Citation: Bichen Zhu, Xiaoyang Hong, Liyong Tang, Qinqin Liu, Hua Tang. Enhanced Photocatalytic CO₂ Reduction over 2D/1D BiOBr_0.5Cl_0.5/WO₃ S-Scheme Heterostructure[J]. Acta Physico-Chimica Sinica, ;2022, 38(7): 211100. doi: 10.3866/PKU.WHXB202111008 shu

Enhanced Photocatalytic CO₂ Reduction over 2D/1D BiOBr_0.5Cl_0.5/WO₃ S-Scheme Heterostructure

Bichen Zhu ^{1, †} ,
Xiaoyang Hong ^{1, †} ,
Liyong Tang ^1,, ,
Qinqin Liu ¹ ,
Hua Tang ^2,,

1.
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
2.
School of Environmental Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China

Corresponding author: Liyong Tang, 1000003184@mail.ujs.edu.cn Hua Tang, huatang79@163.com

^†

Received Date: 4 November 2021
Revised Date: 27 November 2021
Accepted Date: 1 December 2021
Available Online: 6 December 2021
Fund Project: the National Natural Science Foundation of China 21975110the National Natural Science Foundation of China 21972058

Catalytic reduction of CO₂ to CO has been considered promising for converting the greenhouse gas into chemical intermediates. Compared to other catalytic methods, photocatalytic CO₂ reduction, which uses solar energy as the energy input, has attracted significant attention because it is a clean and inexhaustible resource. Therefore, using high-performance photocatalysts for effective CO₂ reduction under mild reaction conditions is an active research hotspot. However, several current photocatalysts suffer from low solar energy conversion efficiency due to the extensive charge recombination and few active sites, leading to low CO₂ reduction efficiency. Generally, constructing an S-scheme heterojunction can not only promote charge separation but also help maintain strong redox ability. Therefore, the S-scheme heterojunction is expected to help in achieving high conversion activity and CO₂ reduction efficiency. Here, 2D tetragonal BiOBr_0.5Cl_0.5 nanosheets and hexagonal WO₃ nanorods were prepared using a simple hydrothermal synthesis method, and the 2D/1D BiOBr_0.5Cl_0.5 nanosheets/WO₃ nanorods (BiOBr_0.5Cl_0.5/WO₃) S-scheme heterojunction with near infrared (NIR) light (> 780 nm) response were prepared via the electrostatic self-assembly method for the photocatalytic CO₂ reduction. Following characterization and analysis, including diffuse reflectance spectra (DRS), Mott-Schottky plots, transient photocurrent response, time-resolution photoluminescence spectrum (TRPL), electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV), and electron spin resonance (ESR) measurements, it can be demonstrated that an S-scheme carrier transfer route was formed between the 2D BiOBr_0.5Cl_0.5 nanosheets and 1D WO₃ nanorods. Driven by the internal electric field, which was formed between the two semiconductors, electron migration was boosted, thus inhibiting the recombination of photogenerated carriers, while the stronger redox ability was maintained, thus providing good reduction efficiency over BiOBr_0.5Cl_0.5/WO₃ composite in CO₂ reduction. In addition, the 2D/1D nanosheet/nanorod structure allowed for enhanced interface contact with abundant active sites, which favored charge separation and increased photocatalytic activity. Furthermore, the amount of WO₃ nanorods added during the preparation of the composites was altered, which led to the optimal amount of 5% (w, mass fraction) for the photocatalytic CO₂ reduction. As a result, the BiOBr_0.5Cl_0.5/WO₃ composite exhibited superior photocatalytic reduction performance with a CO yield of 16.68 μmol·g^-1·h^-1 in the presence of any precious metal cocatalyst or sacrificial agent, which was 1.7 and 9.8 times that of pure BiOBr_0.5Cl_0.5 and WO₃, respectively. In addition, the BiOBr_0.5Cl_0.5/WO₃ composite provided continuously increased CO yields with excellent selectivity under full-spectrum light irradiation, suggesting good photocatalytic stability. This work describes a novel idea for the construction of 2D/1D S-scheme heterojunction photocatalysts for efficient CO₂ reduction.
- 2D/1D heterostructure,
- BiOBr_0.5Cl_0.5 nanosheets,
- WO₃ nanorods,
- CO₂ reduction,
- S-scheme
1. [1]
  Li, Y. F.; Zhang, M.; Zhou, L.; Yang, S. J.; Wu, Z. S.; Ma, Y. H. Acta Phys. -Chim. Sin. 2021, 37, 2009030. doi: 10.3866/PKU.WHXB202009030
2. [2]
  Fei, X. G.; Tan, H. Y.; Cheng, B.; Zhu, B. C.; Zhang, L. Y. Acta Phys. -Chim. Sin. 2021, 37, 2010027. doi: 10.3866/PKU.WHXB202010027
3. [3]
  Wageh, S.; Al-Ghamdi, A. A.; Liu, L. J. Acta Phys. -Chim. Sin. 2021, 37, 2010024. doi: 10.3866/PKU.WHXB202010024
4. [4]
  Wang, Z. J.; Hong, J. J.; Ng, S. -F.; Liu, W.; Huang, J. J.; Chen, P. F.; Ong, W. -J. Acta Phys. -Chim. Sin. 2021, 37, 2011033. doi: 10.3866/PKU.WHXB202011033
5. [5]
  Liu, Q. Q.; He, X. D.; Peng, J. J.; Yu, X. H.; Tang, H.; Zhang, J. Chin. J. Catal. 2021, 42, 1478. doi: 10.1016/s1872-2067(20)63753-6 doi: 10.1016/s1872-2067(20)63753-6
6. [6]
  Wang, Z. L.; Chen, Y. F.; Zhang, L. Y.; Cheng, B.; Yu, J. G.; Fan, J. J. J. Mater. Sci. Technol. 2020, 56, 143. doi: 10.1016/j.jmst.2020.02.062 doi: 10.1016/j.jmst.2020.02.062
7. [7]
  Li, K. Y.; Chen, J.; Ao, Y. H.; Wang, P. F. Sep. Purif. Technol. 2021, 259, 118177. doi: 10.1016/j.seppur.2020.118177v doi: 10.1016/j.seppur.2020.118177v
8. [8]
  Mu, R. H.; Ao, Y. H.; Wu, T. F.; Wang, C.; Wang, P. F. J. Alloys Compd. 2020, 812, 151990. doi: 10.1016/j.jallcom.2019.151990 doi: 10.1016/j.jallcom.2019.151990
9. [9]
  Zhang, Y.; Qin, H. N.; Li, B. L.; Wu, B. Chin. J. Struc. Chem. 2021, 40, 595. doi: 10.14102/j.cnki.0254-5861.2011-2989 doi: 10.14102/j.cnki.0254-5861.2011-2989
10. [10]
  Che, H. N.; Gao, X.; Chen, J.; Hou, J.; Ao, Y. H.; Wang, P. F. Angew. Chem. Int. Ed. 2021, 60, 2. doi: 10.1002/anie.202111769 doi: 10.1002/anie.202111769
11. [11]
  Liu, X. T.; Gu, S. N.; Zhao, Y. J.; Zhou, G. W.; Li, W. J. J. Mater. Sci. Technol. 2020, 56, 45. doi: 10.1016/j.jmst.2020.04.023 doi: 10.1016/j.jmst.2020.04.023
12. [12]
  Zhang, J. Y.; Liao, H. G.; Sun, S. G. Chin. J. Struc. Chem. 2020, 39, 1019. doi: 10.14102/j.cnki.0254-5861.2011-2553 doi: 10.14102/j.cnki.0254-5861.2011-2553
13. [13]
  Han, S. T.; Li, W. Y.; Xi, H. L.; Yuan, R. S.; Long, J. L.; Xu, C. J. Hazard. Mater. 2021, 423, 127012. doi: 10.1016/j.jhazmat.2021.127012v doi: 10.1016/j.jhazmat.2021.127012v
14. [14]
  Li, D. S.; Huang, Y.; Li, S. M.; Wang, C. H.; Li, Y. Y.; Zhang, X. T.; Liu, Y. C. Chin. J. Catal. 2021, 41, 154. doi: 10.1016/s1872-2067(19)63475-3 doi: 10.1016/s1872-2067(19)63475-3
15. [15]
  Lu, Y.; Fan, D. Q.; Wang, Y. D.; Xu, H. L.; Lu, C. H.; Yang, X. F. ACS Nano 2021, 15, 10366. doi: 10.1021/acsnano.1c02578 doi: 10.1021/acsnano.1c02578
16. [16]
  Sayed, M.; Zhu, B. C.; Kuang, P. Y.; Liu, X. Y.; Cheng, B.; Ghamdi, A. A. A.; Wageh, S.; Zhang, L. Y.; Yu, J. G. Adv. Sust. Syst. 2021, 2100264. doi: 10.1002/adsu.202100264 doi: 10.1002/adsu.202100264
17. [17]
  Wang, L. B.; Cheng, B.; Zhang, L. Y.; Yu, J. G. Small 2021, 17, 2103447. doi: 10.1002/smll.202103447 doi: 10.1002/smll.202103447
18. [18]
  Lin, H.; Ma, Z. Y.; Zhao, J. W.; Liu, Y.; Chen, J. Q.; Wang, J. H.; Wu, K. F.; Jia, H. P.; Zhang, X. M.; Cao, X. H.; et al. Angew. Chem. Int. Ed. 2021, 60, 1235. doi: 10.1002/anie.202009267 doi: 10.1002/anie.202009267
19. [19]
  Zhang, L.; Xiao, W. P.; Zhang, Y.; Han, F. Y.; Yang, X. F. Compos. Commun. 2021, 26, 100792. doi: 10.1016/j.coco.2021.100792. doi: 10.1016/j.coco.2021.100792
20. [20]
  Wang, J. F.; Chen, J.; Wang, P. F.; Hou, J.; Wang, C.; Ao, Y. H. Appl. Catal. B Environ. 2018, 239, 578. doi: 10.1016/j.apcatb.2018.08.048 doi: 10.1016/j.apcatb.2018.08.048
21. [21]
  Zhou, S. Q.; Wang, Y.; Zhou, K.; Ba, D. Y.; Ao, Y. H.; Wang, P. F. Chin. Chem. Lett. 2021, 32, 2179. doi: 10.1016/j.cclet.2020.12.002 doi: 10.1016/j.cclet.2020.12.002
22. [22]
  Wageh, S.; Al-Ghamdi, A. A.; Rashida, J.; Li, X.; Zhang, P. Chin. J. Catal. 2021, 42, 667. doi: 10.1016/S1872-2067(20)63705-6 doi: 10.1016/S1872-2067(20)63705-6
23. [23]
  Fan, D. Q.; Lu, Y.; Zhang, H.; Xu, H. L.; Lu, C. H.; Tang, Y. C.; Yang, X. F. Appl. Catal. B Environ. 2021, 295, 120285. doi: 10.1016/j.apcatb.2021.120285 doi: 10.1016/j.apcatb.2021.120285
24. [24]
  Liu, L. Z.; Hu, T. P.; Dai, K.; Zhang, J. F.; Liang, C. H. Chin. J. Catal. 2021, 42, 46. doi: 10.1016/s1872-2067(20)63560-4 doi: 10.1016/s1872-2067(20)63560-4
25. [25]
  Wang, R.; Shen, J.; Sun, K. H.; Tang, H.; Liu, Q. Q. Appl. Surf. Sci. 2019, 493, 1142. doi: 10.1016/j.apsusc.2019.07.121 doi: 10.1016/j.apsusc.2019.07.121
26. [26]
  Lu, Y.; Zhang, H.; Fan, D. Q.; Chen, Z. P.; Yang, X. F. J. Hazard. Mater. 2021, 423, 127128. doi: 10.1016/j.jhazmat.2021.127128 doi: 10.1016/j.jhazmat.2021.127128
27. [27]
  Liu, X.; Zhao, Y. X.; Yang, X. F.; Liu, Q. Q.; Yu, X. H.; Li, Y. Y.; Tang, H.; Zhang, T. R. Appl. Catal. B Environ. 2020, 275, 119144. doi: 10.1016/j.apcatb.2020.119144 doi: 10.1016/j.apcatb.2020.119144
28. [28]
  Yan, S. W.; Song, H. J.; Li, Y.; Yang, J.; Jia, X. H.; Wang, S. Z.; Yang, X. F. Appl. Catal. B Environ. 2022, 301, 120820. doi: 10.1016/j.apcatb.2021.120820 doi: 10.1016/j.apcatb.2021.120820
29. [29]
  Xie, Q.; He, W. N.; Liu, S. W.; Li, C. H.; Zhang, J. F.; Wong, P. K. Chin. J. Catal. 2020, 41, 140. doi: 10.1016/s1872-2067(19)63481-9 doi: 10.1016/s1872-2067(19)63481-9
30. [30]
  Wang, L.; Zhu, C. L.; Yin, L. S.; Huang, W. Acta Phys. -Chim. Sin. 2020, 36, 1907001. doi: 10.3866/PKU.WHXB201907001
31. [31]
  Sayed, M.; Xu, F. Y.; Kuang, P. Y.; Low, J. X.; Wang, S. Y.; Zhang, L. Y.; Yu, J. G. Nat. Commun. 2021, 12, 4936. doi: 10.1038/s41467-021-26467-6 doi: 10.1038/s41467-021-26467-6
32. [32]
  Prasad, C.; Tang, H.; Liu, Q. Q.; Bahadur, I.; Karlapudi, S.; Jiang, Y. J. Int. J. Hydrog. Energy 2020, 45, 337. doi: 10.1016/j.ijhydene.2019.07.070 doi: 10.1016/j.ijhydene.2019.07.070
33. [33]
  Kuang, P. Y.; Wang, Y. R.; Zhu, B. C.; Xia, F. J.; Tung, C. W.; Wu, J. S.; Chen, H. M.; Yu, J. G. Adv. Mater. 2021, 33, 2008599. doi: 10.1002/adma.202008599 doi: 10.1002/adma.202008599
34. [34]
  Bie, C. B.; Yu, H. G.; Cheng, B.; Ho, W. K.; Fan, J. J.; Yu, J. G. Adv. Mater. 2021, 33, 2003521. doi: 10.1002/adma.202003521 doi: 10.1002/adma.202003521
35. [35]
  Tao, J. N.; Yu, X. H.; Liu, Q. Q.; Liu, G. W.; Tang, H. J. Colloid Interface Sci. 2021, 585, 470. doi: 10.1016/j.jcis.2020.10.028 doi: 10.1016/j.jcis.2020.10.028
36. [36]
  Wang, R.; Shen, J.; Zhang, W. J.; Liu, Q. Q.; Zhang, M. Y.; Zulfiqar; Tang, H. Ceram. Int. 2020, 46, 23. doi: 10.1016/j.ceramint.2019.08.226 doi: 10.1016/j.ceramint.2019.08.226
37. [37]
  Wu, J.; Xie, Y.; Ling, Y.; Si, J. C.; Li, X.; Wang, J. L.; Ye, H.; Zhao, J. S.; Li, S. Q.; Zhao, Q. D.; et al. Chem. Eng. J. 2020, 400, 125944. doi: 10.1016/j.cej.2020.125944 doi: 10.1016/j.cej.2020.125944
38. [38]
  Zhang, Z. Y.; Chi, M. F.; Veith, G. M.; Zhang, P. F.; Lutterman, D. A.; Rosenthal, J.; Overbury, S. T.; Dai, S.; Zhu, H. Y. ACS Catal. 2016, 6, 6255. doi: 10.1021/acscatal.6b01297 doi: 10.1021/acscatal.6b01297
39. [39]
  Han, L. L.; Song, S. J.; Liu, M. J.; Yao, S. Y.; Liang, Z. X.; Cheng, H.; Ren, Z. H.; Liu, W.; Lin, R. Q.; Qi, G. C.; et al. J. Am. Chem. Soc. 2020, 142, 12563. doi: 10.1021/jacs.9b12111 doi: 10.1021/jacs.9b12111
40. [40]
  Jia, X. M.; Han, Q. F.; Wang, X.; Zhu, J. W. Photochem. Photobiol. 2018, 94, 942. doi: 10.1111/php.12943 doi: 10.1111/php.12943
41. [41]
  Wilczewska, P.; Bielicka-Giełdoń, A.; Borzyszkowska, A. F.; Ryl, J.; Klimczuk, T.; Siedlecka, E. M. J. Photochem. Photobiol. A Chem. 2019, 382, 111932. doi: 10.1016/j.jphotochem.2019.111932 doi: 10.1016/j.jphotochem.2019.111932
42. [42]
  Liu, Y. Y.; Son, W. J.; Lu, J. B.; Huang, B. B.; Dai, Y.; Whangbo, M. H. Chem. Eur. J. 2011, 17, 9342. doi: 10.1002/chem.201100952 doi: 10.1002/chem.201100952
43. [43]
  Bao, Y. P.; Lee, W. J.; Guan, C. T.; Liang, Y. N.; Lim T. T.; Hu, X. J. Mater. Chem. B 2021, 9, 3079. doi: 10.1016/j.seppur.2021.119203 doi: 10.1016/j.seppur.2021.119203
44. [44]
  Sanaa, S. K.; Vladimir, U.; Yulia, K.; Ella, M.; Inna, P.; Yoel, S. Catal. Commun. 2011, 12, 1136. doi: 10.1016/j.catcom.2011.03.014 doi: 10.1016/j.catcom.2011.03.014
45. [45]
  Zhang, B.; Ji, G. B.; Liu, Y. S.; Gondal, M. A.; Chang, X. F. Catal. Commun. 2013, 36, 25. doi: 10.1016/j.catcom.2013.02.021 doi: 10.1016/j.catcom.2013.02.021
46. [46]
  Li, Y.; Zheng, X. N.; Yang, J.; Zhao, Z. H.; Cui, S. H. J. Taiwan Inst. Chem. E 2021, 119, 213. doi: 10.1016/j.jtice.2021.02.014 doi: 10.1016/j.jtice.2021.02.014
47. [47]
  Zhang, M.; Cheng, J.; Xuan, X. X.; Zhou, J. H.; Cen, K. F. Chem. Eur. J. 2017, 322, 22. doi: 10.1016/j.cej.2017.03.126 doi: 10.1016/j.cej.2017.03.126
48. [48]
  Pan, Y. X.; You, Y.; Xin, S.; Li, Y. T.; Fu, G. T.; Cui, Z. M.; Men, Y. L.; Cao, F. F.; Yu, S. H.; Goodenough, J. B. J. Am. Chem. Soc. 2017, 139, 4123. doi: 10.1021/jacs.7b00266 doi: 10.1021/jacs.7b00266
49. [49]
  Gu, S. S.; Marianov, A. N.; Xu, H. M.; Jiang, Y. J. J. Mater. Sci. Technol. 2021, 80, 20. doi: 10.1016/j.jmst.2020.09.053 doi: 10.1016/j.jmst.2020.09.053
50. [50]
  Tang, H.; Xia, Z. H.; Chen, R.; Liu, Q. Q.; Zhou, T. H. Chem. Asian J. 2020, 15, 3456. doi: 10.1002/asia.202000912 doi: 10.1002/asia.202000912
51. [51]
  Hong, X. Y.; Yu, X. H.; Wang, L. L.; Liu, Q. Q.; Sun, J. F.; Tang, H. Inorg. Chem. 2021, 60, 12506. doi: 10.1021/acs.inorgchem.1c01716 doi: 10.1021/acs.inorgchem.1c01716
52. [52]
  Tahir, M.; Tahir, B. J. Mater. Sci. Technol. 2022, 106, 195. doi: 10.1016/j.jmst.2021.08.019 doi: 10.1016/j.jmst.2021.08.019
53. [53]
  Liu, D. N.; Chen, D. Y.; Li, N. J.; Xu, Q. F.; Li, H.; He, J. H.; Lu, M. J. Angew. Chem. Int. Ed. 2021, 133, 1521. doi: 10.1002/ange.201914949 doi: 10.1002/ange.201914949
54. [54]
  Dehkordi, A. B.; Ziarati, A.; Ghasemi, J. B.; Badiei, A. Sol. Energy 2020, 205, 465. doi: 10.1016/j.solener.2020.05.071 doi: 10.1016/j.solener.2020.05.071
55. [55]
  Xu, Q. L.; Zhang, L. Y.; Cheng, B.; Fan, J. J.; Yu, J. G. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
56. [56]
  Liu, Q. Q.; He, X. D.; Tao, J. N.; Tang, H.; Liu, Z. Q. ChemNanoMat. 2021, 7, 44. doi: 10.1002/cnma.202000536 doi: 10.1002/cnma.202000536
57. [57]
  Peng, J. J.; Shen, J.; Yu, X. H.; Tang, H.; Zulfiqar; Liu, Q. Q. Chin. J. Catal. 2021, 42, 87. doi: 10.1016/S1872-2067(20)63595-1 doi: 10.1016/S1872-2067(20)63595-1
58. [58]
  Xu, F. Y.; Meng, K.; Cheng, B.; Wang, S. Y.; Xu, J. S.; Yu, J. G. Nat. Commun. 2020, 11, 4613. doi: 10.1038/s41467-020-18350-7 doi: 10.1038/s41467-020-18350-7
59. [59]
  Girish, K. S.; Koteswara, R. K. S. R. Appl. Surf. Sci. 2015, 355, 939. doi: 10.1016/j.apsusc.2015.07.003 doi: 10.1016/j.apsusc.2015.07.003
60. [60]
  Wang, L. L.; Tang, G. G.; Liu, S.; Dong, H. L.; Liu, Q. Q.; Sun, J. F.; Tang, H. Chem. Eng. J. 2022, 428, 131338. doi: 10.1016/j.cej.2021.131338 doi: 10.1016/j.cej.2021.131338
61. [61]
  Xia, Y.; Tian, Z. H.; Heil, T.; Meng, A.; Cheng, B.; Cao, S. W.; Yu, J. G.; Antonietti, M. Joule 2019, 3, 2792. doi: 10.1016/j.joule.2019.08.011 doi: 10.1016/j.joule.2019.08.011
62. [62]
  Ye, L.; Wen, Z. H. Int. J. Hydrog. Energy 2019, 44, 3751. doi: 10.1016/j.ijhydene.2018.12.093 doi: 10.1016/j.ijhydene.2018.12.093
63. [63]
  Gao, M. C.; Yang, J. X.; Sun, T.; Zhang, Z. Z.; Zhang, D. F.; Huang, H. J.; Lin, H. X.; Fang, Y.; Wang, X. X. Appl. Catal. B Environ. 2019, 243, 734. doi: 10.1016/j.apcatb.2018.11.020 doi: 10.1016/j.apcatb.2018.11.020
64. [64]
  Tang, M. L.; Ao, Y. H.; Wang, P. F.; Wang, C. J. Hazard. Mater. 2020, 387, 121713. doi: 10.1016/j.jhazmat.2019.121713 doi: 10.1016/j.jhazmat.2019.121713
65. [65]
  Wang, S. L.; Zhu, Y.; Luo, X.; Huang, Y.; Chai, J. W.; Wong, T. I.; Xu, G. Q. Adv. Funct. Mater. 2018, 28, 1705357. doi: 10.1002/adfm.201705357 doi: 10.1002/adfm.201705357
66. [66]
  Fu, J. W.; Xu, Q. L.; Low, J. X.; Jiang, C. J.; Yu, J. G. Appl. Catal. B Environ. 2019, 243, 556. doi: 10.1016/j.apcatb.2018.11.011 doi: 10.1016/j.apcatb.2018.11.011
67. [67]
  Liu, Q. Q.; Huang, J. X.; Tang, H.; Yu, X. H.; Shen, J. J. Mater. Sci. Technol. 2020, 56, 196. doi: 10.1016/j.jmst.2020.04.026 doi: 10.1016/j.jmst.2020.04.026
68. [68]
  Manthiram, K.; Alivisatos, A. P. J. Am. Chem. Soc. 2012, 134, 3995. doi: 10.1021/ja211363w doi: 10.1021/ja211363w
69. [69]
  An, Z.; Zhou, T. H. Chin. J. Struc. Chem. 2019, 38, 644. doi: 10.14102/j.cnki.0254-5861.2011-2112 doi: 10.14102/j.cnki.0254-5861.2011-2112
70. [70]
  Ma, B. R.; Xin, S. S.; Xin, Y. J.; Ma, X. M.; Zhang, C. L.; Gao, M. C.; Ma, F.; Ma, Y. M. Sep. Purif. Technol. 2021, 268, 1383. doi: 10.1016/j.seppur.2021.118699 doi: 10.1016/j.seppur.2021.118699
71. [71]
  Sun, H. G.; Tian, Z. X.; Zhou, G. L.; Zhang, J. M.; Li, P. Appl. Surf. Sci. 2019, 469, 125. doi: 10.1016/j.apsusc.2018.11.006 doi: 10.1016/j.apsusc.2018.11.006
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  Weixia Wang , Yongji Zhang , Fei Zhao , Libo Wang , Fanpeng Meng , Shuchao Qin , Jinsheng Zhao . Engineering π-delocalized network in fused-thiophene based polymers/g-C3N4 S-scheme heterojunctions for photocatalytic H2 evolution. Chinese Journal of Structural Chemistry, 2026, 45(3): 100833-100833. doi: 10.1016/j.cjsc.2025.100833
2. [2]
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3. [3]
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4. [4]
  Hongrui Zhang , Miaoying Cui , Yongjie Lv , Yongfang Rao , Yu Huang . A short review on research progress of ZnIn₂S₄-based S-scheme heterojunction: Improvement strategies. Chinese Chemical Letters, 2025, 36(4): 110108-. doi: 10.1016/j.cclet.2024.110108
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6. [6]
  Zhou Li , Mengxue Yu , Shixin Chang , Zhibin Huang , Zhenmin Cheng , Weibin Zhang , Sónia A. C. Carabineiro , Zhigao Xu , Kangle Lv . Enhancing the photocatalytic activity of crystalline g-C3N4 towards NO oxidation and CO2 reduction through K+-doping and cyano defect engineering. Chinese Journal of Structural Chemistry, 2026, 45(1): 100698-100698. doi: 10.1016/j.cjsc.2025.100698
7. [7]
  Yueting Ma , Zhiyan Feng , Yuxin Dong , Zhiyong Yan , Hou Wang , Yan Wu . Harnessing the interfacial sulfur-edge and metal-edge sites in ZnIn₂S₄/MnS heterojunctions boosts charge transfer for photocatalytic hydrogen production. Chinese Chemical Letters, 2025, 36(6): 110922-. doi: 10.1016/j.cclet.2025.110922
8. [8]
  Sihong Li , Weiping Deng , Qijie Mo , Haili Song , Chunying Chen , Li Zhang . Engineering S-coordinated Ru single-atoms in a porphyrinic metal-organic framework for CO2 photoreduction. Chinese Journal of Structural Chemistry, 2026, 45(3): 100841-100841. doi: 10.1016/j.cjsc.2025.100841
9. [9]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
10. [10]
  Xinxin Liang , Yongqian Cui , Qingyun Tian , Tingting Jia , Qibing Dong , Ximing Li , Ting Gao , Chao Ma , Chuanyi Wang . Photoreforming polylactic acid plastics into pyruvate over CdS/Bi₄Ti₃O₁₂ S-scheme heterojunction: Successive removal of hydrogen from α-C. Chinese Chemical Letters, 2026, 37(2): 111097-. doi: 10.1016/j.cclet.2025.111097
11. [11]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
12. [12]
  Na Lu , Tingting Pang , Xuedong Jing , Yongan Zhu , Linqun Yu , Sining Ben , Yuchan Song , Shiwen Du , Wei Lu , Zhenyi Zhang . Optimizing the Schottky Barrier in AuAg Alloy Decorated TiO2 Nanofibers to Enhance Hot-Electron-Induced CO2 Reduction. Chinese Journal of Structural Chemistry, 2025, 44(8): 100633-100633. doi: 10.1016/j.cjsc.2025.100633
13. [13]
  Zekun Zhang , Shiji Li , Qian Zhang , Shanshan Li , Liu Yang , Wei Yan , Hao Xu . Further study of CO₂ electrochemical reduction to gas products on Cu: Influence of the electrolyte. Chinese Chemical Letters, 2025, 36(9): 110742-. doi: 10.1016/j.cclet.2024.110742
14. [14]
  Huarui Han , Yangrui Xu , Yu Cheng , Liguang Tang , Jie Jin , Xinlin Liu , Changchang Ma , Ziyang Lu . Frustrated Lewis pairs in CO2 photoreduction: A review on synergistic activation and charge separation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100728-100728. doi: 10.1016/j.cjsc.2025.100728
15. [15]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
16. [16]
  Cheng-Cheng Jiao , Guang-Xing Dong , Ke Su , You-Xiang Feng , Min Zhang , Tong-Bu Lu . The construction of InVO₄/BiVO₄ heterojunction via cation-exchange for efficient and highly selective CO₂ photoreduction to methanol. Chinese Chemical Letters, 2026, 37(1): 110752-. doi: 10.1016/j.cclet.2024.110752
17. [17]
  Min Zhang , Weimin Wang , Jun Li , Xun Zhu , Qian Fu . Efficient large-current conversion of CO₂ to C₂H₅OH via a ^*CO-^*OCH₂ coupling pathway on alkanethiol-modified Cu₂O array electrode. Chinese Chemical Letters, 2026, 37(1): 111926-. doi: 10.1016/j.cclet.2025.111926
18. [18]
  Jiaqi Yang , Xuqiang Hao , Jiejie Jing , Yuqiang Hao , Zhiliang Jin . 3D/2D ReSe₂/ZnCdS S-scheme photocatalyst with efficient interfacial charge separation for optimized hydrogen production. Acta Physico-Chimica Sinica, 2025, 41(10): 100131-0. doi: 10.1016/j.actphy.2025.100131
19. [19]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
20. [20]
  Yanping Qiu , Jiatong Zhang , Linping Li , Yangqin Gao , Ning Li , Lei Ge . MOF-derived g-C₃N₄/ZnIn₂S₄ S-scheme heterojunction: interface-engineering enhanced photocatalytic NO conversion. Acta Physico-Chimica Sinica, 2026, 42(4): 100175-0. doi: 10.1016/j.actphy.2025.100175

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced Photocatalytic CO2 Reduction over 2D/1D BiOBr0.5Cl0.5/WO3 S-Scheme Heterostructure

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通讯作者: 陈斌, bchen63@163.com

Enhanced Photocatalytic CO₂ Reduction over 2D/1D BiOBr_0.5Cl_0.5/WO₃ S-Scheme Heterostructure