Citation: Wenqian He, Ya Di, Nan Jiang, Zunfeng Liu, Yongsheng Chen. Graphene-Oxide Seeds Nucleate Strong and Tough Hydrogel-Based Artificial Spider Silk[J]. Acta Physico-Chimica Sinica, ;2022, 38(9): 220405. doi: 10.3866/PKU.WHXB202204059 shu

Graphene-Oxide Seeds Nucleate Strong and Tough Hydrogel-Based Artificial Spider Silk

Wenqian He ¹ ,
Ya Di ² ,
Nan Jiang ² ,
Zunfeng Liu ^1,, ,
Yongsheng Chen ^1,,

1.
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin 300071, China
2.
Innovation Center of Hangyu Lifesaving Equipment, Wuhan 430000, China

Corresponding author: Zunfeng Liu, liuzunfeng@nankai.edu.cn Yongsheng Chen, yschen99@nankai.edu.cn
Received Date: 30 April 2022
Revised Date: 13 June 2022
Accepted Date: 15 June 2022
Available Online: 22 June 2022
Fund Project: the National Natural Science Foundation of China 52090034the National Natural Science Foundation of China 51973093the National Natural Science Foundation of China 51773094the National Key Research and Development Program of China 2019YFE0119600Frontiers Science Center for New Organic Matter, Nankai University 63181206

Natural spider silk is composed of spun spidroin protein containing beta-sheet crosslinking sites drawn from an S-shaped spinning duct. It exhibits an excellent combination of strength (1150 ± 200 MPa) and toughness (165 ± 30 MJ·m⁻³) that originates from its hierarchical structure, including crosslinking sites, highly aligned nano-aggregates, and a sheath-core structure. In this work, we prepared a hydrogel fiber that contains crosslinking sites, highly aligned nano-aggregates, and a sheath-core structure, by draw-spinning a bulk hydrogel composed of polyacrylic acid crosslinked with vinyl-functionalized silica nanoparticles (SNVs). The core-sheath structure was prepared by the water-evaporation-controlled self-assembly of the polyacrylic hydrogel, while nanometer-sized aggregates were formed by the self-assembly of polyacrylic acid chains. The addition of a tiny amount of graphene oxide (GO: 0.01%), a 2D nanomaterial, enhanced the mechanical properties of the fiber (breaking strength: 560 MPa; fracture toughness: 200 MJ·m⁻³; damping capacity: 94%). In addition, we investigated the factors responsible for the mechanical properties of the gel fibers, including fiber diameter, drying time in air, relative air humidity, and stretching speed. A higher breaking strength and a lower fracture strain was obtained by decreasing the fiber diameter, increasing the drying time, or increasing the stretching speed, while a lower fracture strain and higher breaking strength were obtained by increasing the relative air humidity. Polarized optical and SEM images revealed that the GO-seeded material is better aligned and contains smaller nano-aggregates, with GO seeding found to play a key role in the formation of nano-aggregates and polymer-chain alignment. The prepared fiber exhibited excellent mechanical properties compared to gel fibers prepared by other methods (e.g., electro-, wet, dry, and microfluidic spinning, as well as templating, and 3D printing, etc.). Repeated mechanical testing involving stretch-release cycles to 70% strain at 20% relative humidity revealed that the fibers have an energy-damping capacity of 93.6%, which exceeds that of natural spider silk and many types of artificial fiber. The relaxed stretched fiber recovered its initial length when exposed to 80% relative humidity, while the fiber recovered its initial mechanical properties when stored for 2 h at room temperature. A yarn composed of three hundred of the prepared gel fibers was shown to lift a 3 kg object without breaking; the prepared fiber was also shown to absorb dynamic energy and lower the impact force of a falling object.
- Functional fiber,
- Polymer composite,
- Biomimetic,
- Spinning,
- Nanomaterials,
- Graphene oxide,
- Damp capacity
1. [1]
  Ling, S.; Qin, Z.; Li, C.; Huang, W.; Kaplan, D. L.; Buehler, M. J. Nat. Commun. 2017, 8, 1. doi: 10.1038/s41467-017-00613-5 doi: 10.1038/s41467-017-00613-5
2. [2]
  Omenetto, F. G.; Kaplan, D. L. Science 2010, 329, 528. doi: 10.1126/science.1188936 doi: 10.1126/science.1188936
3. [3]
  Vollrath, F.; Knight, D. P. Nature 2001, 410, 541. doi: 10.1038/35069000 doi: 10.1038/35069000
4. [4]
  Rising, A.; Johansson, J. Nat. Chem. Biol. 2015, 11, 309. doi: 10.1038/nchembio.1789 doi: 10.1038/nchembio.1789
5. [5]
  Yarger, J. L.; Cherry, B. R.; Van Der Vaart, A. Nat. Rev. Mater. 2018, 3, 1. doi: 10.1038/natrevmats.2018.8 doi: 10.1038/natrevmats.2018.8
6. [6]
  Yoshioka, T.; Tsubota, T.; Tashiro, K.; Jouraku, A.; Kameda, T. Nat. Commun. 2019, 10, 1. doi: 10.1038/s41467-019-09350-3 doi: 10.1038/s41467-019-09350-3
7. [7]
  Du, N.; Yang, Z.; Liu, X. Y.; Li, Y.; Xu, H. Y. Adv. Funct. Mater. 2011, 21, 772. doi: 10.1002/adfm.201001397 doi: 10.1002/adfm.201001397
8. [8]
  Eisoldt, L.; Smith, A.; Scheibel, T. Mater. Today 2011, 14, 80. doi: 10.1016/S1369-7021(11)70057-8 doi: 10.1016/S1369-7021(11)70057-8
9. [9]
  Lefèvre, T.; Auger, M. Int. Mater. Rev. 2016, 61, 127. doi: 10.1080/09506608.2016.1148894 doi: 10.1080/09506608.2016.1148894
10. [10]
  Lin, T.-Y.; Masunaga, H.; Sato, R.; Malay, A. D.; Toyooka, K.; Hikima, T.; Numata, K. Biomacromolecules 2017, 18, 1350. doi: 10.1021/acs.biomac.7b00086 doi: 10.1021/acs.biomac.7b00086
11. [11]
  Yazawa, K.; Malay, A. D.; Masunaga, H.; Numata, K. Macromol. Bioscience 2019, 19, 1800220. doi: 10.1002/mabi.201800220 doi: 10.1002/mabi.201800220
12. [12]
  Gao, H.-L.; Zhao, R.; Cui, C.; Zhu, Y.-B.; Chen, S.-M.; Pan, Z.; Meng, Y.-F.; Wen, S.-M.; Liu, C.; Wu, H.-A. Natl. Sci. Rev. 2020, 7, 73. doi: 10.1093/nsr/nwz077 doi: 10.1093/nsr/nwz077
13. [13]
  Mittal, N.; Jansson, R.; Widhe, M.; Benselfelt, T.; Håkansson, K. M.; Lundell, F.; Hedhammar, M.; Söderberg, L. D. ACS Nano 2017, 11, 5148. doi: 10.1021/acsnano.7b02305 doi: 10.1021/acsnano.7b02305
14. [14]
  Mohammadi, P.; Aranko, A. S.; Landowski, C. P.; Ikkala, O.; Jaudzems, K.; Wagermaier, W.; Linder, M. B. Sci. Adv. 2019, 5, eaaw2541. doi: 10.1126/sciadv.aaw2541 doi: 10.1126/sciadv.aaw2541
15. [15]
  Yu, Y.; He, Y.; Mu, Z.; Zhao, Y.; Kong, K.; Liu, Z.; Tang, R. Adv. Funct. Mater. 2020, 30, 1908556. doi: 10.1002/adfm.201908556 doi: 10.1002/adfm.201908556
16. [16]
  Dou, Y.; Wang, Z.-P.; He, W.; Jia, T.; Liu, Z.; Sun, P.; Wen, K.; Gao, E.; Zhou, X.; Hu, X. Nat. Commun. 2019, 10, 1. doi: 10.1038/s41467-019-09234-6 doi: 10.1038/s41467-019-09234-6
17. [17]
  Wu, Y.; Shah, D. U.; Liu, C.; Yu, Z.; Liu, J.; Ren, X.; Rowland, M. J.; Abell, C.; Ramage, M. H.; Scherman, O. A. Proc. Nat. Acad. Sci. U. S. A. 2017, 114, 8163. doi: 10.1073/pnas.1705380114 doi: 10.1073/pnas.1705380114
18. [18]
  Deptula, A.; Wade, M.; Rogers, S. A.; Espinosa‐Marzal, R. M. Adv. Funct. Mater. 2022, 32, 2111414. doi: 10.1002/adfm.202111414 doi: 10.1002/adfm.202111414
19. [19]
  Heidebrecht, A.; Eisoldt, L.; Diehl, J.; Schmidt, A.; Geffers, M.; Lang, G.; Scheibel, T. Adv. Mater. 2015, 27, 2189. doi: 10.1002/adma.201404234 doi: 10.1002/adma.201404234
20. [20]
  Li, J.; Zhu, Y.; Yu, H.; Dai, B.; Jun, Y.-S.; Zhang, F. ACS Nano 2021, 15, 11843. doi: 10.1021/acsnano.1c02944 doi: 10.1021/acsnano.1c02944
21. [21]
  Li, Y.; Li, J.; Sun, J.; He, H.; Li, B.; Ma, C.; Liu, K.; Zhang, H. Angew. Chem. Int. Ed. 2020, 132, 8225. doi: 10.1002/anie.202102158 doi: 10.1002/anie.202102158
22. [22]
  Kabir, M. H.; Ahmed, K.; Gong, J.; Furukawa, H. The Effect of Cross-Linker Concentration in the Physical Properties of Shape Memory Gel. In: Proceedings of SPIE, 2015, 9432, 94320Q. Conference on Behavior and Mechanics of Multifunctional Materials and Composites, San Diego, CA, MAR 09–11, 2015. doi: 10.1117/12.2084181
23. [23]
  Andersson, M.; Jia, Q.; Abella, A.; Lee, X.-Y.; Landreh, M.; Purhonen, P.; Hebert, H.; Tenje, M.; Robinson, C. V.; Meng, Q. Nat. Chem. Biol. 2017, 13, 262. doi: 10.1038/NCHEMBIO.2269 doi: 10.1038/NCHEMBIO.2269
24. [24]
  Wei, P.; Hou, K.; Chen, T.; Chen, G.; Mugaanire, I. T.; Zhu, M. Mater. Horiz. 2020, 7, 811. doi: 10.1039/C9MH01390C doi: 10.1039/C9MH01390C
25. [25]
  Jin, Y.; Zhang, Y.; Hang, Y.; Shao, H.; Hu, X. J. Mater. Res. 2013, 28, 2897. doi: 10.1557/jmr.2013.276 doi: 10.1557/jmr.2013.276
26. [26]
  Sun, M.; Zhang, Y.; Zhao, Y.; Shao, H.; Hu, X. J. Mater. Chem. 2012, 22, 18372. doi: 10.1039/C2JM32576D doi: 10.1039/C2JM32576D
27. [27]
  Yue, X.; Zhang, F.; Wu, H.; Ming, J.; Fan, Z.; Zuo, B. Mater. Lett. 2014, 128, 175. doi: 10.1016/j.matlet.2014.04.116 doi: 10.1016/j.matlet.2014.04.116
28. [28]
  Liao, X.; Dulle, M.; e Silva, J. M. d. S.; Wehrspohn, R. B.; Agarwal, S.; Förster, S.; Hou, H.; Smith, P.; Greiner, A. Science 2019, 366, 1376. doi: 10.1126/science.aay903 doi: 10.1126/science.aay903
29. [29]
  Xue, J.; Wu, T.; Dai, Y.; Xia, Y. Chem. Rev. 2019, 119, 5298. doi: 10.1021/acs.chemrev.8b00593 doi: 10.1021/acs.chemrev.8b00593
30. [30]
  Kang, E.; Choi, Y. Y.; Chae, S. K.; Moon, J. H.; Chang, J. Y.; Lee, S. H. Adv. Mater. 2012, 24, 4271. doi: 10.1002/adma.201201232 doi: 10.1002/adma.201201232
31. [31]
  Mittal, N.; Benselfelt, T.; Ansari, F.; Gordeyeva, K.; Roth, S. V.; Wågberg, L.; Söderberg, L. D. Angew. Chem. Int. Ed. 2019, 131, 18735. doi: 10.1002/ange.201910603 doi: 10.1002/ange.201910603
32. [32]
  Tamayol, A.; Akbari, M.; Zilberman, Y.; Comotto, M.; Lesha, E.; Serex, L.; Bagherifard, S.; Chen, Y.; Fu, G.; Ameri, S. K. Adv. Healthc. Mater. 2016, 5, 711. doi: 10.1002/adhm.201670027 doi: 10.1002/adhm.201670027
33. [33]
  Huang, H. M.; Li, Z.; Wang, C. Solid State Phenomena 2007, 121, 579. doi: 10.4028/www.scientific.net/SSP.121-123.579 doi: 10.4028/www.scientific.net/SSP.121-123.579
34. [34]
  Lu, H.; Zhang, L.; Xing, W.; Wang, H.; Xu, N. Macromol. Chem. Phys. 2005, 94, 322. doi: 10.1039/C9TA14082D doi: 10.1039/C9TA14082D
35. [35]
  Hou, K.; Hu, Z.; Mugaanire, I. T.; Li, C.; Chen, G.; Zhu, M. Polymer 2019, 183, 121903. doi: 10.1016/j.polymer.2019.121903 doi: 10.1016/j.polymer.2019.121903
36. [36]
  Hou, K.; Wang, H.; Lin, Y.; Chen, S.; Yang, S.; Cheng, Y.; Hsiao, B. S.; Zhu, M. Macromol. Rapid Commun. 2016, 37, 1795. doi: 10.1002/marc.201600430 doi: 10.1002/marc.201600430
37. [37]
  Song, J.; Chen, S.; Sun, L.; Guo, Y.; Zhang, L.; Wang, S.; Xuan, H.; Guan, Q.; You, Z. Adv. Mater. 2020, 32, 1906994. doi: 10.1002/adma.201906994 doi: 10.1002/adma.201906994
38. [38]
  Chen, G.; Wang, G.; Tan, X.; Hou, K.; Meng, Q.; Zhao, P.; Wang, S.; Zhang, J.; Zhou, Z.; Chen, T. Natl. Sci. Rev. 2021, 8, nwaa209. doi: 10.1093/nsr/nwaa209 doi: 10.1093/nsr/nwaa209
39. [39]
  Duan, X.; Yu, J.; Zhu, Y.; Zheng, Z.; Liao, Q.; Xiao, Y.; Li, Y.; He, Z.; Zhao, Y.; Wang, H. ACS Nano 2020, 14, 14929. doi: 10.1021/acsnano.0c04382 doi: 10.1021/acsnano.0c04382
40. [40]
  Ju, M., Wu, B., Sun, S., Wu, P. Adv. Funct. Mater. 2020, 30, 1910387. doi: 10.1002/adfm.201910387 doi: 10.1002/adfm.201910387
41. [41]
  Wu, L.; Li, L.; Fan, M.; Tang, P.; Yang, S.; Pan, L.; Wang, H.; Bin, Y. Composites Part A: Appl. Sci. Manufacturing 2020, 138, 106050. doi: 10.1016/j.compositesa.2020.106050 doi: 10.1016/j.compositesa.2020.106050
42. [42]
  Bettahar, F.; Bekkar, F.; Pérez-Álvarez, L.; Ferahi, M. I.; Meghabar, R., Vilas-Vilela, J. L.; Ruiz-Rubio, L. Polymer 2021, 13, 972. doi: 10.3390/polym13060972 doi: 10.3390/polym13060972
43. [43]
  Yang, Y.; Wang, C.; Wiener, C. G.; Hao, J.; Shatas, S.; Weiss, R., Vogt, B. D. ACS Appl. Mater. Interfaces 2016, 8, 22774. doi: 10.1021/acsami.6b08255 doi: 10.1021/acsami.6b08255
44. [44]
  Chen, T.; Wei, P.; Chen, G.; Liu, H.; Mugaanire, I. T.; Hou, K.; Zhu, M. J. Mater. Chem. A 2021, 9, 12265. doi: 10.1039/d1ta02422a doi: 10.1039/d1ta02422a
45. [45]
  An, Y.; Gao, L.; Wang, T. ACS Appl. Nano Mater. 2020, 3, 5079. doi: 10.1021/acsanm.0c00351 doi: 10.1021/acsanm.0c00351
46. [46]
  Chu, C. K.; Joseph, A. J.; Limjoco, M. D.; Yang, J.; Bose, S.; Thapa, L. S.; Langer, R.; Anderson, D. G. J. Am. Chem. Soc. 2020, 142, 19715. doi: 10.1021/jacs.0c09691 doi: 10.1021/jacs.0c09691
47. [47]
  Zhao, X.; Chen, F.; Li, Y.; Lu, H.; Zhang, N.; Ma, M. Nat. Commun. 2018, 9, 1. doi: 10.1038/s41467-018-05904-z doi: 10.1038/s41467-018-05904-z
48. [48]
  Naficy, S.; Le, T. Y. L.; Oveissi, F.; Lee, A.; Hung, J. C.; Wise, S. G.; Winlaw, D. S.; Dehghani, F. Adv. Mater. Interfaces 2020, 7, 1901770. doi: 10.1002/admi.201901770 doi: 10.1002/admi.201901770
49. [49]
  Peng, L., Liu, Y., Huang, J., Li, J., Gong, J., Ma, J. Eur. Poly. J. 2018, 103, 335. doi: 10.1016/j.eurpolymj.2018.04.019 doi: 10.1016/j.eurpolymj.2018.04.019
50. [50]
  Zhou, M.; Gong, J.; Ma, J. e-Polymers 2019, 19, 215. doi: 10.1515/epoly-2019-0022 doi: 10.1515/epoly-2019-0022
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