Citation: Junwen Lu, Shunan Zhang, Haozhi Zhou, Chaojie Huang, Lin Xia, Xiaofang Liu, Hu Luo, Hui Wang. Ir Single Atoms and Clusters Supported on α-MoC as Catalysts for Efficient Hydrogenation of CO₂ to CO[J]. Acta Physico-Chimica Sinica, ;2023, 39(11): 230202. doi: 10.3866/PKU.WHXB202302021 shu

Ir Single Atoms and Clusters Supported on α-MoC as Catalysts for Efficient Hydrogenation of CO₂ to CO

Junwen Lu ^{1, 2} ,
Shunan Zhang ^3,, ,
Haozhi Zhou ³ ,
Chaojie Huang ^{1, 2} ,
Lin Xia ¹ ,
Xiaofang Liu ¹ ,
Hu Luo ¹ ,
Hui Wang ^{1, 3,,}

1.
CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Institute of Carbon Neutrality, ShanghaiTech University, Shanghai 201203, China

Corresponding author: Shunan Zhang, zhangshn2@shanghaitech.edu.cn Hui Wang, wanghh@sari.ac.cn
Received Date: 14 February 2023
Revised Date: 20 March 2023
Accepted Date: 21 March 2023
Available Online: 24 March 2023
Fund Project: the National Key Research and Development Program of China 2022YFA1504800the National Key Research and Development Program of China 2022YFA1504702the National Key Research and Development Program of China 2022YFB4101900the National Natural Science Foundation of China 22108289the National Natural Science Foundation of China 22279158the National Natural Science Foundation of China 21905291CNOOC Institute of Chemicals & Advanced Materials YJSCZX07956YJShanghai Institute of Cleantech Innovation E244831E01

The conversion of CO₂ into CO via the reverse water gas shift (RWGS) reaction has recently attracted considerable attention owing to the increase in atmospheric CO₂ emissions. However, metal-supported catalysts easily undergo sintering and become inactive at high temperatures. To fabricate highly active and stable catalysts, molybdenum carbide (Mo_xC), with properties similar to those of precious metals, has been extensively investigated. In particular, it has been demonstrated that face-centered cubic α-MoC can strongly interact with support metals, rendering it an attractive candidate as a catalyst for the RWGS reaction. Furthermore, it has been previously demonstrated that metallic Ir, with unique electronic properties and a low CO desorption barrier, is active for the RWGS at low temperatures (250–300 ℃). Accordingly, in this study, a system of Ir species and α-MoC was constructed using a solvent evaporation self-assembly method. The catalytic performance of the Ir/MoC catalysts for the RWGS reaction was considerably superior to that of pure α-MoC over a wide temperature range (200–500 ℃) owing to the synergistic effect of Ir and α-MoC. The optimal 0.5%Ir/MoC catalyst yielded a CO₂ conversion of 48.4% at 500 ℃, 0.1 MPa, and 300000 mL·g⁻¹·h⁻¹, which was comparable to the equilibrium conversion (49.9%). The CO selectivity and space-time yield of CO over 0.5%Ir/MoC reached 94.0% and 423.1 μmol·g⁻¹·s⁻¹, respectively, which were higher than most of the previously reported values. Moreover, 0.5%Ir/MoC retained its catalytic properties over 100 h and demonstrated excellent stability at high temperatures. Several characterization methods were used to demonstrate that the Ir species supported on α-MoC substrates were highly dispersed. The strong metal-support interaction between Ir and α-MoC, which occurred via electron transfer, considerably improved the stability of the Ir/MoC catalysts. For the Ir/MoC catalysts with Ir loadings > 0.2% (mass fraction), Ir single atoms (Ir₁) and clusters (Ir_n) coexisted to create Ir_n-Ir₁-C-Mo synergistic sites between Ir and α-MoC. The number of Ir₁ species and size of Ir_n species of 0.5%Ir/MoC were higher and smaller, respectively, than those of the other Ir/MoC catalysts. This conferred 0.5%Ir/MoC an optimal electron density, which contributed to the remarkable adsorption and activation of CO₂ and H₂ during the RWGS. In situ diffuse reflectance infrared Fourier transform spectroscopy experiments revealed that the RWGS reaction mechanism occurred via a formate pathway. Although the formation of Ir_n-Ir₁-C-Mo synergistic sites did not affect the reaction mechanism, the generation and decomposition of formate intermediates were distinctly promoted. Therefore, the catalytic performance of Ir/MoC was effectively improved by the synergistic effect. This study provides a guide for designing efficient and stable catalysts for CO₂ utilization.
- Reverse water gas shift reaction,
- Metal-support interaction,
- Synergistic effect,
- Molybdenum carbide,
- Iridium catalyst
1. [1]
  Su, X.; Yang, X.; Zhao, B.; Huang, Y. J. Energy Chem. 2017, 26 (5), 854. doi: 10.1016/j.jechem.2017.07.006 doi: 10.1016/j.jechem.2017.07.006
2. [2]
  Chu, W.; Wang, L. -N.; Chernavskii, P. A.; Khodakov, A. Y. Angew. Chem. Int. Ed. 2008, 47 (27), 5052. doi: 10.1002/anie.200800657 doi: 10.1002/anie.200800657
3. [3]
  Zhang, D.; Luo, J.; Wang, J.; Xiao, X.; Liu, Y.; Qi, W.; Su, D. S.; Chu, W. Chin. J. Catal. 2018, 39 (1), 157. doi: 10.1016/S1872-2067(17)62967-X doi: 10.1016/S1872-2067(17)62967-X
4. [4]
  Varvoutis, G.; Lykaki, M.; Papista, E.; Carabineiro, S. A. C.; Psarras, A. C.; Marnellos, G. E.; Konsolakis, M. J. CO₂ Util. 2021, 44, 101408. doi: 10.1016/j.jcou.2020.101408 doi: 10.1016/j.jcou.2020.101408
5. [5]
  Loiland, J. A.; Wulfers, M. J.; Marinkovic, N. S.; Lobo, R. F. Catal. Sci. Technol. 2016, 6 (14), 5267. doi: 10.1039/C5CY02111A doi: 10.1039/C5CY02111A
6. [6]
  Lu, B.; Kawamoto, K. J. Environ. Chem. Eng. 2013, 1 (3), 300. doi: 10.1016/j.jece.2013.05.008 doi: 10.1016/j.jece.2013.05.008
7. [7]
  Vovchok, D.; Zhang, C.; Hwang, S.; Jiao, L.; Zhang, F.; Liu, Z.; Senanayake, S. D.; Rodriguez, J. A. ACS Catal. 2020, 10 (17), 10216. doi: 10.1021/acscatal.0c01584 doi: 10.1021/acscatal.0c01584
8. [8]
  Jung, H.S.; Zafar, F.; Wang, X.; Nguyen, T. X.; Hong, C. H.; Hur, Y. G.; Choung, J. W.; Park, M. -J.; Bae, J. W. ACS Catal. 2021, 11 (22), 14210. doi: 10.1021/acscatal.1c04451 doi: 10.1021/acscatal.1c04451
9. [9]
  Liu, H. -X.; Li, S. -Q.; Wang, W. -W.; Yu, W. -Z.; Zhang, W. -J.; Ma, C.; Jia, C. J. Nat. Commun. 2022, 13 (1), 867. doi: 10.1038/s41467-022-28476-5 doi: 10.1038/s41467-022-28476-5
10. [10]
  Morse, J. R.; Juneau, M.; Baldwin, J. W.; Porosoff, M. D.; Willauer, H. D. J. CO₂ Util. 2020, 35, 38. doi: 10.1016/j.jcou.2019.08.024 doi: 10.1016/j.jcou.2019.08.024
11. [11]
  Rodriguez, J. A.; Evans, J.; Feria, L.; Vidal, A. B.; Liu, P.; Nakamura, K.; Illas, F. J. Catal. 2013, 307, 162. doi: 10.1016/j.jcat.2013.07.023 doi: 10.1016/j.jcat.2013.07.023
12. [12]
  Porosoff, M. D.; Yan, B.; Chen, J. G. Energ Environ. Sci. 2016, 9 (1), 62. doi: 10.1039/C5EE02657A doi: 10.1039/C5EE02657A
13. [13]
  Li, J.; Liu, L.; Liu, Y.; Li, M.; Zhu, Y.; Liu, H.; Kou, Y.; Zhang, J.; Han, Y.; Ma, D. Energ Environ. Sci. 2014, 7 (1), 393. doi: 10.1039/C3EE41945B doi: 10.1039/C3EE41945B
14. [14]
  Ma, Y.; Guo, Z.; Jiang, Q.; Wu, K. -H.; Gong, H.; Liu, Y. J. Energy Chem. 2020, 50, 37. doi: 10.1016/j.jechem.2020.03.012 doi: 10.1016/j.jechem.2020.03.012
15. [15]
  Zhang, X.; Zhu, X.; Lin, L.; Yao, S.; Zhang, M.; Liu, X.; Wang, X.; Li, Y. -W.; Shi, C.; Ma, D. ACS Catal. 2016, 7 (1), 912. doi: 10.1021/acscatal.6b02991 doi: 10.1021/acscatal.6b02991
16. [16]
  Li, S.; Cao, R.; Xu, M.; Deng, Y.; Lin, L.; Yao, S.; Liang, X.; Peng, M.; Gao, Z.; Ge, Y. Nat. Sci. Rev. 2021, 9 (1), 2095. doi: 10.1093/nsr/nwab026 doi: 10.1093/nsr/nwab026
17. [17]
  Lin, L.; Zhou, W.; Gao, R.; Yao, S.; Zhang, X.; Xu, W.; Zheng, S.; Jiang, Z.; Yu, Q.; Li, Y. -W. Nature 2017, 544 (7648), 80. doi: 10.1038/nature21672 doi: 10.1038/nature21672
18. [18]
  Ge, Y.; Qin, X.; Li, A.; Deng, Y.; Lin, L.; Zhang, M.; Yu, Q.; Li, S.; Peng, M.; Xu, Y. J. Am. Chem. Soc. 2021, 143 (2), 628. doi: 10.1021/jacs.0c11285 doi: 10.1021/jacs.0c11285
19. [19]
  Fan, X.; Liu, C.; Wu, M.; Gao, B.; Zheng, L.; Zhang, Y.; Zhang, H.; Gao, Q.; Cao, X.; Tang, Y. Appl. Catal. B 2022, 318, 121867. doi: 10.1016/j.apcatb.2022.121867 doi: 10.1016/j.apcatb.2022.121867
20. [20]
  Reddy, K. P.; Dama, S.; Mhamane, N. B.; Ghosalya, M. K.; Raja, T.; Satyanarayana, C. V.; Gopinath, C. S. Dalton Trans. 2019, 48 (32), 12199. doi: 10.1039/C9DT01774G doi: 10.1039/C9DT01774G
21. [21]
  Gao, J.; Wu, Y.; Jia, C.; Zhong, Z.; Gao, F.; Yang, Y.; Liu, B. Catal. Commun. 2016, 84, 147. doi: 10.1016/j.catcom.2016.06.026 doi: 10.1016/j.catcom.2016.06.026
22. [22]
  Ma, D. Acta Phys. -Chim. Sin. 2019, 35 (8), 794. doi: 10.3866/PKU.WHXB201810033
23. [23]
  Deng, Y.; Ge, Y.; Xu, M.; Yu, Q.; Xiao, D.; Yao, S.; Ma, D. Acc. Chem. Res. 2019, 52 (12), 3372. doi: 10.1021/acs.accounts.9b00182 doi: 10.1021/acs.accounts.9b00182
24. [24]
  Yao, S.; Zhang, X.; Zhou, W.; Gao, R.; Xu, W.; Ye, Y.; Lin, L.; Wen, X.; Liu, P.; Chen, B. Science 2017, 357 (6349), 389. doi: 10.1126/science.aah4321 doi: 10.1126/science.aah4321
25. [25]
  Lin, L.; Yao, S.; Gao, R.; Liang, X.; Yu, Q.; Deng, Y.; Liu, J.; Peng, M.; Jiang, Z.; Li, S. Nat. Nanotechnol. 2019, 14 (4), 354. doi: 10.1038/s41565-019-0366-5 doi: 10.1038/s41565-019-0366-5
26. [26]
  Wu, K. Acta Phys. -Chim. Sin. 2017, 33 (6), 1073. doi: 10.3866/PKU.WHXB201704122
27. [27]
  Jin, C.; Wang, B.; Zhou, Y.; Yang, F.; Guo, P.; Liu, Z.; Shen, W. Chem. Commun. 2022, 58 (52), 7313. doi: 10.1039/D2CC02478K doi: 10.1039/D2CC02478K
28. [28]
  Guo, Y.; Wang, M.; Zhu, Q.; Xiao, D.; Ma, D. Nat. Catal. 2022, 5 (9), 766. doi: 10.1038/s41929-022-00839-7 doi: 10.1038/s41929-022-00839-7
29. [29]
  Chen, X.; Su, X.; Su, H. -Y.; Liu, X.; Miao, S.; Zhao, Y.; Sun, K.; Huang, Y.; Zhang, T. ACS Catal. 2017, 7 (7), 4613. doi: 10.1021/acscatal.7b00903 doi: 10.1021/acscatal.7b00903
30. [30]
  Perumal, S.; Lim, T.; Seenivasan, S.; Seo, J. Appl. Surf. Sci. 2022, 604, 154553. doi: 10.1016/j.apsusc.2022.154553 doi: 10.1016/j.apsusc.2022.154553
31. [31]
  Zhang, Y.; Zhang, Z.; Yang, X.; Wang, R.; Duan, H.; Shen, Z.; Li, L.; Su, Y.; Yang, R.; Zhang, Y. Green Chem. 2020, 22 (20), 6855. doi: 10.1039/D0GC02302G doi: 10.1039/D0GC02302G
32. [32]
  Li, S.; Xu, Y.; Chen, Y.; Li, W.; Lin, L.; Li, M.; Deng, Y.; Wang, X.; Ge, B.; Yang, C. Angew. Chem. Int. Ed. 2017, 56 (36), 10761. doi: 10.1002/anie.201705002 doi: 10.1002/anie.201705002
33. [33]
  Lin, L.; Yu, Q.; Peng, M.; Li, A.; Yao, S.; Tian, S.; Liu, X.; Li, A.; Jiang, Z.; Gao, R. J. Am. Chem. Soc. 2021, 143 (1), 309. doi: 10.1021/jacs.0c10776 doi: 10.1021/jacs.0c10776
34. [34]
  Zuo, J.; Na, W.; Zhang, P.; Yang, X.; Wen, J.; Zheng, M.; Wang, H. Mol. Catal. 2022, 526, 112357. doi: 10.1016/j.mcat.2022.112357 doi: 10.1016/j.mcat.2022.112357
35. [35]
  Pahija, E.; Panaritis, C.; Gusarov, S.; Shadbahr, J.; Bensebaa, F.; Patience, G.; Boffito, D. C. ACS Catal. 2022, 12 (12), 6887. doi: 10.1021/acscatal.2c01099 doi: 10.1021/acscatal.2c01099
36. [36]
  Zhang, Q.; Pastor-Pérez, L.; Jin, W.; Gu, S.; Reina, T. R. Appl. Catal. B. 2019, 244, 889. doi: 10.1016/j.apcatb.2018.12.023 doi: 10.1016/j.apcatb.2018.12.023
37. [37]
  Wang, L. -X.; Guan, E.; Wang, Z.; Wang, L.; Gong, Z.; Cui, Y.; Yang, Z.; Wang, C.; Zhang, J.; Meng, X. ACS Catal. 2020, 10 (16), 9261. doi: 10.1021/acscatal.0c00907 doi: 10.1021/acscatal.0c00907
38. [38]
  Xu, J.; Gong, X.; Hu, R.; Liu, Z. -W.; Liu, Z. -T. Mol. Catal. 2021, 516, 111954. doi: 10.1016/j.mcat.2021.111954 doi: 10.1016/j.mcat.2021.111954
39. [39]
  Ma, Y.; Ren, Y.; Zhou, Y.; Liu, W.; Baaziz, W.; Ersen, O.; Cuong, P.; Greiner, M.; Chu, W.; Wang, A. Angew. Chem. Int. Ed. 2020, 59 (48), 21613. doi: 10.1002/anie.202007707 doi: 10.1002/anie.202007707
40. [40]
  Gu, F.; Zheng, L.; Wei, H.; Mi, W.; Zhang, C.; Su, Q.; Zhu, W.; Lin, W. Appl. Surf. Sci. 2022, 606, 155008. doi: 10.1016/j.apsusc.2022.155008 doi: 10.1016/j.apsusc.2022.155008
41. [41]
  Tang, Y.; Yang, Z.; Guo, C.; Han, H.; Jiang, Y.; Wang, Z.; Liu, J.; Wu, L.; Wang, F. J. Mater. Chem. A 2022, 10 (22), 12157. doi: 10.1039/D2TA00933A doi: 10.1039/D2TA00933A
42. [42]
  Yang, Q.; Sun, K.; Xu, Y.; Ding, Z.; Hou, R. Appl. Catal. A-Gen. 2022, 630, 118455. doi: 10.1016/j.apcata.2021.118455 doi: 10.1016/j.apcata.2021.118455
43. [43]
  Chen, J. G. Chem. Rev. 1996, 96 (4), 1477. doi: 10.1021/cr950232u doi: 10.1021/cr950232u
44. [44]
  Xia, Z.; Zhang, H.; Shen, K.; Qu, Y.; Jiang, Z. Phys. B Condens. Matter. 2018, 542, 12. doi: 10.1016/j.physb.2018.04.039 doi: 10.1016/j.physb.2018.04.039
45. [45]
  Ravel, B.; Newville, M. J. Synchrot. Radiat. 2005, 12 (4), 537. doi: 10.1107/S0909049505012719 doi: 10.1107/S0909049505012719
46. [46]
  Wang, S. -G.; Liao, X. -Y.; Cao, D. -B.; Huo, C. -F.; Li, Y. -W.; Wang, J.; Jiao, H. J. Phys. Chem. 2007, 111 (45), 16934. doi: 10.1021/jp074570y doi: 10.1021/jp074570y
47. [47]
  Liu, H. -X.; Li, J. -Y.; Qin, X.; Ma, C.; Wang, W. -W.; Xu, K.; Yan, H.; Xiao, D.; Jia, C. -J.; Fu, Q. Nat. Commun. 2022, 13 (1), 5800. doi: 10.1038/s41467-022-33308-7 doi: 10.1038/s41467-022-33308-7
48. [48]
  Alvarez-Galvan, C.; Lustemberg, P. G.; Oropeza, F. E.; Bachiller-Baeza, B.; Dapena Ospina, M.; Herranz, M.; Cebollada, J.; Collado, L.; Campos-Martin, J. M.; de la Peña-O'Shea, V. A. ACS Appl. Mater. Interfaces 2022, 14 (45), 50739. doi: 10.1021/acsami.2c11248 doi: 10.1021/acsami.2c11248
49. [49]
  Zhang, Y.; Liang, L.; Chen, Z.; Wen, J.; Zhong, W.; Zou, S.; Fu, M.; Chen, L.; Ye, D. Appl. Surf. Sci. 2020, 516, 146035. doi: 10.1016/j.apsusc.2020.146035 doi: 10.1016/j.apsusc.2020.146035
50. [50]
  Zhang, X.; Liu, Y.; Zhang, M.; Yu, T.; Chen, B.; Xu, Y.; Crocker, M.; Zhu, X.; Zhu, Y.; Wang, R. Chem 2020, 6 (12), 3312. doi: 10.1016/j.chempr.2020.09.016 doi: 10.1016/j.chempr.2020.09.016
51. [51]
  Xu, D.; Ding, M.; Hong, X.; Liu, G. ACS Catal. 2020, 10 (24), 14516. doi: 10.1021/acscatal.0c03575 doi: 10.1021/acscatal.0c03575
52. [52]
  Zheng, H.; Liao, W.; Ding, J.; Xu, F.; Jia, A.; Huang, W.; Zhang, Z. ACS Catal. 2022, 12 (24), 15451. doi: 10.1021/acscatal.2c04437 doi: 10.1021/acscatal.2c04437
53. [53]
  Bobadilla, L. F.; Santos, J. L.; Ivanova, S.; Odriozola, J. A.; Urakawa, A. ACS Catal. 2018, 8 (8), 7455. doi: 10.1021/acscatal.8b02121 doi: 10.1021/acscatal.8b02121
1. [1]
  Zimo Peng , Quan Zhang , Gaocan Qi , Hao Zhang , Qian Liu , Guangzhi Hu , Jun Luo , Xijun Liu . Nanostructured Pt@RuOx catalyst for boosting overall acidic seawater splitting. Chinese Journal of Structural Chemistry, 2024, 43(1): 100191-100191. doi: 10.1016/j.cjsc.2023.100191
2. [2]
  Jiangping Chen , Hongju Ren , Kai Wu , Huihuang Fang , Chongqi Chen , Li Lin , Yu Luo , Lilong Jiang . Boosting hydrogen production of ammonia decomposition via the construction of metal-oxide interfaces. Chinese Journal of Structural Chemistry, 2024, 43(2): 100236-100236. doi: 10.1016/j.cjsc.2024.100236
3. [3]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
4. [4]
  Ke Gong , Jinghan Liao , Jiangtao Lin , Quan Wang , Zhihua Wu , Liting Wang , Jiali Zhang , Yi Dong , Yourong Duan , Jianhua Chen . Mitochondria-targeted nanoparticles overcome chemoresistance via downregulating BACH1/CD47 axis in ovarian carcinoma. Chinese Chemical Letters, 2024, 35(5): 108888-. doi: 10.1016/j.cclet.2023.108888
5. [5]
  Liping Zhao , Xixi Guo , Zhimeng Zhang , Xi Lu , Qingxuan Zeng , Tianyun Fan , Xintong Zhang , Fenbei Chen , Mengyi Xu , Min Yuan , Zhenjun Li , Jiandong Jiang , Jing Pang , Xuefu You , Yanxiang Wang , Danqing Song . Novel berberine derivatives as adjuvants in the battle against Acinetobacter baumannii: A promising strategy for combating multi-drug resistance. Chinese Chemical Letters, 2024, 35(10): 109506-. doi: 10.1016/j.cclet.2024.109506
6. [6]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
7. [7]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
8. [8]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
9. [9]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
10. [10]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
11. [11]
  Chenlu Huang , Xinyu Yang , Qingyu Yu , Linhua Zhang , Dunwan Zhu . Gas-generating polymersomes-based amplified photoimmunotherapy for abscopal effect and tumor metastasis inhibition. Chinese Chemical Letters, 2024, 35(6): 109680-. doi: 10.1016/j.cclet.2024.109680
12. [12]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
13. [13]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
14. [14]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
15. [15]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
16. [16]
  Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN₄-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
17. [17]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
18. [18]
  Yixuan Wang , Jiexin Li , Zhihao Shang , Chengcheng Feng , Jianmin Gu , Maosheng Ye , Ran Zhao , Danna Liu , Jingxin Meng , Shutao Wang . Wettability-driven synergistic resistance of scale and oil on robust superamphiphobic coating. Chinese Chemical Letters, 2024, 35(7): 109623-. doi: 10.1016/j.cclet.2024.109623
19. [19]
  Jinyu Guo , Yandai Lin , Shaohua He , Yueqing Chen , Fenglu Li , Renjie Ruan , Gaoxing Pan , Hexin Nan , Jibin Song , Jin Zhang . Utilizing dual-responsive iridium(Ⅲ) complex for hepatocellular carcinoma: Integrating photoacoustic imaging with chemotherapy and photodynamic therapy. Chinese Chemical Letters, 2024, 35(9): 109537-. doi: 10.1016/j.cclet.2024.109537
20. [20]
  Chun-Yun Ding , Ru-Yuan Zhang , Yu-Wu Zhong , Jiannian Yao . Binary and heterostructured microplates of iridium and ruthenium complexes: Preparation, characterization, and thermo-responsive emission. Chinese Journal of Structural Chemistry, 2024, 43(10): 100393-100393. doi: 10.1016/j.cjsc.2023.100393

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1065)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ir Single Atoms and Clusters Supported on α-MoC as Catalysts for Efficient Hydrogenation of CO2 to CO

Metrics

通讯作者: 陈斌, bchen63@163.com

Ir Single Atoms and Clusters Supported on α-MoC as Catalysts for Efficient Hydrogenation of CO₂ to CO