Citation: Chen Pu, Daijie Deng, Henan Li, Li Xu. Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability[J]. Acta Physico-Chimica Sinica, ;2024, 40(2): 230402. doi: 10.3866/PKU.WHXB202304021 shu

Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability

Institute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China

Corresponding author: Henan Li, lhn@ujs.edu.cn Li Xu, xulichem@ujs.edu.cn
Received Date: 10 April 2023
Revised Date: 22 May 2023
Accepted Date: 23 May 2023
Available Online: 8 June 2023
Fund Project: the National Natural Science Foundation of China 22178148the National Natural Science Foundation of China 22278193

Rechargeable zinc-air batteries (ZABs) have been extensively investigated owing to their high power density and environmental friendliness. However, the slow kinetics of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) processes limit their practical application. Currently, IrO₂ and RuO₂ are considered the optimal OER electrocatalysts, and Pt/C is the most effective ORR electrocatalyst. However, the practical application of Pt, Ir, and Ru in ZABs is severely limited owing to their low natural abundance and high cost. Therefore, the fabrication of inexpensive and high-performance bifunctional catalysts is essential for the development of rechargeable ZABs. Transition-metal alloys have a high electrical conductivity and low energy barrier for the reaction of oxygen, and thus they are considered promising ORR electrocatalysts. Transition-metal nitride-transition-metal alloy core-shell nanostructures can be fabricated to improve the bifunctional electrocatalytic activity. In this study, a bifunctional electrocatalyst with Fe_0.64Ni_0.36@Fe₃NiN core-shell structures encapsulated in N-doped carbon nanotubes (Fe_0.64Ni_0.36@Fe₃NiN/NCNT) was designed for highly efficient rechargeable ZABs. Fe_0.64Ni_0.36@Fe₃NiN/NCNT was synthesized by pyrolyzing the nickel-iron-layered double hydroxide (NiFe-LDH) precursor, followed by ammonia etching of the Fe_0.64Ni_0.36 alloy. The core-shell structure produced more ORR/OER active sites. The Fe_0.64Ni_0.36 core exhibited high electrical conductivity, which facilitates charge transfer. The Fe₃NiN shell enhanced the OER performance and improved the bifunctional performance. Moreover, the NCNT structures not only efficiently enhanced the mass transfer efficiency and intrinsic electrical conductivity, but also provided a large electrochemical active surface area. The high anticorrosion property of the Fe₃NiN shell effectively protected the Fe_0.64Ni_0.36 core, which consequently enhanced electrocatalyst stability during the electrochemical processes. The protective carbon layer and the superior chemical stability of the Fe₃NiN shell resulted in the ultrahigh stability of Fe_0.64Ni_0.36@Fe₃NiN/NCNT. The catalyst exhibited an excellent bifunctional oxygen electrocatalytic performance, with a half-wave potential of 0.88 V for the ORR and low OER overpotential of 380 mV at 10 mA∙cm⁻². Moreover, the catalyst exhibited electrochemical stability (92.8% current retention after 8 h). In addition, the Fe_0.64Ni_0.36@Fe₃NiN/NCNT-based ZAB exhibited a higher peak power density (214 mW·cm⁻²) than the ZABs based on Pt/C+IrO₂ (155 mW·cm⁻²) and Fe_0.64Ni_0.36/NCNT (89 mW·cm⁻²). Moreover, the Fe_0.64Ni_0.36@Fe₃NiN/NCNT-based ZAB delivered a high capacity of 781 mAh·g⁻¹, while the ZABs based on Fe_0.64Ni_0.36/NCNT and Pt/C+IrO₂ reached capacities of 688 and 739 mAh·g⁻¹, respectively. Furthermore, the Fe_0.64Ni_0.36@Fe₃NiN/NCNT-based ZAB exhibited ultralong cycling stability (cycle life > 1100 h), which exceeded those of Pt/C (50 h) and Fe_0.64Ni_0.36/NCNT (450 h). We propose that this study will facilitate the design of novel catalysts for highly stable and efficient ZABs.
- Bifunctional electrocatalyst,
- Fe₃NiN,
- Core-shell structure,
- Zinc-air battery,
- Ultra-long cycle stability
1. [1]
  Kundu, A.; Mallick, S.; Ghora, S.; Raj, C. R. ACS Appl. Mater. Interfaces 2021, 13, 40172. doi: 10.1021/acsami.1c08462 doi: 10.1021/acsami.1c08462
2. [2]
  Wu, M.; Zhang, G.; Wu, M.; Prakash, J.; Sun, S. Energy Storage Mater. 2019, 21, 253. doi: 10.1016/j.ensm.2019.05.018 doi: 10.1016/j.ensm.2019.05.018
3. [3]
  Tian, H.; Song, A. L.; Zhang, P.; Sun, K. A.; Wang, J.; Sun, B.; Fan, Q. H.; Shao, G. J.; Chen, C.; Liu, H.; et al. Adv. Mater. 2023, 35, 2210714. doi: 10.1002/adma.202210714 doi: 10.1002/adma.202210714
4. [4]
  Anand, P.; Wong, M. S.; Fu, Y. P. Energy Storage Mater. 2023, 58, 362. doi: 10.1016/j.ensm.2023.03.033 doi: 10.1016/j.ensm.2023.03.033
5. [5]
  Deng, D. J.; Ma, H. X.; Wu, S. Q.; Wang, H.; Qian, J. C.; Wu, J. C.; Li, H. M.; Yan, C.; Li, H. N.; Xu, L. Renewables 2023, 1, 362372. doi: 10.31635/renewables.023.202200020 doi: 10.31635/renewables.023.202200020
6. [6]
  Wu, S. Q.; Deng, D. J.; Zhang, E. J.; Li, H. N.; Xu, L. Carbon 2022, 196, 347. doi: 10.1016/j.carbon.2022.04.043 doi: 10.1016/j.carbon.2022.04.043
7. [7]
  Lee, C.; Shin, K.; Park, Y.; Yun, Y. H.; Doo, G.; Jung, G. H.; Kim, M.; Cho, W.; Kim, C.; Lee, H. M.; et al. Adv. Funct. Mater. 2023, 32, 2301557. doi: 10.1002/adfm.202301557 doi: 10.1002/adfm.202301557
8. [8]
  Hong, S.; Ham, K.; Hwang, J.; Kang, S.; Seo, M. H.; Choi, Y.; Han, B.; Lee, J.; Cho, K. Adv. Funct. Mater. 2023, 33, 2209543. doi: 10.1002/adfm.202209543 doi: 10.1002/adfm.202209543
9. [9]
  Zhao, S. Y.; Liu, T.; Dai, Y. W.; Wang, J.; Wang, Y.; Guo, Z. J.; Yu, J.; Bello, I. T.; Ni, M. Appl. Catal. B 2023, 320, 121992. doi: 10.1016/j.apcatb.2022.121992 doi: 10.1016/j.apcatb.2022.121992
10. [10]
  Liu, M. L.; Zhao, Z. P.; Duan, X. F.; Huang, Y. Adv. Mater. 2019, 31, 1802234. doi: 10.1002/adma.201802234 doi: 10.1002/adma.201802234
11. [11]
  Lai, C.; Gong, M.; Zhou, Y.; Fang, J.; Huang, L.; Deng, Z.; Liu, X.; Zhao, T.; Lin, R.; Wang, K.; et al. Appl. Catal. B 2020, 274, 119086. doi: 10.1016/j.apcatb.2020.119086 doi: 10.1016/j.apcatb.2020.119086
12. [12]
  Liu, W.; Zhang, J.; Bai, Z.; Jiang, G.; Li, M.; Feng, K.; Yang, L.; Ding, Y.; Yu, T.; Chen, Z.; et al. Adv. Funct. Mater. 2018, 28, 1706675. doi: 10.1002/adfm.201706675 doi: 10.1002/adfm.201706675
13. [13]
  Wu, M.; Zhang, G.; Chen, N.; Hu, Y.; Regier, T.; Rawach, D.; Sun, S. ACS Energy Lett. 2021, 6, 1153. doi: 10.1021/acsenergylett.1c00037 doi: 10.1021/acsenergylett.1c00037
14. [14]
  Wang, H.; Li, J.; Li, K.; Lin, Y.; Chen, J.; Gao, L.; Nicolosi, V.; Xiao, X.; Lee, J. M. Chem. Soc. Rev. 2021, 50, 1354. doi: 10.1039/D0CS00415D doi: 10.1039/D0CS00415D
15. [15]
  Xiong, Q.; Zheng, J.; Liu, B.; Liu, Y.; Li, H.; Yang, M. Appl. Catal. B 2023, 321, 122067. doi: 10.1016/j.apcatb.2022.122067 doi: 10.1016/j.apcatb.2022.122067
16. [16]
  Ma, Y.; Chen, W.; Jiang, Z.; Tian, X.; Wang, X.; Chen, G.; Jiang, Z. -J. J. Mater. Chem. A 2022, 10, 12616. doi: 10.1039/D2TA03110H doi: 10.1039/D2TA03110H
17. [17]
  Kim, K.; Min, K.; Go, Y.; Lee, Y.; Shim, S. E.; Lim, D.; Baeck, S. H. Appl. Catal. B 2022, 315, 121501. doi: 10.1016/j.apcatb.2022.121501 doi: 10.1016/j.apcatb.2022.121501
18. [18]
  Wu, Z.; Lu, X. F.; Zang, S.; Lou, X. W. Adv. Funct. Mater. 2020, 30, 1910274. doi: 10.1002/adfm.201910274 doi: 10.1002/adfm.201910274
19. [19]
  Huang, Z. F.; Wang, J.; Peng, Y.; Jung, C. Y.; Fisher, A.; Wang, X. Adv. Energy Mater. 2017, 7, 1700544. doi: 10.1002/aenm.201700544 doi: 10.1002/aenm.201700544
20. [20]
  Li, G.; Tang, Y.; Fu, T.; Xiang, Y.; Xiong, Z.; Si, Y.; Guo, C.; Jiang, Z. S. Chem. Eng. J. 2022, 429, 132174. doi: 10.1016/j.cej.2021.132174 doi: 10.1016/j.cej.2021.132174
21. [21]
  Chen, K.; Kim, S.; Rajendiran, R.; Prabakar, K.; Li, G.; Shi, Z.; Jeong, C.; Kang, J.; Li, O. L. J. Colloid Interface Sci 2021, 582, 977. doi: 10.1016/j.jcis.2020.08.101 doi: 10.1016/j.jcis.2020.08.101
22. [22]
  Sheng, K.; Yi, Q.; Chen, A. L.; Wang, Y.; Yan, Y.; Nie, H.; Zhou, X. ACS Appl. Mater. Interfaces 2021, 13, 45394. doi: 10.1021/acsami.1c10671 doi: 10.1021/acsami.1c10671
23. [23]
  Xu, X.; Xie, J.; Liu, B.; Wang, R.; Liu, M.; Zhang, J.; Liu, J.; Cai, Z.; Zou, J. Appl. Catal. B 2022, 316, 121687. doi: 10.1016/j.apcatb.2022.121687 doi: 10.1016/j.apcatb.2022.121687
24. [24]
  He, X.; Tian, Y.; Huang, Z.; Xu, L.; Wu, J.; Qian, J.; Zhang, J.; Li, H. J. Mater. Chem. A 2021, 9, 2301. doi: 10.1039/D0TA10370E doi: 10.1039/D0TA10370E
25. [25]
  Liu, Z.; Liu, D.; Zhao, L.; Tian, J.; Yang, J.; Feng, L. J. Mater. Chem. A 2021, 9, 7750. doi: 10.1039/D1TA01014J doi: 10.1039/D1TA01014J
26. [26]
  Ban, J.; Xu, H.; Cao, G.; Fan, Y.; Pang, W. K.; Shao, G.; Hu, J. Adv. Funct. Mater. 2023, 33, 2300623. doi: 10.1002/adfm.202300623 doi: 10.1002/adfm.202300623
27. [27]
  Jiang, R.; Tung, S. O.; Tang, Z.; Li, L.; Ding, L.; Xi, X.; Liu, Y.; Zhang, L.; Zhang, J. Energy Storage Mater. 2018, 12, 260. doi: 10.1016/j.ensm.2017.11.005 doi: 10.1016/j.ensm.2017.11.005
28. [28]
  Guo, Y.; Yuan, P.; Zhang, J.; Xia, H.; Cheng, F.; Zhou, M.; Li, J.; Qiao, Y.; Mu, S.; Xu, Q. Adv. Funct. Mater. 2018, 28, 1805641. doi: 10.1002/adfm.201805641 doi: 10.1002/adfm.201805641
29. [29]
  Ong, W. J.; Tan, L. L.; Ng, Y. H.; Yong, S. T.; Chai, S. P. Chem. Rev. 2016, 116, 7159. doi: 10.1021/acs.chemrev.6b00075 doi: 10.1021/acs.chemrev.6b00075
30. [30]
  Kang, J.; Zhang, H. Y.; Duan, X. G.; Sun, H. Q.; Tan, X. Y.; Liu, S. M.; Wang, S.B. Chem. Eng. J. 2019, 362, 251. doi: 10.1016/j.cej.2019.01.035. doi: 10.1016/j.cej.2019.01.035
31. [31]
  Yang, L.; Zhang, X.; Yu, L.; Hou, J.; Zhou, Z.; Lv, R. Adv. Mater. 2022, 34, 2105410. doi: 10.1002/adma.202105410 doi: 10.1002/adma.202105410
32. [32]
  Zhao, B.; Wu, Y.; Han, L.; Xia, Z.; Wang, Q.; Chang, S.; Liu, B.; Wang, G.; Shang, Y.; Cao, A. Energy Storage Mater. 2022, 50, 344. doi: 10.1016/j.ensm.2022.05.029 doi: 10.1016/j.ensm.2022.05.029
33. [33]
  Chen, Z.; Qin, Y.; Ren, Y.; Lu, W.; Orendorff, C.; Roth, E. P.; Amine, K. Energy Environ. Sci. 2011, 4, 4023. doi: 10.1039/c1ee01786a doi: 10.1039/c1ee01786a
34. [34]
  Wang, J.; Shu, R.; Chai, J.; Rao, S. G.; Le Febvrier, A.; Wu, H.; Zhu, Y.; Yao, C.; Luo, L.; Li, W.; et al. Mater. Des. 2022, 219, 110749. doi: 10.1016/j.matdes.2022.110749 doi: 10.1016/j.matdes.2022.110749
35. [35]
  Liu, Z.; Tan, H.; Liu, D.; Liu, X.; Xin, J.; Xie, J.; Zhao, M.; Song, L.; Dai, L.; Liu, H. Adv. Sci 2019, 6, 1801829. doi: 10.1002/advs.201801829 doi: 10.1002/advs.201801829
36. [36]
  Kuttiyiel, K. A.; Sasaki, K.; Chen, W. F.; Su, D.; Adzic, R. R. J. Mater. Chem. A 2014, 2, 591. doi: 10.1039/C3TA14301E doi: 10.1039/C3TA14301E
37. [37]
  Deng, D.; Qian, J.; Liu, X.; Li, H.; Su, D.; Li, H.; Li, H.; Xu, L. Adv. Funct. Materials 2022, 32, 2203471. doi: 10.1002/adfm.202203471 doi: 10.1002/adfm.202203471
38. [38]
  Deng, D.; Wu, S.; Li, H.; Li, H.; Xu, L. Small 2023, 19, 2205469. doi: 10.1002/smll.202205469 doi: 10.1002/smll.202205469
39. [39]
  López-Callejas, R.; Valencia-Alvarado, R.; Muñoz-Castro, A. E.; Godoy-Cabrera, O. G.; Barocio, S. R.; Chávez-Alarcón, E. Vacuum 2004, 76, 287. doi: 10.1016/j.vacuum.2004.07.060 doi: 10.1016/j.vacuum.2004.07.060
40. [40]
  Zhang, C.; Li, J.; Shi, C.; He, C.; Liu, E.; Zhao, N. J. Energy Chem. 2014, 23, 324. doi: 10.1016/S2095-4956(14)60154-6 doi: 10.1016/S2095-4956(14)60154-6
41. [41]
  Chen, M.; Lu, S.; Fu, X.; Luo, J. Adv. Sci. 2020, 7, 1903777. doi: 10.1002/advs.201903777 doi: 10.1002/advs.201903777
42. [42]
  Wu, M.; Zhang, G.; Qiao, J.; Chen, N.; Chen, W.; Sun, S. Nano Energy 2019, 61, 86. doi: 10.1016/j.nanoen.2019.04.031 doi: 10.1016/j.nanoen.2019.04.031
43. [43]
  Park, J.; Yoon, K. Y.; Kwak, M. J.; Lee, J. E.; Kang, J.; Jang, J. H. ACS Appl. Mater. Interfaces 2021, 13, 54906. doi: 10.1021/acsami.1c13872 doi: 10.1021/acsami.1c13872
44. [44]
  Xu, L.; Wu, S.; He, X.; Wang, H.; Deng, D.; Wu, J.; Li, H. Chem. Eng. J. 2022, 437, 135291. doi: 10.1016/j.cej.2022.135291 doi: 10.1016/j.cej.2022.135291
45. [45]
  Lou, Y.; Liu, J.; Liu, M.; Wang, F. ACS Catal. 2020, 10, 2443. doi: 10.1021/acscatal.9b03716 doi: 10.1021/acscatal.9b03716
46. [46]
  Xia, D.; Yang, X.; Xie, L.; Wei, Y.; Jiang, W.; Dou, M.; Li, X.; Li, J.; Gan, L.; Kang, F. Adv. Funct. Mater. 2019, 29, 1970332. doi: 10.1002/adfm.201970332 doi: 10.1002/adfm.201970332
47. [47]
  Zhang, J.; Sun, Y.; Zhu, J.; Kou, Z.; Hu, P.; Liu, L.; Li, S.; Mu, S.; Huang, Y. Nano Energy 2018, 52, 307. doi: 10.1016/j.nanoen.2018.08.003 doi: 10.1016/j.nanoen.2018.08.003
48. [48]
  Tang, H.; Yang, D.; Lu, M.; Kong, S.; Hou, Y.; Liu, D.; Liu, D.; Yan, S.; Chen, Z.; Yu, T.; et al. J. Mater. Chem. A 2021, 9, 25435. doi: 10.1039/D1TA07561F doi: 10.1039/D1TA07561F
1. [1]
  Meng-Yin Wang , Ruo-Bei Huang , Jian-Feng Xiong , Jing-Hua Tian , Jian-Feng Li , Zhong-Qun Tian . Critical Role and Recent Development of Separator in Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2307017-0. doi: 10.3866/PKU.WHXB202307017
2. [2]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
5. [5]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
6. [6]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
7. [7]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
8. [8]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
9. [9]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
10. [10]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
11. [11]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
12. [12]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
13. [13]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
14. [14]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
17. [17]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb₁₂WO₃₃ Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(338)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fe0.64Ni0.36@Fe3NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability

Metrics

通讯作者: 陈斌, bchen63@163.com

Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability