Citation: Zehao Zhang, Zheng Wang, Haibo Li. V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230802. doi: 10.3866/PKU.WHXB202308020 shu

V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性

Zehao Zhang ^1,2 ,
Zheng Wang ^1,, ,
Haibo Li ^2,,

1.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China;
2.
Ningxia Key Laboratory of Photovoltaic Materials, School of Materials and New Energy, Ningxia University, Yinchuan 750021, China

Corresponding author: Zheng Wang, Haibo Li,
Received Date: 15 August 2023
Revised Date: 10 September 2023
Accepted Date: 12 September 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22272085, 22169015).

采用同源金属V₂CF_x MXene作为前驱体制备了三氧化二钒@多孔碳(V₂O₃@porous carbon，V₂O₃@PC)纳米片作为电容去离子(CDI)阳极，研究其脱盐特性。实验探究了在不同在碳化温度下V₂O₃@PC的结构、结晶度、润湿性、石墨化程度和电化学特性。研究表明，所制备的V₂O₃@PC呈现出典型的2D纳米片结构，高结晶度的V₂O₃纳米颗粒被高石墨化度的PC牢牢束缚。这种结构具有良好的界面润湿性和高导电性，因而可以促进电解质的渗透，加速界面电荷的转移以并促进盐离子的传输和扩散。此外，PC也能较好的抑制V₂O₃在多次循环后的体积膨胀。电化学结果表明，V的可逆电化学转化在一定程度上提高了Na⁺的储存。当电压为1.2 V时，NaCl电导率为1000 μS·cm⁻¹时，优化后的V₂O₃@PC电极具有高达2.20 mmol∙g⁻¹的脱盐容量，0.13 mmol∙g⁻¹∙min⁻¹的脱盐速率，62%的水回收率以及24.0 Wh∙m⁻³的低能耗。
- Capacitive deionization,
- V₂O₃,
- Metal organic frameworks,
- MXene,
- Electrochemistry
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V2CFx MXene衍生2D V2O3@介孔碳纳米片的制备及其电容脱盐特性

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V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性