Citation: Gaopeng Liu, Lina Li, Bin Wang, Ningjie Shan, Jintao Dong, Mengxia Ji, Wenshuai Zhu, Paul K. Chu, Jiexiang Xia, Huaming Li. Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230604. doi: 10.3866/PKU.WHXB202306041 shu

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction

Gaopeng Liu ¹ ,
Lina Li ¹ ,
Bin Wang ^1,2 ,
Ningjie Shan ¹ ,
Jintao Dong ¹ ,
Mengxia Ji ¹ ,
Wenshuai Zhu ^1,, ,
Paul K. Chu ² ,
Jiexiang Xia ^1,, ,
Huaming Li ^1,,

1.
Institute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China;
2.
Department of Physics, Department of Materials Science and Engineering, and Department of Biomedical Engineering, City University of Hong Kong, Hong Kong 999077, China

Corresponding author: Wenshuai Zhu, Jiexiang Xia, Huaming Li,
Received Date: 26 June 2023
Revised Date: 13 August 2023
Accepted Date: 29 August 2023

Fund Project: The project was supported by the China Postdoctoral Science Foundation (2022M721380, 2020M680065), Jiangsu Funding Program for Excellent Postdoctoral Talent (2023ZB214), National Natural Science Foundation of China (22108106, 22108108), Hong Kong Scholar Program (XJ2021021), City University of Hong Kong Donation Research Grant (DON-RMG, 9229021), City University of Hong Kong Strategic Research Grant (SRG, 7005505), and City University of Hong Kong Donation Grant (9220061).

The continuous increase in the consumption of coal, oil, and natural gas has not only led to the depletion of unsustainable energy sources, but has also caused excessive CO₂ emissions, thus resulting in serious energy crises and climate issues. In such a scenario, it is imperative to explore clean and sustainable energy conversion technologies to address the escalating energy demands and environmental crises. Photocatalytic CO₂ conversion, inspired by natural photosynthesis, utilizes solar energy to convert CO₂ and water into valuable chemicals. After decades of development, artificial photosynthesis has emerged as a green, cost-effective, and sustainable approach to achieving carbon neutrality. However, the challenges of low carrier separation efficiency and insufficient active sites in photocatalysts remain significant hurdles in achieving high-performance CO₂ photoreduction. To address this challenge, the integration of metal nanoparticles with semiconductors to create an Ohmic junction can enhance electron-hole migration by the assist of interfacial electric field (IEF). In this study, an Ohmic junction photocatalyst is constructed by in situ formation of Bi nanoparticles on the surface of BiOCl nanosheets through a solvothermal process. The composition and morphology of the photocatalysts were analyzed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) was employed to assess the light absorption performance of the photocatalyst. Transient photocurrent response, electrochemical impedance spectroscopy (EIS), and electron spin resonance (ESR) were utilized to evaluate the efficiency of electron-hole transfer. The distinct work function difference between Bi nanoparticles and BiOCl nanosheets leads to favorable charge transfer characteristics within the formed Ohmic junction, significantly improving the utilization efficiency of photogenerated carriers. Besides, the Bi nanoparticles serve as co-catalysts, enhancing the activation of inert CO₂. As a result, the optimized Bi/BiOCl composite (Bi/BiOCl-2) exhibits enhanced generation rates of CO (34.31 µmol·g^-1) and CH₄ (1.57 µmol g^-1) during 4-h of irradiation, which is 2.55 and 4.76 times compared to pristine BiOCl nanosheets, respectively. Isotope tracer experiments suggest that the obtained carbon-based products are generated through CO₂ photoreduction in the presence of water molecule under irradiation. Moreover, in situ Fourier-transform infrared spectroscopy (in situ FTIR) results indicate the formation of *CHO, *CH₃O, b-CO₃^2-, m-CO₃^2-, HCO^-₃, HCOOH, *COOH, and HCOO^- species during the CO₂ reduction process and a possible mechanism for CO₂ photoreduction into CO and CH₄ is proposed based on these findings. After 25-h of CO₂ photoreduction reaction, the yields of CO and CH₄ continue to increase. Furthermore, the stability of the prepared material is confirmed by XRD pattern, XPS analysis, and TEM image. These outcomes underscore an effective strategy for constructing advanced photocatalysts tailored for high-performance solar-driven CO₂ reduction.
- BiOCl nanosheet,
- Bi nanoparticle,
- CO₂ photoreduction,
- Ohmic junction,
- Charge transfer
1. [1]
  (1) Liang, J. X.; Yu, H.; Shi, J. J.; Li, B.; Wu, L. X.; Wang, M. Adv. Mater. 2023, 35, 2209814. doi:10.1002/adma.202209814
2. [2]
  (2) Wang, B.; Zhang, W.; Liu, G. P.; Chen, H. L.; Weng, Y.-X.; Li, H. M.; Chu, P. K.; Xia, J. X. Adv. Funct. Mater. 2022, 32, 2202885. doi:10.1002/adfm.202202885
3. [3]
4. [4]
  (4) Yan, P. C.; Ji, F. W.; Zhang, W.; Mo, Z.; Qian, J. C.; Zhu, L. H.; Xu, L. J. Colloid Interface Sci. 2023, 634, 1005. doi:10.1016/j.jcis.2022.12.063
5. [5]
6. [6]
  (6) Yang, J. M.; Jing, L. Q.; Zhu, X. W.; Zhang, W.; Deng J. J.; She, Y. B.; Nie, K. Q.; Wei, Y. C.; Li, H. M.; Xu, H. Appl. Catal. B 2023, 320, 122005. doi:10.1016/j.apcatb.2022.122005
7. [7]
  (7) Das, R.; Paul, R.; Parui, A.; Shrotri, A.; Atzori, C.; Lomachenko, K. A.; Singh, A. K.; Mondal, J.; Peter, S. C. J. Am. Chem. Soc. 2023, 145, 422. doi:10.1021/jacs.2c10351
8. [8]
  (8) Liu, G. P.; Wang, L.; Chen, X.; Zhu, X. W.; Wang, B.; Xu, X. Y.; Chen, Z. R.; Zhu, W. S.; Li, H. M.; Xia, J. X. Green Chem. Eng. 2022, 3, 157. doi:10.1016/j.gce.2021.11.007
9. [9]
  (9) Li, J.; Yu, X. M.; Xue, W. J.; Nie, L.; Huang, H. L.; Zhong, C. L. AIChE J. 2023, 69, e17906. doi:10.1002/aic.17906
10. [10]
  (10) Li, S. G.; Chen, F.; Chu, S. Q.; Zhang, Z. Y.; Huang, J. D.; Wang, S. Y.; Feng, Y. B.; Wang, C.; Huang, H. W. Small 2023, 19, 2203559. doi:10.1002/smll.202203559
11. [11]
  (11) Dong, Y.-L.; Liu, H.-R.; Wang, S.-M.; Guan, G.-W.; Yang, Q.-Y. ACS Catal. 2023, 13, 2547. doi:10.1021/acscatal.2c04588
12. [12]
  (12) Ni, M. M.; Zhu, Y. J.; Guo, C. F.; Chen, D.-L.; Ning, J. Q.; Zhong, Y. J.; Hu, Y. ACS Catal. 2023, 13, 2502. doi:10.1021/acscatal.2c05577
13. [13]
  (13) Wei, J. J.; Dong, H. L.; Gao, Y. X.; Su, X.; Tan, H. W.; Li, J. J.; Zhao, Q.; Guan, X. W.; Lu, Z. L.; Ouyang, J.; et al. J. Mater. Chem. A 2023, 11, 4057. doi:10.1039/d2ta08812f
14. [14]
  (14) Cheng, S. W.; Sun, Z. H.; Lim, K. H.; Zhang, T. X.; Hondo, E.; Du, T.; Liu, L. Y.; Judd, M.; Cox, N.; Yin, Z. Y.; et al. ACS Appl. Nano Mater. 2023, 6, 3608. doi:10.1021/acsanm.2c05364
15. [15]
  (15) Kong, B.; Zeng, T. X.; Wang, W. T. Phys. Chem. Chem. Phys. 2021, 23, 19841. doi:10.1039/d1cp02794h
16. [16]
  (16) Chen, C. Y.; Jiang, T.; Hou, J. H.; Zhang, T. T.; Zhang, G. S.; Zhang, Y. C.; Wang, X. Z. J. Mater. Sci. Technol. 2022, 114, 240. doi:10.1016/j.jmst.2021.12.006
17. [17]
  (17) Song, Y.; Ye, C. C.; Yu, X.; Tang, J. Y.; Zhao, Y. X.; Cai, W. Appl. Surf. Sci. 2022, 583, 152463. doi:10.1016/j.apsusc.2022.152463
18. [18]
  (18) Wang, S.-S.; Liang, X.; Lv, Y.-K.; Li, Y.-Y.; Zhou, R.-H.; Yao, H.-C.; Li, Z.-J. ACS Appl. Energy Mater. 2022, 5, 1149. doi:10.1021/acsaem.1c03531
19. [19]
  (19) Gao, M. C.; Yang, J. X.; Sun, T.; Zhang, Z. Z.; Zhang, D. F.; Huang, H. J.; Lin, H. X.; Fang, Y.; Wang, X. X. Appl. Catal. B 2019, 243, 734. doi:10.1016/j.apcatb.2018.11.020
20. [20]
  (20) Zhang, L.; Wang, W. Z.; Jiang, D.; Gao, E. P.; Sun, S. M. Nano Res. 2015, 8, 821. doi:10.1007/s12274-014-0564-2
21. [21]
  (21) Gong, S. W.; Rao, F.; Zhang, W. B.; Hassan, Q.-U.; Liu, Z. Q.; Gao, J. Z.; Lu, J. B.; Hojamberdiev, M.; Zhu, G. Q. Chin. Chem. Lett. 2022, 33, 4385. doi:10.1016/j.cclet.2021.12.039
22. [22]
  (22) Yao, D. F.; Liang, K. J.; Chen, G. L.; Qu, Y. D.; Liu, J. Y.; Chilivery, R.; Li, S.; Ji, M. W.; Li, Z.; Zhong, Z. Y.; et al. J. Catal. 2023, 422, 56. doi:10.1016/j.jcat.2023.04.004
23. [23]
  (23) Li, Y.-L.; Liu, Y.; Mu, H.-Y.; Liu, R.-H.; Hao, Y.-J.; Wang, X.-J.; Hildebrandt, D.; Liu, X. Y.; Li, F.-T. Nanoscale 2021, 13, 2585. doi:10.1039/D0NR08314C
24. [24]
  (24) Liu, X. Y.; Ye, M.; Zhang, S. P.; Huang, G. C.; Li, C. H.; Yu, J. G.; Wong, P. K.; Liu, S. W. J. Mater. Chem. A 2018, 6, 24245. doi:10.1039/c8ta09661a
25. [25]
  (25) Yan, F. P.; Wu, Y. H.; Jiang, L. Q.; Xue, X. G.; Lv, J. Q.; Lin, L. Y.; Yu, Y. L.; Zhang, J. Y.; Yang, F. G.; Qiu, Y. ChemSusChem 2020, 13, 876. doi:10.1002/cssc.201903437
26. [26]
  (26) Pan, C.; Mao, Z.; Yuan, X.; Zhang, H. J.; Mei, L.; Ji, X. Y. Adv. Sci. 2022, 9, 2105747. doi:10.1002/advs.202105747
27. [27]
  (27) Wang, S. M.; Guan, Y.; Lu, L.; Shi, Z.; Yan, S. C.; Zou, Z. G. Appl. Catal. B 2018, 224, 10. doi:10.1016/j.apcatb.2017.10.043
28. [28]
  (28) Li, Z.; Huang, F.; Xu, Y. F.; Yan, A. H.; Dong, H. M.; Xiong, X.; Zhao, X. H. Chem. Eng. J. 2022, 429, 132476. doi:10.1016/j.cej.2021.132476
29. [29]
  (29) Yang, Q.; Luo, M. L.; Liu, K. W.; Cao, H. M.; Yan, H. J. Chem. Commun. 2019, 55, 5728. doi:10.1039/c9cc01732a
30. [30]
  (30) Safardoust-Hojaghan, H.; Salavati-Niasari, M.; Motaghedifard, M. H.; Hosseinpour-Mashkani, S. M. New J. Chem. 2015, 39, 4676. doi:10.1039/c5nj00532a
31. [31]
  (31) Li, X. B.; Hu Y.; Dong, F.; Huang, J. T.; Han, L.; Deng, F.; Luo, Y. D.; Xie, Y.; He, C. Z.; Feng, Z. J.; et al. Appl. Catal. B 2023, 325, 122341. doi:10.1016/j.apcatb.2022.122341
32. [32]
  (32) Li, X. B.; Kang, B. B.; Dong, F.; Deng, F.; Han, L.; Gao, X. M.; Xu, J. L.; Hou, X. F.; Feng, Z. J.; Chen, Z.; et al. Appl. Surf. Sci. 2022, 593, 153422. doi:10.1016/j.apsusc.2022.153422
33. [33]
  (33) Huang, Y. W.; Zhu, Y. S.; Chen, S. J.; Xie, X. Q.; Wu, Z. J.; Zhang, N. Adv. Sci. 2021, 8, 2003626. doi:10.1002/advs.202003626
34. [34]
  (34) Gao, F. D.; Zeng, D. W.; Huang, Q. W.; Tian, S. Q.; Xie, C. S. Phys. Chem. Chem. Phys. 2012, 14, 10572. doi:10.1039/c2cp41045a
35. [35]
  (35) Peng, Y.; Mao, Y. G.; Kan, P. F.; Liu, J. Y.; Fang, Z. New J. Chem. 2018, 42, 16911. doi:10.1039/c8nj03323d
36. [36]
  (36) Wang, B.; Zhu, X. W.; Huang, F. C.; Quan, Y.; Liu, G. P.; Zhang, X. L.; Xiong, F. Y.; Huang, C.; Ji, M. X.; Li, H. M.; et al. Appl. Catal. B 2023, 325, 122304. doi:10.1016/j.apcatb.2022.122304
37. [37]
  (37) Wang, L.; Lv, D. D.; Yue, Z. J.; Zhu, H.; Wang, L.; Wang, D. F.; Xu, X.; Hao, W. C.; Dou, S. X.; Du, Y. Nano Energy 2019, 57, 398. doi:10.1016/j.nanoen.2018.12.071
38. [38]
  (38) Wu, Z. X.; Wu, H. B.; Cai, W. Q.; Wen, Z. H.; Jia, B. H.; Wang, L.; Jin, W.; Ma, T. Y. Angew. Chem. Int. Ed. 2021, 60, 12554. doi:10.1002/anie.202102832
39. [39]
40. [40]
  (40) Liu, G. P.; Wang, L.; Wang, B.; Zhu, X. W.; Yang, J. M.; Liu, P. J.; Zhu, W. S.; Chen, Z. R.; Xia, J. X. Chin. Chem. Lett. 2023, 34, 107962. doi:10.1016/j.cclet.2022.107962
41. [41]
  (41) Liu, J. Y.; Zhu, S. M.; Wang, B.; Yang, R. Z.; Wang, R.; Zhu, X. W.; Song, Y. H.; Yuan, J. J.; Xu, H.; Li., H. M. Chin. Chem. Lett. 2023, 34, 107749. doi:10.1016/j.cclet.2022.107749
42. [42]
43. [43]
  (43) Yan, X. W.; Wang, B.; Ji, M. X.; Jiang, Q.; Liu, G. P.; Liu, P. J.; Yin, S.; Li, H. M.; Xia, J. X. Chin. J. Struct. Chem. 2022, 41, 2208044. doi:10.14102/j.cnki.0254-5861.2022-0141
44. [44]
  (44) Yang, J. H.; Hou, Y. P.; Sun, J. L.; Liang, J. X.; Yu, Z. B.; Zhu, H. X.; Wang, S. F. Sep. Purif. Technol. 2022, 299, 121701. doi:10.1016/j.seppur.2022.121701
45. [45]
  (45) Bai, S.; Li, X. Y.; Kong, Q.; Long, R.; Wang, C. M.; Jiang, J.; Xiong, Y. J. Adv. Mater. 2015, 27, 3444. doi:10.1002/adma.201501200
46. [46]
  (46) Gong, S. W.; Zhu, G. Q.; Wang, R.; Rao, F.; Shi, X. J.; Gao, J. Z.; Huang, Y.; He, C. Z.; Hojamberdiev, M. Appl. Catal. B 2021, 297, 120413. doi:10.1016/j.apcatb.2021.120413
47. [47]
  (47) Zhu, X. W.; Wang, Z. L.; Zhong, K.; Li, Q. D.; Ding, P. H.; Feng, Z. Y.; Yang, J. M.; Du, Y. S.; Song, Y. H.; Hua, Y. J.; et al. Chem. Eng. J. 2022, 429, 132204. doi:10.1016/j.cej.2021.132204
48. [48]
  (48) Yang, J. M.; Zhu, X. W.; Yu, Q.; He, M. Q.; Zhang, W.; Mo, Z.; Yuan, J. J.; She, Y. B.; Xu, H.; Li, H. M. Chin. J. Catal. 2022, 43, 1286. doi:10.1016/s1872-2067(21)63954-2
49. [49]
50. [50]
  (50) Mo, Z.; Miao, Z. H.; Yan, P. C.; Sun, P. P.; Wu, G. Y.; Zhu, X. W.; Ding, C.; Zhu, Q.; Lei, Y. C.; Xu, H. J. Colloid Interface Sci. 2023, 645, 525. doi:10.1016/j.jcis.2023.04.123
51. [51]
52. [52]
  (52) Zhang, Y.; Guo, F. Y.; Wang, K. K.; Di, J.; Min, B.; Zhu, H. Y.; Chen, H. L.; Weng, Y.-X.; Dai, J. Y.; She, Y. B.; et al. Chem. Eng. J. 2023, 465, 142663. doi:10.1016/j.cej.2023.142663
53. [53]
  (53) Yu, Y. Y.; Dong, X. A.; Chen, P.; Geng, Q.; Wang, H.; Li, J. Y.; Zhou, Y.; Dong, F. ACS Nano 2021, 15, 14453. doi:10.1021/acsnano.1c03961
54. [54]
  (54) Li, D. S.; Zhu, B. C.; Sun, Z. T.; Liu, Q. Q.; Wang, L. L.; Tang, H. Front. Chem. 2021, 9, 804204. doi:10.3389/fchem.2021.804204
55. [55]
  (55) Yu, H. B.; Huang, J. H.; Jiang, L. B.; Leng, L. J.; Yi, K. X.; Zhang, W.; Zhang, C. Y.; Yuan, X. Z. Appl. Catal. 2021, 298, 120618. doi:10.1016/j.apcatb.2021.120618
56. [56]
  (56) Xu, Y. X.; Jin, X. L.; Ge, T.; Xie, H. Q.; Sun, R. X.; Su, F. Y.; Li, X.; Ye, L. Q. Chem. Eng. J. 2021, 409, 128178. doi:10.1016/j.cej.2020.128178
57. [57]
  (57) Jin, X. L.; Cao, J.; Wang, H. Q.; Lv, C. D.; Xie, H. Q.; Su, F. Y.; Li, X.; Sun, R. X.; Shi, S. K.; Dang, M. F.; et al. Appl. Surf. Sci. 2022, 598, 153758. doi:10.1016/j.apsusc.2022.153758
58. [58]
  (58) Meng, J. Z.; Duan, Y. Y.; Jing, S. J.; Ma, J. P.; Wang, K. W.; Zhou, K.; Ban, C. G.; Wang, Y.; Hu, B. H.; Yu, D. M.; et al. Nano Energy 2022, 92, 106671. doi:10.1016/j.nanoen.2021.106671
59. [59]
  (59) Sun, Z.; Liu, T. W.; Shen, Q. Q.; Li, H. M.; Liu, X. G.; Jia, H. S.; Xue, J. B. Appl. Surf. Sci. 2023, 616, 156530. doi:10.1016/j.apsusc.2023.156530
60. [60]
  (60) Li, X. F.; Li, K. M.; Ding, D.; Yan, J. T.; Wang, C. L.; Carabineiro, S. A. C.; Liu, Y.; Lv, K. L. Sep. Purif. Technol. 2023, 309, 123054. doi:10.1016/j.seppur.2022.123054
61. [61]
  (61) Di, J.; Zhao, X. X.; Lian, C.; Ji, M. X.; Xia, J. X.; Xiong, J.; Zhou, W.; Cao, X. Z.; She, Y. B.; Liu, H. L.; et al. Nano Energy 2019, 61, 54. doi:10.1016/j.nanoen.2019.04.029
62. [62]
  (62) Wang, J. Q.; Cheng, H.; Wei, D. Q.; Li, Z. H. Chin. J. Catal. 2022, 43, 2606. doi:10.1016/S1872-2067(22)64091-9
63. [63]
  (63) Si, S. H.; Shou, H. W.; Mao, Y. Y.; Bao, X. L.; Zhai, G. Y.; Song, K. P.; Wang, Z. Y.; Wang, P.; Liu, Y. Y.; Zheng, Z. K.; et al. Angew. Chem. Int. Ed. 2022, 61, e202209446. doi:10.1002/anie.202209446
64. [64]
  (64) Ji, M. X.; Feng, J.; Zhao, J. Z.; Zhang, Y.; Wang, B.; Di, J.; Xu, X. Y.; Chen, Z. R.; Xia, J. X.; Li, H. M. ACS Appl. Nano Mater. 2022, 5, 17226. doi:10.1021/acsanm.2c04232
65. [65]
  (65) Li, X. D.; Sun, Y. F.; Xu, J. Q.; Shao, Y. J.; Wu, J.; Xu, X. L.; Pan, Y.; Ju, H. X.; Zhu, J. F.; Xie, Y. Nat. Energy 2019, 4, 690. doi:10.1038/s41560-019-0431-1
66. [66]
  (66) Wang, J. Y.; Bo, T. T.; Shao, B. Y.; Zhang, Y. Z.; Jia, L. X.; Tan, X.; Zhou, W.; Yu, T. Appl. Catal. B 2021, 297, 120498. doi:10.1016/j.apcatb.2021.120498
67. [67]
  (67) Xu, J. Q.; Ju, Z. Y.; Zhang, W.; Pan, Y.; Zhu, J. F.; Mao, J. W.; Zheng, X. L.; Fu, H. Y.; Yuan, M. L.; Chen, H.; et al. Angew. Chem. Int. Ed. 2021, 60, 8705. doi:10.1002/anie.202017041
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15. [15]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
16. [16]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
17. [17]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
20. [20]
  Di Wang , Qing-Song Chen , Yi-Ran Lin , Yun-Xin Hou , Wei Han , Juan Yang , Xin Li , Zhen-Hai Wen . Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(8): 100346-100346. doi: 10.1016/j.cjsc.2024.100346

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO2 Reduction

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通讯作者: 陈斌, bchen63@163.com

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction