Citation: Da Wang, Xiaobin Yin, Jianfang Wu, Yaqiao Luo, Siqi Shi. All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230702. doi: 10.3866/PKU.WHXB202307029 shu

All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation

Da Wang ^{1, 2} ,
Xiaobin Yin ¹ ,
Jianfang Wu ³ ,
Yaqiao Luo ¹ ,
Siqi Shi ^{1, 4,,}

1.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
2.
21C Innovation Laboratory (21C LAB), Contemporary Amperex Technology Ltd., Ningde 352100, Fujian Province, China
3.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
4.
Materials Genome Institute, Shanghai University, Shanghai 200444, China

Corresponding author: Siqi Shi, sqshi@shu.edu.cn
Received Date: 15 July 2023
Revised Date: 21 August 2023
Accepted Date: 28 August 2023
Available Online: 8 September 2023
Fund Project: the National Key Research and Development Program of China 2021YFB3802104the National Natural Science Foundation of China 52372208the National Natural Science Foundation of China U2030206the National Natural Science Foundation of China 11874254Innovation Laboratory, Contemporary Amperex Technology Ltd. 21C-OP-202205

All-solid-state batteries (ASSBs) using inorganic solid electrolytes (SEs) have emerged as crucial components in energy storage applications due to their superior safety and cycle life. In recent years, due to the extensive developments of SEs with high room temperature ionic conductivity (> 10⁻³ S·cm⁻¹), the sluggish diffusion kinetics of lithium ions in SEs are no longer the primary bottleneck impeding the enhancement of ASSBs. On the contrary, the notable resistance at the cathode/SE interface has emerged as a pressing issue demanding immediate resolution. The interfacial resistances arising from various factors, including the formation of the space-charge layer, interfacial chemical reactions, and lack of intimate contact, stand as fundamental reasons for a range of performance deteriorations, such as short cycling life, low coulombic efficiency, and poor power performance. These interconnected aspects further result in differences in the orders of magnitude of the reported interfacial resistances at different fabrication temperatures and/or routes, even within the same material system. Among these factors, the solid-solid contact or chemical reaction degree is closely related to the structural and electronic properties of the selected cathode and SE materials. The observed space-charge layer effect is universal and independent of the specific components or types of ion-conductive materials. Thus, obtaining a comprehensive understanding of the physics governing the space-charge layer at the interfaces of ASSBs is pivotal for researchers to fundamentally address the high interfacial resistance stemming from it. This forms the foundation for incorporating other mechanisms (such as interfacial reactions) to more accurately quantify interfacial resistance and expedite interface research in ASSBs. In this review, we strictly derive the theoretical model of the formation of the space-charge layer caused by the inherent chemical potential difference between the cathode and SE from fundamental concepts of (electro)chemical potential and electric potential, and reveal the physical picture of its influence on interfacial resistance. Subsequently, the most recent experimental characterizations and theoretical calculations of the space-charge layer at the cathode/SE interface are comprehensively discussed. While the existence of the space-charge layer is observable through experimentation, its characterization is complicated by factors like loss of interfacial contact and interfacial reactions. Therefore, it becomes imperative to further quantify the concentration of lithium ions in the space-charge layer and its impact on interfacial resistance through theoretical calculations. However, when combining the space-charge layer model with numerical and first-principles calculations to quantitatively study interfacial resistance, accurately determining the interfacial electric potential difference at the cathode/SE interface remains challenging, resulting in several orders of magnitude difference between predicted results and experimental measurements. Consequently, grounded in the foundational physical framework of the interfacial electric potential difference, the intricate connections between this potential difference and the electronic structure of the cathode/SE interface are explored. As a result, a strategy is proposed to ascertain the interfacial electric potential difference by directly calculating the Fermi level of the cathode and SE under real bonding conditions. This endeavor is anticipated to broaden the utility of the space-charge layer model in quantitatively calculating cathode/SE interfacial resistance, offering valuable insights for optimizing the cathode/SE interface and enhancing the overall performance of ASSBs.
- Cathode,
- Solid electrolyte,
- Space-charge layer,
- Interfacial electric-potential difference,
- Interfacial resistance
1. [1]
  Zhang, S.; Ma, J.; Dong, S.; Cui, G. Electrochem. Energy Rev. 2023, 6 (1), 4. doi: 10.1007/s41918-022-00143-9 doi: 10.1007/s41918-022-00143-9
2. [2]
  Huo, S.; Sheng, L.; Xue, W.; Wang, L.; Xu, H.; Zhang, H.; Su, B.; Lyu, M.; He, X. Adv. Energy Mater. 2023, 13 (15), 2204343. doi: 10.1002/aenm.202204343 doi: 10.1002/aenm.202204343
3. [3]
  Janek, J.; Zeier, W. G. Nat. Energy 2023, 8 (3), 230. doi: 10.1038/s41560-023-01208-9 doi: 10.1038/s41560-023-01208-9
4. [4]
  Bates, A. M.; Preger, Y.; Torres-Castro, L.; Harrison, K. L.; Harris, S. J.; Hewson, J. Joule 2022, 6 (4), 742. doi: 10.1016/j.joule.2022.02.007 doi: 10.1016/j.joule.2022.02.007
5. [5]
  Rettenwander, D.; Redhammer, G.; Preishuber-Pflügl, F.; Cheng, L.; Miara, L.; Wagner, R.; Welzl, A.; Suard, E.; Doeff, M. M.; Wilkening, M.; et al. Chem. Mater. 2016, 28 (7), 2384. doi: 10.1021/acs.chemmater.6b00579 doi: 10.1021/acs.chemmater.6b00579
6. [6]
  Liang, J.; Chen, N.; Li, X.; Li, X.; Adair, K. R.; Li, J.; Wang, C.; Yu, C.; Norouzi Banis, M.; Zhang, L.; et al. Chem. Mater. 2020, 32 (6), 2664. doi: 10.1021/acs.chemmater.9b04764 doi: 10.1021/acs.chemmater.9b04764
7. [7]
  Xu, G.; Luo, L.; Liang, J.; Zhao, S.; Yang, R.; Wang, C.; Yu, T.; Wang, L.; Xiao, W.; Wang, J.; et al. Nano Energy 2022, 92, 106674. doi: 10.1016/j.nanoen.2021.106674 doi: 10.1016/j.nanoen.2021.106674
8. [8]
  Zou, Z.; Li, Y.; Lu, Z.; Wang, D.; Cui, Y.; Guo, B.; Li, Y.; Liang, X.; Feng, J.; Li, H.; et al. Chem. Rev. 2020, 120 (9), 4169. doi: 10.1021/acs.chemrev.9b00760 doi: 10.1021/acs.chemrev.9b00760
9. [9]
  Jiang, Y.; Lai, A.; Ma, J.; Yu, K.; Zeng, H.; Zhang, G.; Huang, W.; Wang, C.; Chi, S.; Wang, J.; et al. ChemSusChem 2023, 16 (9), e202202156. doi: 10.1002/cssc.202202156 doi: 10.1002/cssc.202202156
10. [10]
  Gandi, S.; Chidambara Swamy Vaddadi, V. S.; Sripada Panda, S. S.; Goona, N. K.; Parne, S. R.; Lakavat, M.; Bhaumik, A. J. Power Sources 2022, 521, 230930. doi: 10.1016/j.jpowsour.2021.230930 doi: 10.1016/j.jpowsour.2021.230930
11. [11]
  Deng, Z.; Kumar, V.; Bölle, F. T.; Caro, F.; Franco, A. A.; Castelli, I. E.; Canepa, P.; Seh, Z. W. Energy Environ. Sci. 2022, 15 (2), 579. doi: 10.1039/D1EE02324A doi: 10.1039/D1EE02324A
12. [12]
  Wang, L.; Xie, R.; Chen, B.; Yu, X.; Ma, J.; Li, C.; Hu, Z.; Sun, X.; Xu, C.; Dong, S.; et al. Nat. Commun. 2020, 11 (1), 5889. doi: 10.1038/s41467-020-19726-5 doi: 10.1038/s41467-020-19726-5
13. [13]
  Yi, J.; He, P.; Liu, H.; Ni, H.; Bai, Z.; Fan, L.-Z. J. Energy Chem. 2021, 52, 202. doi: 10.1016/j.jechem.2020.03.057 doi: 10.1016/j.jechem.2020.03.057
14. [14]
  Park, B. K.; Kim, H.; Kim, K. S.; Kim, H.; Han, S. H.; Yu, J.; Hah, H. J.; Moon, J.; Cho, W.; Kim, K. J. Adv. Energy Mater. 2022, 12 (37), 2201208. doi: 10.1002/aenm.202201208 doi: 10.1002/aenm.202201208
15. [15]
  Tian, H.-K.; Qi, Y. J. Electrochem. Soc. 2017, 164 (11), E3512. doi: 10.1149/2.0481711jes doi: 10.1149/2.0481711jes
16. [16]
  Lewis, J. A.; Tippens, J.; Cortes, F. J. Q.; McDowell, M. T. Trends Chem. 2019, 1 (9), 845. doi: 10.1016/j.trechm.2019.06.013 doi: 10.1016/j.trechm.2019.06.013
17. [17]
  Kim, J.; Kim, M. J.; Kim, J.; Lee, J. W.; Park, J.; Wang, S. E.; Lee, S.; Kang, Y. C.; Paik, U.; Jung, D. S.; et al. Adv. Funct. Mater. 2023, 33 (12), 2211355. doi: 10.1002/adfm.202211355 doi: 10.1002/adfm.202211355
18. [18]
  Jung, S.-K.; Gwon, H.; Lee, S.-S.; Kim, H.; Lee, J. C.; Chung, J. G.; Park, S. Y.; Aihara, Y.; Im, D. J. Mater. Chem. A 2019, 7 (40), 22967. doi: 10.1039/C9TA08517C doi: 10.1039/C9TA08517C
19. [19]
  Gao, B.; Jalem, R.; Tateyama, Y. ACS Appl. Mater. Interfaces 2021, 13 (10), 11765. doi: 10.1021/acsami.0c19091 doi: 10.1021/acsami.0c19091
20. [20]
  Ren, F.; Liang, Z.; Zhao, W.; Zuo, W.; Lin, M.; Wu, Y.; Yang, X.; Gong, Z.; Yang, Y. Energy Environ. Sci. 2023, 16 (6), 2579. doi: 10.1039/D3EE00870C doi: 10.1039/D3EE00870C
21. [21]
  Swift, M. W.; Jagad, H.; Park, J.; Qie, Y.; Wu, Y.; Qi, Y. Curr. Opin. Solid State Mater. Sci. 2022, 26 (3), 100990. doi: 10.1016/j.cossms.2022.100990 doi: 10.1016/j.cossms.2022.100990
22. [22]
  Maier, J. Ber. Bunsen-Ges. Phys. Chem. 1984, 88 (11), 1057. doi: 10.1002/bbpc.198400007 doi: 10.1002/bbpc.198400007
23. [23]
  Maier, J. Prog. Solid State Chem. 1995, 23 (3), 171. doi: 10.1016/0079-6786(95)00004-E doi: 10.1016/0079-6786(95)00004-E
24. [24]
  Wu, J.-F.; Guo, X. Phys. Chem. Chem. Phys. 2017, 19 (8), 5880. doi: 10.1039/C6CP07757A doi: 10.1039/C6CP07757A
25. [25]
  Frenkel, J. Kinetic Theory of Liquids; Oxford University Press: Oxford, UK, 1946.
26. [26]
  Lehovec, K. J. Chem. Phys. 1953, 21 (7), 1123. doi: 10.1063/1.1699148 doi: 10.1063/1.1699148
27. [27]
  Kliewer, K. L.; Koehler, J. S. Phys. Rev. 1965, 140 (4A), A1226. doi: 10.1103/PhysRev.140.A1226 doi: 10.1103/PhysRev.140.A1226
28. [28]
  Liang, C. C. J. Electrochem. Soc. 1973, 120 (10), 1289. doi: 10.1149/1.2403248 doi: 10.1149/1.2403248
29. [29]
  Dudney, N. J. J. Am. Ceram. Soc. 1985, 68 (10), 538. doi: 10.1111/j.1151-2916.1985.tb11520.x doi: 10.1111/j.1151-2916.1985.tb11520.x
30. [30]
  Maier, J. J. Phys. Chem. Solids 1985, 46 (3), 309. doi: 10.1016/0022-3697(85)90172-6 doi: 10.1016/0022-3697(85)90172-6
31. [31]
  Jow, T.; Wagner, J. B. J. Electrochem. Soc. 1979, 126 (11), 1963. doi: 10.1149/1.2128835 doi: 10.1149/1.2128835
32. [32]
  Nakamura, O.; Goodenough, J. B. Solid State Ion. 1982, 7 (2), 119. doi: 10.1016/0167-2738(82)90004-2 doi: 10.1016/0167-2738(82)90004-2
33. [33]
  Maier, J. Ber. Bunsen-Ges. Phys. Chem. 1985, 89 (4), 355. doi: 10.1002/bbpc.19850890402 doi: 10.1002/bbpc.19850890402
34. [34]
  Modine, F. A.; Lubben, D.; Bates, J. B. J. Appl. Phys. 1993, 74 (4), 2658. doi: 10.1063/1.354657 doi: 10.1063/1.354657
35. [35]
  Maier, J. Ber. Bunsen-Ges. Phys. Chem. 1986, 90 (1), 26. doi: 10.1002/bbpc.19860900105 doi: 10.1002/bbpc.19860900105
36. [36]
  Maier, J.; Lauer, U. Ber. Bunsen-Ges. Phys. Chem. 1990, 94 (9), 973. doi: 10.1002/bbpc.19900940918 doi: 10.1002/bbpc.19900940918
37. [37]
  Guo, X.; Vasco, E.; Mi, S.; Szot, K.; Wachsman, E.; Waser, R. Acta Mater. 2005, 53 (19), 5161. doi: 10.1016/j.actamat.2005.07.033 doi: 10.1016/j.actamat.2005.07.033
38. [38]
  Guo, X.; Maier, J. Adv. Funct. Mater. 2009, 19 (1), 96. doi: 10.1002/adfm.200800805 doi: 10.1002/adfm.200800805
39. [39]
  Sata, N.; Eberman, K.; Eberl, K.; Maier, J. Nature 2000, 408 (6815), 946. doi: 10.1038/35050047 doi: 10.1038/35050047
40. [40]
  Ohta, N.; Takada, K.; Zhang, L.; Ma, R.; Osada, M.; Sasaki, T. Adv. Mater. 2006, 18 (17), 2226. doi: 10.1002/adma.200502604 doi: 10.1002/adma.200502604
41. [41]
  Balaya, P.; Li, H.; Kienle, L.; Maier, J. Adv. Funct. Mater. 2003, 13 (8), 621. doi: 10.1002/adfm.200304406 doi: 10.1002/adfm.200304406
42. [42]
  Maier, J. Angew. Chem. Int. Ed. 2013, 52 (19), 4998. doi: 10.1002/anie.201205569 doi: 10.1002/anie.201205569
43. [43]
  Maier, J. Nat. Mater. 2005, 4 (11), 805. doi: 10.1038/nmat1513 doi: 10.1038/nmat1513
44. [44]
  Li, C.; Gu, L.; Guo, X.; Samuelis, D.; Tang, K.; Maier, J. Nano Lett. 2012, 12 (3), 1241. doi: 10.1021/nl203623h doi: 10.1021/nl203623h
45. [45]
  Li, C.; Maier, J. Solid State Ion. 2012, 225, 408. doi: 10.1016/j.ssi.2012.02.036 doi: 10.1016/j.ssi.2012.02.036
46. [46]
  de Klerk, N. J. J.; Wagemaker, M. ACS Appl. Energy Mater. 2018, 10 (1), 5609. doi: 10.1021/acsaem.8b01141 doi: 10.1021/acsaem.8b01141
47. [47]
  Cheng, Z.; Liu, M.; Ganapathy, S.; Li, C.; Li, Z.; Zhang, X.; He, P.; Zhou, H.; Wagemaker, M. Joule 2020, 4 (6), 1311. doi: 10.1016/j.joule.2020.04.002 doi: 10.1016/j.joule.2020.04.002
48. [48]
  Takada, K.; Ohta, N.; Zhang, L.; Xu, X.; Hang, B. T.; Ohnishi, T.; Osada, M.; Sasaki, T. Solid State Ion. 2012, 225, 594. doi: 10.1016/j.ssi.2012.01.009 doi: 10.1016/j.ssi.2012.01.009
49. [49]
  Haruyama, J.; Sodeyama, K.; Han, L.; Takada, K.; Tateyama, Y. Chem. Mater. 2014, 26 (14), 4248. doi: 10.1021/cm5016959 doi: 10.1021/cm5016959
50. [50]
  Li, X.; Sun, Q.; Wang, Z.; Song, D.; Zhang, H.; Shi, X.; Li, C.; Zhang, L.; Zhu, L. J. Power Sources 2020, 456, 227997. doi: 10.1016/j.jpowsour.2020.227997 doi: 10.1016/j.jpowsour.2020.227997
51. [51]
  Liu, Y.; Yu, T.; Guo, S.; Zhou, H. Acta Phys. -Chim. Sin. 2023, 39, 2301027. doi: 10.3866/PKU.WHXB202301027
52. [52]
  Zhao, Y.; Chen, C.; Liu, W.; Hu, W.; Liu, J. Acta Phys. -Chim. Sin. 2023, 39, 2211017. doi: 10.3866/PKU.WHXB202211017
53. [53]
  Seino, Y.; Ota, T.; Takada, K. J. Power Sources 2011, 196 (15), 6488. doi: 10.1016/j.jpowsour.2011.03.090 doi: 10.1016/j.jpowsour.2011.03.090
54. [54]
  Sakuda, A.; Kitaura, H.; Hayashi, A.; Tadanaga, K.; Tatsumisago, M. J. Electrochem. Soc. 2009, 156 (1), A27. doi: 10.1149/1.3005972 doi: 10.1149/1.3005972
55. [55]
  Takada, K.; Ohta, N.; Zhang, L.; Fukuda, K.; Sakaguchi, I.; Ma, R.; Osada, M.; Sasaki, T. Solid State Ion. 2008, 179 (27–32), 1333. doi: 10.1016/j.ssi.2008.02.017 doi: 10.1016/j.ssi.2008.02.017
56. [56]
  Machida, N.; Kashiwagi, J.; Naito, M.; Shigematsu, T. Solid State Ion. 2012, 225, 354. doi: 10.1016/j.ssi.2011.11.026 doi: 10.1016/j.ssi.2011.11.026
57. [57]
  Woo, J. H.; Trevey, J. E.; Cavanagh, A. S.; Choi, Y. S.; Kim, S. C.; George, S. M.; Oh, K. H.; Lee, S.-H. J. Electrochem. Soc. 2012, 159 (7), A1120. doi: 10.1149/2.085207jes doi: 10.1149/2.085207jes
58. [58]
  Wang, C.-W.; Ren, F.-C.; Zhou, Y.; Yan, P.-F.; Zhou, X.-D.; Zhang, S.-J.; Liu, W.; Zhang, W.-D.; Zou, M.-H.; Zeng, L.-Y.; et al. Energy Environ. Sci. 2021, 14 (1), 437. doi: 10.1039/D0EE03212C doi: 10.1039/D0EE03212C
59. [59]
  Xu, Z.-M.; Bo, S.-H.; Zhu, H. ACS Appl. Mater. Interfaces 2018, 10 (43), 36941. doi: 10.1021/acsami.8b12026 doi: 10.1021/acsami.8b12026
60. [60]
  Nolan, A. M.; Liu, Y.; Mo, Y. ACS Energy Lett. 2019, 4 (10), 2444. doi: 10.1021/acsenergylett.9b01703 doi: 10.1021/acsenergylett.9b01703
61. [61]
  Zhang, H.; Liu, H.; Piper, L. F. J.; Whittingham, M. S.; Zhou, G. Chem. Rev. 2022, 122 (6), 5641. doi: 10.1021/acs.chemrev.1c00327 doi: 10.1021/acs.chemrev.1c00327
62. [62]
  Haruta, M.; Shiraki, S.; Suzuki, T.; Kumatani, A.; Ohsawa, T.; Takagi, Y.; Shimizu, R.; Hitosugi, T. Nano Lett. 2015, 15 (3), 1498. doi: 10.1021/nl5035896 doi: 10.1021/nl5035896
63. [63]
  Hart, F. X.; Bates, J. B. J. Appl. Phys. 1998, 83 (12), 7560. doi: 10.1063/1.367521 doi: 10.1063/1.367521
64. [64]
  Lucovsky, G.; Liang, W. Y.; White, R. M.; Pisharody, K. R. Solid State Commun. 1976, 19 (4), 303. doi: 10.1016/0038-1098(76)91337-5 doi: 10.1016/0038-1098(76)91337-5
65. [65]
  Trevey, J. E.; Stoldt, C. R.; Lee, S.-H. J. Electrochem. Soc. 2011, 158 (12), A1282. doi: 10.1149/2.017112jes doi: 10.1149/2.017112jes
66. [66]
  Cai, L.; Zhang, Q.; Mwizerwa, J. P.; Wan, H.; Yang, X.; Xu, X.; Yao, X. ACS Appl. Mater. Interfaces 2018, 10 (12), 10053. doi: 10.1021/acsami.7b18798 doi: 10.1021/acsami.7b18798
67. [67]
  Chen, F.; Kong, L.; Song, W.; Jiang, C.; Tian, S.; Yu, F.; Qin, L.; Wang, C.; Zhao, X. J. Materiomics 2019, 5 (1), 73. doi: 10.1016/j.jmat.2018.10.001 doi: 10.1016/j.jmat.2018.10.001
68. [68]
  Yada, C.; Ohmori, A.; Ide, K.; Yamasaki, H.; Kato, T.; Saito, T.; Sagane, F.; Iriyama, Y. Adv. Energy Mater. 2014, 4 (9), 1301416. doi: 10.1002/aenm.201301416 doi: 10.1002/aenm.201301416
69. [69]
  Kim, S.; Fleig, J.; Maier, J. Phys. Chem. Chem. Phys. 2003, 5 (11), 2268. doi: 10.1039/B300170A doi: 10.1039/B300170A
70. [70]
  Gregori, G.; Merkle, R.; Maier, J. Prog. Mater. Sci. 2017, 89, 252. doi: 10.1016/j.pmatsci.2017.04.009 doi: 10.1016/j.pmatsci.2017.04.009
71. [71]
  Yamamoto, K.; Iriyama, Y.; Asaka, T.; Hirayama, T.; Fujita, H.; Fisher, C. A. J.; Nonaka, K.; Sugita, Y.; Ogumi, Z. Angew. Chem. Int. Ed. 2010, 49 (26), 4414. doi: 10.1002/anie.200907319 doi: 10.1002/anie.200907319
72. [72]
  Masuda, H.; Ishida, N.; Ogata, Y.; Ito, D.; Fujita, D. Nanoscale 2017, 9 (2), 893. doi: 10.1039/C6NR07971G doi: 10.1039/C6NR07971G
73. [73]
  Tsuchiya, B.; Ohnishi, J.; Sasaki, Y.; Yamamoto, T.; Yamamoto, Y.; Motoyama, M.; Iriyama, Y.; Morita, K. Adv. Mater. Interfaces 2019, 6 (14), 1900100. doi: 10.1002/admi.201900100 doi: 10.1002/admi.201900100
74. [74]
  Katzenmeier, L.; Carstensen, L.; Schaper, S. J.; Müller-Buschbaum, P.; Bandarenka, A. S. Adv. Mater. 2021, 33 (24), 2100585. doi: 10.1002/adma.202100585 doi: 10.1002/adma.202100585
75. [75]
  Katzenmeier, L.; Helmer, S.; Braxmeier, S.; Knobbe, E.; Bandarenka, A. S. ACS Appl. Mater. Interfaces 2021, 13 (4), 5853. doi: 10.1021/acsami.0c21304 doi: 10.1021/acsami.0c21304
76. [76]
  Katzenmeier, L.; Carstensen, L.; Bandarenka, A. S. ACS Appl. Mater. Interfaces 2022, 14 (13), 15811. doi: 10.1021/acsami.2c00650 doi: 10.1021/acsami.2c00650
77. [77]
  Swift, M. W.; Qi, Y. Phys. Rev. Lett. 2019, 122 (16), 167701. doi: 10.1103/PhysRevLett.122.167701 doi: 10.1103/PhysRevLett.122.167701
78. [78]
  Liu, Y.; Bai, Y.; Jaegermann, W.; Hausbrand, R.; Xu, B.-X. ACS Appl. Mater. Interfaces 2021, 13 (4), 5895. doi: 10.1021/acsami.0c22986 doi: 10.1021/acsami.0c22986
79. [79]
  Sinzig, S.; Hollweck, T.; Schmidt, C. P.; Wall, W. A. J. Electrochem. Soc. 2023, 170 (4), 040513. doi: 10.1149/1945-7111/acc692 doi: 10.1149/1945-7111/acc692
80. [80]
  Katzenmeier, L.; Gößwein, M.; Gagliardi, A.; Bandarenka, A. S. J. Phys. Chem. C 2022, 126 (26), 10900. doi: 10.1021/acs.jpcc.2c02481 doi: 10.1021/acs.jpcc.2c02481
81. [81]
  Nomura, Y.; Yamamoto, K.; Hirayama, T.; Ouchi, S.; Igaki, E.; Saitoh, K. Angew. Chem. 2019, 131 (16), 5346. doi: 10.1002/ange.201814669 doi: 10.1002/ange.201814669
82. [82]
  Zhang, J.; Zheng, C.; Li, L.; Xia, Y.; Huang, H.; Gan, Y.; Liang, C.; He, X.; Tao, X.; Zhang, W. Adv. Energy Mater. 2020, 10 (4), 1903311. doi: 10.1002/aenm.201903311 doi: 10.1002/aenm.201903311
83. [83]
  Lu, G.; Geng, F.; Gu, S.; Li, C.; Shen, M.; Hu, B. ACS Appl. Mater. Interfaces 2022, 14 (22), 25556. doi: 10.1021/acsami.2c05239 doi: 10.1021/acsami.2c05239
84. [84]
  Fingerle, M.; Buchheit, R.; Sicolo, S.; Albe, K.; Hausbrand, R. Chem. Mater. 2017, 29 (18), 7675. doi: 10.1021/acs.chemmater.7b00890 doi: 10.1021/acs.chemmater.7b00890
85. [85]
  Tian, H.-K.; Jalem, R.; Gao, B.; Yamamoto, Y.; Muto, S.; Sakakura, M.; Iriyama, Y.; Tateyama, Y. ACS Appl. Mater. Interfaces 2020, 12 (49), 54752. doi: 10.1021/acsami.0c16463 doi: 10.1021/acsami.0c16463
86. [86]
  Wang, D.; Jiao, Y.; Shi, W.; Pu, B.; Ning, F.; Yi, J.; Ren, Y.; Yu, J.; Li, Y.; Wang, H.; et al. Prog. Mater. Sci. 2023, 133, 101055. doi: 10.1016/j.pmatsci.2022.101055 doi: 10.1016/j.pmatsci.2022.101055
87. [87]
  Goodenough, J. B.; Kim, Y. Chem. Mater. 2010, 22 (3), 587. doi: 10.1021/cm901452z doi: 10.1021/cm901452z
88. [88]
  Cherkashinin, G.; Hausbrand, R.; Jaegermann, W. J. Electrochem. Soc. 2019, 166 (3), A5308. doi: 10.1149/2.0441903jes doi: 10.1149/2.0441903jes
89. [89]
  Boettcher, S. W.; Oener, S. Z.; Lonergan, M. C.; Surendranath, Y.; Ardo, S.; Brozek, C.; Kempler, P. A. ACS Energy Lett. 2021, 6 (1), 261. doi: 10.1021/acsenergylett.0c02443 doi: 10.1021/acsenergylett.0c02443
90. [90]
  Yu, P.; Li, C.; Guo, X. J. Phys. Chem. C 2014, 118 (20), 10616. doi: 10.1021/jp5010693 doi: 10.1021/jp5010693
91. [91]
  Usiskin, R.; Lu, Y.; Popovic, J.; Law, M.; Balaya, P.; Hu, Y.-S.; Maier, J. Nat. Rev. Mater. 2021, 6 (11), 1020. doi: 10.1038/s41578-021-00324-w doi: 10.1038/s41578-021-00324-w
92. [92]
  Li, X.; Su, J.; Li, Z.; Zhao, Z.; Zhang, F.; Zhang, L.; Ye, W.; Li, Q.; Wang, K.; Wang, X.; et al. Sci. Bull. 2022, 67 (11), 1145. doi: 10.1016/j.scib.2022.04.001 doi: 10.1016/j.scib.2022.04.001
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沈阳化工大学材料科学与工程学院沈阳 110142