Citation: Ke Li, Chuang Liu, Jingping Li, Guohong Wang, Kai Wang. Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240300. doi: 10.3866/PKU.WHXB202403009 shu

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water

Ke Li ^{1, †} ,
Chuang Liu ^{1, †} ,
Jingping Li ¹ ,
Guohong Wang ^1,, ,
Kai Wang ^{1, 2, 3,,}

1.
Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, College of Chemistry and Chemical Engineering, Huangshi Key Laboratory of Prevention and Control of Soil Pollution, Hubei Normal University, Huangshi 435002, Hubei Province, China
2.
Engineering Research Center for Clean Production of Textile Printing and Dyeing, Ministry of Education, Wuhan Textile University, Wuhan 430073, China
3.
School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore

Corresponding author: Guohong Wang, wanggh2003@163.com Kai Wang, wangkai@hbnu.edu.cn

^†

Received Date: 12 March 2024
Revised Date: 8 April 2024
Accepted Date: 8 April 2024
Available Online: 11 April 2024
Fund Project: the National Natural Science Foundation of China 22378104the National Natural Science Foundation of China 52104254the Open Subject of Engineering Research Center for Clean Production of Textile Printing and Dyeing, Ministry of Education 2023GCZX008

Hydrogen peroxide (H₂O₂) plays a significant role as an industrial chemical and potential energy carrier. However, common H₂O₂ photosynthesis catalysts face challenges such as limited solar spectrum absorption, severe agglomeration, and difficulty in reuse, hindering their widespread application. In this study, an inorganic/organic heterojunction photocatalyst comprising g-C₃N₄ nanosheets and Bi₄Ti₃O₁₂ nanofibers is synthesized using electrospinning assisted self-assembly methods. The Bi₄Ti₃O₁₂/g-C₃N₄ heterojunction exhibits significantly enhanced H₂O₂ yield of 1650 μmol∙g⁻¹∙h⁻¹ and efficient H₂O₂ photosynthesis directly from pure water. The improved performance is attributed to enhanced visible light absorption, charge separation efficiency, and boosting redox properties of photoinduced carriers in S-scheme heterojunctions. Additionally, the utilization of in situ X-ray photoelectron spectroscopy (ISXPS) enables the investigation of the S-scheme mechanism and dynamics of inorganic/organic Bi₄Ti₃O₁₂/g-C₃N₄ heterojunctions. This research presents a novel approach for designing inorganic/organic heterojunction photocatalysts for solar-driven H₂O₂ production.
- Heterojunction,
- Photocatalysis,
- Hydrogen peroxide production,
- S-scheme mechanism
1. [1]
  Liu, W.; Wang, P.; Chen, J.; Gao, X.; Che, H.; Liu, B.; Ao, Y. Adv. Funct. Mater. 2022, 32, 2205119. doi: 10.1002/adfm.202205119 doi: 10.1002/adfm.202205119
2. [2]
  Yang, Y.; Cheng, B.; Yu, J.; Wang, L.; Ho, W. Nano Res. 2023, 16, 4506. doi: 10.1007/s12274-021-3733-0 doi: 10.1007/s12274-021-3733-0
3. [3]
  Zheng, D.; Su, Y.; Wen, D.; Zhang, Z.; Yang, P.; Ma, X.; Chen, Y.; Deng, L.; Zhou, S.; Meng, S. J. Catal. . 2023, 428, 115180. doi: 10.1016/j.jcat.2023.115180 doi: 10.1016/j.jcat.2023.115180
4. [4]
  Wen, D.; Su, Y.; Fang, J.; Zheng, D.; Yu, Y.; Zhou, S.; Meng, A.; Han, P.; Wong, C. Nano Energy 2023, 117, 108917. doi: 10.1016/j.nanoen.2023.108917 doi: 10.1016/j.nanoen.2023.108917
5. [5]
  He, R.; Xu, D.; Li, X. J. Mater. Sci. Technol. 2023, 138, 256. doi: 10.1016/j.jmst.2022.09.002 doi: 10.1016/j.jmst.2022.09.002
6. [6]
  Wang, K.; Li, J.; Liu, X.; Cheng, Q.; Du, Y.; Li, D.; Wang, G.; Liu, B. Appl. Catal. B 2024, 342, 123349. doi: 10.1016/j.apcatb.2023.123349 doi: 10.1016/j.apcatb.2023.123349
7. [7]
  Che, H.; Ao, Y. Chin. J. Struc. Chem. 2022, 41, 2205093. doi: 10.14102/j.cnki.0254-5861.2022-0107 doi: 10.14102/j.cnki.0254-5861.2022-0107
8. [8]
  Tang, X.; Li, F.; Li, F.; Jiang, Y.; Yu, C. Chin. J. Catal. 2023, 52, 79. doi: 10.1016/s1872-2067(23)64498-5 doi: 10.1016/s1872-2067(23)64498-5
9. [9]
  Xie, Y.; Zhang, Q.; Sun, H.; Teng, Z.; Su, C. Acta Phys.-Chim. Sin. 2023, 39, 2301001. doi: 10.3866/PKU.WHXB202301001 doi: 10.3866/PKU.WHXB202301001
10. [10]
  Li, F; Tang, X.; Hu, Z.; Li, X.; Li, F; Xie, Y.; Jiang, Y.; Yu, C. Chin. J. Catal. 2023, 55, 253. doi: 10.1016/s1872-2067(23)64555-3 doi: 10.1016/s1872-2067(23)64555-3
11. [11]
  Liu, F.; Zhou, P.; Hou, Y.; Tan, H.; Liang, Y.; Liang, J.; Zhang, Q.; Guo, S.; Tong, M.; Ni, J. Nat. Commun. 2023, 14, 4344. doi: 10.1038/s41467-023-40007-4 doi: 10.1038/s41467-023-40007-4
12. [12]
  Zhang, P; Li, Y. J.; Li, X. Chin. J. Catal. 2023, 44, 4. doi: 10.1016/s1872-2067(22)64185-8 doi: 10.1016/s1872-2067(22)64185-8
13. [13]
  Xu, X.; Sui, Y.; Chen, W.; Huang, W; Li, X.; Li, Y.; Liu, D.; Gao, S.; Wu, W.; Pan, C.; et al. Appl. Catal. B 2024, 341, 123271. doi: 10.1016/j.apcatb.2023.123271 doi: 10.1016/j.apcatb.2023.123271
14. [14]
  Shen, X.; Wang, Z.; Guo, H.; Lei, Z.; Liu, Z.; Wang, L. Small 2023, 19, 2303156. doi: 10.1002/smll.202303156 doi: 10.1002/smll.202303156
15. [15]
  Li, Y.; Liu, Y.; Wang, Z.; Wang, P; Zheng, Z.; Cheng, H.; Dai, Y.; Huang, B. Chin. J. Catal. 2023, 45, 132. doi: 10.1016/s1872-2067(22)64163-9 doi: 10.1016/s1872-2067(22)64163-9
16. [16]
  Liu, T; Pan, Z.; Vequizo, J.; Kato, K; Wu, B.; Yamakata, A.; Katayama, K.; Chen, B.; Chu, C.; Domen, K. Nat. Commun. 2022, 13, 1034. doi: 10.1038/s41467-022-28686-x doi: 10.1038/s41467-022-28686-x
17. [17]
  Jiang, Z.; Zhang, Y.; Zhang, L.; Cheng, B.; Wang, L. Chin. J. Catal. 2022, 43, 226. doi: 10.1016/s1872-2067(21)63832-9 doi: 10.1016/s1872-2067(21)63832-9
18. [18]
  Jiang, Z.; Cheng, B.; Zhang, Y.; Wageh, S.; Al-Ghamdi, A.; Yu, J.; Wang, L. J. Mater. Sci. Technol. 2022, 124, 193. doi: 10.1016/j.jmst.2022.01.029 doi: 10.1016/j.jmst.2022.01.029
19. [19]
  He, B.; Luo, C.; Wang, Z.; Zhang, L.; Yu, J. Appl. Catal. B 2023, 323, 122200. doi: 10.1016/j.apcatb.2022.122200 doi: 10.1016/j.apcatb.2022.122200
20. [20]
  Xu, Y.; Tai, W.; Wang, Z.; Zhang, L.; Wang, D.; Liao, J. Sci. China-Mater. 2024, 67, 153. doi: 10.1007/s40843-023-2659-9 doi: 10.1007/s40843-023-2659-9
21. [21]
  Shen, S.; Li, X.; Zhou, Y.; Han, L.; Xie, Y.; Deng, F.; Huang, J.; Chen, Z.; Feng, Z.; Xu, J.; Dong, F. J. Mater. Sci. Technol. 2023, 155, 148. doi: 10.1016/j.jmst.2023.03.006 doi: 10.1016/j.jmst.2023.03.006
22. [22]
  Wu, Y; Yang, Y.; Gu, M.; Bie, C.; Tan, H.; Cheng, B.; Xu, J. Chin. J. Catal. 2023, 53, 123. doi: 10.1016/s1872-2067(23)64514-0 doi: 10.1016/s1872-2067(23)64514-0
23. [23]
  Shao, C.; He, Q.; Zhang, M.; Jia, L.; Ji, Y.; Hu, Y.; Li, Y.; Huang, W.; Li, Y. Chin. J. Catal. 2023, 46, 28. doi: 10.1016/s1872-2067(22)64205-0 doi: 10.1016/s1872-2067(22)64205-0
24. [24]
  Zhang, H.; Liu, J.; Zhang, Y; Cheng, B.; Zhu, B.; Wang, L. J. Mater. Sci. Technol. 2023, 166, 241. doi: 10.1016/j.jmst.2023.05.030 doi: 10.1016/j.jmst.2023.05.030
25. [25]
  Zhou, S.; Hu, H.; Hu, H.; Jiang, Q.; Xie, H.; Li, C.; Gao, S.; Kong, Y.; Hu, Y. Sci. China-Mater. 2023, 66, 1837. doi: 10.1007/s40843-022-2337-7 doi: 10.1007/s40843-022-2337-7
26. [26]
  Yong, Z.; Ma, T. Angew. Chem. Int. Ed. 2023, 62, e202308980. doi: 10.1002/anie.202308980 doi: 10.1002/anie.202308980
27. [27]
  Wang, J.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Struc. Chem. 2023, 42, 100202. doi: 10.1016/j.cjsc.2023.100202 doi: 10.1016/j.cjsc.2023.100202
28. [28]
  Han, G.; Xu, F.; Cheng, B.; Li, Y.; Yu, J.; Zhang, L. Acta Phys.-Chim. Sin. 2022, 38, 2112037. doi: 10.3866/PKU.WHXB202112037 doi: 10.3866/PKU.WHXB202112037
29. [29]
  Che, H.; Gao, X.; Chen, J.; Hou, J.; Ao, Y.; Wang, P. Angew. Chem. Int. Ed. 2021, 60, 25546. doi: 10.1002/anie.202111769 doi: 10.1002/anie.202111769
30. [30]
  Li, H.; Zhu, B.; Cheng, B.; Luo, G.; Xu, J.; Cao, S. J. Mater. Sci. Technol. 2023, 161, 192. doi: 10.1016/j.jmst.2023.03.039 doi: 10.1016/j.jmst.2023.03.039
31. [31]
  You, Q.; Zhang, C.; Cao, M.; Wang, B.; Huang, J; Wang, Y.; Deng, S.; Yu, G. Appl. Catal. B 2023, 321, 121941. doi: 10.1016/j.apcatb.2022.121941 doi: 10.1016/j.apcatb.2022.121941
32. [32]
  Xie, L.; Wang, X.; Zhang, Z.; Ma, Y.; Du, T.; Wang, R.; Wang, J. Small 2023, 19, 2301007. doi: 10.1002/smll.202301007 doi: 10.1002/smll.202301007
33. [33]
  Wang, C.; Chen, F.; Hu, C.; Ma, T.; Zhang, Y.; Huang, H. Chem. Eng. J. 2022, 431, 133930. doi: 10.1016/j.cej.2021.133930 doi: 10.1016/j.cej.2021.133930
34. [34]
  Shi, H.; Tan, H.; Zhu, W.; Sun, Z.; Ma, Y.; Wang, E. J. Mater. Chem. A 2015, 3, 6586. doi: 10.1039/c4ta06736c doi: 10.1039/c4ta06736c
35. [35]
  Xiao, Y.; Yao, C.; Su, C.; Liu, B. EcoEnergy 2023, 1, 60. doi: 10.1002/ece2.6 doi: 10.1002/ece2.6
36. [36]
  Wang, K.; Qin, H.; Li, J.; Cheng, Q.; Zhu, Y.; Hu, H.; Peng, J.; Chen, S.; Wang, G.; Chou, S.; Dou, S.; Xiao, Y. Appl. Catal. B 2023, 332, 122763. doi: 10.1016/j.apcatb.2023.122763 doi: 10.1016/j.apcatb.2023.122763
37. [37]
  Wang, K.; Du, Y.; Li, Y.; Wu, X.; Hu, H.; Wang, G.; Xiao, Y; Chou, S.; Zhang, G. Carbon Energy 2022, 5, e264. doi: 10.1002/cey2.264 doi: 10.1002/cey2.264
38. [38]
  Hou, W., Guo, H., Wu, M.; Wang, L. ACS Nano 2023, 17, 20560. doi: 10.1021/acsnano.3c07411 doi: 10.1021/acsnano.3c07411
39. [39]
  Li, K.; Mei, J.; Li, J.; Liu, Y.; Wang, G.; Hu, D.; Yan, S.; Wang, K. Sci. China Mater. 2024, 67, 484. doi: 10.1007/s40843-023-2717-0 doi: 10.1007/s40843-023-2717-0
40. [40]
  Hou, H.; Zeng, X.; Zhang, X. Angew. Chem. Int. Ed. 2020, 59, 17356. doi: 10.1002/anie.201911609 doi: 10.1002/anie.201911609
41. [41]
  Wang, Z.; Wang, J.; Zhang, J.; Dai, K. Acta Phys.-Chim. Sin. 2023, 39, 2209037. doi: 10.3866/PKU.WHXB202209037 doi: 10.3866/PKU.WHXB202209037
42. [42]
  Wang, K.; Feng, X.; Shangguan, Y.; Wu, X.; Chen, H. Chin. J. Catal. 2022, 43, 246. doi: 10.1016/s1872-2067(21)63819-6 doi: 10.1016/s1872-2067(21)63819-6
43. [43]
  Wang, K.; Qin, H.; Shao, X.; Jiang, L.; Li, K.; Wang, J.; Zhou, L.; Cheng, Q.; Wang, G.; Wang, H. Solar RRL 2022, 7, 2200963. doi: 10.1002/solr.202200963 doi: 10.1002/solr.202200963
44. [44]
  Li, S.; Wang, C.; Liu, Y.; Liu, Y.; Cai, M.; Zhao, W.; Duan, X. Chem. Eng. J. 2023, 455, 140943. doi: 10.1016/j.cej.2022.140943 doi: 10.1016/j.cej.2022.140943
45. [45]
  Meng, A.; Zhou, S.; Wen, D.; Han, P.; Su, Y. Chin. J. Catal. 2022, 43, 2548. doi: 10.1016/S1872-2067(22)64111-1 doi: 10.1016/S1872-2067(22)64111-1
46. [46]
  Zan, Z.; Li, X.; Gao, X.; Huang, J.; Luo, Y.; Han, L. Acta Phys.-Chim. Sin. 2023, 39, 2209016. doi: 10.3866/PKU.WHXB202209016 doi: 10.3866/PKU.WHXB202209016
47. [47]
  Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/s1872-2067(22)64106-8 doi: 10.1016/s1872-2067(22)64106-8
48. [48]
  Li, X.; Kang, B.; Dong, F., Zhang, Z.; Luo, X.; Han, L.; Huang, J.; Feng, Z.; Chen, Z., Xu, J.; Peng, B.; Wang, Z. Nano Energy 2021, 81, 105671. doi: 10.1016/j.nanoen.2020.105671 doi: 10.1016/j.nanoen.2020.105671
49. [49]
  Zhang, K.; Li, Y.; Yuan, S.; Zhang, L.; Wang, Q. Acta Phys.-Chim. Sin. 2023, 39, 2212010. doi: 10.3866/PKU.WHXB202212010 doi: 10.3866/PKU.WHXB202212010
50. [50]
  Yu, Z.; Guan, C.; Yue, X.; Xiang, Q. Chin. J. Catal. 2023, 50, 361. doi: 10.1016/s1872-2067(23)64448-1 doi: 10.1016/s1872-2067(23)64448-1
51. [51]
  Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys.-Chim. Sin. 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009 doi: 10.3866/PKU.WHXB202212009
52. [52]
  Huang, B.; Fu, X.; Wang, K.; Wang, L.; Zhang, H.; Liu, Z.; Liu, B.; Li, J. Adv. Powd. Mater. 2024, 3, 100140. doi: 10.1016/j.apmate.2023.100140 doi: 10.1016/j.apmate.2023.100140
53. [53]
  Wageh, S.; Al-Ghamdi, A.; Al-Hartomy, O.; Alotaibi, M.; Wang, L. Chin. J. Catal. 2022, 43, 586. doi: 10.1016/s1872-2067(21)63925-6 doi: 10.1016/s1872-2067(21)63925-6
54. [54]
  Cai, M.; Liu, Y.; Dong, K.; Chen, X.; Li, S. Chin. J. Catal. 2023, 52, 239. doi: 10.1016/s1872-2067(23)64496-1 doi: 10.1016/s1872-2067(23)64496-1
55. [55]
  Luo, C.; Long, Q.; Cheng, B.; Zhu, B.; Wang, L. Acta Phys.-Chim. Sin. 2023, 39, 2212026. doi: 10.3866/PKU.WHXB202212026 doi: 10.3866/PKU.WHXB202212026
56. [56]
  Shao, X.; Wang, K., Peng, L.; Li, K.; Wen, H.; Le, X.; Wu, X.; Wang, G. Colloids Surfaces A 2022, 652, 129846. doi: 10.1016/j.colsurfa.2022.129846 doi: 10.1016/j.colsurfa.2022.129846
57. [57]
  Wang, K.; Cheng, Q.; Hou, W.; Guo, H.; Wu, X.; Wang, J.; Li, J.; Liu, Z.; Wang, L. Adv. Funct. Mater. 2023, 34, 2309603. doi: 10.1002/adfm.202309603 doi: 10.1002/adfm.202309603
58. [58]
  Yu, W.; Bie, C. Acta Phys.-Chim. Sin. 2024, 40, 2307022. doi: 10.3866/PKU.WHXB202307022 doi: 10.3866/PKU.WHXB202307022
59. [59]
  Shao, X.; Li, K.; Li, J.; Cheng, Q.; Wang, G.; Wang, K. Chin. J. Catal. 2023, 51, 193. doi: 10.1016/s1872-2067(23)64478-x doi: 10.1016/s1872-2067(23)64478-x
60. [60]
  Zhang, Y.; Zhang, L.; Zeng, D.; Wang, W.; Wang, J.; Wang, W.; Wang, W. Chin. J. Catal. 2022, 43, 2690. doi: 10.1016/s1872-2067(22)64114-7 doi: 10.1016/s1872-2067(22)64114-7
61. [61]
  Jiang, Z.; Long, Q.; Cheng, B.; He, R.; Wang, L. J. Mater. Sci. Technol. 2023, 162, 1. doi: 10.1016/j.jmst.2023.03.045 doi: 10.1016/j.jmst.2023.03.045
62. [62]
  Wang, J.; Guo, C.; Jiang, Y.; Wan, J.; Zheng, B.; Li, Y.; Jiang, B. Sci. China-Mater. 2023, 66, 1053. doi: 10.1007/s40843-022-2218-7 doi: 10.1007/s40843-022-2218-7
63. [63]
  Zhang, Y.; Cao, N.; Liu, X.; He, F.; Zheng, B.; Zhao, C.; Wang, Y. Sci. China-Mater. 2023, 66, 2274. doi: 10.1007/s40843-022-2345-1 doi: 10.1007/s40843-022-2345-1
64. [64]
  Wan, S.; Xu, J.; Cao, S.; Yu, J. Interdiscip. Mater. 2022, 1, 294. doi: 10.1002/idm2.12024 doi: 10.1002/idm2.12024
65. [65]
  Wang, K.; Shao, X.; Zhang, K.; Wang, J.; Wu, X.; Wang, H. Appl. Surf. Sci. 2022, 596, 153444. doi: 10.1016/j.apsusc.2022.153444 doi: 10.1016/j.apsusc.2022.153444
66. [66]
  He, B.; Wang, Z.; Xiao, P.; Chen, T.; Yu, J.; Zhang, L. Adv. Mater. 2022, 34, 2203225. doi: 10.1002/adma.202203225 doi: 10.1002/adma.202203225
67. [67]
  Gu, M.; Yang, Y.; Zhang, L.; Zhu, B.; Liang, G.; Yu, J. Appl. Catal. B 2023, 324, 122227. doi: 10.1016/j.apcatb.2022.122227 doi: 10.1016/j.apcatb.2022.122227
68. [68]
  Li, F.; Yue, X.; Liao, Y.; Qiao, L.; Lv, K.; Xiang, Q. Nat. Commun. 2023, 14, 3901. doi: 10.1038/s41467-023-39578-z doi: 10.1038/s41467-023-39578-z
69. [69]
  Xu, F.; Meng, K.; Cao, S.; Jiang, C.; Chen, T.; Xu, J.; Yu, J. ACS Catal. 2022, 12, 164. doi: 10.1021/acscatal.1c04903 doi: 10.1021/acscatal.1c04903
70. [70]
  Luo, J.; Wei, X.; Qiao, Y.; Wu, C.; Li, L.; Chen, L.; Shi, J. Adv. Mater. 2023, 35, 2210110. doi: 10.1002/adma.202210110 doi: 10.1002/adma.202210110
71. [71]
  Zhu, B.; Sun, J.; Zhao, Y.; Zhang, L.; Yu, J. Adv. Mater. 2024, 36, 2310600. doi: 10.1002/adma.202310600 doi: 10.1002/adma.202310600
72. [72]
  Qiu, J.; Meng, K.; Zhang, Y.; Cheng, B.; Zhang, J.; Wang, L.; Yu, J. Adv. Mater. 2024, 36, 2400288. doi: 10.1002/adma.202400288. doi: 10.1002/adma.202400288
73. [73]
  Yang, Y.; Liu, J.; Gu, M.; Cheng, B.; Wang, L.; Yu, J. Appl. Catal. B 2023, 333, 122780. doi: 10.1016/j.apcatb.2023.122780 doi: 10.1016/j.apcatb.2023.122780
74. [74]
  Zhu, B.; Liu, J.; Sun, J.; Xie, F.; Tan, H.; Cheng, B.; Zhang, J. J. Mater. Sci. Technol. 2023, 162, 90. doi: 10.1016/j.jmst.2023.03.054 doi: 10.1016/j.jmst.2023.03.054
75. [75]
  Wang, L.; Sun, J.; Cheng, B.; He, R.; Yu, J. J. Phys. Chem. Lett. 2023, 14, 4803. doi: 10.1021/acs.jpclett.3c00811 doi: 10.1021/acs.jpclett.3c00811
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4. [4]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016
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  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
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  Yukai SHEN , Zhaochao YAN , Yangjun ZHOU , Mei HUANG . Nickel foam-supported NiFeP/NiFcDCA heterojunction electrocatalyst for efficient urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 237-246. doi: 10.11862/CJIC.20250257
8. [8]
  Jingjing Liu , Aoqi Wei , Hao Zhang , Shuwang Duo . SnS₂-based heterostructures: advances in photocatalytic and gas-sensing applications. Acta Physico-Chimica Sinica, 2025, 41(12): 100185-0. doi: 10.1016/j.actphy.2025.100185
9. [9]
  Min WANG , Dehua XIN , Guoqiang TAN , Xiaolu WU , Wei ZHANG , Tong CHANG , Lijuan JIA , Yuchun WANG , Zhaorong LIU . Construction and full-spectrum-driven photocatalytic antibiotics degradation performance of Z-scheme nitrogen vacancy g-C₃N₄/Ti₃C₂T_x/W₁₈O₄₉ heterojunction. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1613-1626. doi: 10.11862/CJIC.20260086
10. [10]
  Ze Luo , Yukun Zhu , Yadan Luo , Guangmin Ren , Yonghong Wang , Hua Tang . Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(3): 100166-0. doi: 10.1016/j.actphy.2025.100166
11. [11]
  Deyun Ma , Fenglan Liang , Qingquan Xue , Yanping Liu , Chunqiang Zhuang , Shijie Li . Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Physico-Chimica Sinica, 2025, 41(12): 100190-0. doi: 10.1016/j.actphy.2025.100190
12. [12]
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13. [13]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
14. [14]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
15. [15]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
16. [16]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
17. [17]
  Yanping Qiu , Jiatong Zhang , Linping Li , Yangqin Gao , Ning Li , Lei Ge . MOF-derived g-C₃N₄/ZnIn₂S₄ S-scheme heterojunction: interface-engineering enhanced photocatalytic NO conversion. Acta Physico-Chimica Sinica, 2026, 42(4): 100175-0. doi: 10.1016/j.actphy.2025.100175
18. [18]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
19. [19]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
20. [20]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi4Ti3O12 Coupling with g-C3N4 for Photocatalytic H2O2 Production from Pure Water

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通讯作者: 陈斌, bchen63@163.com

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water