Citation: Shi-Yu Lu, Wenzhao Dou, Jun Zhang, Ling Wang, Chunjie Wu, Huan Yi, Rong Wang, Meng Jin. Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230802. doi: 10.3866/PKU.WHXB202308024 shu

Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production

Shi-Yu Lu ^1,, ,
Wenzhao Dou ² ,
Jun Zhang ¹ ,
Ling Wang ² ,
Chunjie Wu ² ,
Huan Yi ² ,
Rong Wang ^1,, ,
Meng Jin ^1,,

1.
College of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing 401331, China
2.
College of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, China

Corresponding author: Shi-Yu Lu, lushiyu@cqust.edu.cn Rong Wang, rongwang@cqust.edu.cn Meng Jin, jinmeng@cqust.edu.cn
Received Date: 15 August 2023
Revised Date: 26 September 2023
Accepted Date: 27 September 2023
Available Online: 11 October 2023
Fund Project: the Young Elite Scientists Sponsorship Program by CAST 2021QNRC001Natural Science Foundation of Chongqing CSTB2022NSCQ-MSX0557Natural Science Foundation of Chongqing cstc2020jcyj-msxmX0670Natural Science Foundation of Chongqing 2023NSCQ-MSX3724Talent Introduction of Chongqing University of Science and Technology ckrc2021050Talent Introduction of Chongqing University of Science and Technology ckrc20230401Talent Introduction of Chongqing University of Science and Technology ckrc2021053Science and Technology Research Program of Chongqing Municipal Education Commission KJQN202001525Science and Technology Research Program of Chongqing Municipal Education Commission KJQN202201532Science and Technology Research Program of Chongqing Municipal Education Commission KJQN202301542National Natural Science Foundation of China 22109016Open Research Fund of CNMGE Platform & NSCC-TJ CNMGE2023016

Large-scale hydrogen production through the electrochemical water splitting technique is an important way for addressing the impending energy and environmental crisis. This approach requires highly efficient and robust bifunctional cost-effective electrocatalysts. Engineering amorphous and crystalline phases within electrocatalysts is a key method for enhancing the catalytic kinetics of water electrolysis, due to their unique physicochemical properties. The interface and amorphous regions constructed within heterostructures serve as highly active sites that play a crucial role in electrochemical reactions. On the other hand, highly crystalline regions within the heterostructure demonstrated high tolerance in harsh environments, which helps to improve the stability of the overall catalyst. However, effectively tailoring the crystalline state of catalysts within a microenvironment presents a significant challenge. Herein, construction of a novel CrS/CoS₂ heterojunction with precise control over crystallinity were presented. The optimized amorphous CrS/highly crystalline CoS₂ heterojunction (A-CrS/HC-CoS₂) exhibits a low overpotential of 90.6 mV (at 10 mA∙cm⁻²) and 370.5 mV (at 50 mA∙cm⁻²) for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively. X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations reveal that charge redistribution induces variations in the d-band center value at the A-CrS/HC-CoS₂ heterostructure interface, enhancing the catalytic activity for both HER and OER. The displacement of the d-band due to charge redistribution in the Cr―S―Co bond within A-CrS/HC-CoS₂ contributes to the modulation of the adsorption capacity of H* and OOH* intermediates on the catalyst surface, thereby optimizing the rate-determining step for HER and OER. The amorphous/highly crystalline structure also facilitates the structural and compositional evolution of A-CrS/HC-CoS₂ during water electrolysis, ensuring excellent stability. As a bifunctional catalyst in a methanol-assisted energy-saving hydrogen production device, A-CrS/HC-CoS₂ operates at a low cell voltage of 1.51 Ⅴ to deliver a current density of 10 mA∙cm⁻², making it a promising candidate among metal-based catalysts. The well-preserved amorphous/crystalline heterointerfaces in A-CrS/HC-CoS₂, along with favorable changes in surface composition, contribute to robust HER and OER stability. This work provides valuable insights into the manipulation of catalytic activity through crystalline control within amorphous/crystalline heterojunctions for bifunctional transition metal compound electrocatalysts.
- Amorphous-crystalline interface,
- Heterostructure,
- Crystalline degree modulation,
- Water-splitting,
- Energy-saving hydrogen device
1. [1]
  Faber, M. S.; Dziedzic, R.; Lukowski, M. A.; Kaiser, N. S.; Ding, Q.; Jin, S. J. Am. Chem. Soc. 2014, 136 (28), 10053. doi: 10.1021/ja504099w doi: 10.1021/ja504099w
2. [2]
  Huang, G.; Xiao, Z.; Chen, R.; Wang, S. ACS Sustain. Chem. Eng. 2018, 6 (12), 15954. doi: 10.1021/acssuschemeng.8b04397 doi: 10.1021/acssuschemeng.8b04397
3. [3]
  Liu, Z.; Zhao, L.; Liu, Y.; Gao, Z.; Yuan, S.; Li, X.; Li, N.; Miao, S. Appl. Catal. B-Environ. 2019, 246, 296. doi: 10.1016/j.apcatb.2019.01.062 doi: 10.1016/j.apcatb.2019.01.062
4. [4]
  Lu, S. -Y.; Jin, M.; Zhang, Y.; Niu, Y. -B.; Gao, J. -C.; Li, C. M. Adv. Energ. Mater. 2018, 8 (11), 1702545. doi: 10.1002/aenm.201702545 doi: 10.1002/aenm.201702545
5. [5]
  Yu, Y.; Rao, P.; Feng, S.; Chen, M.; Deng, P.; Li, J.; Miao, Z.; Kang, Z.; Shen, Y.; Tian, X. Acta Phys. -Chim. Sin. 2023, 39 (8), 2210039. doi: 10.3866/PKU.WHXB202210039
6. [6]
  Yu, L.; Huang, X.; Zhang, Q.; Zhang, Z. Acta Phys. -Chim. Sin. 2022, 38 (6), 2109020. doi: 10.3866/PKU.WHXB202109020
7. [7]
  Tang, S.; Wang, C.; Pu, X.; Gu, X.; Chen, Z. Acta Phys. -Chim. Sin. 2023, 39 (8), 2212037. doi: 10.3866/PKU.WHXB202212037
8. [8]
  Sun, K.; Zhao, Y.; Yin, J.; Jin, J.; Liu, H.; Xi, P. Acta Phys. -Chim. Sin. 2022, 38 (6), 2107005. doi: 10.3866/PKU.WHXB202107005
9. [9]
  Feng, L. L.; Yu, G.; Wu, Y.; Li, G. D.; Li, H.; Sun, Y.; Asefa, T.; Chen, W.; Zou, X. J. Am. Chem. Soc. 2015, 137 (44), 14023. doi: 10.1021/jacs.5b08186 doi: 10.1021/jacs.5b08186
10. [10]
  Gao, Z.; Li, M.; Wang, J.; Zhu, J.; Zhao, X.; Huang, H.; Zhang, J.; Wu, Y.; Fu, Y.; Wang, X. Carbon 2018, 139, 369. doi: 10.1016/j.carbon.2018.07.006 doi: 10.1016/j.carbon.2018.07.006
11. [11]
  Li, Y.; Sun, Y.; Qin, Y.; Zhang, W.; Wang, L.; Luo, M.; Yang, H.; Guo, S. Adv. Energy Mater. 2020, 10 (11), 1903120. doi: 10.1002/aenm.201903120 doi: 10.1002/aenm.201903120
12. [12]
  Zhang, L.; Zhang, J.; Fang, J.; Wang, X. Y.; Yin, L.; Zhu, W.; Zhuang, Z. Small 2021, 17 (28), 2100832. doi: 10.1002/smll.202100832 doi: 10.1002/smll.202100832
13. [13]
  Wang, S. Acta Phys. -Chim. Sin. 2021, 37 (7), 2011013. doi: 10.3866/PKU.WHXB202011013
14. [14]
  Guo, Y.; Gan, L.; Shang, C.; Wang, E.; Wang, J. Advan. Funct. Mater. 2017, 27 (5), 1602699. doi: 10.1002/adfm.201602699 doi: 10.1002/adfm.201602699
15. [15]
  Zhu, Y.; Song, L.; Song, N.; Li, M.; Wang, C.; Lu, X. ACS Sustain. Chem. Eng. 2019, 7 (3), 2899. doi: 10.1021/acssuschemeng.8b05462 doi: 10.1021/acssuschemeng.8b05462
16. [16]
  Chen, B.; Wang, J.; He, S.; Shen, Y.; Huang, S.; Zhou, H. J. Alloy. Compd. 2023, 948, 169655. doi: 10.1016/j.jallcom.2023.169655 doi: 10.1016/j.jallcom.2023.169655
17. [17]
  Lu, S. -Y.; Li, S.; Jin, M.; Gao, J.; Zhang, Y. Appl. Catal. B-Environ. 2020, 267, 118675. doi: 10.1016/j.apcatb.2020.118675 doi: 10.1016/j.apcatb.2020.118675
18. [18]
  Peng, W.; Wang, Z.; Lu, R.; Li, Q.; Wang, Z.; Zhao, Y.; Xu, L.; Mai, L. Chem. Eng. J. 2023, 457, 141173. doi: 10.1016/j.cej.2022.141173 doi: 10.1016/j.cej.2022.141173
19. [19]
  Han, L.; Wu, Y.; Zhao, B.; Meng, W.; Zhang, D.; Li, M.; Pang, R.; Zhang, Y.; Cao, A.; Shang, Y. ACS Appl. Mater. Interfaces 2022, 14 (27), 30847. doi: 10.1021/acsami.2c06122 doi: 10.1021/acsami.2c06122
20. [20]
  Xu, H.; Zhang, W. D.; Yao, Y.; Yang, J.; Liu, J.; Gu, Z. G.; Yan, X. J. Colloid Interface Sci. 2022, 629, 501. doi: 10.1016/j.jcis.2022.09.072 doi: 10.1016/j.jcis.2022.09.072
21. [21]
  Jin, M.; Lu, S. -Y.; Ma, L.; Gan, M. -Y.; Lei, Y.; Zhang, X. -L.; Fu, G.; Yang, P. -S.; Yan, M. -F. J. Power Sources 2017, 341, 294. doi: 10.1016/j.jpowsour.2016.12.013 doi: 10.1016/j.jpowsour.2016.12.013
22. [22]
  Zhang, J.; Xiao, B.; Liu, X.; Liu, P.; Xi, P.; Xiao, W.; Ding, J.; Gao, D.; Xue, D. J. Mater. Chem. A 2017, 5 (33), 17601. doi: 10.1039/c7ta05433e doi: 10.1039/c7ta05433e
23. [23]
  Zhang, J.; Liu, Y.; Sun, C.; Xi, P.; Peng, S.; Gao, D.; Xue, D. ACS Energy Lett. 2018, 3 (4), 779. doi: 10.1021/acsenergylett.8b00066 doi: 10.1021/acsenergylett.8b00066
24. [24]
  Xie, M.; Li, C.; Zhang, S.; Zhang, Z.; Li, Y.; Chen, X. B.; Shi, Z.; Feng, S. Small 2023, 2301436. doi: 10.1002/smll.202301436 doi: 10.1002/smll.202301436
25. [25]
  Yang, L.; Huang, L.; Yao, Y.; Jiao, L. Appl. Catal. B-Environ. 2021, 282, 119584. doi: 10.1016/j.apcatb.2020.119584 doi: 10.1016/j.apcatb.2020.119584
26. [26]
  Han, K. H.; Seok, J. Y.; Kim, I. H.; Woo, K.; Kim, J. H.; Yang, G. G.; Choi, H. J.; Kwon, S.; Jung, E. I.; Kim, S. O. Adv. Mater. 2022, 34 (34), 2203992. doi: 10.1002/adma.202203992 doi: 10.1002/adma.202203992
27. [27]
  Shifa, T. A.; Gradone, A.; Yusupov, K.; Ibrahim, K. B.; Jugovac, M.; Sheverdyaeva, P. M.; Rosen, J.; Morandi, V.; Moras, P.; Vomiero, A. Chem. Eng. J. 2023, 453, 139781. doi: 10.1016/j.cej.2022.139781 doi: 10.1016/j.cej.2022.139781
28. [28]
  Sun, F.; Hong, A.; Zhou, W.; Yuan, C.; Zhang, W. Mater. Today 2020, 25, 101707. doi: 10.1016/j.mtcomm.2020.101707 doi: 10.1016/j.mtcomm.2020.101707
29. [29]
  Fang, B.; He, N.; Li, Y.; Lu, T.; He, P.; Chen, X.; Zhao, Z.; Pan, L. Electrochim. Acta 2023, 448, 142187. doi: 10.1016/j.electacta.2023.142187 doi: 10.1016/j.electacta.2023.142187
30. [30]
  Wu, Q.; Liu, L.; Guo, H.; Li, L.; Tai, X. J. Alloy. Compd. 2020, 821, 153219. doi: 10.1016/j.jallcom.2019.153219 doi: 10.1016/j.jallcom.2019.153219
31. [31]
  Ma, X.; Wang, J.; Liu, D.; Kong, R.; Hao, S.; Du, G.; Asiri, A. M.; Sun, X. New J. Chem. 2017, 41 (12), 4754. doi: 10.1039/c7nj00326a doi: 10.1039/c7nj00326a
32. [32]
  Hao, J.; Yang, W.; Peng, Z.; Zhang, C.; Huang, Z.; Shi, W. ACS Catal. 2017, 7, 4214. doi: 10.1021/acscatal.7b00792 doi: 10.1021/acscatal.7b00792
33. [33]
  Jin, M.; Wang, R.; Jia, B.; Zhang, J.; Liu, H.; Lu, S. -Y. Appl. Surf. Sci. 2022, 591, 153201. doi: 10.1016/j.apsusc.2022.153201 doi: 10.1016/j.apsusc.2022.153201
34. [34]
  Wang, P.; Bai, P.; Mu, J.; Jing, J.; Wang, L.; Su, Y. J. Colloid Interface Sci. 2023, 642, 1. doi: 10.1016/j.jcis.2023.03.133 doi: 10.1016/j.jcis.2023.03.133
35. [35]
  Cao, X.; Wang, T.; Qin, H.; Lin, G.; Zhao, L.; Jiao, L. Nano Res. 2022, 16 (3), 3665. doi: 10.1007/s12274-022-4635-5 doi: 10.1007/s12274-022-4635-5
36. [36]
  Cao, F.; Li, M.; Hu, Y.; Wu, X.; Li, X.; Meng, X.; Zhang, P.; Li, S.; Qin, G. Chem. Eng. J. 2023, 472, 144970. doi: 10.1016/j.cej.2023.144970 doi: 10.1016/j.cej.2023.144970
37. [37]
  Zhang, S. -H.; Wu, M. -F.; Tang, T. -T.; Xing, Q. -J.; Peng, C. -Q.; Li, F.; Liu, H.; Luo, X. -B.; Zou, J. -P.; Min, X. -B.; et al. Chem. Eng. J. 2018, 335, 945. doi: 10.1016/j.cej.2017.10.182 doi: 10.1016/j.cej.2017.10.182
38. [38]
  Wu, Y.; Tao, X.; Qing, Y.; Xu, H.; Yang, F.; Luo, S.; Tian, C.; Liu, M.; Lu, X. Adv. Mater. 2019, 31 (15), 1900178. doi: 10.1002/adma.201900178 doi: 10.1002/adma.201900178
39. [39]
  Dong, C.; Yuan, X.; Wang, X.; Liu, X.; Dong, W.; Wang, R.; Duan, Y.; Huang, F. J. Mater. Chem. A 2016, 4 (29), 11292. doi: 10.1039/c6ta04052g doi: 10.1039/c6ta04052g
40. [40]
  Liu, D.; Tong, R.; Qu, Y.; Zhu, Q.; Zhong, X.; Fang, M.; Ho Lo, K.; Zhang, F.; Ye, Y.; Tang, Y.; et al. Appl. Catal. B-Environ. 2020, 267, 118721. doi: 10.1016/j.apcatb.2020.118721 doi: 10.1016/j.apcatb.2020.118721
41. [41]
  Zhu, L.; Susac, D.; Teo, M.; Wong, K.; Wong, P.; Parsons, R.; Bizzotto, D.; Mitchell, K.; Campbell, S. J. Catal. 2008, 258 (1), 235. doi: 10.1016/j.jcat.2008.06.016 doi: 10.1016/j.jcat.2008.06.016
42. [42]
  Jin, M.; Lu, S. -Y.; Zhong, X.; Liu, H.; Liu, H.; Gan, M.; Ma, L. ACS Sustain. Chem. Eng. 2020, 8 (4), 1933. doi: 10.1021/acssuschemeng.9b06329 doi: 10.1021/acssuschemeng.9b06329
43. [43]
  Lu, S. Y.; Wang, J.; Wang, X.; Yang, W.; Jin, M.; Xu, L.; Yang, H.; Ge, X.; Shang, C.; Chao, Y.; et al. Small Methods 2022, 6 (6), 2101551. doi: 10.1002/smtd.202101551 doi: 10.1002/smtd.202101551
44. [44]
  Fu, T.; Li, Z. Chem. Eng. Sci. 2015, 135, 3. doi: 10.1016/j.ces.2015.03.007 doi: 10.1016/j.ces.2015.03.007
1. [1]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
2. [2]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . Recent Advances in Iron-based Heterostructure Anode Materials for Sodium Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-0. doi: 10.3866/PKU.WHXB202311015
3. [3]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-0. doi: 10.3866/PKU.WHXB202405005
4. [4]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
5. [5]
  Rohit Kumar , Anita Sudhaik , Aftab Asalam Pawaz Khan , Van Huy Neguyen , Archana Singh , Pardeep Singh , Sourbh Thakur , Pankaj Raizada . Designing tandem S-scheme photo-catalytic systems: Mechanistic insights, characterization techniques, and applications. Acta Physico-Chimica Sinica, 2025, 41(11): 100150-0. doi: 10.1016/j.actphy.2025.100150
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
7. [7]
  Junqing WEN , Ruoqi WANG , Jianmin ZHANG . Regulation of photocatalytic hydrogen production performance in GaN/ZnO heterojunction through doping with Li and Au. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 923-938. doi: 10.11862/CJIC.20240243
8. [8]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
9. [9]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
10. [10]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
11. [11]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
12. [12]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
13. [13]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
14. [14]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . Adjusting the electronic structure of Keggin-type polyoxometalates to construct S-scheme heterojunction for photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-0. doi: 10.1016/j.actphy.2025.100051
15. [15]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
16. [16]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
17. [17]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
18. [18]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
19. [19]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
20. [20]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(550)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Amorphous-Crystalline Interfaces Coupling of CrS/CoS2 Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production

Metrics

通讯作者: 陈斌, bchen63@163.com

Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production