Citation: Shijie Li,  Ke Rong,  Xiaoqin Wang,  Chuqi Shen,  Fang Yang,  Qinghong Zhang. Design of Carbon Quantum Dots/CdS/Ta3N5 S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal[J]. Acta Physico-Chimica Sinica, ;2024, 40(12): 240300. doi: 10.3866/PKU.WHXB202403005 shu

Design of Carbon Quantum Dots/CdS/Ta3N5 S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal

  • Corresponding author: Shijie Li,  Qinghong Zhang, 
  • Received Date: 7 March 2024
    Revised Date: 18 April 2024
    Accepted Date: 19 April 2024

    Fund Project: This work has been financially supported by the State Key Laboratory for Modification of Chemical Fibers and Polymer Materials (KF2321), the Natural Science Foundation of Zhejiang Province of China (LY20E080014), and the Science and Technology Project of Zhoushan of China (2022C41011).

  • Photocatalytic pollutant removal provides a competitive manner for wastewater purification. The exploration of efficient and durable photocatalysts is significant for this technique. Integrating carbon quantum dots and S-scheme junction into one system represents an effective strategy for achieving the outstanding photocatalytic efficacy. In comparison to S-scheme junction, photocatalysts combining carbon quantum dots and S-scheme junction harness the merits of both, thus holding greater potential. Herein, a multicomponent fibrous photocatalyst of carbon quantum dots/CdS/Ta3N5that incorporates S-scheme heterojunction and carbon quantum dots is developed for high-efficient destruction of levofloxacin antibiotic. The as-prepared carbon quantum dots/CdS/Ta3N5 heterojunction nanofibers manifest a significantly strengthened photocatalytic levofloxacin degradation activity, with the rate constant (0.0404 min-1) exceeding Ta3N5, CdS/Ta3N5, and CdS by 39.4, 2.1, and 7.2 folds. Such remarkable photocatalytic performance is credited to the unique 1D/0D/0D core-shell heterostructure with compact-bound hetero-interface, which favors the synergistic effect between carbon quantum dots modification and S-scheme junction. This work offers a new way for developing new Ta3N5-based heterojunctions for environmental remediation.
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