013, 4, 3244. doi: 10.1039/C3SC51203G doi: 10.1039/C3SC51203G
43. [43]
  Kim, D. E.; Park, J. W.; Seo, S. Y.; Baeg, K. Jun. ACS Appl. Mater. Interfaces 2022, 14, 13560. doi: 10.1021/acsami.1c21864 doi: 10.1021/acsami.1c21864
44. [44]
  Zhang, J.; Zhang, M.; Lin, S.; Fu, X.; Wang, X. J. Catal. 2014, 310, 24. doi: 10.1016/j.jcat.2013.01.008 doi: 10.1016/j.jcat.2013.01.008
45. [45]
  Liu, Q.; Wei, L.; Xi, Q.; Lei, Y.; Wang, F. Chem. Eng. J. 2020, 383, 123792. doi: 10.1016/j.cej.2019.123792 doi: 10.1016/j.cej.2019.123792
46. [46]
  Zhang, G.; Xu, Y.; Mi, H.; Zhang, P.; Li, H.; Lu, Y. ChemSusChem 2021, 14, 4516. doi: 10.1002/cssc.202101431 doi: 10.1002/cssc.202101431
47. [47]
  Fang, Z.; Li, D.; Chen, R.; Huang, Y.; Luo. B.; Shi, W. ACS Appl. Mater. Interfaces 2019, 11, 22255. doi: 10.1021/acsami.9b03745 doi: 10.1021/acsami.9b03745
48. [48]
  Haiber, D. M.; Levin, B. D. A.; Treacy, M. M. J.; Crozier, P. A. Chem. Mater. 2020, 33, 195. doi: 10.1021/acs.chemmater.0c03343 doi: 10.1021/acs.chemmater.0c03343
49. [49]
  Song, H.; Liu, X.; Wang, Y.; Chen, L.; Zhang, J.; Zhao, C.; He, F.; Dong, P.; Li, B.; Wang, S.; et al. Colloid Interf. Sci. 2022, 607, 1603. doi: 10.1016/j.jcis.2021.09.088 doi: 10.1016/j.jcis.2021.09.088
50. [50]
  Wang, C.; Hou, Y.; Cheng, J.; Lin, M.; Wang, X. Appl. Catal. B 2021, 294, 120259. doi: 10.1016/j.apcatb.2021.120259 doi: 10.1016/j.apcatb.2021.120259
51. [51]
  Ho, W.; Zhang, Z.; Lin, W.; Huang, S.; Zhang, X.; Wang, X.; Huang, Y. ACS Appl. Mater. Interfaces 2015, 7, 5497. doi: 10.1021/am509213x doi: 10.1021/am509213x
52. [52]
  Zhou, T.; Li, T.; Hou, J.; Wang, Y.; Hu, B.; Sun, D.; Wu, Y.; Jiang, W.; Che, G.; Liu, C. Chem. Eng. J. 2022, 445, 136643. doi: 10.1016/j.cej.2022.136643 doi: 10.1016/j.cej.2022.136643
53. [53]
  Katsumata, H.; Sakakibara, K.; Tateishi, I.; Furukawa, M.; Kaneco, S. Catal. Today 2020, 352, 47. doi: 10.1016/j.cattod.2019.12.007 doi: 10.1016/j.cattod.2019.12.007
54. [54]
  Gao, S.; Wan, S.; Yu, J.; Cao, S. Adv. Sustain. Syst. 2023, 7, 2200130. doi: 10.1002/adsu.202200130 doi: 10.1002/adsu.202200130
55. [55]
  Yang, F.; Li, C.; Xu, C.; Kan, J.; Tian, B.; Qu, H.; Guo, Y.; Geng, Y.; Dong, Y. Chem. Commun. 2022, 58, 1530. doi: 10.1039/D1CC06184D doi: 10.1039/D1CC06184D
56. [56]
  Wang, X.; Chen, G.; Wang, H.; Wu, Y.; Wei, X.; Wen, J.; Hu, L.; Gu, W.; Zhu, C. J. Catal. 2021, 399, 192. doi: 10.1016/j.jcat.2021.05.007 doi: 10.1016/j.jcat.2021.05.007
57. [57]
  Yang, C.; Li, X.; Li, M.; Liang, G.; Jin, Z. Chin. J. Catal. 2024, 56, 88. doi: 10.1016/S1872-2067(23)64563-2 doi: 10.1016/S1872-2067(23)64563-2
58. [58]
  Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys.-Chim.Sin. 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009 doi: 10.3866/PKU.WHXB202212009
59. [59]
  Yang, Q.; Chen, C.; Zhang, Q.; Zhang, Z.; Fang, X. Carbon 2020, 164, 337. doi: 10.1016/j.carbon.2020.04.015 doi: 10.1016/j.carbon.2020.04.015
60. [60]
  Cheng, J.; Wan, S.; Cao, S. Angew. Chem. Int. Ed. 2023, 62, e202310476. doi: 10.1002/anie.202310476 doi: 10.1002/anie.202310476
1. [1]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
2. [2]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
3. [3]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
4. [4]
  Yun Chen , Daijie Deng , Li Xu , Xingwang Zhu , Henan Li , Chengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144
5. [5]
  Fan Fan , Hao Xiu , Yuting Wang , Yongpeng Cui , Yajun Wang . Construction of NH₂-MIL-125/Na-doped g-C₃N₄ composite S-scheme heterojunction and its performance in photocatalytic hydrogen peroxide production. Acta Physico-Chimica Sinica, 2026, 42(2): 100143-0. doi: 10.1016/j.actphy.2025.100143
6. [6]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . Built-in Electric Fields Enhancing Photocarrier Separation and H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-0. doi: 10.3866/PKU.WHXB202311001
7. [7]
  Xiaoyu Wang , Yifan Li , Ruibo Liu , Li An , Dan Qu , Yichang Liu , Zaicheng Sun . Graphitic Carbon Nitride Catalyzed Photochemical Minisci Reaction: A Comprehensive Experimental Design Derived from Scientific Research. University Chemistry, 2026, 41(4): 363-371. doi: 10.12461/PKU.DXHX202502065
8. [8]
  Yuan Xue , Yanjun Zhang , Jun Du , Zushun Xu , Guangfu Liao , Qing Li . Introducing dual-functional site on carbon nitride: steering carrier migration and O₂ activation for boosted H₂O₂ photosynthesis. Acta Physico-Chimica Sinica, 2026, 42(9): 100311-0. doi: 10.1016/j.actphy.2026.100311
9. [9]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
10. [10]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
11. [11]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
12. [12]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
13. [13]
  Kaiqiang Xu , Jia Yu , Wei Xia , Jianjun Zhang , Sheng Han . Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity. Acta Physico-Chimica Sinica, 2026, 42(7): 100211-. doi: 10.1016/j.actphy.2025.100211
14. [14]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
15. [15]
  Chengyan Ge , Jiawei Hu , Xingyu Liu , Yuxi Song , Chao Liu , Zhigang Zou . Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism. Acta Physico-Chimica Sinica, 2026, 42(1): 100154-0. doi: 10.1016/j.actphy.2025.100154
16. [16]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
17. [17]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
18. [18]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-0. doi: 10.3866/PKU.WHXB202309047
19. [19]
  Yunhan Gao , Xing Sun , Mengxia Ji , Xingchang Qiu , Tiange Wei , Qing Xu , Sheng Yin , Jiexiang Xia , Huaming Li . Hierarchical ZIF-derived carbon/Bi₁₂O₁₇Cl₂ heterostructures synergistically enhance electron dynamics and optical properties to boost CO₂ photoreduction in pure water. Acta Physico-Chimica Sinica, 2026, 42(10): 100264-0. doi: 10.1016/j.actphy.2026.100264
20. [20]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1029)
HTML views(184)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142