Citation: Xue Xiao, Jiachun Li, Xiangtong Meng, Jieshan Qiu. 硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230700. doi: 10.3866/PKU.WHXB202307006 shu

硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能

State Key Laboratory of Organic-Inorganic Composites, State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Xiangtong Meng, Jieshan Qiu,
Received Date: 3 July 2023
Revised Date: 4 August 2023
Accepted Date: 5 August 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52002014, U2003216), the Natural Science Foundation of Guangxi (2021GXNSFAA220018), and the Shenzhen Science and Technology Program (CJGJZD20210408092801005).

铁硫化物因其较高的理论容量，被认为是一种很有前途的钠离子电池负极材料。然而，铁硫化物在充放电过程中存在较大的体积变化，导致其倍率性能和稳定性较差。本文通过简单的一步法策略，制备了一种具有三维簇状结构的硫掺杂碳包覆的Fe_0.95S_1.05纳米球（Fe_0.95S_1.05@SC），并研究了其储钠性能。硫掺杂碳层可提高材料的导电率，缓解Fe_0.95S_1.05纳米球在反应过程中产生的体积膨胀，故提升了材料的稳定性。Fe_0.95S_1.05@SC的相互贯通的簇状结构，为电子和离子的传输提供了通道，使材料具备优异的倍率性能。在半电池体系中，Fe_0.95S_1.05@SC在0.1 A·g^-1下循环100圈后，保留614.7 mAh·g^-1的高比容量，10 A·g^-1下比容量仍可以达到235.7 mAh·g^-1。在全电池体系中，在0.1和10 A·g^-1时，Fe_0.95S_1.05@SC的可逆容量分别为482.8和288.3 mAh·g^-1。该材料具有良好电化学性能，在钠离子电池中具有广阔的应用前景。
- Sodium ion battery,
- Anode,
- Sulfur-doped carbon,
- Fe_0.95S_1.05@SC electrode
1. [1]
  (1) Perveen, T.; Siddiq, M.; Shahzad, N.; Ihsan, R.; Ahmad, A.; Shahzad, M. Renew. Sust. Energ. Rev. 2020, 119, 109549. doi:10.16/j.rser.2019.109549
2. [2]
  (2) Bai, Y.; Liu, Y.; Li, Y.; Ling, L.; Wu, F.; Wu, C. RSC Adv. 2017, 7, 5519. doi:10.1039/c6ra27212f
3. [3]
  (3) Zhao, L.; Zhang, T.; Li, W.; Li, T.; Zhang, L.; Zhang, X.; Wang, Z. Engineering 2023, doi:10.1016/j.eng.2021.08.032
4. [4]
  (4) Zhang, T.; Li, C.; Wang, F.; Noori, A.; Mousavi, M.; Xia, X.; Zhang, Y. Chem. Rec. 2022, 22, e202200083. doi:10.1002/tcr.202200083
5. [5]
  (5) Hwang, J.; Myung, S.; Sun, Y. Chem. Soc. Rev. 2017, 46, 3529. doi:10.1039/c6cs00776g
6. [6]
  (6) Nayak, P.; Yang, L.; Brehm, W.; Adelhelm, P. Angew. Chem. Int. Ed. 2018, 57, 102. doi:10.1002/anie.201703772
7. [7]
  (7) Sun, L.; Xie, J.; Zhang, X.; Zhang, L.; Wu, J.; Shao, R.; Jiang, R.; Jin, Z. Dalton Trans. 2020, 49, 15712. doi:10.1039/D0DT03258A
8. [8]
  (8) Ma, L.; Chen, R.; Hu, Y.; Zhu, G.; Chen, T.; Lu, H.; Liang, J.; Tie, Z.; Jin, Z.; Liu, J. Nanoscale 2016, 8, 17911. doi:10.1039/C6NR06307A
9. [9]
  (9) Sun, L.; Song, X.; Liu, Y.; Xie, J.; Wu, J.; Cheng, F.; Zhang, X.; Tie, Z.; Jin, Z. FlatChem 2021, 28, 100258. doi:10.1016/j.flatc.2021.100258
10. [10]
  (10) Chen, T.; Cheng, B.; Chen, R.; Hu, Y.; Lv, H.; Zhu, G.; Wang, Y.; Ma, L.; Liang, J.; Tie, Z.; et al. ACS Appl. Mater. Interfaces 2016, 8, 26834. doi:10.1021/acsami.6b08911
11. [11]
12. [12]
  (12) Zhang, H.; Huang, Y.; Ming, H.; Cao, G.; Zhang, W.; Ming, J.; Chen, R. J. Mater. Chem. A 2020, 8, 1604. doi:10.1039/C9TA09984K
13. [13]
  (13) Miao, X.; Sun, D.; Zhou, X.; Lei, Z. Chem. Eng. J. 2019, 364, 208. doi:10.1016/j.cej.2019.01.158
14. [14]
  (14) Xiao, Y.; Lee, S.; Sun, Y. Adv. Energy Mater. 2017, 7, 1601329. doi:10.1002/aenm.201601329
15. [15]
  (15) Zhang, K.; Park, M.; Zhou, L.; Lee, G.; Shin, J.; Hu, Z.; Chou, S.; Chen, J.; Kang, Y. Angew.Chem. Int. Ed. 2016, 55, 12822. doi:10.1002/anie.201607469
16. [16]
  (16) Zhu, Y.; Nie, P.; Shen, L.; Dong, S.; Sheng, Q.; Li, H.; Luo, H.; Zhang, X. Nanoscale 2015, 7, 3309. doi:10.1039/C4NR05242K
17. [17]
  (17) Walter, M.; Zünd, T.; Kovalenko, M. Nanoscale 2015, 7, 9158. doi:10.1039/C5NR00398A
18. [18]
  (18) Wang, Y.; Yang, J.; Chou, S.; Liu, H.; Zhang, W.; Zhao, D.; Dou, S. Nat. Commun. 2015, 6, 8689. doi:10.1038/ncomms9689
19. [19]
  (19) Bu, F.; Xiao, P.; Chen, J.; Aly, A. M.; Shakir, I.; Xu, Y. J. Mater. Chem. A 2018, 6, 6414. doi:10.1039/c7ta11111h
20. [20]
  (20) Kandula, S.; Sik, Y. B.; Cho, J.; Lim, H.; Gon, S. J. Chem. Eng. J. 2022, 439, 135678. doi:10.1016/j.cej.2022.135678
21. [21]
  (21) Ma, H.; Su, D.; Klein, H. A.; Jin, G.; Guo, X. Carbon 2006, 44, 2254. doi:10.1016/j.carbon.2006.02.033
22. [22]
  (22) Qian, J.; Wu, F.; Ye, Y.; Zhang, M.; Huang, Y.; Xing, Y.; Qu, W.; Li, L.; Chen, R. Adv. Energy Mater. 2018, 8, 1703159. doi:10.1002/aenm.201703159
23. [23]
  (23) Pan, Q.; Zheng, F.; Liu, Y.; Li, Y.; Zhong, W.; Chen, G.; Hu, J.; Yang, C.; Liu, M. J. Mater. Chem. A 2019, 7, 20229. doi:10.1039/c9ta07302g
24. [24]
  (24) Xiao, Y.; Hwang, J.; Belharouak, I.; Sun, Y. ACS Energy Lett. 2017, 2, 364. doi:10.1021/acsenergylett.6b00660
25. [25]
  (25) Huang, S.; Li, Y.; Chen, S.; Wang, Y.; Wang, Z.; Fan, S.; Zhang, D.; Yang, H. Energy Storage Mater. 2020, 32, 151. doi:10.1016/j.ensm.2020.06.039
26. [26]
  (26) Wang, Q.; Zhang, W.; Guo, C.; Liu, Y.; Wang, C.; Guo, Z. Adv. Funct. Mater. 2017, 27, 1703390. doi:10.1002/adfm.201703390
27. [27]
  (27) Xu, Y.; Li, W.; Zhang, F.; Zhang, X.; Zhang, W.; Lee, C.; Tang, Y. J. Mater. Chem. A 2016, 4, 3697. doi:10.1039/C5TA09138A
28. [28]
  (28) Chen, B.; Qin, H.; Li, K.; Zhang, B.; Liu, E.; Zhao, N.; Shi, C.; He, C. Nano Energy 2019, 66, 104133. doi:10.1016/j.nanoen.2019.104133
29. [29]
  (29) Lu, Z.; Wang, N.; Zhang, Y.; Xue, P.; Guo, M.; Tang, B.; Xu, X.; Wang, W.; Bai, Z.; Dou, S. ACS Appl. Energy Mater. 2018, 1, 6234. doi:10.1021/acsaem.8b01239
30. [30]
  (30) Luo, W.; Cao, X.; Liang, S.; Huang, J.; Su, Q.; Wang, Y.; Fang, G.; Shan, L.; Zhou, J. ACS Appl. Energy Mater. 2019, 2, 4567. doi:10.1021/acsaem.9b00632
31. [31]
  (31) Peng, Q.; Lu, Y.; Qi, S.; Liang, M.; Xu, D.; Sun, W.; Lv, L.; Wei, Y.; Chen, S.; Wang, Y. ACS Appl. Energy Mater. 2022, 5, 3199. doi:10.1021/acsaem.1c03810
32. [32]
  (32) Xia, G.; Li, X.; Gu, Y.; Dong, P.; Zhang, Y.; Duan, J.; Wang, D.; Zhang, Y. Ionics 2020, 27, 191. doi:10.1007/s11581-020-03818-9
33. [33]
  (33) Xie, D.; Cai, S.; Sun, X.; Hou, T.; Shen, K.; Ling, R.; Fan, A.; Zhang, R.; Jiang, S.; Lin, Y. Inorg. Chem. Commun. 2020, 11, 107635. doi:10.1016/j.inoche.2019.107635
34. [34]
  (34) Haridas, A.; Angulakshmi, N.; Stephan, A.; Lee, Y.; Ahn, J. Molecules 2021, 26, 4349. doi:10.3390/molecules26144349
35. [35]
  (35) Chen, Y.; Zhao, Y.; Liu, H.; Ma, T. ACS Omega 2023, 8, 9145. doi:10.1021/acsomega.2c06429
36. [36]
  (36) Chen, C.; Wen, Y.; Hu, X.; Ji, X.; Yan, M.; Mai, L.; Hu, P.; Shan, B.; Huang, Y. Nat. Commun. 2015, 6, 6929. doi:10.1038/ncomms7929
37. [37]
  (37) Fang, Y.; Yu, X.; Lou, X. Angewa. Chem. Int. Ed. 2018, 57, 9859. doi:10.1002/anie.201805552
38. [38]
  (38) Fang, G.; Wu, Z.; Zhou, J.; Zhu, C.; Cao, X.; Lin, T.; Chen, Y.; Wang, C.; Pan, A.; Liang, S. Adv. Energy Mater. 2018, 8, 1703115. doi:10.1002/aenm.201703155
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硫掺杂碳包覆Fe0.95S1.05纳米球复合材料的储钠性能

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硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能