Citation: Jianyin He, Liuyun Chen, Xinling Xie, Zuzeng Qin, Hongbing Ji, Tongming Su. Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240403. doi: 10.3866/PKU.WHXB202404030 shu

Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution

Jianyin He ¹ ,
Liuyun Chen ¹ ,
Xinling Xie ¹ ,
Zuzeng Qin ¹ ,
Hongbing Ji ^{1, 2} ,
Tongming Su ^1,,

1.
Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
2.
Institute of Green Petroleum Processing and Light Hydrocarbon Conversion, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Tongming Su, sutm@gxu.edu.cn
Received Date: 19 April 2024
Revised Date: 20 May 2024
Accepted Date: 21 May 2024
Available Online: 28 May 2024
Fund Project: the National Natural Science Foundation of China 22208065Guangxi Natural Science Foundation 2022GXNSFBA035483Opening Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology 2023K012

Photocatalytic hydrogen evolution by heterojunction photocatalysts is considered an effective way to address environmental and energy crises. In this work, a novel ZnCoP/CdLa₂S₄ Schottky heterojunction was prepared via a physical mixing method assisted by water bath heating and used to enhance the efficiency of photocatalytic hydrogen production. Owing to the higher work function and metallic conductivity of ZnCoP, the photoinduced electrons can transfer from CdLa₂S₄ to ZnCoP through the ZnCoP/CdLa₂S₄ interface, which suppresses the recombination of photoinduced electrons and holes. Moreover, the Schottky heterojunction formed at the interface between ZnCoP and CdLa₂S₄ inhibits electron backflow from ZnCoP to CdLa₂S₄, which further promotes the separation of electron-hole pairs. Meanwhile, the ZnCoP/CdLa₂S₄ heterojunction exhibited enhanced visible light absorption compared to CdLa₂S₄. In addition, ZnCoP acts as an electron acceptor and hydrogen evolution active site. The synergistic effect of the tight ZnCoP/CdLa₂S₄ interface, the higher work function and metallic conductivity of ZnCoP, and the formation of Schottky junctions significantly enhance the photocatalytic hydrogen production evolution performance of CdLa₂S₄. When the amount of ZnCoP was 30 wt% (wt%, mass fraction), the 30ZCP/CLS composite showed the highest photocatalytic performance, and the hydrogen production rate reached 10.26 mmol·g^-1·h^-1 under visible light irradiation and with Na₂S and Na₂SO₃ as sacrificial agents, which was 7.7 times that of CdLa₂S₄. Combined with the activity data and characterization results, a potential mechanism for photocatalytic hydrogen production over ZnCoP/CdLa₂S₄ Schottky heterojunctions was proposed.
- CdLa₂S₄,
- ZnCoP,
- Schottky heterojunction,
- Photocatalytic,
- Charge transfer
1. [1]
  Liao, M.; Wang, T.; Zuo, T.; Meng, L.; Yang, M.; Chen, Y. X.; Hu, T.; Xie, Y. Inorg. Chem. 2021, 60, 13136. doi: 10.1021/acs.inorgchem.1c01540 doi: 10.1021/acs.inorgchem.1c01540
2. [2]
  Trang, T. N. Q.; Phan, T. B.; Nam, N. D.; Thu, V. T. H. ACS Appl. Mater. Interfaces 2020, 12, 12195. doi: 10.1021/acsami.9b15578 doi: 10.1021/acsami.9b15578
3. [3]
  Qin, Z.; Wu, J.; Li, B.; Su, T.; Ji, H. Acta Phys. -Chim. Sin. 2021, 37, 2005027. doi: 10.3866/PKU.WHXB202005027 doi: 10.3866/PKU.WHXB202005027
4. [4]
  Almazroai, L.; El-Mekawy, R. E.; Musa, R.; Ali, L. RSC Adv. 2022, 12, 15992. doi: 10.1039/d2ra00788f doi: 10.1039/d2ra00788f
5. [5]
  Anasori, B.; Lukatskaya, M. R.; Gogotsi, Y. Nat. Rev. Mater. 2017, 2, 16098. doi: 10.1038/natrevmats.2016.98 doi: 10.1038/natrevmats.2016.98
6. [6]
  Bang, J.; Das, S.; Yu, E.-J.; Kim, K.; Lim, H.; Kim, S.; Hong, J. W. Nano Lett. 2020, 20, 6263. doi: 10.1021/acs.nanolett.0c00983 doi: 10.1021/acs.nanolett.0c00983
7. [7]
  Huang, K.; Li, C.; Li, H.; Ren, G.; Wang, L.; Wang, W.; Meng, X. ACS Appl. Nano Mater. 2020, 3, 9581. doi: 10.1021/acsanm.0c02481 doi: 10.1021/acsanm.0c02481
8. [8]
  Yan, J.; Zhang, X.; Zheng, W.; Lee, L. Y. S. ACS Appl. Mater. Interfaces 2021, 13, 24723. doi: 10.1021/acsami.1c03240 doi: 10.1021/acsami.1c03240
9. [9]
  Yan, B.; Li, J.; Lin, Z.; Du, C.; Yang, G. ACS Appl. Nano Mater. 2019, 2, 6783. doi: 10.1021/acsanm.9b01773 doi: 10.1021/acsanm.9b01773
10. [10]
  Zhang, Q.; Zhang, J.; Wang, X.; Li, L.; Li, Y.-F.; Dai, W.-L. ACS Catal. 2021, 11, 6276. doi: 10.1021/acscatal.0c05520 doi: 10.1021/acscatal.0c05520
11. [11]
  Fan, H.-T.; Wu, Z.; Liu, K.-C.; Liu, W.-S. Chem. Eng. J. 2022, 433, 134474. doi: 10.1016/j.cej.2021.134474 doi: 10.1016/j.cej.2021.134474
12. [12]
  Sun, Y.; Li, Y.; He, J.; Chen, L.; Ji, H.; Qin, Z.; Su, T. Chin. J. Struct. Chem. 2023, 42, 100145. doi: 10.1016/j.cjsc.2023.100145 doi: 10.1016/j.cjsc.2023.100145
13. [13]
  Su, T.; Hood, Z. D.; Naguib, M.; Bai, L.; Luo, S.; Rouleau, C. M.; Ivanov, I. N.; Ji, H.; Qin, Z.; Wu, Z. Nanoscale 2019, 11, 8138. doi: 10.1039/c9nr00168a doi: 10.1039/c9nr00168a
14. [14]
  Du, S.; Chen, L.; Men, C.; Ji, H.; Su, T.; Qin, Z. J. Alloys Compd. 2023, 955, 170265. doi: 10.1016/j.jallcom.2023.170265 doi: 10.1016/j.jallcom.2023.170265
15. [15]
  Kim, H.; Yoon, U. H.; Ryu, T. I.; Jeong, H. J.; il Kim, S.; Park, J.; Kye, Y. S.; Hwang, S.-R.; Kim, D.; Cho, Y.; et al. New J. Chem. 2022, 8653. doi: 10.1039/d2nj00850e doi: 10.1039/d2nj00850e
16. [16]
  Xiao, L.; Li, X.; Zhang, J.; He, Z. ACS Appl. Nano Mater. 2021, 4, 12779. doi: 10.1021/acsanm.1c03497 doi: 10.1021/acsanm.1c03497
17. [17]
  Zhao, M.-Q.; Xie, X.; Ren, C. E.; Makaryan, T.; Anasori, B.; Wang, G.; Gogotsi, Y. Adv. Mater. 2017, 29, 1702410. doi: 10.1002/adma.201702410 doi: 10.1002/adma.201702410
18. [18]
  Bie, C.; Wang, L.; Yu, J. Chem 2022, 8, 1567. doi: 10.1016/j.chempr.2022.04.013 doi: 10.1016/j.chempr.2022.04.013
19. [19]
  Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0 doi: 10.1038/238037a0
20. [20]
  Liu, X.; Chen, X.; Wang, S.; Yan, L.; Yan, J.; Guo, H.; Yang, F.; Lin, J. Int. J. Hydrog. Energy 2022, 47, 2327. doi: 10.1016/j.ijhydene.2021.10.227 doi: 10.1016/j.ijhydene.2021.10.227
21. [21]
  Zhang, S.; Zhang, Z.; Si, Y.; Li, B.; Deng, F.; Yang, L.; Liu, X.; Dai, W.; Luo, S. ACS Nano 2021, 15, 15238. doi: 10.1021/acsnano.1c05834 doi: 10.1021/acsnano.1c05834
22. [22]
  Cao, A.; Zhang, L.; Wang, Y.; Zhao, H.; Deng, H.; Liu, X.; Lin, Z.; Su, X.; Yue, F. ACS Sustain. Chem. Eng. 2018, 7, 2492. doi: 10.1021/acssuschemeng.8b05396 doi: 10.1021/acssuschemeng.8b05396
23. [23]
  Chen, Q.; Li, J.; Cheng, L.; Liu, H. Chem. Eng. J. 2020, 379, 122389. doi: 10.1016/j.cej.2019.122389 doi: 10.1016/j.cej.2019.122389
24. [24]
  Zhao, J.; Liu, F.; Wang, W.; Wang, Y.; Wen, N.; Zhang, Z.; Dai, W.; Yuan, R.; Ding, Z.; Long, J. ACS Appl. Nano Mater. 2023, 6, 8927. doi: 10.1021/acsanm.3c01443 doi: 10.1021/acsanm.3c01443
25. [25]
  Hou, J.; Yang, C.; Wang, Z.; Jiao, S.; Zhu, H. RSC Adv. 2012, 2, 10330. doi: 10.1039/c2ra21641h doi: 10.1039/c2ra21641h
26. [26]
  Reshak, A. H. Phys. Chem. Chem. Phys. 2018, 20, 8848. doi: 10.1039/c8cp00373d doi: 10.1039/c8cp00373d
27. [27]
  Guru, S.; Kumar, S.; Bellamkonda, S.; Gangavarapu, R. R. Int. J. Hydrog. Energy 2021, 46, 16414. doi: 10.1016/j.ijhydene.2020.08.102 doi: 10.1016/j.ijhydene.2020.08.102
28. [28]
  Wang, C.; Zhang, W.; Fan, J.; Sun, W.; Liu, E. Ceram. Int. 2021, 47, 30194. doi: 10.1016/j.ceramint.2021.07.199 doi: 10.1016/j.ceramint.2021.07.199
29. [29]
  He, Z.; Tang, Q.; Liu, X.; Yan, X.; Li, K.; Yue, D. Energy Fuels 2021, 35, 15005. doi: 10.1021/acs.energyfuels.1c01482 doi: 10.1021/acs.energyfuels.1c01482
30. [30]
  Chu, J.; Sun, Y.; Han, X.; Zhang, B.; Du, Y.; Song, B.; Xu, P. ACS Appl. Mater. Interfaces 2019, 11, 18475. doi: 10.1021/acsami.9b04787 doi: 10.1021/acsami.9b04787
31. [31]
  Zhang, Y.; Gao, M.; Chen, S.; Wang, H.; Huo, P. Acta Phys. -Chim. Sin. 2023, 39, 2211051. doi: 10.3866/PKU.WHXB202211051 doi: 10.3866/PKU.WHXB202211051
32. [32]
  He, B.; Xiao, P.; Wan, S.; Zhang, J.; Chen, T.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, 202313172. doi: 10.1002/anie.202313172 doi: 10.1002/anie.202313172
33. [33]
  Dai, M.; Yu, H.; Chen, W.; Qu, K.-A.; Zhai, D.; Liu, C.; Zhao, S.; Wang, S.; He, Z. Chem. Eng. J. 2023, 470, 144240. doi: 10.1016/j.cej.2023.144240 doi: 10.1016/j.cej.2023.144240
34. [34]
  Liu, H.; Xu, Z.; Zhang, Z.; Ao, D. Appl. Catal. B-Environ. 2016, 192, 234. doi: 10.1016/j.apcatb.2016.03.074 doi: 10.1016/j.apcatb.2016.03.074
35. [35]
  Fan, Y.; Yu, S.; Wang, Y.; Xie, Y.; Qiu, X. Sep. Purif. Technol. 2024, 335, 126243. doi: 10.1016/j.seppur.2023.126243 doi: 10.1016/j.seppur.2023.126243
36. [36]
  Zhang, J.; Le, Y.; Zhang, Y. J. Mater. Sci. Technol. 2023, 142, 121. doi: 10.1016/j.jmst.2022.11.001 doi: 10.1016/j.jmst.2022.11.001
37. [37]
  Zeng, Q.; Zheng, L.; Wang, L.; Liu, Y.; Yu, Q.; Fujita, T.; Zeng, D. J. Alloy. Compd. 2023, 942, 169006. doi: 10.1016/j.jallcom.2023.169006 doi: 10.1016/j.jallcom.2023.169006
38. [38]
  Xie, M.; Jia, K.; Lu, J.; Zhao, R. CrystEngComm 2020, 22, 546. doi: 10.1039/c9ce01575b doi: 10.1039/c9ce01575b
39. [39]
  Chu, W.; Hou, Y.; Liu, J.; Bai, X.; Gao, Y. f.; Cao, Z. Electrochim. Acta 2020, 364, 137063. doi: 10.1016/j.electacta.2020.137063 doi: 10.1016/j.electacta.2020.137063
40. [40]
  Li, C.; Zhu, D.; Cheng, S.; Zuo, Y.; Wang, Y.; Ma, C.; Dong, H. Chin. Chem. Lett. 2022, 33, 1141. doi: 10.1016/j.cclet.2021.07.057 doi: 10.1016/j.cclet.2021.07.057
41. [41]
  Xu, J.; Cao, S.; Zhong, M.; Ren, S.; Chen, X.; Li, W.; Wang, C.; Wang, Z.; Lu, X.; Lu, X. J. Colloid Interface Sci. 2024, 657, 83. doi: 10.1016/j.jcis.2023.11.141 doi: 10.1016/j.jcis.2023.11.141
42. [42]
  Dai, M.; Zhao, D.; Liu, H.; Tong, Y.; Hu, P.; Wu, X. Mater. Today Energy 2020, 16, 100412. doi: 10.1016/j.mtener.2020.100412 doi: 10.1016/j.mtener.2020.100412
43. [43]
  Huang, H.-b.; Luo, S.-h.; Liu, C.-l.; Yi, T.-f.; Zhai, Y.-c. ACS Appl. Mater. Interfaces 2018, 10, 21281. doi: 10.1021/acsami.8b03736 doi: 10.1021/acsami.8b03736
44. [44]
  Cheng, L.; Chen, Q.; Li, J.; Liu, H. Appl. Catal. B-Environ. 2020, 267, 118379. doi: 10.1016/j.apcatb.2019.118379 doi: 10.1016/j.apcatb.2019.118379
45. [45]
  Su, T.; Men, C.; Chen, L.; Chu, B.; Luo, X.; Ji, H.; Chen, J.; Qin, Z. Adv. Sci. 2022, 9, 2103715. doi: 10.1002/advs.202103715 doi: 10.1002/advs.202103715
46. [46]
  Gao, Z.; Chen, K.; Wang, L.; Bai, B.; Liu, H.; Wang, Q. Appl. Catal. B-Environ. 2020, 268, 118462. doi: 10.1016/j.apcatb.2019.118462 doi: 10.1016/j.apcatb.2019.118462
47. [47]
  Zhang, H.; Sun, B.; Wang, J.; Zhu, Q.; Hou, D.; Li, C.; Qiao, X. Q.; Li, D. S. J. Colloid Interface Sci. 2023, 645, 429. doi: 10.1016/j.jcis.2023.04.146 doi: 10.1016/j.jcis.2023.04.146
48. [48]
  Le, K. T. N.; Hoa, V. H.; Le, H. T.; Tran, D. T.; Kim, N. H.; Lee, J. H. Appl. Surf. Sci. 2022, 600, 154206. doi: 10.1016/j.apsusc.2022.154206 doi: 10.1016/j.apsusc.2022.154206
49. [49]
  Li, Y.; Jin, Z.; Tsubaki, N. ACS Appl. Nano Mater. 2022, 5, 14677. doi: 10.1021/acsanm.2c03031 doi: 10.1021/acsanm.2c03031
50. [50]
  Hsiang, H.-I.; Chiou, Y.-Y.; Chung, S.-H. J. Energy Storage 2022, 55, 105402. doi: 10.1016/j.est.2022.105402 doi: 10.1016/j.est.2022.105402
51. [51]
  Jin, C.; Xu, C.; Chang, W.; Ma, X.; Hu, X.; Liu, E.; Fan, J. J. Alloy. Compd. 2019, 803, 205. doi: 10.1016/j.jallcom.2019.06.252 doi: 10.1016/j.jallcom.2019.06.252
52. [52]
  Dai, Z.; Geng, H.; Wang, J.; Luo, Y.; Li, B.; Zong, Y.; Yang, J.; Guo, Y.; Zheng, Y.; Wang, X.; et al. ACS Nano 2017, 11, 11031. doi: 10.1021/acsnano.7b05050 doi: 10.1021/acsnano.7b05050
53. [53]
  Cabán-Acevedo, M.; Stone, M. L.; Schmidt, J. R.; Thomas, J. G.; Ding, Q.; Chang, H.-C.; Tsai, M.-L.; He, J.-H.; Jin, S. Nat. Mater. 2015, 14, 1245. doi: 10.1038/nmat4410 doi: 10.1038/nmat4410
54. [54]
  Dong, G.; Zhang, Y.; Wang, Y.; Deng, Q.; Qin, C.; Hu, Y.; Zhou, Y.; Tian, G. ACS Appl. Energy Mater. 2021, 4, 14342. doi: 10.1021/acsaem.1c03019 doi: 10.1021/acsaem.1c03019
55. [55]
  Fajrina, N.; Tahir, M. Int. J. Hydrog. Energy 2019, 44, 540. doi: 10.1016/j.ijhydene.2018.10.200 doi: 10.1016/j.ijhydene.2018.10.200
56. [56]
  Men, C.; Chen, L.; Ji, H.; Qin, Z.; Su, T. Chem. Eng. J. 2023, 473, 145173. doi: 10.1016/j.cej.2023.145173 doi: 10.1016/j.cej.2023.145173
57. [57]
  Zhong, T.; Yu, Z.; Jiang, R.; Hou, Y.; Chen, H.; Ding, L.; Lian, C.; Zou, B. Sol. RRL 2021, 6, 2100863. doi: 10.1002/solr.202100863 doi: 10.1002/solr.202100863
58. [58]
  Li, H.; Gong, H.; Jin, Z. Acta Phys. -Chim. Sin. 2022, 38, 2201037. doi: 10.3866/PKU.WHXB202201037 doi: 10.3866/PKU.WHXB202201037
59. [59]
  Wang, Z.; Li, C.; Domen, K. Chem. Soc. Rev. 2019, 48, 2109. doi: 10.1039/c8cs00542g doi: 10.1039/c8cs00542g
60. [60]
  Ren, T.; Huang, H.; Li, N.; Chen, D.; Xu, Q.; Li, H.; He, J.; Lu, J. J. Colloid Interface Sci. 2021, 598, 398. doi: 10.1016/j.jcis.2021.04.027 doi: 10.1016/j.jcis.2021.04.027
61. [61]
  Zhang, L.; Wu, Y.; Tsubaki, N.; Jin, Z. Acta Phys. -Chim. Sin. 2023, 39, 2302051. doi: 10.3866/PKU.WHXB202302051 doi: 10.3866/PKU.WHXB202302051
62. [62]
  Bi, L.; Gao, X.; Zhang, L.; Wang, D.; Zou, X.; Xie, T. ChemSusChem 2017, 11, 276. doi: 10.1002/cssc.201701574 doi: 10.1002/cssc.201701574
63. [63]
  Yang, H.; Jin, Z.; Liu, D.; Fan, K.; Wang, G. J. Phys. Chem. C 2018, 122, 10430. doi: 10.1021/acs.jpcc.8b01666 doi: 10.1021/acs.jpcc.8b01666
64. [64]
  Jin, Y.; Zhang, H.; Song, C.; Wang, L.; Lu, Q.; Gao, F. Sci. Rep. 2016, 6, 29997. doi: 10.1038/srep29997 doi: 10.1038/srep29997
65. [65]
  Xiao, L.; Ren, W.; Shen, S.; Chen, M.; Liao, R.; Zhou, Y.; Li, X. Acta Phys. -Chim. Sin. 2024, 40, 2308036. doi: 10.3866/PKU.WHXB202308036 doi: 10.3866/PKU.WHXB202308036
66. [66]
  Han, C.; Zhang, R.; Ye, Y.; Wang, L.; Ma, Z.; Su, F.; Xie, H.; Zhou, Y.; Wong, P. K.; Ye, L. J. Mater. Chem. A 2019, 7, 9726. doi: 10.1039/C9TA01061K doi: 10.1039/C9TA01061K
67. [67]
  Yue, X.; Yi, S.; Wang, R.; Zhang, Z.; Qiu, S. Nano Energy 2018, 47, 463. doi: 10.1016/j.nanoen.2018.03.014 doi: 10.1016/j.nanoen.2018.03.014
68. [68]
  Li, L.; Zhang, R.; Lin, Y.; Wang, D.; Xie, T. Chem. Eng. J. 2023, 453, 139970. doi: 10.1016/j.cej.2022.139970 doi: 10.1016/j.cej.2022.139970
69. [69]
  Kong, X.; Lv, F.; Zhang, H.; Yu, F.; Wang, Y.; Yin, L.; Huang, J.; Feng, Q. J. Alloy. Compd. 2022, 903, 163864. doi: 10.1016/j.jallcom.2022.163864 doi: 10.1016/j.jallcom.2022.163864
70. [70]
  Wang, L.; Cheng, B.; Zhang, L.; Yu, J. Small 2021, 17, 2103447. doi: 10.1002/smll.202103447 doi: 10.1002/smll.202103447
71. [71]
  Jin, Z.; Wang, X. Mater. Today Energy 2022, 30, 101164. doi: 10.1016/j.mtener.2022.101164 doi: 10.1016/j.mtener.2022.101164
72. [72]
  Wang, Y.; Pan, Y.; Zhu, H.; Xiang, Y.; Han, R.; Huang, R.; Du, C.; Pan, C. Acta Phys. -Chim. Sin. 2024, 40, 2304050. doi: 10.3866/PKU.WHXB202304050 doi: 10.3866/PKU.WHXB202304050
73. [73]
  Feng, F.; Hua, H.; Li, L.; Xu, R.; Tang, J.; Dong, D.; Zhang, J.; Li, X. a. ACS Appl. Energy Mater. 2021, 4, 4365. doi: 10.1021/acsaem.0c03168 doi: 10.1021/acsaem.0c03168
74. [74]
  Du, J.; Shen, Y.; Yang, F.; Zhang, B.; Jiang, X.; An, C.; Ye, J. Inorg. Chem. Front. 2023, 10, 832. doi: 10.1039/D2QI01665F doi: 10.1039/D2QI01665F
1. [1]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
2. [2]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . 具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-0. doi: 10.1016/j.actphy.2025.100075
3. [3]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031
4. [4]
  Deyun Ma , Fenglan Liang , Qingquan Xue , Yanping Liu , Chunqiang Zhuang , Shijie Li . Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Physico-Chimica Sinica, 2025, 41(12): 100190-0. doi: 10.1016/j.actphy.2025.100190
5. [5]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
6. [6]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
7. [7]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
8. [8]
  Bowen Liu , Jianjun Zhang , Han Li , Bei Cheng , Chuanbiao Bie . MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation. Acta Physico-Chimica Sinica, 2025, 41(10): 100121-0. doi: 10.1016/j.actphy.2025.100121
9. [9]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
10. [10]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
11. [11]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
12. [12]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
13. [13]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
14. [14]
  Jingjing Liu , Aoqi Wei , Hao Zhang , Shuwang Duo . SnS₂-based heterostructures: advances in photocatalytic and gas-sensing applications. Acta Physico-Chimica Sinica, 2025, 41(12): 100185-0. doi: 10.1016/j.actphy.2025.100185
15. [15]
  Shiyi Chen , Jialong Fu , Jianping Qiu , Guoju Chang , Shiyou Hao . Waste medical mask-derived carbon quantum dots enhance the photocatalytic degradation of polyethylene terephthalate (PET) over BiOBr/g-C₃N₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(1): 100135-0. doi: 10.1016/j.actphy.2025.100135
16. [16]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
17. [17]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . Improving Photocatalytic H₂O₂ Production over iCOF/Bi₂O₃ S-Scheme Heterojunction in Pure Water via Dual Channel Pathways. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-0. doi: 10.3866/PKU.WHXB202407012
18. [18]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C₃N₅ 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014
19. [19]
  Yushan Cai , Fang-Xing Xiao . Revisiting MXenes-based Photocatalysis Landscape: Progress, Challenges, and Future Perspectives. Acta Physico-Chimica Sinica, 2024, 40(8): 2306048-0. doi: 10.3866/PKU.WHXB202306048
20. [20]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(467)
HTML views(109)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Construction of ZnCoP/CdLa2S4 Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution