Citation: Wentao Xu, Xuyan Mo, Yang Zhou, Zuxian Weng, Kunling Mo, Yanhua Wu, Xinlin Jiang, Dan Li, Tangqi Lan, Huan Wen, Fuqin Zheng, Youjun Fan, Wei Chen. 双金属浸出诱导催化剂重构用于高活性和高稳定性电化学水氧化[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230800. doi: 10.3866/PKU.WHXB202308003 shu

双金属浸出诱导催化剂重构用于高活性和高稳定性电化学水氧化

Wentao Xu ¹ ,
Xuyan Mo ¹ ,
Yang Zhou ¹ ,
Zuxian Weng ¹ ,
Kunling Mo ¹ ,
Yanhua Wu ¹ ,
Xinlin Jiang ¹ ,
Dan Li ¹ ,
Tangqi Lan ¹ ,
Huan Wen ² ,
Fuqin Zheng ^1,, ,
Youjun Fan ^1,, ,
Wei Chen ^1,,

1.
School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, Guangxi, China;
2.
Guangxi Key Laboratory of Electrochemical Energy Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China

Corresponding author: Fuqin Zheng, Youjun Fan, Wei Chen,
Received Date: 1 August 2023
Revised Date: 22 September 2023
Accepted Date: 22 September 2023

Fund Project: The project was supported by the Natural Science Foundation of Guangxi, China (2019GXNSFGA245003, 2021GXNSFBA220058), the National Natural Science Foundation of China (22002026, 22272036), the Guangxi Technology Base and Talent Subject, China (GUIKE AD23026272), and the Guangxi Normal University Research Grant, China (2022TD).

析氧反应(OER)催化剂在催化反应过程中不可避免地会发生表面重构，这一过程使得设计、构筑高性能和高稳定性的OER电催化剂充满挑战。在此，我们采用双金属浸出诱导表面重构的策略，构建了高活性和高稳定性的水氧化电催化剂。在该策略中，通过水热、离子交换和后续的退火工艺处理，将由α-CoMoO₄、K₂Co₂(MoO₄)₃、Co₃O₄和CoFe₂O₄四种氧化物晶相组成的材料阵列转换为OER预催化剂。原位电化学拉曼光谱和非原位X射线衍射(XRD)分析表明，其中的不稳定成分K₂Co₂(MoO₄)₃的快速溶解引发了Mo和K的适度浸出，从而在低电压下加速了表面富集的α-Co(OH)₂向CoOOH活性相的转化。此外，CoFe₂O₄相耦合重构产生新相CoO与无定形层CoOOH，从而形成了CoFe₂O₄@CoO@CoOOH紧密的多相结构，起到了“纳米栅栏”的作用，可有效防止催化剂的过度重构，从而赋予重构后的催化剂优异的催化活性和稳定性。本工作为设计高电流密度下具有优异活性和稳定性的OER催化剂提供了新的思路。
- Oxygen evolution reaction,
- Surface reconstruction,
- Ion leaching,
- Water splitting,
- Electrocatalysis,
- Catalyst
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