Citation:
Xue Xiao, Jiachun Li, Xiangtong Meng, Jieshan Qiu. 硫掺杂碳包覆Fe0.95S1.05纳米球复合材料的储钠性能[J]. Acta Physico-Chimica Sinica,
;2024, 40(6): 230700.
doi:
10.3866/PKU.WHXB202307006
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铁硫化物因其较高的理论容量,被认为是一种很有前途的钠离子电池负极材料。然而,铁硫化物在充放电过程中存在较大的体积变化,导致其倍率性能和稳定性较差。本文通过简单的一步法策略,制备了一种具有三维簇状结构的硫掺杂碳包覆的Fe0.95S1.05纳米球(Fe0.95S1.05@SC),并研究了其储钠性能。硫掺杂碳层可提高材料的导电率,缓解Fe0.95S1.05纳米球在反应过程中产生的体积膨胀,故提升了材料的稳定性。Fe0.95S1.05@SC的相互贯通的簇状结构,为电子和离子的传输提供了通道,使材料具备优异的倍率性能。在半电池体系中,Fe0.95S1.05@SC在0.1 A·g-1下循环100圈后,保留614.7 mAh·g-1的高比容量,10 A·g-1下比容量仍可以达到235.7 mAh·g-1。在全电池体系中,在0.1和10 A·g-1时,Fe0.95S1.05@SC的可逆容量分别为482.8和288.3 mAh·g-1。该材料具有良好电化学性能,在钠离子电池中具有广阔的应用前景。
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