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Citation: Xin Xu. Thermodynamic Origin of Homochirality for Macromolecules in Nature[J]. Acta Physico-Chimica Sinica, ;2021, 37(10): 201107. doi: 10.3866/PKU.WHXB202011078 shu

Thermodynamic Origin of Homochirality for Macromolecules in Nature

Xin Xu

Department of Chemistry, Fudan University, Shanghai 200433, China

Author Bio: Xin Xu, Email: xxchem@fudan.edu.cn
Available Online: 7 December 2020

1. [1]
  Garay, A. D.; Keszthelyi, L.; Demeter, I.; Hrasko, P. Nature 1974, 250, 332. doi: 10.1038/250332a0 doi: 10.1038/250332a0
2. [2]
  Mason, S. F. Chem. Soc. Rev. 1988, 17, 347. doi: 10.1039/CS9881700347 doi: 10.1039/CS9881700347
3. [3]
  Kondepudi, D. K.; Kaufman, R. J.; Singh, N. Science 1990, 250, 975. doi: 10.1126/science.250.4983.975 doi: 10.1126/science.250.4983.975
4. [4]
  Skolnick, J.; Zhou, H.; Gao, M. Proc. Natl. Acad. Sci. USA 2019, 116, 26571. doi: 10.1073/pnas.1908241116 doi: 10.1073/pnas.1908241116
5. [5]
  Blackmond, D.G. Chem. Rev. 2020, 120, 4831. doi: 10.1021/acs.chemrev.9b00557 doi: 10.1021/acs.chemrev.9b00557
6. [6]
  Liu, S. B. J. Phys. Chem. Lett. 2020, 11, 8690. doi: 10.1021/acs.jpclett.0c02144 doi: 10.1021/acs.jpclett.0c02144
7. [7]
  Liu, S. B. J. Chem. Phys. 2007, 126, 244103. doi: 10.1063/1.2747247 doi: 10.1063/1.2747247
8. [8]
  Rong, C.; Zhao, D.; Yu, D.; Liu, S. B. Phys. Chem. Chem. Phys. 2018, 20, 17990. doi: 10.1039/C8CP03092H doi: 10.1039/C8CP03092H
9. [9]
  Zhou, T.; Liu, S.; Yu, D.; Zhao, D.; Rong, C.; Liu, S. B. Chem. Phys. Lett. 2019, 716, 192. doi: 10.1016/j.cplett.2018.12.019 doi: 10.1016/j.cplett.2018.12.019
10. [10]
  Rong, C.; Zhao, D.; Zhou, T.; Liu, S.; Yu, D.; Liu, S. B. J. Phys. Chem. Lett. 2019, 10, 1716. doi: 10.1021/acs.jpclett.9b00639 doi: 10.1021/acs.jpclett.9b00639
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