Citation: Hongpeng He, Mengmeng Zhang, Mengjiao Hao, Wei Du, Haibing Xia. 不同长径比的具有固定宽度金纳米棒的合成[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230404. doi: 10.3866/PKU.WHXB202304043 shu

不同长径比的具有固定宽度金纳米棒的合成

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
2.
School of Environment and Material Engineering, Yantai University, Yantai 264005, Shandong Province, China

Received Date: 24 April 2023
Revised Date: 17 May 2023
Accepted Date: 18 May 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22072076, 21773142), the Taishan Scholarship in Shandong Province (tstp20221106) and the Fundamental Research Fund of Shandong University.

金纳米棒在光学、电学、信息学和生物医学等领域具有广泛的应用。然而，一些具有特殊要求的金纳米棒还不能通过常规的方法制备。在本研究中，我们创新地将十二醇(LA)分子引入到传统种子生长方法中，成功实现了具有固定宽度的不同长径比(AR)金纳米棒(FW-Au NR)的按需制备。此外，通过合理地选择相应的反应条件(如氯金酸和硝酸银的浓度)，可以在130–38.4，109–26.4和16–46 nm范围之间分别调节FW²³-Au NRs，FW¹⁴-Au NRs和FW^6.5-Au NRs (右上角的标注数字表示金纳米棒的宽度)的长度。即，可在一个较大的长度范围内调节具有固定宽度的金纳米棒的长径比。并且，在合适浓度的十二醇，0.24–0.30 mmol·L^-1范围内调节硝酸银浓度，可以使这些金纳米棒的宽度固定在6.5–23 nm之间。另外，实现FW-Au NRs制备的关键是银离子和十二醇分子对分布在金种子晶面上的CTA-Br-Ag⁺化合物的密度的协同影响。
- Gold nanorods,
- Lauryl alcohol,
- Fixed width,
- Symmetry-breaking efficiency,
- Effective particle number
1. [1]
  (1) Ye, J. M.; Wen, Q.; Wu, Y.; Fu, Q. R.; Zhang, X.; Wang, J. M.; Gao, S.; Song, J. B. Nano Res. 2022, 15 (7), 6372. doi: 10.1007/s12274-022-4191-z
2. [2]
  (2) Zheng, J. P.; Cheng, X. Z.; Zhang, H.; Bai, X. P.; Ai, R.; Shao, L.; Wang, J. F. Chem. Rev. 2021, 121 (21), 13342. doi: 10.1021/acs.chemrev.1c00422
3. [3]
  (3) Ali, M. R. K.; Rahman, M. A.; Wu, Y.; Han, T. G.; Peng, X. H.; Mackey, M. A.; Wang, D. S.; Shin, H. J.; Chen, Z. G.; Xiao, H. P.; et al. Proc. Natl. Acad. Sci. U. S. A. 2017, 114 (15), E3110. doi: 10.1073/pnas.1619302114
4. [4]
  (4) Tsai, M.-F.; Chang, S.-H. G.; Cheng, F.-Y.; Shanmugam, V.; Cheng, Y.-S.; Su, C.-H.; Yeh, C.-S. ACS Nano 2013, 7 (6), 5330. doi: 10.1021/nn401187c
5. [5]
  (5) Wang, Z.; Shao, D.; Chang, Z. M.; Lu, M. M.; Wang, Y. S.; Yue, J.; Yang, D.; Li, M. Q.; Xu, Q. B.; Dong, W. F. ACS Nano 2017, 11 (12), 12732. doi: 10.1021/acsnano.7b07486
6. [6]
  (6) Zhang, H. Y.; Hao, C. L.; Qu, A. H.; Sun, M. Z.; Xu, L. G.; Xu, C. L.; Kuang, H. Adv. Funct. Mater. 2018, 28 (48), 1805320. doi: 10.1002/adfm.201805320
7. [7]
  (7) Fu, Q. R.; Ye, J. M.; Wang, J. J.; Liao, N. S.; Feng, H. J.; Su, L. C.; Ge, X. G.; Yang, H. H.; Song, J. B. Small 2021, 17 (26), 2008061. doi: 10.1002/smll.202008061
8. [8]
  (8) Dong, Q.; Wang, X.; Hu, X. X.; Xiao, L. Q.; Zhang, L.; Song, L. J.; Xu, M. L.; Zou, Y. X.; Chen, L.; Chen, Z.; et al. Angew. Chem. Int. Ed. 2018, 57 (1), 177. doi: 10.1002/anie.201709648
9. [9]
  (9) González-Rubio, G.; Mosquera, J.; Kumar, V.; Pedrazo-Tardajos, A.; Llombart, P.; Solís, D. M.; Lobato, I.; Noya, E. G.; Guerrero-Martínez, A.; Taboada, J. M.; et al. Science 2020, 368 (6498), 1472. doi: 10.1126/science.aba0980
10. [10]
  (10) Ni, W. H.; Kou, X. S.; Yang, Z.; Wang, J. F. ACS Nano 2008, 2 (4), 677. doi: 10.1021/nn7003603
11. [11]
12. [12]
  (12) Lu, J.; Xue, Y.; Bernardino, K.; Zhang, N.-N.; Gomes, W. R.; Ramesar, N. S.; Liu, S.; Hu, Z.; Sun, T.; de Moura, A. F.; et al. Science 2021, 371 (6536), 1368. doi: 10.1126/science.abd8576
13. [13]
  (13) Huang, X. H.; Neretina, S.; El-Sayed, M. A. Adv. Mater. 2009, 21 (48), 4880. doi: 10.1002/adma.200802789
14. [14]
  (14) Song, J. B.; Yang, X. Y.; Jacobson, O.; Huang, P.; Sun, X. L.; Lin, L. S.; Yan, X. F.; Niu, G.; Ma, Q. J.; Chen, X. T. Adv. Mater. 2015, 27 (33), 4910. doi: 10.1002/adma.201502486
15. [15]
  (15) Park, K.; Biswas, S.; Kanel, S.; Nepal, D.; Vaia, R. A. J. Phys. Chem. C 2014, 118 (11), 5918. doi: 10.1021/jp5013279
16. [16]
  (16) Jia, H. L.; Fang, C. H.; Zhu, X.-M.; Ruan, Q. F.; Wang, Y.-X. J.; Wang, J. F. Langmuir 2015, 31 (26), 7418. doi: 10.1021/acs.langmuir.5b01444
17. [17]
  (17) Park, J.-E.; Kim, M.; Hwang, J.-H.; Nam, J.-M. Small Methods 2017, 1 (3), 1600032. doi: 10.1002/smtd.201600032
18. [18]
  (18) Tang, H. L; Xu, X. J.; Chen, Y. X.; Xin, H. H.; Wan, T.; Li, B. W.; Pan, H. M.; Li, D.; Ping, Y. Adv. Mater. 2021, 33 (12), 2006003. doi: 10.1002/adma.202006003
19. [19]
  (19) Yang, H.; He, H. P.; Tong, Z. R.; Xia, H. B.; Mao, Z. W.; Gao, C. Y. J. Colloid Interface Sci. 2020, 565, 186. doi: 10.1016/j.jcis.2020.01.026
20. [20]
  (20) Ye, X. C.; Jin, L. H.; Caglayan, H.; Chen, J.; Xing, G. Z.; Zheng, C.; Doan-Nguyen, V.; Kang, Y.; Engheta, N.; Kagan, C. R.; et al. ACS Nano 2012, 6 (3), 2804. doi: 10.1021/nn300315j
21. [21]
  (21) Vigderman, L.; Zubarev, E. R. Chem. Mater. 2013, 25 (8), 1450. doi: 10.1021/cm303661d
22. [22]
  (22) Chang, H.-H.; Murphy, C. J. Chem. Mater. 2018, 30 (4), 1427. doi: 10.1021/acs.chemmater.7b05310
23. [23]
  (23) Walsh, M. J.; Tong, W. M.; Katz-Boon, H.; Mulvaney, P.; Etheridge, J.; Funston, A. M. Acc. Chem. Res. 2017, 50 (12), 2925. doi: 10.1021/acs.accounts.7b00313
24. [24]
  (24) Tong, W.; Walsh, M. J.; Mulvaney, P.; Etheridge, J.; Funston, A. M. J. Phys. Chem. C 2017, 121 (6), 3549. doi: 10.1021/acs.jpcc.6b10343
25. [25]
  (25) Walsh, M. J.; Barrow, S. J.; Tong, W.; Funston, A. M.; Etheridge, J. ACS Nano 2015, 9 (1), 715. doi: 10.1021/nn506155r
26. [26]
  (26) Song, Y. H.; Zhang, M. M.; Fang, H. T.; Xia, H. B. ChemPhysMater 2023, 2 (2), 97. doi: 10.1016/j.chphma.2022.04.006
27. [27]
  (27) Zhu, J.; Lennox, R. B. ACS Appl. Nano Mater. 2021, 4 (4), 3790. doi: 10.1021/acsanm.1c00230
28. [28]
  (28) Sau, T. K.; Murphy, C. J. Langmuir 2004, 20 (15), 6414. doi: 10.1021/la049463z
29. [29]
  (29) Nikoobakht, B.; El-Sayed, M. A. Chem. Mater. 2003, 15 (10), 1957. doi: 10.1021/cm020732l
30. [30]
  (30) Lohse, S. E.; Murphy, C. J. Chem. Mater. 2013, 25 (8), 1250. doi: 10.1021/cm303708p
31. [31]
  (31) Burrows, N. D.; Harvey, S.; Idesis, F. A.; Murphy, C. J. Langmuir 2017, 33 (8), 1891. doi: 10.1021/acs.langmuir.6b03606
32. [32]
  (32) Zhang, X.; Tran, N.; Egan, T.; Sharma, B.; Chen, G. J. Phys. Chem. C 2021, 125 (24), 13350. doi: 10.1021/acs.jpcc.1c01375
33. [33]
  (33) González-Rubio, G.; Scarabelli, L.; Guerrero-Martínez, A.; Liz-Marzán, L. M. ChemNanoMat 2020, 6 (5), 698. doi: 10.1002/cnma.201900754
34. [34]
  (34) Meena, S. K.; Sulpizi, M. Angew. Chem. Int. Ed. 2016, 55 (39), 11960. doi: 10.1002/anie.201604594
35. [35]
  (35) Seibt, S.; Zhang, H.; Mudie, S.; Förster, S.; Mulvaney, P. J. Phys. Chem. C 2021, 125 (36), 19947. doi: 10.1021/acs.jpcc.1c06778
36. [36]
  (36) González-Rubio, G.; Kumar, V.; Llombart, P.; Díaz-Núñez, P.; Bladt, E.; Altantzis, T.; Bals, S.; Peña-Rodríguez, O.; Noya, E. G.; MacDowell, L. G.; et al. ACS Nano 2019, 13 (4), 4424. doi: 10.1021/acsnano.8b09658
37. [37]
  (37) He, H. P.; Wu, C. S.; Bi, C. X.; Song, Y. H.; Wang, D. Y.; Xia, H. B. Chem. Eur. J. 2021, 27 (27), 7549. doi: 10.1002/chem.202005422
38. [38]
  (38) Llombart, P.; Palafox, M. A.; MacDowell, L. G.; Noya, E. G. Colloids Surf. A-Physicochem. Eng. Aspects 2019, 580, 123730. doi: 10.1016/j.colsurfa.2019.123730
39. [39]
  (39) Kim, W.-J.; Yang, S.-M.; Kim, M. J. Colloid Interface Sci. 1997, 194 (1), 108. doi: 10.1006/jcis.1997.5093
40. [40]
  (40) Dubey, N. J. Mol. Liq. 2013, 184, 60. doi: 10.1016/j.molliq.2013.04.022
41. [41]
  (41) Karayil, J.; Kumar, S.; Hassan, P. A.; Talmon, Y.; Sreejith, L. RSC Adv. 2015, 5 (16), 12434. doi: 10.1039/C4RA10052B
42. [42]
  (42) Rodríguez-Fernández, J.; Pérez-Juste, J.; Mulvaney, P.; Liz-Marzán, L. M. J. Phys. Chem. B 2005, 109 (30), 14257. doi: 10.1021/jp052516g
43. [43]
  (43) Gallagher, R.; Zhang, X.; Altomare, A.; Lawrence, D.; Shawver, N.; Tran, N.; Beazley, M.; Chen, G. Nano Res. 2021, 14 (4), 1167. doi: 10.1007/s12274-020-3167-0
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