Citation: Ye Wang, Ruixiang Ge, Xiang Liu, Jing Li, Haohong Duan. An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230701. doi: 10.3866/PKU.WHXB202307019 shu

An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol

Ye Wang ¹ ,
Ruixiang Ge ¹ ,
Xiang Liu ¹ ,
Jing Li ¹ ,
Haohong Duan ^1,2,,

1.
Department of Chemistry, Tsinghua University, Beijing 100084, China;
2.
Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: Haohong Duan, hhduan@mail.tsinghua.edu.cn
Received Date: 11 July 2023
Revised Date: 25 August 2023
Accepted Date: 25 August 2023

Fund Project: This project was supported by Beijing Natural Science Foundation, China (JQ22003), the National Natural Science Foundation of China (21978147, 21935001) and Beijing Municipal Natural Science Foundation, China (2214063).

Nucleophile oxidation reaction (NOR) is emerging as a significant approach for the sustainable production of value-added chemicals. Among the various types, electrocatalytic glycerol oxidation reaction (GOR) stands out as a crucial method for producing C₁ to C₃ chemicals including formic acid (FA). Non-noble-metal-based (oxy)hydroxides have found extensive use in GOR, yet achieving industrially-demanded current densities (> 300 mA·cm^-2) at moderate potentials remains a challenge. It is well documented that GOR catalyzed by (oxy)hydroxides follows an indirect oxidation mechanism. Specifically, the nucleophile, glycerol, undergoes oxidation by the electrogenerated oxyhydroxides with electrophilic adsorption oxygen. Therefore, comprehending the evolution of the electrocatalyst in GOR is critically important. In this paper, we have developed molybdenum-doped nickel oxyhydroxides (Mo-NiOOH) through cyclic voltammetry (CV) activation of nickel molybdate (NiMoO₄). We demonstrated that Mo species leach from NiMoO₄, and the resulting Mo-NiOOH retains the nanosheet array morphology of NiMoO₄. We subjected the freshly prepared Mo-NiOOH to systematic characterizations employing techniques such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) mapping, Raman spectroscopy, inductively coupled plasma-mass spectrometry (ICP-MS), and X-ray photoelectron spectroscopy (XPS). The above structural characterizations confirm that Mo-NiOOH inherits the nanosheet array morphology of the NiMoO₄ precursor with reduced Mo content, thereby indicating the phase reconstruction from oxides to oxyhydroxides post CV activation. Furthermore, the Ni³⁺/Ni²⁺ ratio in Mo-NiOOH surpasses that in NiOOH derived from CV activation of Ni(OH)₂. Mo-NiOOH exhibits elevated electrochemically active surface areas (ECSAs) and a higher Ni³⁺/Ni²⁺ ratio compared to NiOOH obtained through CV activation of Ni(OH)₂, facilitating the Mo-NiOOH exhibits higher ratio of Ni³⁺/Ni²⁺, higher electrochemically active surface areas (ECSAs) than NiOOH, and facilitated oxidation of Ni²⁺ to Ni³⁺. Consequently, Mo-NiOOH requires a lower applied potential than NiOOH (1.51 V versus 1.84 V vs. reversible hydrogen electrode (RHE)) to achieve a high current density (400 mA·cm^-2). Additionally, Mo-NiOOH demonstrates higher Faradaic efficiency towards formate (FE_formate) in contrast to NiOOH (84.7% versus 59.6%), indicating enhanced carbon-carbon (C―C) bond cleavage due to Mo doping. Multi-potential step (STEP) experiments indicate that GOR catalyzed by NiOOH and Mo-NiOOH follows a similar indirect oxidation mechanism mediated by oxyhydroxides. Operando electrochemical impedance spectroscopy (EIS) and in situ Raman spectroscopy confirmed that Mo doping in NiOOH accelerates GOR kinetics and the oxidation of Ni²⁺ to Ni³⁺, contributing to the higher activity and formate selectivity of Mo-NiOOH than NiOOH. The strategy of surface modulation of oxyhydroxides through leaching of soluble anions offers guidelines for the rational design of high-performance NOR electrocatalysts.
- CV activation,
- Electrocatalysis,
- Glycerol electro-oxidation,
- Oxyhydroxides,
- Reconstruction
1. [1]
  (1) Zhou, H.; Li, Z.; Kong, X.; Duan, H. Chem. J. Chin. Univ. 2020, 41, 1449. doi:10.7503/cjcu20200212
2. [2]
  (2) Zeng, L.; Chen, Y.; Sun, M.; Huang, Q.; Sun, K.; Ma, J.; Li, J.; Tan, H.; Li, M.; Pan, Y.; et al. J. Am. Chem. Soc. 2023, 145, 17577. doi:10.1021/jacs.3c02570
3. [3]
  (3) Wang, T.; Cao, X.; Jiao, L. Angew. Chem. Int. Ed. 2022, 61. doi:10.1002/anie.202213328
4. [4]
  (4) Wang, F.; Duan, H. Chem Catal. 2022, 2, 644. doi:10.1016/j.checat.2022.03.014
5. [5]
  (5) Zhou, P.; Zhang, J. Sci. China Chem. 2023, 66, 1011. doi:10.1007/s11426-022-1511-2
6. [6]
  (6) Sheng, H.; Janes, A. N.; Ross, R. D.; Hofstetter, H.; Lee, K.; Schmidt, J. R.; Jin, S. Nat. Catal. 2022, 5, 716. doi:10.1038/s41929-022-00826-y
7. [7]
  (7) Kwon, Y.; Birdja, Y.; Spanos, I.; Rodriguez, P.; Koper, M. T. M. ACS Catal. 2012, 2, 759. doi:10.1021/cs200599g
8. [8]
  (8) Vo, T.-G.; Ho, P.-Y.; Chiang, C.-Y. Appl. Catal. B 2022, 300, 120723. doi:10.1016/j.apcatb.2021.120723
9. [9]
  (9) Dai, C.; Sun, L.; Liao, H.; Khezri, B.; Webster, R. D.; Fisher, A. C.; Xu, Z. J. J. Catal. 2017, 356, 14. doi:10.1016/j.jcat.2017.10.010
10. [10]
  (10) Yan, Y.; Zhou, H.; Xu, S.-M.; Yang, J.; Hao, P.; Cai, X.; Ren, Y.; Xu, M.; Kong, X.; Shao, M.; et al. J. Am. Chem. Soc. 2023, 145, 6144. doi:10.1021/jacs.2c11861
11. [11]
  (11) Morales, D. M.; Jambrec, D.; Kazakova, M. A.; Braun, M.; Sikdar, N.; Koul, A.; Brix, A. C.; Seisel, S.; Andronescu, C.; Schuhmann, W. ACS Catal. 2022, 12, 982. doi:10.1021/acscatal.1c04150
12. [12]
  (12) Wu, J. X.; Liu, X.; Hao, Y. M.; Wang, S. Y.; Wang, R.; Du, W.; Cha, S. S.; Ma, X. Y.; Yang, X. J.; Gong, M. Angew. Chem. Int. Ed. 2023, 62, e202216083. doi:10.1002/anie.202216083
13. [13]
  (13) Li, Y.; Wei, X.; Han, S.; Chen, L.; Shi, J. Angew. Chem. Int. Ed. 2021, 60, 21464. doi:10.1002/anie.202107510
14. [14]
  (14) Li, Y.; Wei, X.; Chen, L.; Shi, J.; He, M. Nat. Commun. 2019, 10, 5335. doi:10.1038/s41467-019-13375-z
15. [15]
  (15) Fan, L.; Ji, Y.; Wang, G.; Chen, J.; Chen, K.; Liu, X.; Wen, Z. J. Am. Chem. Soc. 2022, 144, 7224. doi:10.1021/jacs.1c13740
16. [16]
  (16) Bulushev, D. A.; Ross, J. R. H. ChemSusChem 2018, 11, 821. doi:10.1002/cssc.201702075
17. [17]
  (17) Govind Rajan, A.; Martirez, J. M. P.; Carter, E. A. J. Am. Chem. Soc. 2020, 142, 3600. doi:10.1021/jacs.9b13708
18. [18]
  (18) Huang, J.; Li, Y.; Zhang, Y.; Rao, G.; Wu, C.; Hu, Y.; Wang, X.; Lu, R.; Li, Y.; Xiong, J. Angew. Chem. Int. Ed. 2019, 58, 17458. doi:10.1002/anie.201910716
19. [19]
  (19) He, J.; Zou, Y.; Huang, Y.; Li, C.; Liu, Y.; Zhou, L.; Dong, C.-L.; Lu, X.; Wang, S. Sci. China Chem. 2020, 63, 1684. doi:10.1007/s11426-020-9844-2
20. [20]
  (20) Liu, B.; Xu, S.; Zhang, M.; Li, X.; Decarolis, D.; Liu, Y.; Wang, Y.; Gibson, E. K.; Catlow, C. R. A.; Yan, K. Green Chem. 2021, 23, 4034. doi:10.1039/d1gc00901j
21. [21]
  (21) Goetz, M. K.; Bender, M. T.; Choi, K.-S. Nat. Commun. 2022, 13. doi:10.1038/s41467-022-33637-7
22. [22]
  (22) Fu, G.; Kang, X.; Zhang, Y.; Yang, X.; Wang, L.; Fu, X.-Z.; Zhang, J.; Luo, J.-L.; Liu, J. Nano-Micro Lett. 2022, 14, 200. doi:10.1007/s40820-022-00940-3
23. [23]
  (23) Böhm, D.; Beetz, M.; Kutz, C.; Zhang, S.; Scheu, C.; Bein, T.; Fattakhova-Rohlfing, D. Chem. Mater. 2020, 32, 10394. doi:10.1021/acs.chemmater.0c02851
24. [24]
  (24) Zhao, P.; Ma, L.; Guo, J. J. Phys. Chem. Solids 2022, 164, 110634. doi:10.1016/j.jpcs.2022.110634
25. [25]
  (25) Qin, H.; Ye, Y.; Li, J.; Jia, W.; Zheng, S.; Cao, X.; Lin, G.; Jiao, L. Adv. Funct. Mater. 2022, 33, 2209698. doi:10.1002/adfm.202209698
26. [26]
  (26) Wang, F.; Zhang, K.; Li, S.; Zha, Q.; Ni, Y. ACS Sustain. Chem. Eng. 2022, 10, 10383. doi:10.1021/acssuschemeng.2c03166
27. [27]
  (27) Yan, J.; Kong, L.; Ji, Y.; White, J.; Li, Y.; Zhang, J.; An, P.; Liu, S.; Lee, S.-T.; Ma, T. Nat. Commun. 2019, 10, 2149. doi:10.1038/s41467-019-09845-z
28. [28]
  (28) Chen, W.; Xie, C.; Wang, Y.; Zou, Y.; Dong, C.-L.; Huang, Y.-C.; Xiao, Z.; Wei, Z.; Du, S.; Chen, C.; et al. Chem 2020, 6, 2974. doi:10.1016/j.chempr.2020.07.022
29. [29]
  (29) Bender, M. T.; Lam, Y. C.; Hammes-Schiffer, S.; Choi, K.-S. J. Am. Chem. Soc. 2020, 142, 21538. doi:10.1021/jacs.0c10924
30. [30]
  (30) Zhang, P.; Sun, L. Chin. J. Chem. 2020, 38, 996. doi:10.1002/cjoc.201900467
31. [31]
  (31) Duan, Y.; Lee, J. Y.; Xi, S.; Sun, Y.; Ge, J.; Ong, S. J. H.; Chen, Y.; Dou, S.; Meng, F.; Diao, C.; et al. Angew. Chem. Int. Ed. 2021, 60, 7418. doi:10.1002/anie.202015060
32. [32]
  (32) Wang, Y.; Zhu, Y.; Zhao, S.; She, S.; Zhang, F.; Chen, Y.; Williams, T.; Gengenbach, T.; Zu, L.; Mao, H.; et al. Matter 2020, 3, 2124. doi:10.1016/j.matt.2020.09.016
33. [33]
  (33) Liu, X.; Meng, J.; Ni, K.; Guo, R.; Xia, F.; Xie, J.; Li, X.; Wen, B.; Wu, P.; Li, M.; et al. Cell Rep. Phys. Sci. 2020, 1, 100241. doi:10.1016/j.xcrp.2020.100241
34. [34]
  (34) Lin, T.-W.; Dai, C.-S.; Hung, K.-C. Sci. Rep. 2014, 4, 7274. doi:10.1038/srep07274
35. [35]
  (35) Kuai, C.; Zhang, Y.; Han, L.; Xin, H. L.; Sun, C.-J.; Nordlund, D.; Qiao, S.; Du, X.-W.; Lin, F. J. Mater. Chem. A 2020, 8, 10747. doi:10.1039/d0ta04244g
36. [36]
  (36) Yang, C.; Wang, H.; Lu, S.; Wu, C.; Liu, Y.; Tan, Q.; Liang, D.; Xiang, Y. Electrochim. Acta 2015, 182, 834. doi:10.1016/j.electacta.2015.09.155
37. [37]
  (37) Kim, J.-H.; Kim, K. J.; Park, M.-S.; Lee, N. J.; Hwang, U.; Kim, H.; Kim, Y.-J. Electrochem. Commun. 2011, 13, 997. doi:10.1016/j.elecom.2011.06.022
38. [38]
  (38) Gouda, L.; Sévery, L.; Moehl, T.; Mas-Marzá, E.; Adams, P.; Fabregat-Santiago, F.; Tilley, S. D. Green Chem. 2021, 23, 8061. doi:10.1039/d1gc02031e
39. [39]
  (39) Liu, B.; Zheng, Z.; Liu, Y.; Zhang, M.; Wang, Y.; Wan, Y.; Yan, K. J. Energy Chem. 2023, 78, 412. doi:10.1016/j.jechem.2022.11.041
40. [40]
  (40) Chen, D.; Ding, Y.; Cao, X.; Wang, L.; Lee, H.; Lin, G.; Li, W.; Ding, G.; Sun, L. Angew. Chem. Int. Ed. 2023, e202309478. doi:10.1002/anie.202309478
41. [41]
  (41) Sun, Y.; Shin, H.; Wang, F.; Tian, B.; Chiang, C.-W.; Liu, S.; Li, X.; Wang, Y.; Tang, L.; Goddard, W. A.; et al. J. Am. Chem. Soc. 2022, 144, 15185. doi:10.1021/jacs.2c05403
42. [42]
  (42) Tao, S.; Wen, Q.; Jaegermann, W.; Kaiser, B. ACS Catal. 2022, 12, 1508. doi:10.1021/acscatal.1c04589
43. [43]
  (43) Deabate, S.; Fourgeot, F.; Henn, F. J. Power Sources 2000, 87, 125. doi:10.1016/S0378-7753(99)00437-1
44. [44]
  (44) Zhou, D.; Wang, S.; Jia, Y.; Xiong, X.; Yang, H.; Liu, S.; Tang, J.; Zhang, J.; Liu, D.; Zheng, L.; et al. Angew. Chem. Int. Ed. 2019, 58, 736. doi:10.1002/anie.201809689
45. [45]
  (45) Solomon, G.; Landström, A.; Mazzaro, R.; Jugovac, M.; Moras, P.; Cattaruzza, E.; Morandi, V.; Concina, I.; Vomiero, A. Adv. Energy Mater. 2021, 11, 2101324. doi:10.1002/aenm.202101324
46. [46]
  (46) Dürr, R. N.; Maltoni, P.; Tian, H.; Jousselme, B.; Hammarström, L.; Edvinsson, T. ACS Nano 2021, 15, 13504. doi:10.1021/acsnano.1c04126
47. [47]
48. [48]
  (48) Chen, P.; Cao, C.; Ding, C.; Yin, Z.; Qi, S.; Guo, J.; Zhang, M.; Sun, Z. J. Power Sources 2022, 521, 230920. doi:10.1016/j.jpowsour.2021.230920
49. [49]
  (49) Wang, L.; Zhang, L.; Ma, W.; Wan, H.; Zhang, X.; Zhang, X.; Jiang, S.; Zheng, J. Y.; Zhou, Z. Adv. Funct. Mater. 2022, 32, 2203342. doi:10.1002/adfm.202203342
50. [50]
  (50) Menezes, P. W.; Yao, S.; Beltrán-Suito, R.; Hausmann, J. N.; Menezes, P. V.; Driess, M. Angew. Chem. Int. Ed. 2021, 133, 4690. doi:10.1002/anie.202014331
51. [51]
  (51) Zhong, M.; Hisatomi, T.; Kuang, Y.; Zhao, J.; Liu, M.; Iwase, A.; Jia, Q.; Nishiyama, H.; Minegishi, T.; Nakabayashi, M.; et al. J. Am. Chem. Soc. 2015, 137, 5053. doi:10.1021/jacs.5b00256
52. [52]
  (52) Zheng, X.; Cao, Y.; Han, X.; Liu, H.; Wang, J.; Zhang, Z.; Wu, X.; Zhong, C.; Hu, W.; Deng, Y. Sci. China Mater. 2019, 62, 1096. doi:10.1007/s40843-019-9413-5
53. [53]
  (53) Owusu, K. A.; Qu, L.; Li, J.; Wang, Z.; Zhao, K.; Yang, C.; Hercule, K. M.; Lin, C.; Shi, C.; Wei, Q.; et al. Nat. Commun. 2017, 8, 14264. doi:10.1038/ncomms14264
54. [54]
  (54) Pang, X.; Bai, H.; Zhao, H.; Fan, W.; Shi, W. ACS Catal. 2022, 12, 1545. doi:10.1021/acscatal.1c04880
55. [55]
  (55) Idriss, H. Surf. Sci. 2021, 712, 121894. doi:10.1016/j.susc.2021.121894
56. [56]
  (56) Xiao, Z.; Huang, Y.-C.; Dong, C.-L.; Xie, C.; Liu, Z.; Du, S.; Chen, W.; Yan, D.; Tao, L.; Shu, Z.; et al. J. Am. Chem. Soc. 2020, 142, 12087. doi:10.1021/jacs.0c00257
57. [57]
  (57) Ye, F.; Zhang, S.; Cheng, Q.; Long, Y.; Liu, D.; Paul, R.; Fang, Y.; Su, Y.; Qu, L.; Dai, L.; et al. Nat. Commun. 2023, 14. doi:10.1038/s41467-023-37679-3
58. [58]
  (58) Chen, Y.-Y.; Zhang, Y.; Zhang, X.; Tang, T.; Luo, H.; Niu, S.; Dai, Z.-H.; Wan, L.-J.; Hu, J.-S. Adv. Mater. 2017, 29, 1703311. doi:10.1002/adma.201703311
59. [59]
  (59) Kong, X.; Zhang, C.; Hwang, S. Y.; Chen, Q.; Peng, Z. Small 2017, 13, 1700334. doi:10.1002/smll.201700334
60. [60]
  (60) Deng, X.; Xu, G. Y.; Zhang, Y. J.; Wang, L.; Zhang, J.; Li, J. F.; Fu, X. Z.; Luo, J. L. Angew. Chem. Int. Ed. 2021, 60, 20535. doi:10.1002/anie.202108955
61. [61]
62. [62]
  (62) Zhang, Y.; Ouyang, B.; Xu, J.; Chen, S.; Rawat, R. S.; Fan, H. J. Adv. Energy Mater. 2016, 6, 1600221. doi:10.1002/aenm.201600221
63. [63]
  (63) Suen, N.-T.; Hung, S.-F.; Quan, Q.; Zhang, N.; Xu, Y.-J.; Chen, H. M. Chem. Soc. Rev. 2017, 46, 337. doi:10.1039/c6cs00328a
64. [64]
  (64) Wu, J.; Li, J.; Li, Y.; Ma, X. Y.; Zhang, W. Y.; Hao, Y.; Cai, W. B.; Liu, Z. P.; Gong, M. Angew. Chem. Int. Ed. 2022, 61, e202113362. doi:10.1002/anie.202113362
65. [65]
  (65) Ge, R.; Li, J.; Duan, H. Sci. China Mater. 2022, 65, 3273. doi:10.1007/s40843-022-2076-y
66. [66]
  (66) Wang, Y.; Zhu, Y.-Q.; Xie, Z.; Xu, S.-M.; Xu, M.; Li, Z.; Ma, L.; Ge, R.; Zhou, H.; Li, Z.; et al. ACS Catal. 2022, 12, 12432. doi:10.1021/acscatal.2c03162
67. [67]
  (67) Ge, R.; Wang, Y.; Li, Z.; Xu, M.; Xu, S. M.; Zhou, H.; Ji, K.; Chen, F.; Zhou, J.; Duan, H. Angew. Chem. Int. Ed. 2022, 61, e202200211. doi:10.1002/anie.202200211
68. [68]
  (68) Zhou, P.; Lv, X.; Tao, S.; Wu, J.; Wang, H.; Wei, X.; Wang, T.; Zhou, B.; Lu, Y.; Frauenheim, T.; et al. Adv. Mater. 2022, 2204089. doi:10.1002/adma.202204089
69. [69]
  (69) Xue, X.; Wang, Y.; Zhou, L.; Ge, R.; Yang, J.; Kong, X.; Xu, M.; Li, Z.; Ma, L.; Duan, H. Chin. J. Chem. 2022, 40, 2741. doi:10.1002/cjoc.202200414
70. [70]
  (70) Zhu, Y.-Q.; Zhou, H.; Dong, J.; Xu, S.-M.; Xu, M.; Zheng, L.; Xu, Q.; Ma, L.; Li, Z.; Shao, M.; et al. Angew. Chem. Int. Ed. 2023, 62, e202219048. doi:10.1002/anie.202219048
71. [71]
  (71) Zhou, B.; Li, Y.; Zou, Y.; Chen, W.; Zhou, W.; Song, M.; Wu, Y.; Lu, Y.; Liu, J.; Wang, Y.; et al. Angew. Chem. Int. Ed. 2021, 60, 22908. doi:10.1002/anie.202109211
72. [72]
  (72) Chen, W.; Wang, Y.; Wu, B.; Shi, J.; Li, Y.; Xu, L.; Xie, C.; Zhou, W.; Huang, Y. C.; Wang, T.; et al. Adv. Mater. 2022, 34, 2105320. doi:10.1002/adma.202105320
73. [73]
  (73) Wang, H.-Y.; Hung, S.-F.; Chen, H.-Y.; Chan, T.-S.; Chen, H. M.; Liu, B. J. Am. Chem. Soc. 2016, 138, 36. doi:10.1021/jacs.5b10525
74. [74]
  (74) Qi, Y.; Zhang, Y.; Yang, L.; Zhao, Y.; Zhu, Y.; Jiang, H.; Li, C. Nat. Commun. 2022, 13, 4602. doi:10.1038/s41467-022-32443-5
75. [75]
  (75) Tang, L.; Xia, M.; Cao, S.; Bo, X.; Zhang, S.; Zhang, Y.; Liu, X.; Zhang, L.; Yu, L.; Deng, D. Nano Energy 2022, 101, 107562. doi:10.1016/j.nanoen.2022.107562
76. [76]
  (76) Gu, K.; Wang, D.; Xie, C.; Wang, T.; Huang, G.; Liu, Y.; Zou, Y.; Tao, L.; Wang, S. Angew. Chem. Int. Ed. 2021, 60, 20253. doi:10.1002/anie.202107390
77. [77]
  (77) Wang, S.; Chen, W.; Xu, L.; Zhu, X.; Huang, Y.-C.; Zhou, W.; Wang, D.; Zhou, Y.; Du, S.; Li, Q.; et al. Angew. Chem. Int. Ed. 2020, 60, 7297. doi:10.1002/anie.202015773
78. [78]
  (78) Qi, Y.; Zhang, Y.; Yang, L.; Zhao, Y.; Zhu, Y.; Jiang, H.; Li, C. Nat. Commun. 2022, 13, 4602. doi:10.1038/s41467-022-32443-5
79. [79]
  (79) Kuang, Z.; Liu, S.; Li, X.; Wang, M.; Ren, X.; Ding, J.; Ge, R.; Zhou, W.; Rykov, A. I.; Sougrati, M. T.; et al. J. Energy Chem. 2021, 57, 212. doi:10.1016/j.jechem.2020.09.014
80. [80]
  (80) Xu, J.; Wang, B.-X.; Lyu, D.; Wang, T.; Wang, Z. Int. J. Hydrog. Energy 2023, 48, 10724. doi:10.1016/j.ijhydene.2022.12.118
81. [81]
  (81) Bai, L.; Lee, S.; Hu, X. Angew. Chem. Int. Ed. 2021, 60, 3095. doi:10.1002/anie.202011388
82. [82]
  (82) Lee, S.; Bai, L.; Hu, X. Angew. Chem. Int. Ed. 2020, 59, 8072. doi:10.1002/anie.201915803
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20. [20]
  .
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沈阳化工大学材料科学与工程学院沈阳 110142