Citation: Weicheng Feng, Jingcheng Yu, Yilan Yang, Yige Guo, Geng Zou, Xiaoju Liu, Zhou Chen, Kun Dong, Yuefeng Song, Guoxiong Wang, Xinhe Bao. 调控双钙钛矿中高熵组分促进高温析氧反应[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230601. doi: 10.3866/PKU.WHXB202306013 shu

调控双钙钛矿中高熵组分促进高温析氧反应

Weicheng Feng ^1,2 ,
Jingcheng Yu ^1,2 ,
Yilan Yang ³ ,
Yige Guo ^1,2 ,
Geng Zou ^1,2 ,
Xiaoju Liu ⁴ ,
Zhou Chen ⁵ ,
Kun Dong ⁶ ,
Yuefeng Song ^1,, ,
Guoxiong Wang ^1,, ,
Xinhe Bao ¹

1.
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China;
2.
College of Energy, University of Chinese Academy of Sciences, Beijing 100049, China;
3.
School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, China;
4.
School of Chemistry and Chemical Engineering, Yulin University, Yulin 719100, Shannxi Province, China;
5.
College of Materials, Xiamen University, Xiamen 361005, Fujian Province, China;
6.
Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Yuefeng Song, Guoxiong Wang,
Received Date: 5 June 2023
Revised Date: 31 July 2023
Accepted Date: 31 July 2023

Fund Project: The project was supported by the National Key R&D Program of China (2021YFA1502400), the National Natural Science Foundation of China (22272176, 22002166, 22125205, 22072146, 22002158), the DNL Cooperation Fund, CAS (DNL202007), the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy (YLU-DNL Fund 2022008) and the CAS Youth Innovation Promotion (Y201938).

固体氧化物电解池（SOEC）中阳极析氧反应动力学较为迟缓，限制了SOEC器件电催化转化能力，因此针对阳极材料的改性研究对于进一步提升SOEC电化学性能十分关键。高熵钙钛矿（HEP）在许多反应中表现出良好的催化活性，但在SOEC中的应用鲜有研究。本文通过在双钙钛矿的A位或A'位分别掺杂不同的稀土金属、碱土金属或碱金属离子，合成了（Pr_0.2La_0.2Sm_0.2Nd_0.2Gd_0.2） BaCo₂O_6-δ（A-HEP）和Pr （Ba_0.2Sr_0.2Ca_0.2Na_0.2K_0.2） Co₂O_6-δ（A'-HEP）两种高熵钙钛矿材料。由于掺杂离子平均半径和氧化态的差异，A-HEP保持四方双钙钛矿相结构而A'-HEP则转变为正交单钙钛矿相。物理化学表征结果表明，A-HEP中Co平均价态更高，Co 2p-O 1s杂化更强，从而增加了电子转移路径并降低了转移能垒。同时，A-HEP中表面氧空位浓度更高，可为阳极析氧反应提供更多的活性位点。因此，在具有A-HEP阳极的SOEC中，与氧输运、电子传输和表界面反应过程相关的阳极极化电阻显著降低，并在800℃下实现最高1.76 A·cm^-2的电流密度和200 h的稳定性。本工作为高熵钙钛矿材料在SOEC阳极中的应用提供了新的策略。
- Solid oxide electrolysis cell,
- High entropy perovskite,
- Oxygen evolution reaction,
- Oxygen vacancy,
- Electron transfer
1. [1]
  (1) Hauch, A.; Kungas, R.; Blennow, P.; Hansen, A. B.; Hansen, J. B.; Mathiesen, B. V.; Mogensen, M. B. Science 2020, 370, eaba6118. doi:10.1126/science.aba6118
2. [2]
  (2) Zheng, Y.; Wang, J. C.; Yu, B.; Zhang, W. Q.; Chen, J.; Qiao, J. L.; Zhang, J. J. Chem. Soc. Rev. 2017, 46, 1427. doi:10.1039/C6CS00403B
3. [3]
  (3) Ebbesen, S.; Jensen, S.; Hauch, A.; Mogensen, M. Chem. Rev. 2014, 114, 10697. doi:10.1021/cr5000865
4. [4]
  (4) Song, Y. F.; Zhang, X. M.; Xie, K.; Wang, G. X.; Bao, X. H. Adv. Mater. 2019, 31, e1902033. doi:10.1002/adma.201902033
5. [5]
  (5) Hwang, J.; Rao, R. R.; Giordano, L.; Katayama, Y.; Yu, Y.; Shao-Horn, Y. Science 2017, 358, 751. doi:10.1126/science.aam7092
6. [6]
  (6) Choi, J.; Park, S.; Han, H.; Kim, M.; Park, M.; Han, J.; Kim, W. B. J. Mater. Chem. A 2021, 9, 8740. doi:10.1039/d0ta11328j
7. [7]
  (7) Ai, N.; He, S.; Li, N.; Zhang, Q.; Rickard, W. D. A.; Chen, K. F.; Zhang, T.; Jiang, S. P. J. Power Sources 2018, 384, 125. doi:10.1016/j.jpowsour.2018.02.082
8. [8]
  (8) Shao, Z. P.; Haile, S. M. Nature 2004, 431, 170. doi:10.1038/nature02863
9. [9]
  (9) Jiang, S. P. Solid State Ionics 2002, 146, 1. doi:10.1016/S0167-2738(01)00997-3
10. [10]
  (10) Chen, K. F.; Ai, N.; Jiang, S. P. Int. J. Hydrogen Energy 2014, 39, 0349. doi:10.1016/j.ijhydene.2014.05.013
11. [11]
  (11) Woodward, P. M.; Suard, E.; Karen, P. J. Am. Chem. Soc. 2003, 125, 8889. doi:10.1021/ja034813+
12. [12]
  (12) Woodward, P. M.; Karen, P. Inorg. Chem. 2003, 42, 1121. doi:10.1021/ic026022z
13. [13]
  (13) King, G.; Woodward, P. M. J. Mater. Chem. 2010, 20, 5785. doi:10.1039/B926757C
14. [14]
  (14) Karen, P.; Woodward, P. M.; Lindén, J.; Vogt, T.; Studer, A.; Fischer, P. Phys. Rev. B 2001, 64, 214405. doi:10.1103/PhysRevB.64.214405
15. [15]
  (15) Karen, P.; M. Woodward, P. J. Mater. Chem. 1999, 9, 789. doi:10.1039/A809302D
16. [16]
  (16) Zhukov, V. P.; Chulkov, E. V.; Politov, B. V.; Suntsov, A. Y.; Kozhevnikov, V. L. Phys. Chem. Chem. Phys. 2021, 23, 2313. doi:10.1039/D0CP05497F
17. [17]
  (17) Taskin, A. A.; Lavrov, A. N.; Ando, Y. Prog. Solid State Chem. 2007, 35, 481. doi:10.1016/j.progsolidstchem.2007.01.014
18. [18]
  (18) Taskin, A. A.; Lavrov, A. N.; Ando, Y. Appl. Phys. Lett. 2005, 86, 091910. doi:10.1063/1.1864244
19. [19]
  (19) Shin, T. H.; Myung, J.-H.; Verbraeken, M.; Kim, G.; Irvine, J. T. S. Faraday Discuss. 2015, 182, 227. doi:10.1039/C5FD00025D
20. [20]
  (20) Seymour, I. D.; Tarancón, A.; Chroneos, A.; Parfitt, D.; Kilner, J. A.; Grimes, R. W. Solid State Ionics 2012, 216, 41. doi:10.1016/j.ssi.2011.09.002
21. [21]
  (21) Kim, G.; Wang, S.; Jacobson, A. J.; Reimus, L.; Brodersen, P.; Mims, C. A. J. Mater. Chem. 2007, 17, 2500. doi:10.1039/B618345J
22. [22]
  (22) Dong, F.; Ni, M.; Chen, Y.; Chen, D.; Tadé, M. O.; Shao, Z. J. Mater. Chem. A 2014, 2, 20520. doi:10.1039/C4TA04372C
23. [23]
  (23) Akande, S. O.; Boulfrad, S.; Schwingenschlögl, U. J. Mater. Chem. A 2016, 4, 3560. doi:10.1039/C5TA06858D
24. [24]
  (24) Rost, C. M.; Sachet, E.; Borman, T.; Moballegh, A.; Dickey, E. C.; Hou, D.; Jones, J. L.; Curtarolo, S.; Maria, J.-P. Nat. Commun. 2015, 6, 8485. doi:10.1038/ncomms9485
25. [25]
  (25) Wright, A. J.; Wang, Q. Y.; Huang, C. Y.; Nieto, A.; Chen, R. K.; Luo, J. J. Eur. Ceram. Soc. 2020, 40, 2120. doi:10.1016/j.jeurceramsoc.2020.01.015
26. [26]
  (26) Jiang, S. Y.; Sun, D.; Zhang, Y. Q.; Wang, S. B.; Zhao, C. Z. J. Mater. Sci. 2017, 52, 3199. doi:10.1007/s10853-016-0609-x
27. [27]
  (27) Xu, H. D.; Zhang, Z. H.; Liu, J. X.; Do-Thanh, C.-L.; Chen, H.; Xu, S. H.; Lin, Q. J.; Jiao, Y.; Wang, J. L.; Wang, Y.; et al. Nat. Commun. 2020, 11, 3908. doi:10.1038/s41467-020-17738-9
28. [28]
  (28) Chen, H.; Fu, J.; Zhang, P. F.; Peng, H. G.; Abney, C. W.; Jie, K. C.; Liu, X. M.; Chi, M. F.; Dai, S. J. Mater. Chem. A 2018, 6, 11129. doi:10.1039/C8TA01772G
29. [29]
  (29) Sarkar, A.; Wang, Q.; Schiele, A.; Chellali, M. R.; Bhattacharya, S. S.; Wang, D.; Brezesinski, T.; Hahn, H.; Velasco, L.; Breitung, B. Adv. Mater. 2019, 31, e1806236. doi:10.1002/adma.201806236
30. [30]
  (30) Shi, Y. C.; Ni, N.; Ding, Q.; Zhao, X. F. J. Mater. Chem. A 2022, 10, 2256. doi:10.1039/d1ta07275g
31. [31]
  (31) Yang, Q.; Wang, G. Q.; Wu, H. D.; Beshiwork, B. A.; Tian, D.; Zhu, S. Y.; Yang, Y.; Lu, X. Y.; Ding, Y. Z.; Ling, Y. H.; et al. J. Alloy. Compd. 2021, 872, 159633. doi:10.1016/j.jallcom.2021.159633
32. [32]
  (32) He, F.; Zhou, Y.; Hu, T.; Xu, Y.; Hou, M.; Zhu, F.; Liu, D.; Zhang, H.; Xu, K.; Liu, M.; Chen, Y. Adv. Mater. 2023, 35, e2209469. doi:10.1002/adma.202209469
33. [33]
  (33) Garcı́a-Muñoz, J. L.; Frontera, C.; Llobet, A.; Carrillo, A. E.; Caneiro, A.; Aranda, M. A. G.; Ritter, C.; Dooryee, E. Phys. B 2004, 350, e277. doi:10.1016/j.physb.2004.03.069
34. [34]
  (34) Brinks, H. W.; Fjellvåg, H.; Kjekshus, A.; Hauback, B. C. J. Solid State Chem. 1999, 147, 464. doi:10.1006/jssc.1999.8384
35. [35]
  (35) Guo, D.; Zhang, M.; Chen, Z.; Liu, X.-X. RSC Adv. 2018, 8, 33374. doi:10.1039/C8RA07032F
36. [36]
  (36) Xin, W.-L.; Lu, K.-K.; Zhu, D.-R.; Zeng, H.-B.; Zhang, X.-J.; Marks, R.-S.; Shan, D. Electrochim. Acta 2019, 307, 375. doi:10.1016/j.electacta.2019.03.196
37. [37]
  (37) Zhao, K.; Shen, Y.; Huang, Z.; He, F.; Wei, G. Q.; Zheng, A. Q.; Li, H. B.; Zhao, Z. L. J. Energy Chem. 2017, 26, 501. doi:10.1016/j.jechem.2016.11.016
38. [38]
  (38) Sunarso, J.; Hashim, S. S.; Zhu, N.; Zhou, W. Prog. Energy Combust. Sci. 2017, 61, 57. doi:10.1016/j.pecs.2017.03.003
39. [39]
  (39) Suntivich, J.; Hong, W. T.; Lee, Y.-L.; Rondinelli, J. M.; Yang, W.; Goodenough, J. B.; Dabrowski, B.; Freeland, J. W.; Shao-Horn, Y. J. Phys. Chem. C 2014, 118, 1856. doi:10.1021/jp410644j
40. [40]
  (40) Miao, X.; Wu, L.; Lin, Y.; Yuan, X.; Zhao, J.; Yan, W.; Zhou, S.; Shi, L. Chem. Commun. 2019, 55, 1442. doi:10.1039/c8cc08817a
41. [41]
  (41) Luo, Q. X.; Lin, D.; Zhan, W. Q.; Zhang, W. Q.; Tang, L. L.; Luo, J. J.; Gao, Z.; Jiang, P.; Wang, M.; Hao, L. Y.; et al. ACS Appl. Energy Mater. 2020, 3, 7149. doi:10.1021/acsaem.0c01192
42. [42]
  (42) Grimaud, A.; Diaz-Morales, O.; Han, B.; Hong, W. T.; Lee, Y. L.; Giordano, L.; Stoerzinger, K. A.; Koper, M. T. M.; Shao-Horn, Y. Nat. Chem. 2017, 9, 457. doi:10.1038/nchem.2695
43. [43]
  (43) Xi, X.; Liu, J. W.; Luo, W. Z.; Fan, Y.; Zhang, J. J.; Luo, J. L.; Fu, X. Z. Adv. Energy Mater. 2021, 11, 2102845. doi:10.1002/aenm.202102845
44. [44]
  (44) Li, J. W.; Fu, Z. M.; Wei, B.; Su, C. X.; Yue, X.; Lü, Z. J. Mater. Chem. A 2020, 8, 18778. doi:10.1039/d0ta04857g
45. [45]
  (45) Guan, F.; Zhang, X. M.; Song, Y. F.; Zhou, Y. J.; Bao, X. H. Chin. J. Catal. 2018, 39, 1484. doi:10.1016/S1872-2067(18)63118-3
46. [46]
  (46) Zhang, X. M.; Song, Y. F.; Guan, F.; Zhou, Y. J.; Lv, H. F.; Wang, G. X.; Bao, X. H. J. Catal. 2018, 359, 8. doi:10.1016/j.jcat.2017.12.027
47. [47]
  (47) Li, Q.; Wu, J. B.; Wu, T.; Jin, H. R.; Zhang, N.; Li, J.; Liang, W. X.; Liu, M. L.; Huang, L.; Zhou, J. Adv. Funct. Mater. 2021, 31, 2102002. doi:10.1002/adfm.202102002
48. [48]
  (48) Song, Y. F.; Zhou, Z. W.; Zhang, X. M.; Zhou, Y. J.; Gong, H. M.; Lv, H. F.; Liu, Q. X.; Wang, G. X.; Bao, X. H. Angew. Chem. Int. Ed. 2019, 58, 4617. doi:10.1002/anie.201814612
49. [49]
  (49) Wang, W. H.; Yang, Y.; Huan, D. M.; Wang, L. K.; Shi, N.; Xie, Y.; Xia, C. R.; Peng, R. R.; Lu, Y. L. J. Mater. Chem. A 2019, 7, 12538. doi:10.1039/c9ta03099a
50. [50]
  (50) Ciucci, F.; Chen, C. Electrochim. Acta 2015, 167, 439. doi:10.1016/j.electacta.2015.03.123
51. [51]
  (51) Saccoccio, M.; Wan, T. H.; Chen, C.; Ciucci, F. Electrochim. Acta 2014, 147, 470. doi:10.1016/j.electacta.2014.09.058
52. [52]
  (52) Li, Y. H.; Li, Y.; Wan, Y. H.; Xie, Y.; Zhu, J. F.; Pan, H. B.; Zheng, X. S.; Xia, C. R. Adv. Energy Mater. 2019, 9, 1803156. doi:10.1002/aenm.201803156
53. [53]
  (53) Lv, H. F.; Lin, L.; Zhang, X. M.; Song, Y. F.; Matsumoto, H.; Zeng, C. B.; Ta, N.; Liu, W.; Gao, D. F.; Wang, G. X.; et al. Adv. Mater. 2020, 32, e1906193. doi:10.1002/adma.201906193
54. [54]
  (54) Song, Y. F.; Zhang, X. M.; Zhou, Y. J.; Lv, H. F.; Liu, Q. X.; Feng, W. F.; Wang, G. X.; Bao, X. H. J. Energy Chem. 2019, 35, 181. doi:10.1016/j.jechem.2019.03.013
55. [55]
  (55) Zhang, X. M.; Song, Y. F.; Guan, F.; Zhou, Y. J.; Lv, H. F.; Liu, Q. X.; Wang, G. X.; Bao, X. H. J. Power Sources 2018, 400, 104. doi:10.1016/j.jpowsour.2018.08.017
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