Citation: Zhenfei Gao, Qingquan Song, Zhihua Xiao, Zhaolong Li, Tao Li, Jiajun Luo, Shanshan Wang, Wanli Zhou, Lanying Li, Junrong Yu, Jin Zhang. Submicron-Sized, High Crystalline Graphene-Reinforced Meta-Aramid Fibers with Enhanced Tensile Strength[J]. Acta Physico-Chimica Sinica, ;2023, 39(10): 230704. doi: 10.3866/PKU.WHXB202307046 shu

Submicron-Sized, High Crystalline Graphene-Reinforced Meta-Aramid Fibers with Enhanced Tensile Strength

Zhenfei Gao ^{1, 3, †} ,
Qingquan Song ^{2, †} ,
Zhihua Xiao ^{1, 3, 4, †} ,
Zhaolong Li ^{1, 3, 5} ,
Tao Li ³ ,
Jiajun Luo ^{1, 3} ,
Shanshan Wang ¹ ,
Wanli Zhou ⁶ ,
Lanying Li ^{1, 6} ,
Junrong Yu ^2,, ,
Jin Zhang ^{1, 3,,}

1.
School of Materials Science and Engineering, College of Chemistry and Molecular Engineering, Academy for Advanced Interdisciplinary Studies, Beijing Science and Engineering Center for Nanocarbons, Peking University, Beijing 100871, China
2.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
3.
Division of Graphene Fiber Technology, Beijing Graphene Institute, Beijing 100095, China
4.
State Key Laboratory of Heavy Oil, China University of Petroleum, Beijing 102249, China
5.
State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
6.
China Bluestar Chengrand Co., Ltd., Chengdu 610000, China

Corresponding author: Junrong Yu, yjr@dhu.edu.cn Jin Zhang, jinzhang@pku.edu.cn

^†

Received Date: 24 July 2023
Revised Date: 7 September 2023
Accepted Date: 8 September 2023
Available Online: 12 September 2023
Fund Project: the Ministry of Science and Technology of China 2022YFA1203302the Ministry of Science and Technology of China 2022YFA1203304the Ministry of Science and Technology of China 2016YFA0200100National Natural Science Foundation of China 52021006National Natural Science Foundation of China 51720105003National Natural Science Foundation of China 21790052National Natural Science Foundation of China 52102035Strategic Priority Research Program of CAS XDB36030100Beijing National Laboratory for Molecular Sciences BNLMS-CXTD-202001Science Foundation of China University of Petroleum (Beijing) ZX20230047

Aramid fiber is highly regarded for its outstanding properties and is widely used in various industrial applications. Among the different types of aramid fibers, meta-aramids, particularly poly(m-phenylene isophthalamide) (PMIA), are known for their exceptional flame retardance, high-temperature resistance, excellent electrical insulation, and remarkable chemical stability. As a result, PMIA-based materials find extensive use in industries focused on fire prevention, heat protection, and related applications. However, PMIA fibers have limitations due to the lack of conjugation between amide and benzene ring bonds in their molecular structure, resulting in flexible segments with low crystallinity, which in turn leads to inferior mechanical strength. Researchers have shown great interest in nanocomposites as a means to overcome these limitations. In this context, graphene nanocomposites have gained significant attention. Graphene, with its benzene ring arrangement within its layers, easily bonds with polymers possessing a similar structure. This property makes graphene a promising candidate for enhancing the mechanical strength of aromatic polymers like PMIA. Moreover, small-sized graphene particles exhibit superior dispersibility within fibrous polymer matrices, leading to more effective reinforcement compared to larger graphene sheets. Consequently, incorporating high-quality, small-sized graphene into polymer matrices can substantially improve the properties of these polymers. There is a growing demand for enhancing the mechanical characteristics of aramid fibers to expand their applications beyond traditional uses. This research demonstrates how sub-micron-sized graphene improves the structural integrity and mechanical strength of PMIA fibers. The results show a remarkable 46% enhancement in tensile strength compared to unmodified PMIA fibers. While the graphene/PMIA fiber exhibits exceptional mechanical properties, it also holds great potential for applications in wearables, flexible sensors, and various other domains, thanks to graphene's versatile characteristics. This research underscores the importance of utilizing small-sized, high-quality graphene to develop more robust carbonaceous nanocomposite fibers suitable for a wide range of commercial purposes. Beyond its immediate impact on PMIA fibers, this research represents a significant step forward in advancing the utilization and growth of graphene materials in various applications.
- Sub-micron-sized graphene,
- Meta-aramid fiber,
- Shear dispersion,
- Tensile strength,
- Internal structure optimization
1. [1]
  Tan, J.; Luo, Y.; Zhang, M.; Yang, B.; Li, F.; Ruan, S. ACS Appl. Mater. Interfaces 2021, 13 (14), 16895. doi: 10.1021/acsami.1c02075 doi: 10.1021/acsami.1c02075
2. [2]
  Pegoretti, A.; Traina, M. Handbook of Properties of Textile and Technical Fibres, 2nd ed.; Elsevier: Cambrige, United States, 2018; pp. 621–697.
3. [3]
  Tang, C.; Li, X.; Li, Z.; Tian, W.; Zhou, Q. Polymers 2018, 10 (12), 1348. doi: 10.3390/polym10121348 doi: 10.3390/polym10121348
4. [4]
  Nazaré, S. Advances in Fire Retardant Materials, 1st ed.; Elsevier: Cambrige, United States, 2008; pp. 492–526
5. [5]
  Patel, A.; Wilcox, K.; Li, Z.; George, I.; Juneja, R.; Lollar, C.; Lazar, S.; Grunlan, J.; Tenhaeff, W.; Lutkenhaus, J. ACS Appl. Mater. Interfaces 2020, 12 (23), 25756. doi: 10.1021/acsami.0c03671 doi: 10.1021/acsami.0c03671
6. [6]
  Horrocks, A.; Nazaré. S.; Masood, R.; Kandola, B.; Price, D. Polym. Adv. Technol. 2011, 22, 29. doi: 10.1002/pat.1707 doi: 10.1002/pat.1707
7. [7]
  Li, X.; Tang, C.; Wang, J.; Tian, W.; Hu, D. J. Mater. Sci. 2019, 54, 8556. doi: 10.1007/s10853-019-03476-x doi: 10.1007/s10853-019-03476-x
8. [8]
  Kang, W.; Deng, N.; Ma, X.; Ju, J.; Li, L.; Liu, X.; Cheng, B. Electrochim. Acta 2016, 216, 276. doi: 10.1016/j.electacta.2016.09.035 doi: 10.1016/j.electacta.2016.09.035
9. [9]
  Lu, Z.; Si, L.; Dang, W.; Zhao, Y. Compos. Part. A-Appl. Sci. Manuf. 2018, 115, 321. doi: 10.1016/j.compositesa.2018.10.009 doi: 10.1016/j.compositesa.2018.10.009
10. [10]
  Ramani, R.; Kotresh, T.; Shekar, R. I.; Sanal, F.; Singh, U.; Renjith, R.; Amarendra, G. Polymer 2018, 135, 39. doi: 10.1016/j.polymer.2017.11.064 doi: 10.1016/j.polymer.2017.11.064
11. [11]
  Yang, C.; Wu, H.; Dai, Y.; Tang, S.; Luo, L.; Liu, X. Polymer 2019, 180, 121687. doi: 10.1016/j.polymer.2019.121687 doi: 10.1016/j.polymer.2019.121687
12. [12]
  Chung, J.; Kwak, S. Eur. Polym. J. 2018, 107, 46. doi: 10.1016/j.eurpolymj.2018.07.051 doi: 10.1016/j.eurpolymj.2018.07.051
13. [13]
  Fei, B. Engineering of High-Performance Textiles, 1st ed.; Elsevier: Cambrige, United States, 2018; pp. 27–58.
14. [14]
  Lee, C.; Wei, X.; Kysar, J. W.; Hone, J. Science 2008, 321, 385. doi: 10.1126/science.1157996 doi: 10.1126/science.1157996
15. [15]
  Suk, J.; Piner, R.; An, J.; Ruoff, R. ACS Nano 2010, 4, 6557. doi: 10.1021/nn101781v doi: 10.1021/nn101781v
16. [16]
  Ramanathan, T.; Abdala, A.; Stankovich, S.; Dikin, D.; Herrera-Alonso, M.; Piner, R.; Adamson, D.; Schniepp, H.; Chen, X.; Ruoff, R.; et al. Nat. Nanotechnol. 2008, 3, 327. doi: 10.1038/nnano.2008.96 doi: 10.1038/nnano.2008.96
17. [17]
  Fan, J.; Shi, Z.; Zhang, L.; Wang, J.; Yin, J. Nanoscale 2012, 4, 7046. doi: 10.1039/C2NR31907A doi: 10.1039/C2NR31907A
18. [18]
  Yang, Z.; Jin, L.; Lu, G.; Xiao, Q.; Zhang, Y.; Jing, L.; Zhang, X.; Yan, Y.; Sun, K. Adv. Funct. Mater. 2014, 24, 3917. doi: 10.1002/adfm.201304091 doi: 10.1002/adfm.201304091
19. [19]
  Sun, K.; Dong, H.; Kou, Y.; Yang, H.; Liu, H.; Li, Y.; Shi, Q. Chem. Eng. J. 2021, 419, 129637. doi: 10.1016/j.cej.2021.129637 doi: 10.1016/j.cej.2021.129637
20. [20]
  Chen, S.; Wu, Q.; Mishra, C.; Kang, J.; Zhang, H.; Cho, K.; Cai, W.; Balandin, A.; Ruoff, R. Nat. Mater. 2012, 11, 203. doi: 10.1038/nmat3207 doi: 10.1038/nmat3207
21. [21]
  Stöberl, U.; Wurstbauer, U.; Wegscheider, W.; Weiss, D.; Eroms, J. Appl. Phys. Lett. 2008, 93, 051906. doi: 10.1063/1.2968310 doi: 10.1063/1.2968310
22. [22]
  Zhang, B.; Lian, T.; Shao, X.; Tian, M. Ind. Eng. Chem. Res. 2021, 60, 2472. doi: 10.1021/acs.iecr.0c05794 doi: 10.1021/acs.iecr.0c05794
23. [23]
  Sun, Y.; Chen, Z.; Gong, H.; Li, X.; Gao, Z.; Xu, S.; Han, X.; Han, B.; Meng, X.; Zhang, J. Adv. Mater. 2020, 32, 2002024. doi: 10.1002/adma.202002024 doi: 10.1002/adma.202002024
24. [24]
  Zeng, L.; Liu, X.; Chen, X.; Soutis, C. Compos. Part. B-Eng. 2021, 220, 108983. doi: 10.1016/j.compositesb.2021.108983 doi: 10.1016/j.compositesb.2021.108983
25. [25]
  Luo, T.; Lloyd, J. Adv. Funct. Mater. 2012, 22, 2495. doi: 10.1002/adfm.201103048 doi: 10.1002/adfm.201103048
26. [26]
  Song, Q.; Wu, W.; Wang, Y.; Yu, J.; Hu, Z.; Wang, Y. Adv. Fiber. Mater. 2022, 4, 436. doi: 10.1007/s42765-021-00110-x doi: 10.1007/s42765-021-00110-x
27. [27]
  Song, Q.; Feng, Y.; Wu, W.; Yu, J.; Hu, Z.; Wang, Y.; Zhu, J. J. Text. Inst. 2021, 112, 2004. doi: 10.1080/00405000.2020.1862491 doi: 10.1080/00405000.2020.1862491
28. [28]
  Sun, Y.; Yang, L.; Xia, K.; Liu, H.; Han, D.; Zhang, Y.; Zhang, J. Adv. Mater. 2018, 30, 1803189. doi: 10.1002/adma.201803189 doi: 10.1002/adma.201803189
29. [29]
  Moghaddam, M.; Goharshadi, E.; Entezari, M.; Nancarrow, P. Chem. Eng. J. 2013, 231, 365. doi: 10.1016/j.cej.2013.07.006 doi: 10.1016/j.cej.2013.07.006
30. [30]
  Chazot, C.; Damirchi, B.; Lee, B.; Van Duin, A.; Hart, A. Nano Lett. 2022, 22, 998. doi: 10.1021/acs.nanolett.1c03866 doi: 10.1021/acs.nanolett.1c03866
31. [31]
  Edwards, H.; Hakiki, S. Brit. Polym. J. 1989, 21, 505. doi: 10.1002/pi.4980210611 doi: 10.1002/pi.4980210611
32. [32]
  Malard, L.; Pimenta, M.; Dresselhaus, G.; Dresselhaus, M. Phys. Rep. 2009, 473, 51. doi: 10.1016/j.physrep.2009.02.003 doi: 10.1016/j.physrep.2009.02.003
1. [1]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
2. [2]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
3. [3]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
4. [4]
  Ze Wang , Hao Liang , Annan Liu , Xingchen Li , Lin Guan , Lei Li , Liang He , Andrew K. Whittaker , Bai Yang , Quan Lin . Strength through unity: Alkaline phosphatase-responsive AIEgen nanoprobe for aggregation-enhanced multi-mode imaging and photothermal therapy of metastatic prostate cancer. Chinese Chemical Letters, 2025, 36(2): 109765-. doi: 10.1016/j.cclet.2024.109765
5. [5]
  Hang Chen , Chengzhi Cui , Hebo Ye , Hanxun Zou , Lei You . Enhancing hydrolytic stability of dynamic imine bonds and polymers in acidic media with internal protecting groups. Chinese Chemical Letters, 2024, 35(5): 109145-. doi: 10.1016/j.cclet.2023.109145
6. [6]
  Haiyan Lu , Jiayue Ye , Yiping Wei , Hua Zhang , Konstantin Chingin , Vladimir Frankevich , Huanwen Chen . Tracing molecular margins of lung cancer by internal extractive electrospray ionization mass spectrometry. Chinese Chemical Letters, 2025, 36(2): 110077-. doi: 10.1016/j.cclet.2024.110077
7. [7]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
8. [8]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
9. [9]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
10. [10]
  Chuyuan Lin , Hui Lin , Lingxing Zeng . Optimization strategy for rechargeable Zn metal batteries over wide-pH aqueous electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100407-100407. doi: 10.1016/j.cjsc.2024.100407
11. [11]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
12. [12]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
13. [13]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
14. [14]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361
15. [15]
  Yuling Ma , Dongqing Liu , Tao Zhang , Chengjie Song , Dongmei Liu , Peizhi Wang , Wei Wang . Bimetallic composite carbon fiber with persulfate mediation for intercepting volatile organic compounds during solar interfacial evaporation. Chinese Chemical Letters, 2025, 36(3): 110000-. doi: 10.1016/j.cclet.2024.110000
16. [16]
  Xu-Hui Yue , Xiang-Wen Zhang , Hui-Min He , Lei Qiao , Zhong-Ming Sun . Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides. Chinese Chemical Letters, 2024, 35(7): 108907-. doi: 10.1016/j.cclet.2023.108907
17. [17]
  Si-Hua Liu , Jun-Hao Zhou , Jian-Ke Sun . Interconnecting zero-dimensional porous organic cages into sub-8 nm nanofilm for bio-inspired separation. Chinese Journal of Structural Chemistry, 2024, 43(7): 100312-100312. doi: 10.1016/j.cjsc.2024.100312
18. [18]
  Jiahao Li , Guinan Chen , Chunhong Chen , Yuanyuan Lou , Zhihao Xing , Tao Zhang , Chengtao Gong , Yongwu Peng . Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification. Chinese Chemical Letters, 2025, 36(1): 109760-. doi: 10.1016/j.cclet.2024.109760
19. [19]
  Jiayi Lu , Yizhang Li , Hao Jiang , Zhiwen Zhu , Fengru Zheng , Qiang Sun . Preparing sub-monolayer metals with continuous coverage spread for high-throughput growth of metal-organic frameworks. Chinese Chemical Letters, 2025, 36(3): 110394-. doi: 10.1016/j.cclet.2024.110394
20. [20]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(274)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142