Citation: Zhenzhong Liu, Siwen Wan, Yang Wu, Boyan Wang, Hongliang Ji. Highly Efficient Degradation of Sulfamethoxazole Using Activating Peracetic Acid with CoFe2O4/CuO[J]. Acta Physico-Chimica Sinica, ;2023, 39(5): 221101. doi: 10.3866/PKU.WHXB202211019 shu

Highly Efficient Degradation of Sulfamethoxazole Using Activating Peracetic Acid with CoFe2O4/CuO

  • Corresponding author: Zhenzhong Liu, liuzz79@126.com
  • Received Date: 12 November 2022
    Revised Date: 13 December 2022
    Accepted Date: 14 December 2022
    Available Online: 23 December 2022

  • Advanced oxidation processes (AOPs), especially AOPs that use transition metals as catalyst activated oxidants, are extremely effective in removing organic pollutants; they can completely degrade pollutants into CO2 and H2O. Thus, they have been widely studied in the field of water treatment. However, owing to the low catalytic efficiency and metal leakage, their applicability is currently limited. In this paper, the composite catalyst CoFe2O4/CuO containing spinel cobalt ferrite and copper oxide was successfully prepared by the chemical precipitation and sol-gel methods with two steps. The prepared CoFe2O4/CuO was characterized using scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD), and its ability to remove sulfamethoxazole (SMX) with different AOPs was evaluated. Characterization results show that CoFe2O4 and CuO are well-complexed together, and the catalyst has good crystallinity. The effects of peracetic acid (PAA) concentration, catalyst dosage, common interfering substances (Cl, HCO3, SO42−, and HA) in water, and different radical scavengers on SMX removal were also investigated. The results show that CoFe2O4/CuO has the characteristics of both CoFe2O4 and CuO. Compared with CoFe2O4 or CuO alone, CoFe2O4/CuO exhibits an excellent activation performance for PAA. Under the optimal reaction conditions (catalyst dosage = 20 mg·L−1, c(PAA) = 200 μmol·L−1, c(SMX) = 10 μmol·L−1), the degradation rate of SMX reaches 92% within 90 s. The existence of Cu+/Cu2+ electron pairs can convert Co from the high valence to low valence state and accelerate the conversion of Co2+/Co3+, thereby improving the catalytic performance. An increase in the PAA concentration increases the removal efficiency of SMX; however, too high a concentration lowers removal efficiency. Compared to acidic or alkaline conditions, the CoFe2O4/CuO reaction system exhibits a better removal rate of SMX under neutral conditions. The common interfering substances in the environment have different effects on the CoFe2O4/CuO reaction system. Cl promotes the degradation of SMX by producing Cl•, HCO3 and HA inhibit the removal of SMX because of their quenching effect on free radicals, and SO42− has no significant effect on the progress of the reaction. The XPS characterization results before and after the reaction show that the valence state of Co changes, indicating that Co is the main element involved in the activation of PAA. Radical quenching experiments demonstrate that the organic radical (R―O•) plays a dominant role in the removal of SMX. Further, the removal rate of SMX decreases after the catalyst is subjected to 3 recycle; nevertheless, it achieves a relatively rapid degradation of SMX (85% within 10 min).
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    1. [1]

      Xie, Y.; Wan, J.; Yan, Z.; Wang, Y.; Xiao, T.; Hou, J.; Chen, H. Chem. Eng. J. 2022, 429, 132237. doi: 10.1016/j.cej.2021.132237  doi: 10.1016/j.cej.2021.132237

    2. [2]

      Fu, J.; Feng, L.; Liu, Y.; Zhang, L.; Li, S. Chemosphere 2022, 287, 132094. doi: 10.1016/j.chemosphere.2021.132094  doi: 10.1016/j.chemosphere.2021.132094

    3. [3]

      Zhu, W.; Sun, F.; Goei, R.; Zhou, Y. Appl. Catal. B 2017, 207, 93. doi: 10.1016/j.apcatb.2017.02.012  doi: 10.1016/j.apcatb.2017.02.012

    4. [4]

      Nguyen, T.-B.; Huang, C.; Doong, R.-A.; Chen, C.-W.; Dong, C.-D. Chem. Eng. J. 2020, 384, 123383. doi: 10.1016/j.cej.2019.123383  doi: 10.1016/j.cej.2019.123383

    5. [5]

      Wang, X.; Lu, W.; Zhao, Z.; Zhong, H.; Zhu, Z.; Chen, W. Chem. Eng. J. 2020, 400, 125872. doi: 10.1016/j.cej.2020.125872  doi: 10.1016/j.cej.2020.125872

    6. [6]

      Kim, J.; Du, P.; Liu, W.; Luo, C.; Zhao, H.; Huang, C.-H. Environ. Sci. Technol. 2020, 54, 5268. doi: 10.1021/acs.est.0c00356  doi: 10.1021/acs.est.0c00356

    7. [7]

      Luukkonen, T.; Heyninck, T.; Rämö, J.; Lassi, U. Water Res. 2015, 85, 275. doi: 10.1016/j.watres.2015.08.037  doi: 10.1016/j.watres.2015.08.037

    8. [8]

      Henao, L. D.; Turolla, A.; Antonelli, M. Chemosphere 2018, 213, 25. doi: 10.1016/j.chemosphere.2018.09.005  doi: 10.1016/j.chemosphere.2018.09.005

    9. [9]

      Zhou, X.; Wu, H.; Zhang, L.; Liang, B.; Sun, X.; Chen, J. Molecules 2020, 25, 2725. doi: 10.3390/molecules25122725  doi: 10.3390/molecules25122725

    10. [10]

      Cai, M.; Sun, P.; Zhang, L.; Huang, C.-H. Environ. Sci. Technol. 2017, 51, 14217. doi: 10.1021/acs.est.7b04694  doi: 10.1021/acs.est.7b04694

    11. [11]

      Chen, S.; Cai, M.; Liu, Y.; Zhang, L.; Feng, L. Water Res. 2019, 150, 153. doi: 10.1016/j.watres.2018.11.044  doi: 10.1016/j.watres.2018.11.044

    12. [12]

      Li, W.; Li, Y.; Zhang, D.; Lan, Y.; Guo, J. J. Hazard. Mater. 2020, 381, 121209. doi: 10.1016/j.jhazmat.2019.121209  doi: 10.1016/j.jhazmat.2019.121209

    13. [13]

      Cruz, D. R.; de Jesus, G. K.; Santos, C. A.; Silva, W. R.; Wisniewski, A., Jr.; Cunha, G. C.; Romão, L. P. Chemosphere 2021, 280, 130675. doi: 10.1016/j.chemosphere.2021.130675  doi: 10.1016/j.chemosphere.2021.130675

    14. [14]

      Yu, J.; Qiu, W.; Xu, H.; Lu, X.; Ma, J.; Lu, D. Chem. Eng. J. 2021, 421, 129498. doi: 10.1016/j.cej.2021.129498  doi: 10.1016/j.cej.2021.129498

    15. [15]

      Ding, R.-R.; Li, W.-Q.; He, C.-S.; Wang, Y.-R.; Liu, X.-C.; Zhou, G.-N.; Mu, Y. Appl. Catal. B 2021, 291, 120069. doi: 10.1016/j.apcatb.2021.120069  doi: 10.1016/j.apcatb.2021.120069

    16. [16]

      Hasanvandian, F.; Shokri, A.; Moradi, M.; Kakavandi, B.; Setayesh, S. R. J. Hazard. Mater. 2022, 423, 127090. doi: 10.1016/j.jhazmat.2021.127090  doi: 10.1016/j.jhazmat.2021.127090

    17. [17]

      Xiong, W.-H.; Zhang, W.-C.; Yu, C.-P.; Shen, R.-Q.; Cheng, J.; Ye, J.-H.; Qin, Z.-C. Acta Phys. -Chim. Sin. 2016, 32, 2093.  doi: 10.3866/PKU.WHXB201605121

    18. [18]

      Ren, Y.; Lin, L.; Ma, J.; Yang, J.; Feng, J.; Fan, Z. Appl. Catal. B 2015, 165, 572. doi: 10.1016/j.apcatb.2014.10.051  doi: 10.1016/j.apcatb.2014.10.051

    19. [19]

      Guan, Y.-H.; Ma, J.; Ren, Y.-M.; Liu, Y.-L.; Xiao, J.-Y.; Lin, L.-Q.; Zhang, C. Water Res. 2013, 47, 5431. doi: 10.1016/j.watres.2013.06.023  doi: 10.1016/j.watres.2013.06.023

    20. [20]

      Chen, X.-L.; Li, F.; Zhang, M.; Liu, B.; Chen, H.; Wang, H. Sci. Total Environ. 2021, 777, 145794. doi: 10.1016/j.scitotenv.2021.145794  doi: 10.1016/j.scitotenv.2021.145794

    21. [21]

      Chu, S.; Li, X.; W. Robertson, A.; Sun, Z. Acta Phys. -Chim. Sin. 2021, 37, 2009023.  doi: 10.3866/PKU.WHXB202009023

    22. [22]

      Wang, M.; Jin, C.; Kang, J.; Liu, J.; Tang, Y.; Li, Z.; Li, S. Chem. Eng. J. 2021, 416, 128118. doi: 10.1016/j.cej.2020.128118  doi: 10.1016/j.cej.2020.128118

    23. [23]

      Kiani, R.; Mirzaei, F.; Ghanbari, F.; Feizi, R.; Mehdipour, F. J. Water Process Eng. 2020, 38, 101623. doi: 10.1016/j.jwpe.2020.101623  doi: 10.1016/j.jwpe.2020.101623

    24. [24]

      Zhou, J.-J.; Ji, W.; Xu, L.; Yang, Y.; Wang, W.; Ding, H.; Xu, X.; Wang, W.; Zhang, P.; Hua, Z. Chem. Eng. J. 2022, 428, 132123. doi: 10.1016/j.cej.2021.132123  doi: 10.1016/j.cej.2021.132123

    25. [25]

      Yu, R.; Zhao, J.; Zhao, Z.; Cui, F. J. Hazard. Mater. 2020, 390, 121998. doi: 10.1016/j.jhazmat.2019.121998  doi: 10.1016/j.jhazmat.2019.121998

    26. [26]

      Lin, J.-Y.; Chen, P.-Y.; Kwon, E.; Da Oh, W.; You, S.; Huang, C.-W.; Ghanbari, F.; Wi-Afedzi, T.; Lin, K.-Y. A. J. Water Process Eng. 2021, 40, 101933. doi: 10.1016/j.jwpe.2021.101933  doi: 10.1016/j.jwpe.2021.101933

    27. [27]

      Li, Y.; Zhu, W.; Guo, Q.; Wang, X.; Zhang, L.; Gao, X.; Luo, Y. Sep. Purif. Technol. 2021, 276. doi: 10.1016/j.seppur.2021.119403  doi: 10.1016/j.seppur.2021.119403

    28. [28]

      Wang, J.; Xiong, B.; Miao, L.; Wang, S.; Xie, P.; Wang, Z.; Ma, J. Appl. Catal. B 2021, 280, 119422. doi: 10.1016/j.apcatb.2020.119422  doi: 10.1016/j.apcatb.2020.119422

    29. [29]

      Zhang, P.; Zhang, X.; Zhao, X.; Jing, G.; Zhou, Z. J. Hazard. Mater. 2022, 424, 127653. doi: 10.1016/j.jhazmat.2021.127653  doi: 10.1016/j.jhazmat.2021.127653

    30. [30]

      Chen, C.; Liu, L.; Guo, J.; Zhou, L.; Lan, Y. Chem. Eng. J. 2019, 361, 1304. doi: 10.1016/j.cej.2018.12.156  doi: 10.1016/j.cej.2018.12.156

    31. [31]

      Li, R.; Manoli, K.; Kim, J.; Feng, M.; Huang, C. H.; Sharma, V. K. Environ. Sci. Technol. 2021, 55, 9150. doi: 10.1021/acs.est.0c06676  doi: 10.1021/acs.est.0c06676

    32. [32]

      Zhang, L.; Chen, J.; Zheng, T.; Xu, Y.; Liu, T.; Yin, W.; Zhang, Y.; Zhou, X. Water Res. 2022, 229, 119462. doi: 10.1016/j.watres.2022.119462  doi: 10.1016/j.watres.2022.119462

    33. [33]

      Kim, J.; Zhang, T.; Liu, W.; Du, P.; Dobson, J. T.; Huang, C.-H. Environ. Sci. Technol. 2019, 53, 13312. doi: 10.1021/acs.est.9b02991  doi: 10.1021/acs.est.9b02991

    34. [34]

      Wu, W.; Tian, D.; Liu, T.; Chen, J.; Huang, T.; Zhou, X.; Zhang, Y. Chem. Eng. J. 2020, 394, 124938. doi: 10.1016/j.cej.2020.124938  doi: 10.1016/j.cej.2020.124938

    35. [35]

      Dong, J.; Xu, W.; Liu, S.; Gong, Y.; Yang, T.; Du, L.; Chen, Q.; Tan, X.; Liu, Y. Chem. Eng. J. 2022, 430, 132868. doi: 10.1016/j.cej.2021.132868  doi: 10.1016/j.cej.2021.132868

    36. [36]

      Liu, Y.; He, X.; Duan, X.; Fu, Y.; Dionysiou, D. D. Chem. Eng. J. 2015, 276, 113. doi: 10.1016/j.cej.2015.04.048  doi: 10.1016/j.cej.2015.04.048

    37. [37]

      Hu, J.; Li, T.; Zhang, X.; Ren, H.; Huang, H. Chemosphere 2022, 287, 132261. doi: 10.1016/j.chemosphere.2021.132261  doi: 10.1016/j.chemosphere.2021.132261

    38. [38]

      Wang, L.; Yan, T.; Tang, R.; Ping, Q.; Li, Y.; Wang, J. Water Res. 2021, 205, 117684. doi: 10.1016/j.watres.2021.117684  doi: 10.1016/j.watres.2021.117684

    39. [39]

      Zhang, L.; Fu, Y.; Wang, Z.; Zhou, G.; Zhou, R.; Liu, Y. Sep. Purif. Technol. 2021, 276, 119319. doi: 10.1016/j.seppur.2021.119319  doi: 10.1016/j.seppur.2021.119319

    40. [40]

      Hu, P.; Long, M. Appl. Catal. B 2016, 181, 103. doi: 10.1016/j.apcatb.2015.07.024  doi: 10.1016/j.apcatb.2015.07.024

    41. [41]

      Chen, Y.; Liu, Y.; Zhang, L.; Xie, P.; Wang, Z.; Zhou, A.; Fang, Z.; Ma, J. J. Hazard. Mater. 2018, 353, 18. doi: 10.1016/j.jhazmat.2018.03.050  doi: 10.1016/j.jhazmat.2018.03.050

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