Citation: Jingkun Yu, Xue Yong, Ang Cao, Siyu Lu. Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230701. doi: 10.3866/PKU.WHXB202307015 shu

Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity

Jingkun Yu ¹ ,
Xue Yong ^2,, ,
Ang Cao ³ ,
Siyu Lu ^1,,

1.
Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
2.
Department of Chemistry, University of Sheffield, Sheffield, S37HF, UK
3.
Department of Physics, Technical University of Denmark, Kongens Lyngby 2800, Denmark

Corresponding author: Xue Yong, x.yong@sheffield.ac.uk Siyu Lu, sylu2013@zzu.edu.cn
Received Date: 6 July 2023
Revised Date: 22 August 2023
Accepted Date: 23 August 2023
Available Online: 28 August 2023
Fund Project: the National Natural Science Foundation of China 51973200the National Natural Science Foundation of China 52122308

Designing efficient single-atom catalysts (SACs) with high selectivity for the electrocatalytic reduction of nitrate to ammonia formation is both crucial and challenging. This challenge arises due to the intricate and competitive electronic interactions among intermediates, metal active centers, and coordination environments. In this work, we present a comprehensive investigation detailing how to enhance the activity and selectivity of the electrocatalytic nitrate reduction reaction (NO₃RR) by transitioning from single-layer SACs to bilayer SACs (BSACs). This enhancement is achieved through axial d–d orbital hybridization, as elucidated by a systematic study of 27 SACs and BSACs utilizing density functional theory (DFT) calculations. Considering potential pathways involving O-terminal, N-terminal, NO-terminal, and NO-dimer configurations, our calculations reveal that among monolayer SAC candidates, Ti-Pc and V-Pc exhibit low limiting potentials (U_L) of −0.24 and −0.48 V, respectively. Furthermore, analyses of formation energy, dissolution potential, and ab initio molecular dynamics results demonstrate the robust stability of these catalysts under reaction conditions. In these single-layer transition metal (TM)-Pc complexes, the d-band energy levels and occupation numbers are influenced by d_xz/d_yz and p_z orbital hybridizations. Notably, the presence of axial d_z² orbitals introduces a novel avenue for fine-tuning d-band characteristics and reactivity through d_z²–d_z² interactions. Building on these insights, the formation of BSACs using Ti-Pc and V-Pc as substrates, facilitated by axial d–d orbital hybridization, offers a distinctive approach to modulating the catalytic performance of NO₃RR. Significantly, we establish a two-dimensional volcano correlation encompassing the d-band center (ε_d), d_xz + d_yz orbital occupation numbers, and U_L to describe NO₃RR catalytic efficacy. Optimal BSACs should possess concurrent appropriate ε_d and d_xz + d_yz occupation numbers. Remarkably, Ti-Mo and Ti-Ta BSACs emerge as exceptional NO₃RR catalyst candidates, both displaying a remarkably low U_L of −0.13 V. The hybridization between d_z²–d_z² orbitals heightens charge transfer and structural stability within double-layer metals. The scarcity of contiguous metal sites introduces a substantial energy barrier hindering NO₂, NO, and N₂ formation, effectively suppressing NO₃RR by-products. In summation, this investigation imparts valuable insights into effectively enhancing nitrate reduction on SACs and BSACs, offering valuable guidance for advancing electrocatalyst development.
- Nitrate reduction,
- First-principles calculation,
- Single-atom catalysts,
- Bilayer single-atom catalysts,
- Axial orbital hybridization
1. [1]
  Kim, H. E.; Kim, J.; Ra, E. C.; Zhang, H.; Jang, Y. J.; Lee, J. S. Angew. Chem. Int. Ed. 2022, 61, e202204117. doi: 10.1002/anie.202204117z doi: 10.1002/anie.202204117z
2. [2]
  Chen, F.-Y.; Wu, Z.-Y.; Gupta, S.; Rivera, D. J.; Lambeets, S. V.; Pecaut, S.; Kim, J. Y. T.; Zhu, P.; Finfrock, Y. Z.; Meira, D. M.; et al. Nat. Nanotechnol. 2022, 17, 759. doi: 10.1038/s41565-022-01121-4 doi: 10.1038/s41565-022-01121-4
3. [3]
  Liang, J.; Liu, Q.; Alshehri, A. A.; Sun, X. Nano Res. Energy 2022, 1, e9120010. doi: 10.26599/NRE.2022.9120010 doi: 10.26599/NRE.2022.9120010
4. [4]
  Song, W.; Yue, L.; Fan, X.; Luo, Y.; Ying, B.; Sun, S.; Zheng, D.; Liu, Q.; Hamdy, M. S.; Sun, X. Inorg. Chem. Front. 2023, 10, 3489. doi: 10.1039/D3QI00554B doi: 10.1039/D3QI00554B
5. [5]
  Li, Z.; Liang, J.; Liu, Q.; Xie, L.; Zhang, L.; Ren, Y.; Yue, L.; Li, N.; Tang, B.; Alshehri, A. A.; et al. Mater. Today Phys. 2022, 23, 100619. doi: 10.1016/j.mtphys.2022.100619 doi: 10.1016/j.mtphys.2022.100619
6. [6]
  Liu, Q.; Xie, L.; Liang, J.; Ren, Y.; Wan, G.; Zhang, Y. L.; Yue, L.; Li, T.; Luo, Y.; Li, N.; et al. Small 2022, 18, 2106961. doi: 10.1002/smll.202106961 doi: 10.1002/smll.202106961
7. [7]
  Xu, X.; Hu, L.; Li, Z.; Xie, L.; Sun, S.; Zhang, L.; Li, J.; Luo, Y.; Yan, X.; Hamdy, et al. Sustain. Energy Fuels 2022, 6, 4130. doi: 10.1039/D2SE00830K doi: 10.1039/D2SE00830K
8. [8]
  Zhao, D.; Ma, C.; Li, J.; Li, R.; Fan, X.; Zhang, L.; Dong, K.; Luo, Y.; Zheng, D.; Sun, S.; et al. Inorg. Chem. Front. 2022, 9, 6412. doi: 10.1039/D2QI01791A doi: 10.1039/D2QI01791A
9. [9]
  Lu, X.; Yu, J.; Cai, J.; Zhang, Q.; Yang, S.; Gu, L.; Waterhouse, G. I. N.; Zang, S.-Q.; Yang, B.; Lu, S. Cell Rep. Phys. Sci. 2022, 3, 100961. doi: 10.1016/j.xcrp.2022.100961 doi: 10.1016/j.xcrp.2022.100961
10. [10]
  Cai, J.; Huang, J.; Cao, A.; Wei, Y.; Wang, H.; Li, X.; Jiang, Z.; Waterhouse, G. I. N.; Lu, S.; Zang, S.-Q. Appl. Catal. B Environ. 2023, 328, 122473. doi: 10.1016/j.apcatb.2023.122473 doi: 10.1016/j.apcatb.2023.122473
11. [11]
  Lin, L.; Li, H.; Wang, Y.; Li, H.; Wei, P.; Nan, B.; Si, R.; Wang, G.; Bao, X. Angew. Chem. Int. Ed. 2021, 60, 26582. doi: 10.1002/ange.202113135 doi: 10.1002/ange.202113135
12. [12]
  Wu, M.; Zhang, Y.; Fu, Z.; Lyu, Z.; Li, Q.; Wang, J. Acta Phys.-Chim. Sin. 2023, 39, 2207007. doi: 10.3866/PKU.WHXB202207007
13. [13]
  Shen, T.; Huang, X.; Xi, S.; Li, W.; Sun, S.; Hou, Y. J. Energy Chem. 2022, 68, 184. doi: 10.1016/j.jechem.2021.10.027 doi: 10.1016/j.jechem.2021.10.027
14. [14]
  Lv, X.; Wei, W.; Zhao, P.; Er, D.; Huang, B.; Dai, Y.; Jacob, T. J. Catal. 2019, 378, 97. doi: 10.1016/j.jcat.2019.08.019 doi: 10.1016/j.jcat.2019.08.019
15. [15]
  Luo, Y.; Wang, D. Acta Phys.-Chim. Sin. 2023, 39, 2212020. doi: 10.3866/PKU.WHXB202212020
16. [16]
  Giulimondi, V.; Mitchell, S.; Pérez-Ramírez, J. ACS Catal. 2023, 13, 2981. doi: 10.1021/acscatal.2c05992 doi: 10.1021/acscatal.2c05992
17. [17]
  Hung, S. F.; Xu, A.; Wang, X.; Li, F.; Hsu, S. H.; Li, Y.; Wicks, J.; Cervantes, E. G.; Rasouli, A. S.; Li, Y. C.; et al. Nat. Commun. 2022, 13, 819. doi: 10.1038/s41467-022-28456-9 doi: 10.1038/s41467-022-28456-9
18. [18]
  Wang, Y.; Liang, Y.; Bo, T.; Meng, S.; Liu, M. J. Phys. Chem. Lett. 2022, 13, 5969. doi: 10.1021/acs.jpclett.2c01381 doi: 10.1021/acs.jpclett.2c01381
19. [19]
  Li, X.; Chen, T.; Yang, B.; Xiang, Z. Angew. Chem. Int. Ed. 2023, 62, e202215441. doi: 10.1002/ange.202215441 doi: 10.1002/ange.202215441
20. [20]
  Bai, L.; Hsu, C.-S.; Alexander, D. T. L.; Chen, H. M.; Hu, X. Nat. Energy 2021, 6, 1054. doi: 10.1038/s41560-021-00925-3 doi: 10.1038/s41560-021-00925-3
21. [21]
  Zhang, Y. X.; Zhang, S.; Huang, H.; Liu, X.; Li, B.; Lee, Y.; Wang, X.; Bai, Y.; Sun, M.; Wu, Y.; et al. J. Am. Chem. Soc. 2023, 145, 4819. doi: 10.1021/jacs.2c13886 doi: 10.1021/jacs.2c13886
22. [22]
  Hu, R.; Li, Y.; Wang, F.; Shang, J. Nanoscale 2020, 12, 20413. doi: 10.1039/D0NR05202G doi: 10.1039/D0NR05202G
23. [23]
  Wu, X.; Wang, Q.; Yang, S.; Zhang, J.; Cheng, Y.; Tang, H.; Ma, L.; Min, X.; Tang, C.; Jiang, S. P.; et al. Energy Environ. Sci. 2022, 15, 1183. doi: 10.1039/D1EE03311E doi: 10.1039/D1EE03311E
24. [24]
  Lv, X. S.; Mou, T.; Li, J. W.; Kou, L. Z.; Frauenheim, T. Adv. Funct. Mater. 2022, 32, 2201262. doi: 10.1002/adfm.202201262 doi: 10.1002/adfm.202201262
25. [25]
  Zhang, K.; Xu, J.; Yan, T.; Jia, L.; Zhang, J.; Shao, C.; Zhang, L.; Han, N.; Li, Y. Adv. Funct. Mater. 2023, 33, 2214062. doi: 10.1002/adfm.202214062 doi: 10.1002/adfm.202214062
26. [26]
  Wang, T.; Zhou, L.; Xia, S.; Yu, L. J. Phys. Chem. C 2023, 127, 2963. doi: 10.1021/acs.jpcc.2c08319 doi: 10.1021/acs.jpcc.2c08319
27. [27]
  Kresse, G.; Furthmüller, J. Comput. Mater. Sci. 1996, 6, 15. doi: 10.1016/0927-0256(96)00008-0 doi: 10.1016/0927-0256(96)00008-0
28. [28]
  Kresse, G.; Hafner, J. Phys. Rev. B 1993, 47, 558. doi: 10.1103/PhysRevB.47.558 doi: 10.1103/PhysRevB.47.558
29. [29]
  Hammer, B.; Hansen, L. B.; Nørskov, J. K. Phys. Rev. B 1999, 59, 7413. doi: 10.1103/PhysRevB.59.7413 doi: 10.1103/PhysRevB.59.7413
30. [30]
  Perdew, J. P.; Chevary, J. A.; Vosko, S. H.; Jackson, K. A.; Pederson, M. R.; Singh, D. J.; Fiolhais, C. Phys. Rev. B 1993, 48, 4978. doi: 10.1103/PhysRevB.48.4978.2 doi: 10.1103/PhysRevB.48.4978.2
31. [31]
  Blöchl, P. E. Phys. Rev. B 1994, 50, 17953. doi: 10.1103/PhysRevB.50.17953 doi: 10.1103/PhysRevB.50.17953
32. [32]
  Grimme, S. J. Comput. Chem. 2006, 27, 1787. doi: 10.1002/jcc.20495 doi: 10.1002/jcc.20495
33. [33]
  Monkhorst, H. J.; Pack, J. D. Phys. Rev. B 1976, 13, 5188. doi: 10.1103/PhysRevB.13.5188 doi: 10.1103/PhysRevB.13.5188
34. [34]
  Tang, W.; Sanville, E.; Henkelman, G. J. Phys. Condens. Matter 2009, 21, 084204. doi: 10.1088/0953-8984/21/8/084204 doi: 10.1088/0953-8984/21/8/084204
35. [35]
  Nosé, S. J. Chem. Phys. 1984, 81, 511. doi: 10.1063/1.447334 doi: 10.1063/1.447334
36. [36]
  Nelson, R.; Ertural, C.; George, J.; Deringer, V. L.; Hautier, G.; Dronskowski, R. J. Comput. Chem. 2020, 41, 1931. doi: 10.1002/jcc.26353 doi: 10.1002/jcc.26353
37. [37]
  Wang, V.; Xu, N.; Liu, J.-C.; Tang, G.; Geng, W.-T. Comput. Phys. Commun. 2021, 267, 108033. doi: 10.1016/j.cpc.2021.108033 doi: 10.1016/j.cpc.2021.108033
38. [38]
  Chen, Z. W.; Chen, L. X.; Jiang, M.; Chen, D.; Wang, Z. L.; Yao, X.; Singh, C. V.; Jiang, Q. J. Mater. Chem. A 2020, 8, 15086. doi: 10.1039/D0TA04919K doi: 10.1039/D0TA04919K
39. [39]
  Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.; Lindqvist, L.; Kitchin, J. R.; Bligaard, T.; Jonsson, H. J. Phys. Chem. B 2004, 108, 17886. doi: 10.1021/jp047349j doi: 10.1021/jp047349j
40. [40]
  Niu, H.; Zhang, Z.; Wang, X.; Wan, X.; Shao, C.; Guo, Y. Adv. Funct. Mater. 2020, 31, 2008533. doi: 10.1002/adfm.202008533 doi: 10.1002/adfm.202008533
41. [41]
  Hammer, B.; Nørskov, J. K. Adv. Catal. 2000, 45, 71. doi: 10.1016/S0360-0564(02)45013-4 doi: 10.1016/S0360-0564(02)45013-4
42. [42]
  Wang, M.; Torbensen, K.; Salvatore, D.; Ren, S.; Joulie, D.; Dumoulin, F.; Mendoza, D.; Lassalle-Kaiser, B.; Isci, U.; Berlinguette, C. P.; et al. Nat. Commun. 2019, 10, 3602. doi: 10.1038/s41467-019-11542-w doi: 10.1038/s41467-019-11542-w
43. [43]
  Zhu, M.; Ye, R.; Jin, K.; Lazouski, N.; Manthiram, K. ACS Energy Lett. 2018, 3, 1381. doi: 10.1021/acsenergylett.8b00519 doi: 10.1021/acsenergylett.8b00519
44. [44]
  Han, A.; Wang, B.; Kumar, A.; Qin, Y.; Jin, J.; Wang, X.; Yang, C.; Dong, B.; Jia, Y.; Liu, J.; Sun, X. Small Methods 2019, 3, 1800471. doi: 10.1002/smtd.201800471 doi: 10.1002/smtd.201800471
45. [45]
  Li, J.; Zhang, L.; Doyle-Davis, K.; Li, R.; Sun, X. Carbon Energy 2020, 2, 488. doi: 10.1002/cey2.74 doi: 10.1002/cey2.74
46. [46]
  Lv, L.; Shen, Y.; Liu, J.; Meng, X.; Gao, X.; Zhou, M.; Zhang, Y.; Gong, D.; Zheng, Y.; Zhou, Z. J. Phys. Chem. Lett. 2021, 12, 11143. doi: 10.1021/acs.jpclett.1c03005 doi: 10.1021/acs.jpclett.1c03005
47. [47]
  Yang, M.; Wang, Z.; Jiao, D.; Li, G.; Cai, Q.; Zhao, J. Appl. Surf. Sci. 2022, 592, 153213. doi: 10.1016/j.apsusc.2022.153213 doi: 10.1016/j.apsusc.2022.153213
48. [48]
  Wang, Y.; Xu, A.; Wang, Z.; Huang, L.; Li, J.; Li, F.; Wicks, J.; Luo, M.; Nam, D. H.; Tan, C. S.; et al. J. Am. Chem. Soc. 2020, 142, 5702. doi: 10.1021/jacs.9b13347 doi: 10.1021/jacs.9b13347
49. [49]
  Hu, T.; Wang, C.; Wang, M.; Li, C. M.; Guo, C. ACS Catal. 2021, 11, 14417. doi: 10.1021/acscatal.1c03666 doi: 10.1021/acscatal.1c03666
50. [50]
  Hu, T.; Wang, M.; Guo, C.; Li, C. M. J. Mater. Chem. A 2022, 10, 8923. doi: 10.1039/D2TA00470D doi: 10.1039/D2TA00470D
51. [51]
  Niu, H.; Wang, X.; Shao, C.; Liu, Y.; Zhang, Z.; Guo, Y. J. Mater. Chem. A 2020, 8, 6555. doi: 10.1039/D0TA00794C doi: 10.1039/D0TA00794C
52. [52]
  Sathishkumar, N.; Wu, S.; Chen, H. App. Surf. Sci. 2022, 598, 153829. doi: 10.1016/j.apsusc.2022.153829 doi: 10.1016/j.apsusc.2022.153829
53. [53]
  Liu, J.-X.; Richards, D.; Singh, N.; Goldsmith, B. R. ACS Catal. 2019, 9, 7052. doi: 10.1021/acscatal.9b02179 doi: 10.1021/acscatal.9b02179
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