Citation: ZilinHu, YaoshenNiu, XiaohuiRong, Yongsheng Hu. Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230600. doi: 10.3866/PKU.WHXB202306005 shu

Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减

ZilinHu ^1,2 ,
YaoshenNiu ¹ ,
XiaohuiRong ^1,2,3,, ,
Yongsheng Hu ^1,2,3,4,,

1.
Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2.
College of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Yangtze River Delta Physics Research Center Co. Ltd., Liyang 213300, Jiangsu Province, China;
4.
Huairou Division, Institute of Physics, Chinese Academy of Sciences, Beijing 101400, China

Corresponding author: XiaohuiRong, Yongsheng Hu,
Received Date: 1 June 2023
Revised Date: 29 June 2023
Accepted Date: 17 July 2023

Fund Project: The project was supported by the National Key R&D Program of China (2022YFB2402500), the National Natural Science Foundation of China (51725206, 52122214, 52072403, 52002394), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020006), the Beijing Municipal Natural Science Foundation (2212022), the Young Elite Scientists Sponsorship Program by CAST (2022QNRC001).

由于钠资源丰富，钠离子电池在大规模储能方面显示出巨大的潜力。随着近年来研究的深入，在正极材料中引入适量的阴离子氧化还原可以有效地提升钠离子电池的能量密度，同时减少高成本过渡金属元素如V、Co和Ni等的用量。有研究表明，材料循环过程中不可逆的氧损失以及Mn⁴⁺/Mn³⁺氧化还原的激活，导致了层状氧化物正极材料持续的电压衰减。本工作通过在Na_x[Li，Ni，Mn]O₂基钠离子电池正极材料中引入Ni³⁺作为Mn⁴⁺/Mn³⁺氧化还原屏障，利用Ni³⁺/Ni²⁺的氧化还原代替Mn⁴⁺/Mn³⁺的氧化还原，成功抑制了材料的电压衰减。电化学测试结果显示，改性材料在不损失容量的前提下，循环稳定性得到明显提升。X射线光电子能谱结果也验证了Ni³⁺的引入有利于维持材料多周循环后Mn价态的稳定。
- Na-ion battery,
- Anion-redox,
- Voltage decay,
- Single-phase solid solution reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Ni3+抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减

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通讯作者: 陈斌, bchen63@163.com

Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减