Citation: Hongpeng He, Mengmeng Zhang, Mengjiao Hao, Wei Du, Haibing Xia. 不同长径比的具有固定宽度金纳米棒的合成[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230404. doi: 10.3866/PKU.WHXB202304043 shu

不同长径比的具有固定宽度金纳米棒的合成

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
2.
School of Environment and Material Engineering, Yantai University, Yantai 264005, Shandong Province, China

Received Date: 24 April 2023
Revised Date: 17 May 2023
Accepted Date: 18 May 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22072076, 21773142), the Taishan Scholarship in Shandong Province (tstp20221106) and the Fundamental Research Fund of Shandong University.

金纳米棒在光学、电学、信息学和生物医学等领域具有广泛的应用。然而，一些具有特殊要求的金纳米棒还不能通过常规的方法制备。在本研究中，我们创新地将十二醇(LA)分子引入到传统种子生长方法中，成功实现了具有固定宽度的不同长径比(AR)金纳米棒(FW-Au NR)的按需制备。此外，通过合理地选择相应的反应条件(如氯金酸和硝酸银的浓度)，可以在130–38.4，109–26.4和16–46 nm范围之间分别调节FW²³-Au NRs，FW¹⁴-Au NRs和FW^6.5-Au NRs (右上角的标注数字表示金纳米棒的宽度)的长度。即，可在一个较大的长度范围内调节具有固定宽度的金纳米棒的长径比。并且，在合适浓度的十二醇，0.24–0.30 mmol·L^-1范围内调节硝酸银浓度，可以使这些金纳米棒的宽度固定在6.5–23 nm之间。另外，实现FW-Au NRs制备的关键是银离子和十二醇分子对分布在金种子晶面上的CTA-Br-Ag⁺化合物的密度的协同影响。
- Gold nanorods,
- Lauryl alcohol,
- Fixed width,
- Symmetry-breaking efficiency,
- Effective particle number
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