Citation: Yue-Zhou Zhu, Kun Wang, Shi-Sheng Zheng, Hong-Jia Wang, Jin-Chao Dong, Jian-Feng Li. Application and Development of Electrochemical Spectroscopy Methods[J]. Acta Physico-Chimica Sinica, ;2024, 40(3): 230404. doi: 10.3866/PKU.WHXB202304040 shu

Application and Development of Electrochemical Spectroscopy Methods

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China;
2.
School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen 518000, Guangdong Province, China

Corresponding author: Shi-Sheng Zheng, Jian-Feng Li,
Received Date: 24 April 2023
Revised Date: 19 May 2023
Accepted Date: 22 May 2023

Fund Project: The project was supported by the National Key Research and Development Program of China (2020YFB1505800) and the National Natural Science Foundation of China (21925404, 22075099, 21991151).

The theoretical and experimental technologies used for electrochemical characterization methods, which are essential for determining surface structures and elucidating electrochemical reaction mechanisms, have been significantly improved after more than two centuries of development. Traditional chemical methods like cyclic voltammetry (CV) can provide the exact electrochemical reaction rate in different potential ranges, which is beneficial for identifying the electrochemical performance of electrocatalytic materials. However, traditional chemical methods alone are often inadequate when it comes to achieving a deep understanding of reaction mechanisms. In this regard, spectroscopic methods, which are powerful tools to identify the active sites and intermediate species during electrochemical reactions, are widely applied to elucidate the electrochemical mechanism at a molecular or even atomic level. In this review, three molecular-vibration-spectroscopy-based electrochemical characterization technologies, viz., infrared (IR) spectroscopy, surface-enhanced Raman spectroscopy (SERS), and sum frequency generation (SFG) spectroscopy, are comprehensively reviewed and discussed. IR, SERS, and SFG are all non-destructive spectroscopic techniques with ultra-high surface sensitivity and are indispensable when detecting surface species during electrochemical reactions. Consequently, researchers have strived to combine these spectroscopic techniques with basic electrochemical instruments. In fundamental electrochemical research, detecting electrochemical reactions in model single-crystal systems and determining the structure of interfacial water molecules have been two major research topics in recent years. Single-crystal surfaces are important in fundamental electrochemical research because of their defined atom arrays and energy states, serving as model systems to help bridge experimental results and theoretical calculations. Meanwhile, the structure of interfacial water influences most electrochemical reaction processes, and as such, probing interfacial water structures is a challenging but valuable target in fundamental electrochemical research. Additionally, the application of electrochemical spectroscopic methods to analyze fuel cells has become important, and this review covers recent SERS studies of oxygen reduction reactions (ORR) and hydrogen oxidation reactions (HOR) in hydrogen fuel cells. Concurrently, electrochemical IR and SFG studies on the electrooxidation of small organic molecules are discussed. Finally, owing to the significance of lithium-ion batteries, studies of electrochemical spectroscopic methods on solid electrolyte interphase (SEI) and cathode-electrolyte interface (CEI) are becoming increasingly important and are introduced here. In conclusion, recent advances and the future developments of electrochemical spectroscopy methods are summarized in this review article.
1. [1]
  (1) Bruckenstein, S.; Miller, B. Acc. Chem. Res. 1977, 10, 54. doi:10.1021/ar50110a004
2. [2]
  (2) Andrieux, C. P.; Hapiot, P.; Saveant, J. M. J. Phys. Chem. 1988, 92, 5992. doi:10.1021/j100332a031
3. [3]
  (3) Elgrishi, N.; Rountree, K. J.; McCarthy, B. D.; Rountree, E. S.; Eisenhart, T. T.; Dempsey, J. L. J. Chem. Educ. 2018, 95, 197. doi:10.1021/acs.jchemed.7b00361
4. [4]
  (4) Sandford, C.; Edwards, M. A.; Klunder, K. J.; Hickey, D. P.; Li, M.; Barman, K.; Sigman, M. S.; White, H. S.; Minteer, S. D. Chem. Sci. 2019, 10, 6404. doi:10.1039/C9SC01545K
5. [5]
  (5) McKenzie, E. C. R.; Hosseini, S.; Petro, A. G. C.; Rudman, K. K.; Gerroll, B. H. R.; Mubarak, M. S.; Baker, L. A.; Little, R. D. Chem. Rev. 2022, 122, 3292. doi:10.1021/acs.chemrev.1c00471
6. [6]
  (6) Mattson, J. S.; Smith, C. A. Science 1973, 181, 1055. doi:10.1126/science.181.4104.1055
7. [7]
  (7) Mattson, J. S.; Jones, T. T. Anal. Chem. 1976, 48, 2164. doi:10.1021/ac50008a028
8. [8]
  (8) Saji, T.; Bard, A. J. J. Am. Chem. Soc. 1977, 99, 2235. doi:10.1021/ja00449a034
9. [9]
  (9) Cooley, J.; Lewis, P.; Welch, P. IEEE Trans. Audio Electroacoust. 1967, 15, 76. doi:10.1109/TAU.1967.1161903
10. [10]
  (10) Clarke, J. S.; Kuhn, A. T.; Orville-Thomas, W. J.; Stedman, M. J. Electroanal. Chem. Interfacial Electrochem. 1974, 49, 199. doi:10.1016/S0022-0728(74)80227-5
11. [11]
  (11) Bewick, A.; Kunimatsu, K. Surf. Sci. 1980, 101, 131. doi:10.1016/0039-6028(80)90604-4
12. [12]
  (12) Bewick, A. J. Electroanal. Chem. Interfacial Electrochem. 1983, 150, 481. doi:10.1016/S0022-0728(83)80228-9
13. [13]
  (13) Ye, J. Y.; Jiang, Y. X.; Sheng, T.; Sun, S. G. Nano Energy 2016, 29, 414. doi:10.1016/j.nanoen.2016.06.023
14. [14]
  (14) Li, H.; Jiang, K.; Zou, S.-Z.; Cai, W.-B. Chin. J. Catal. 2022, 43, 2772. doi:10.1016/S1872-2067(22)64095-6
15. [15]
  (15) Ma, X. Y.; Zhang, W. Y.; Ye, K.; Jiang, K.; Cai, W. B. Anal. Chem. 2022, 94, 11337. doi:10.1021/acs.analchem.2c02092
16. [16]
  (16) Raman, C. V.; Krishnan, K.S. Nature 1928, 121, 501. doi:10.1038/121501c0
17. [17]
  (17) Tian, Z. Q.; Ren, B.; Li, J. F.; Yang, Z. L. Chem. Commun. 2007, 3514. doi:10.1039/B616986D
18. [18]
  (18) Stöckle, R. M.; Suh, Y. D.; Deckert, V.; Zenobi, R. Chem. Phys. Lett. 2000, 318, 131. doi:10.1016/S0009-2614(99)01451-7
19. [19]
  (19) Li, J. F.; Huang, Y. F.; Ding, Y.; Yang, Z. L.; Li, S. B.; Zhou, X. S.; Fan, F.R.; Zhang, W.; Zhou, Z.Y.; Wu, D.Y.; et al. Nature 2010, 464, 392. doi:10.1038/nature08907
20. [20]
21. [21]
  (21) Li, J. F.; Tian, X. D.; Li, S. B.; Anema, J. R.; Yang, Z. L.; Ding, Y.; Wu, Y. F.; Zeng, Y. M.; Chen, Q. Z.; Ren, B.; et al. Nat. Protocols 2013, 8, 52. doi:10.1038/nprot.2012.141
22. [22]
  (22) De, R.; Dietzek-Ivanšić, B. Chem.-Eur. J. 2022, 28, e202200407. doi:10.1002/chem.202200407
23. [23]
  (23) Sun, S. G.; Clavilier, J.; Bewick, A. J. Electroanal. Chem. Interfacial Electrochem. 1988, 240, 147. doi:10.1016/0022-0728(88)80319-X
24. [24]
  (24) Sun, S. G.; Yang, Y. Y. J. Electroanal. Chem. 1999, 467, 121. doi:10.1016/S0022-0728(99)00032-7
25. [25]
  (25) Sun, S. G.; Lin, Y. Electrochim. Acta 1996, 41, 693. doi:10.1016/0013-4686(95)00358-4
26. [26]
  (26) Sun, S. G.; Lin, Y. Electrochim. Acta 1998, 44, 1153. doi:10.1016/S0013-4686(98)00218-7
27. [27]
  (27) Orts, J. M.; Fernandez-Vega, A.; Feliu, J. M.; Aldaz, A.; Clavilier, J. J. Electroanal. Chem. Interfacial Electrochem. 1990, 290, 119. doi:10.1016/0022-0728(90)87424-I
28. [28]
  (28) Spendelow, J. S.; Goodpaster, J. D.; Kenis, P. J. A.; Wieckowski, A. Langmuir 2006, 22, 10457. doi:10.1021/la0615995
29. [29]
  (29) Schnaidt, J.; Heinen, M.; Denot, D.; Jusys, Z.; Behm, R. J. J. Electroanal. Chem. 2011, 661, 250. doi:10.1016/j.jelechem.2011.08.011
30. [30]
  (30) Dong, J. C.; Zhang, X. G.; Briega-Martos, V.; Jin, X.; Yang, J.; Chen, S.; Yang, Z. L.; Wu, D. Y.; Feliu, J. M.; Williams, C. T.; et al. Nat. Energy 2019, 4, 60. doi:10.1038/s41560-018-0292-z
31. [31]
  (31) Dong, J. C.; Su, M.; Briega-Martos, V.; Li, L.; Le, J. B.; Radjenovic, P.; Zhou, X. S.; Feliu, J. M.; Tian, Z. Q.; Li, J. F. J. Am. Chem. Soc. 2020, 142, 715. doi:10.1021/jacs.9b12803
32. [32]
  (32) Su, M.; Dong, J.-C.; Le, J.-B.; Zhao, Y.; Yang, W.-M.; Yang, Z.-L.; Attard, G.; Liu, G.-K.; Cheng, J.; Wei, Y.-M.; et al. Angew. Chem. Int. Ed. 2020, 59, 23554. doi:10.1002/anie.202010431
33. [33]
  (33) Liu, B.; Blaszczyk, A.; Mayor, M.; Wandlowski, T. ACS Nano 2011, 5, 5662. doi:10.1021/nn201307g
34. [34]
  (34) Wang, X.; Zhong, J. H.; Zhang, M.; Liu, Z.; Wu, D.Y.; Ren, B. Anal. Chem. 2016, 88, 915. doi:10.1021/acs.analchem.5b03588
35. [35]
  (35) Wen, B. Y.; Yi, J.; Wang, Y. H.; Madasamy, K.; Zhang, H.; Kathiresan, M.; Li, J. F.; Tian, Z. Q. Electrochem. Commun. 2016, 72, 131. doi:10.1016/j.elecom.2016.08.026
36. [36]
  (36) Martín Sabanés, N.; Ohto, T.; Andrienko, D.; Nagata, Y.; Domke, K. F. Angew. Chem. Int. Ed. 2017, 56, 9796. doi:10.1002/anie.201704460
37. [37]
  (37) Wang, Y. H.; Liang, M. M.; Zhang, Y. J.; Chen, S.; Radjenovic, P.; Zhang, H.; Yang, Z. L.; Zhou, X. S.; Tian, Z. Q.; Li, J. F. Angew. Chem. Int. Ed. 2018, 57, 11257. doi:10.1002/anie.201805464
38. [38]
  (38) Tadjeddine, A.; Peremans, A. J. Electroanal. Chem. 1996, 409, 115. doi:10.1016/0022-0728(96)04508-1
39. [39]
  (39) Braunschweig, B.; Wieckowski, A. J. Electroanal. Chem. 2014, 716, 136. doi:10.1016/j.jelechem.2013.10.019
40. [40]
  (40) Yang, S.; Noguchi, H.; Uosaki, K. J. Phys. Chem. C 2015, 119, 26056. doi:10.1021/acs.jpcc.5b10086
41. [41]
  (41) Willard, A. P.; Reed, S. K.; Madden, P. A.; Chandler, D. Faraday Discuss. 2009, 141, 423. doi:10.1039/B805544K
42. [42]
  (42) Limmer, D. T.; Willard, A. P.; Madden, P.; Chandler, D. Proc. Natl. Acad. Sci. 2013, 110, 4200. doi:10.1073/pnas.1301596110
43. [43]
  (43) Osawa, M.; Ataka, K.-I.; Yoshii, K.; Yotsuyanagi, T. J. Electron. Spectrosc. Relat. Phenom. 1993, 64-65, 371. doi:10.1016/0368-2048(93)80099-8
44. [44]
  (44) Ataka, K.-I.; Yotsuyanagi, T.; Osawa, M. J. Phys. Chem. 1996, 100, 10664. doi:10.1021/jp953636z
45. [45]
  (45) Wandlowski, T.; Ataka, K.; Pronkin, S.; Diesing, D. Electrochim. Acta 2004, 49, 1233. doi:10.1016/j.electacta.2003.06.002
46. [46]
  (46) Osawa, M. Advances in Electrochemical Science and Engineering; Alkire, R. C., Kolb, D. M., Lipkowski, J., Ross, P. N., Eds.; Wiley:Hoboken, NJ, USA, 2006; pp. 269-314. doi:10.1002/9783527616817.ch8
47. [47]
  (47) Osawa, M.; Tsushima, M.; Mogami, H.; Samjeské, G.; Yamakata, A. J. Phys. Chem. C 2008, 112, 4248. doi:10.1021/jp710386g
48. [48]
  (48) Garcia-Araez, N.; Rodriguez, P.; Navarro, V.; Bakker, H. J.; Koper, M. T. M. J. Phys. Chem. C 2011, 115, 21249. doi:10.1021/jp206539a
49. [49]
  (49) Gardner, A. M.; Saeed, K. H.; Cowan, A. J. Phys. Chem. Chem. Phys. 2019, 21, 12067. doi:10.1039/C9CP02225B
50. [50]
  (50) Wang, Y. H.; Li, S.; Zhou, R. Y.; Zheng, S.; Zhang, Y. J.; Dong, J. C.; Yang, Z. L.; Pan, F.; Tian, Z. Q.; Li, J. F. Nat. Protocols 2023, 18, 883. doi:10.1038/s41596-022-00782-8
51. [51]
  (51) Zhang, Y. J.; Su, Z. F.; Li, J. F.; Lipkowski, J. J. Phys. Chem. C 2020, 124, 13240. doi:10.1021/acs.jpcc.0c03453
52. [52]
  (52) Li, C. Y.; Le, J. B.; Wang, Y. H.; Chen, S.; Yang, Z. L.; Li, J. F.; Cheng, J.; Tian, Z. Q. Nat. Mater. 2019, 18, 697. doi:10.1038/s41563-019-0356-x
53. [53]
  (53) Wang, Y. H.; Zheng, S. S.; Yang, W. M.; Zhou, R. Y.; He, Q. F.; Radjenovic, P.; Dong, J. C.; Li, S.; Zheng, J.; Yang, Z. L.; et al. Nature 2021, 600, 81. doi:10.1038/s41586-021-04068-z
54. [54]
  (54) Du, Q.; Freysz, E.; Shen, Y. R. Phys. Rev. Lett. 1994, 72, 238. doi:10.1103/PhysRevLett.72.238
55. [55]
  (55) Becraft, K. A.; Moore, F. G.; Richmond, G. L. Phys. Chem. Chem. Phys. 2004, 6, 1880. doi:10.1039/B313513F
56. [56]
  (56) Schultz, Z. D.; Shaw, S. K.; Gewirth, A. A. J. Am. Chem. Soc. 2005, 127, 15916. doi:10.1021/ja0543393
57. [57]
  (57) Noguchi, H.; Okada, T.; Uosaki, K. Faraday Discuss. 2009, 140, 125. doi:10.1039/B803640C
58. [58]
  (58) Tong, Y.; Lapointe, F.; Thämer, M.; Wolf, M.; Campen, R. K. Angew. Chem. Int. Ed. 2017, 56, 4211. doi:10.1002/anie.201612183
59. [59]
  (59) McGuire, J. A.; Shen, Y. R. Science 2006, 313, 1945. doi:10.1126/science.1131536
60. [60]
  (60) Nihonyanagi, S.; Kusaka, R.; Inoue, K. I.; Adhikari, A.; Yamaguchi, S.; Tahara, T. J. Chem. Phys. 2015, 143, 124707. doi:10.1063/1.4931485
61. [61]
  (61) Singh, P. C.; Inoue, K. I.; Nihonyanagi, S.; Yamaguchi, S.; Tahara, T. Angew. Chem. Int. Ed. 2016, 55, 10621. doi:10.1002/anie.201603676
62. [62]
  (62) Nihonyanagi, S.; Yamaguchi, S.; Tahara, T. Chem. Rev. 2017, 117, 10665. doi:10.1021/acs.chemrev.6b00728
63. [63]
  (63) Eftekhari-Bafrooei, A.; Borguet, E. J. Phys. Chem. Lett. 2011, 2, 1353. doi:10.1021/jz200194e
64. [64]
65. [65]
66. [66]
67. [67]
  (67) Samjeské, G.; Miki, A.; Ye, S.; Yamakata, A.; Mukouyama, Y.; Okamoto, H.; Osawa, M. J. Phys. Chem. B 2005, 109, 23509. doi:10.1021/jp055220j
68. [68]
  (68) Chen, Y. X.; Heinen, M.; Jusys, Z.; Behm, R. J. Angew. Chem. Int. Ed. 2006, 45, 981. doi:10.1002/anie.200502172
69. [69]
  (69) Grozovski, V.; Vidal-Iglesias, F. J.; Herrero, E.; Feliu, J. M. ChemPhysChem 2011, 12, 1641. doi:10.1002/cphc.201100257
70. [70]
  (70) Cuesta, A.; Cabello, G.; Osawa, M.; Gutiérrez, C. ACS Catal. 2012, 2, 728. doi:10.1021/cs200661z
71. [71]
  (71) Liu, S. X.; Liao, L. W.; Tao, Q.; Chen, Y. X.; Ye, S. Phys. Chem. Chem. Phys. 2011, 13, 9725. doi:10.1039/C0CP01728K
72. [72]
  (72) Yang, Y. Y.; Ren, J.; Li, Q. X.; Zhou, Z. Y.; Sun, S. G.; Cai, W. B. ACS Catal. 2014, 4, 798. doi:10.1021/cs401198t
73. [73]
74. [74]
75. [75]
  (75) Wang, Y. H.; Le, J. B.; Li, W. Q.; Wei, J.; Radjenovic, P. M.; Zhang, H.; Zhou, X. S.; Cheng, J.; Tian, Z. Q.; Li, J. F. Angew. Chem. Int. Ed. 2019, 58, 16062. doi:10.1002/anie.201908907
76. [76]
  (76) Sun, Y. L.; A, Y. L.; Yue, M. F.; Chen, H. Q.; Ze, H.; Wang, Y. H.; Dong, J. C.; Tian, Z. Q.; Fang, P. P.; Li, J. F. Anal. Chem. 2022, 94, 4779. doi:10.1021/acs.analchem.1c05566
77. [77]
  (77) Ze, H.; Chen, X.; Wang, X. T.; Wang, Y. H.; Chen, Q. Q.; Lin, J. S.; Zhang, Y. J.; Zhang, X. G.; Tian, Z. Q.; Li, J. F. J. Am. Chem. Soc. 2021, 143, 1318. doi:10.1021/jacs.0c12755
78. [78]
  (78) Subbaraman, R.; Tripkovic, D.; Chang, K. C.; Strmcnik, D.; Paulikas, A. P.; Hirunsit, P.; Chan, M.; Greeley, J.; Stamenkovic, V.; Markovic, N. M. Nat. Mater. 2012, 11, 550. doi:10.1038/nmat3313
79. [79]
  (79) Wang, Y. H.; Wang, X. T.; Ze, H.; Zhang, X. G.; Radjenovic, P. M.; Zhang, Y. J.; Dong, J. C.; Tian, Z. Q.; Li, J. F. Angew. Chem. Int. Ed. 2021, 60, 5708. doi:10.1002/anie.202015571
80. [80]
  (80) Lin, X. M.; Wang, X. T.; Deng, Y. L.; Chen, X.; Chen, H. N.; Radjenovic, P. M.; Zhang, X. G.; Wang, Y. H.; Dong, J. C.; Tian, Z. Q.; et al. Nano Lett. 2022, 22, 5544. doi:10.1021/acs.nanolett.2c01744
81. [81]
  (81) Dong, J. N.; Qian, Z. X.; Xu, P.; Yue, M. F.; Zhou, R. Y.; Wang, Y. J.; Nan, Z. A.; Huang, S.; Dong, Q.; Li, J. F.; et al. Chem. Sci. 2022, 13, 5639. doi:10.1039/D2SC01043G
82. [82]
  (82) Peng, C. K.; Lin, Y. C.; Chiang, C. L.; Qian, Z. X.; Huang, Y. C.; Dong, C. L.; Li, J. F.; Chen, C. T.; Hu, Z. W.; Chen, S. Y.; et al. Nat. Commun. 2023, 14, 529. doi:10.1038/s41467-023-36317-2
83. [83]
  (83) Chen, J.; Liu, G.; Zhu, Y. Z.; Su, M.; Yin, P.; Wu, X. J.; Lu, Q.; Tan, C.; Zhao, M.; Liu, Z.; et al. J. Am. Chem. Soc. 2020, 142, 7161. doi:10.1021/jacs.0c01649
84. [84]
  (84) Chen, H. Q.; Ze, H.; Yue, M. F.; Wei, D. Y.; A, Y. L.; Wu, Y. F.; Dong, J. C.; Zhang, Y. J.; Zhang, H.; Tian, Z. Q.; et al. Angew. Chem. Int. Ed. 2022, 61, e202117834. doi:10.1002/anie.202117834
85. [85]
  (85) Li, J.; Wang, S.; Yue, M. F.; Xing, S. M.; Zhang, Y. J.; Dong, J. C.; Zhang, H.; Chen, Z.; Li, J. F. ACS Catal. 2023, 13, 849. doi:10.1021/acscatal.2c05802
86. [86]
  (86) Peremans, A.; Tadjeddine, A. Phys. Rev. Lett. 1994, 73, 3010. doi:10.1103/PhysRevLett.73.3010
87. [87]
  (87) Kutz, R. B.; Braunschweig, B.; Mukherjee, P.; Behrens, R. L.; Dlott, D. D.; Wieckowski, A. J. Catal. 2011, 278, 181. doi:10.1016/j.jcat.2010.11.018
88. [88]
  (88) Liu, Y.; Yu, W.; Raciti, D.; Gracias, D. H.; Wang, C. J. Phys. Chem. C 2019, 123, 426. doi:10.1021/acs.jpcc.8b08547
89. [89]
  (89) Tong, Y.; Cai, K.; Wolf, M.; Campen, R. K. Catal. Today 2016, 260, 66. doi:10.1016/j.cattod.2015.08.015
90. [90]
  (90) Bagger, A.; Ju, W.; Varela, A. S.; Strasser, P.; Rossmeisl, J. ChemPhysChem 2017, 18, 3266. doi:10.1002/cphc.201700736
91. [91]
  (91) Neri, G.; Donaldson, P. M.; Cowan, A. J. J. Am. Chem. Soc. 2017, 139, 13791. doi:10.1021/jacs.7b06898
92. [92]
  (92) Huang-fu, Z. C.; Song, Q. T.; He, Y. H.; Wang, J. J.; Ye, J. Y.; Zhou, Z. Y.; Sun, S. G.; Wang, Z. H. Phys. Chem. Chem. Phys. 2019, 21, 25047. doi:10.1039/C9CP04346B
93. [93]
94. [94]
95. [95]
  (95) Gao, F.; Tian, X. D.; Lin, J. S.; Dong, J. C.; Lin, X. M.; Li, J. F. Nano Res. 2023, 16, 4855. doi:10.1007/s12274-021-4044-1
96. [96]
  (96) Li, J. T.; Chen, S. R.; Fan, X. Y.; Huang, L.; Sun, S. G. Langmuir 2007, 23, 13174. doi:10.1021/la701168x
97. [97]
  (97) Li, J. T.; Chen, S. R.; Ke, F. S.; Wei, G. Z.; Huang, L.; Sun, S. G. J. Electroanal. Chem. 2010, 649, 171. doi:10.1016/j.jelechem.2010.03.032
98. [98]
  (98) Yang , J.; Solomatin, N.; Kraytsberg, A.; Ein-Eli , Y. ChemistrySelect 2016, 1, 572. doi:10.1002/slct.201600119
99. [99]
  (99) Li, X.; Qiao, Y.; Guo, S.; Jiang, K.; Ishida, M.; Zhou, H. Adv. Mater. 2019, 31, 1807825. doi:10.1002/adma.201807825
100. [100]
  (100) Qiao, Y.; Yang, H.; Chang, Z.; Deng, H.; Li, X.; Zhou, H. Nat. Energy 2021, 6, 653. doi:10.1038/s41560-021-00839-0
101. [101]
  (101) Chen, D.; Mahmoud, M. A.; Wang, J. H.; Waller, G. H.; Zhao, B.; Qu, C.; El-Sayed, M. A.; Liu, M. Nano Lett. 2019, 19, 2037. doi:10.1021/acs.nanolett.9b00179
102. [102]
  (102) Horowitz, Y.; Han, H. L.; Ralston, W. T.; de Araujo, J. R.; Kreidler, E.; Brooks, C.; Somorjai, G. A. Adv. Energy Mater. 2017, 7, 1602060. doi:10.1002/aenm.201602060
103. [103]
  (103) Horowitz, Y.; Han, H. L.; Soto, F. A.; Ralston, W. T.; Balbuena, P. B.; Somorjai, G. A. Nano Lett. 2018, 18, 1145. doi:10.1021/acs.nanolett.7b04688
104. [104]
  (104) Ge, A.; Zhou, D.; Inoue, K. I.; Chen, Y.; Ye, S. J. Phys. Chem. C 2020, 124, 17538. doi:10.1021/acs.jpcc.0c06390
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