Citation: Hua Kaimin, Liu Xiaofang, Wei Baiyin, Zhang Shunan, Wang Hui, Sun Yuhan. Research Progress Regarding Transition Metal-Catalyzed Carbonylations with CO₂/H₂[J]. Acta Physico-Chimica Sinica, ;2021, 37(5): 200909. doi: 10.3866/PKU.WHXB202009098 shu

Research Progress Regarding Transition Metal-Catalyzed Carbonylations with CO₂/H₂

Hua Kaimin ^1,2 ,
Liu Xiaofang ¹ ,
Wei Baiyin ^1,3 ,
Zhang Shunan ^1,2 ,
Wang Hui ^1,, ,
Sun Yuhan ^1,3,4,,

1.
CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, China
2.
University of the Chinese Academy of Sciences, Beijing 100049, China
3.
School of Physical Science and Technology, ShanghaiTech University, Shanghai 201203, China
4.
Shanghai Institute of Clean Technology, Shanghai 201620, China

Corresponding author: Wang Hui, wanghh@sari.ac.cn Sun Yuhan, sunyh@sari.ac.cn
Received Date: 29 September 2020
Revised Date: 20 October 2020
Accepted Date: 20 October 2020
Available Online: 23 October 2020
Fund Project: the National Key Research and Development Program of China 2017YFB0602203Key Research Program of Chinese Academy of Sciences ZDRW-ZS-2018-1-3the National Natural Science Foundation of China 21905291the National Natural Science Foundation of China 21776296Strategic Priority Research Program of the Chinese Academy of Sciences XDA21090201the Shanghai Sailing Program, China 19YF1453000This work was supported by the National Natural Science Foundation of China (21776296, 21905291), the National Key Research and Development Program of China (2017YFB0602203), Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21090201), Key Research Program of Chinese Academy of Sciences (ZDRW-ZS-2018-1-3), and the Shanghai Sailing Program, China (19YF1453000)

Ever-increasing energy demands due to rapid industrialization and urban population growth have drastically reduced petroleum reserves and increased greenhouse-gas production, and the latter has consequently contributed to climate change and environmental damage. Therefore, it is highly desirable to produce fuels and chemicals from non-petroleum feedstocks and to reduce the atmospheric concentrations of greenhouse gases. One solution has involved using carbon dioxide (CO₂), a main greenhouse gas, as a C1 feedstock for producing industrial fuels and chemicals. However, this requires high energy input from reductants or reactants with relatively high free energy (e.g., H₂ gas) because CO₂ is a highly oxidized, thermodynamically stable form of carbon. H₂ can be generated through water photolysis, making it an ideal reductant for hydrogenating CO₂ to CO. In situ generation of CO such as this has been developed for various carbonylation reactions that produce high value-added chemicals and avoid deriving CO from fossil fuels. This is beneficial because CO is toxic, and when extracted from fossil fuels it requires tedious separation and transportation. This combination of CO₂ and H₂ allows for functional molecules to be synthesized as entries into the chemical industry value chain and would generate a carbon footprint much lower than that of conventional petrochemical pathways. Based on this, CO₂/H₂ carbonylations using homogeneous transition metal-based catalysts have attracted increasing attention. Through this process, alkenes have been converted to alcohols, carboxylic acids, amines, and aldehydes. Heterogeneous catalysis has also provided an innovative approach for the carbonylation of alkenes with CO₂/H₂. Based on these alkene carbonylations, the scope of CO₂/H₂ carbonylations has been expanded to include aryl halides, methanol, and methanol derivatives, which give the corresponding aryl aldehyde, acetic acid, and ethanol products. These carbonylations revealed indirect CO₂-HCOOH-CO pathways and direct CO₂ insertion pathways. The use of this process is ever-increasing and has expanded the scope of CO₂ utilization to produce novel, high value-added or bulk chemicals, and has promoted sustainable chemistry. This review summarizes the recent advances in transition-metal-catalyzed carbonylations with CO₂/H₂ and discusses the perspectives and challenges of further research.
- Carbon dioxide hydrogenation,
- Carbonylation,
- Transition metal catalysis,
- Alcohols,
- Aldehydes,
- Carboxylic acids,
- Ethanol,
- Acetic acid
1. [1]
  Aresta, M.; Dibenedetto, A. Dalton Trans. 2007, 2975. doi: 10.1039/b700658f doi: 10.1039/b700658f
2. [2]
  Doney, S. C.; Fabry, V. J.; Feely, R. A.; Kleypas, J. A. Ann. Rev. Mar. Sci. 2009, 1, 169. doi: 10.1146/annurev.marine.010908.163834 doi: 10.1146/annurev.marine.010908.163834
3. [3]
  Alberico, E.; Nielsen, M. Chem. Commun. 2015, 51, 6714. doi: 10.1039/c4cc09471a doi: 10.1039/c4cc09471a
4. [4]
  Porosoff, M. D.; Yan, B.; Chen, J. G. Energy Environ. Sci. 2016, 9, 62. doi: 10.1039/c5ee02657a doi: 10.1039/c5ee02657a
5. [5]
  Abanades, J. C.; Rubin, E. S.; Mazzotti, M.; Herzog, H. J. Energy Environ. Sci. 2017, 10, 2491. doi: 10.1039/C7EE02819A doi: 10.1039/C7EE02819A
6. [6]
  Klankermayer, J.; Wesselbaum, S.; Beydoun, K.; Leitner, W. Angew. Chem. Int. Ed. 2016, 55, 7296. doi: 10.1002/anie.201507458 doi: 10.1002/anie.201507458
7. [7]
  Jessop, P. G.; Ikariya, T.; Noyor, R. Chem. Rev. 1995, 95, 259. doi: 10.1021/cr00034a001 doi: 10.1021/cr00034a001
8. [8]
  Leitner, W. Coord. Chem. Rev.1996, 153, 257. doi: 10.1016/0010-8545(95)01226-5 doi: 10.1016/0010-8545(95)01226-5
9. [9]
  Song, Q. -W.; Zhou, Z. -H.; He, L. -N. Green Chem. 2017, 19, 3707. doi: 10.1039/c7gc00199a doi: 10.1039/c7gc00199a
10. [10]
  Zhou, W.; Guo, J. -K.; Shen, S.; Pan, J.; Tang, J.; Chen, L.; Au, C. -T.; Yin, S. -F. Acta Phys. -Chim. Sin. 2020, 36, 1906048. doi: 10.3866/PKU.WHXB201906048
11. [11]
  Bai, X. -F.; Chen, W.; Wang, B. -Y.; Feng, G. -H.; Wei, W.; Jiao, Z.; Sun, Y. Acta Phys.-Chim. Sin. 2017, 33 2388. doi: 10.3866/PKU.WHXB201706131
12. [12]
  Wang, X.; Xia, C.; Wu, L. Green Chem. 2018, 20, 5415. doi: 10.1039/c8gc03022g doi: 10.1039/c8gc03022g
13. [13]
  Alvarez, A.; Bansode, A.; Urakawa, A.; Bavykina, A. V.; Wezendonk, T. A.; Makkee, M.; Gascon, J.; Kapteijn, F. Chem. Rev. 2017, 117, 9804. doi: 10.1021/acs.chemrev.6b00816 doi: 10.1021/acs.chemrev.6b00816
14. [14]
  Li, X.; He, X.; Liu, X.; He, L. -N. Sci. China Chem. 2017, 60, 841. doi: 10.1007/s11426-016-0473-5 doi: 10.1007/s11426-016-0473-5
15. [15]
  Gao, P.; Dang, S.; Li, S.; Bu, X.; Liu, Z.; Qiu, M.; Yang, C.; Wang, H.; Zhong, L.; Han, Y.; et al. ACS Catal. 2017, 8, 571. doi: 10.1021/acscatal.7b02649 doi: 10.1021/acscatal.7b02649
16. [16]
  Gao, P.; Li, S.; Bu, X.; Dang, S.; Liu, Z.; Wang, H.; Zhong, L.; Qiu, M.; Yang, C.; Cai, J.; et al. Nat. Chem. 2017, 9, 1019. doi: 10.1038/nchem.2794 doi: 10.1038/nchem.2794
17. [17]
  Liao, P.; Zhang, C.; Zhang, L.; Yang, Y.; Zhong, L.; Wang, H.; Sun, Y. Catal. Today 2018, 311, 56. doi: 10.1016/j.cattod.2017.09.022 doi: 10.1016/j.cattod.2017.09.022
18. [18]
  Yang, H.; Zhang, C.; Gao, P.; Wang, H.; Li, X.; Zhong, L.; Wei, W.; Sun, Y. Catal. Sci. Technol. 2017, 7, 4580. doi: 10.1039/c7cy01403a doi: 10.1039/c7cy01403a
19. [19]
  Cui, X.; Shi, F. Acta Phys. -Chim. Sin. 2021, 37, 2006080. doi: 10.3866/PKU.WHXB202006080
20. [20]
  Zhong, L.; Yu, F.; An, Y.; Zhao, Y.; Sun, Y.; Li, Z.; Lin, T.; Lin, Y.; Qi, X.; Dai, Y.; et al. Nature 2016, 538, 84. doi: 10.1038/nature19786 doi: 10.1038/nature19786
21. [21]
  Kar, S.; Goeppert, A.; Prakash, G. K. S. Acc. Chem. Res. 2019, 52, 2892. doi: 10.1021/acs.accounts.9b00324 doi: 10.1021/acs.accounts.9b00324
22. [22]
  Beller, M.; Cornils, B.; Frohning, C. D.; Kohlpaintner, C. W. J. Mol. Catal. A: Chem. 1995, 104, 17. doi: 10.1016/1381-1169(95)00130-1 doi: 10.1016/1381-1169(95)00130-1
23. [23]
  Zhang, X.; Cao, Y.; Chen, Q.; Shen, C.; He, L. Acta Phys. -Chim. Sin. 2021, 37, 2007052. doi: 10.3866/PKU.WHXB202007052
24. [24]
  Klankermayer, J.; Leitner, W. Science 2015, 350, 629. doi: 10.1126/science.aac7997 doi: 10.1126/science.aac7997
25. [25]
  Morimoto, T.; Kakiuchi, K. Angew. Chem. Int. Ed. 2004, 43, 5580. doi: 10.1002/anie.200301736 doi: 10.1002/anie.200301736
26. [26]
  Gual, A.; Godard, C.; Castillón, S.; Claver, C. Tetra. Asymm. 2010, 21, 1135. doi: 10.1016/j.tetasy.2010.05.037 doi: 10.1016/j.tetasy.2010.05.037
27. [27]
  Wang, L.; Sun, W.; Liu, C. Chin. J. Chem. 2018, 36, 353. doi: 10.1002/cjoc.201700746 doi: 10.1002/cjoc.201700746
28. [28]
  Wu, L.; Liu, Q.; Jackstell, R.; Beller, M. Angew. Chem. Int. Ed. 2014, 53, 6310. doi: 10.1002/anie.201400793 doi: 10.1002/anie.201400793
29. [29]
  Tominaga, K.; Sasaki, Y.; Kawai, M.; Watanabe, T.; Saito, M. J. Chem. Soc. Chem. Commun. 1993, 7, 629. doi: 10.1039/c39930000629 doi: 10.1039/c39930000629
30. [30]
  Tominaga, K.; Sasaki, Y.; Hagihara, K.; Watanabe, T.; Saito, M. Chem. Lett. 1994, 23, 1391. doi: 10.1246/cl.1994.1391 doi: 10.1246/cl.1994.1391
31. [31]
  Tominaga K.; Sasaki, Y. Catal. Commun. 2000, 1, 1. doi: 10.1016/S1566-7367(00)00006-6 doi: 10.1016/S1566-7367(00)00006-6
32. [32]
  Jööskelöinen, S.; Haukka, M. Appl. Catal. A: Gen. 2003, 247, 95. doi: 10.1016/s0926-860x(03)00063-2 doi: 10.1016/s0926-860x(03)00063-2
33. [33]
  Kontkanen, M.-L.; Oresmaa, L.; Moreno, M. A.; Jönis, J.; Laurila, E.; Haukka, M. Appl. Catal. A: Gen. 2009, 365, 130. doi: 10.1016/j.apcata.2009.06.006 doi: 10.1016/j.apcata.2009.06.006
34. [34]
  Tominaga, K.; Sasaki, Y. J. Mol. Catal. A: Chem. 2004, 220, 159. doi: 10.1016/j.molcata.2004.06.009 doi: 10.1016/j.molcata.2004.06.009
35. [35]
  Tominaga, K.Catal. Today 2006, 115, 70. doi: 10.1016/j.cattod.2006.02.019 doi: 10.1016/j.cattod.2006.02.019
36. [36]
  Ali, M.; Gual, A.; Ebeling, G.; Dupont, J. ChemCatChem 2014, 6, 2224. doi: 10.1002/cctc.201402226 doi: 10.1002/cctc.201402226
37. [37]
  Liu, Q.; Wu, L.; Fleischer, I.; Selent, D.; Franke, R.; Jackstell, R.; Beller, M. Chem 2014, 20, 6888. doi: 10.1002/chem.201400358 doi: 10.1002/chem.201400358
38. [38]
  Zhang, X.; Tian, X.; Shen, C.; Xia, C.; He, L. ChemCatChem 2019, 11, 1986. doi: 10.1002/cctc.201802091 doi: 10.1002/cctc.201802091
39. [39]
  Ahlers, S. J.; Bentrup, U.; Linke, D.; Kondratenko, E. V. ChemSusChem 2014, 7, 2631. doi: 10.1002/cssc.201402212 doi: 10.1002/cssc.201402212
40. [40]
  Ahlers, S. J.; Kraehnert, R.; Kreyenschulte, C.; Pohl, M. -M.; Linke, D.; Kondratenko, E. V. Catal. Today 2015, 258, 684. doi: 10.1016/j.cattod.2015.04.006 doi: 10.1016/j.cattod.2015.04.006
41. [41]
  Ahlers, S. J.; Pohl, M.-M.; Radnik, J.; Linke, D.; Kondratenko, E. V. Appl. Catal. B: Environ. 2015, 176–177, 570. doi: 10.1016/j.apcatb.2015.04.034 doi: 10.1016/j.apcatb.2015.04.034
42. [42]
  Mavlyankariev, S. A.; Ahlers, S. J.; Kondratenko, V. A.; Linke, D.; Kondratenko, E. V. ACS Catal. 2016, 6, 3317. doi: 10.1021/acscatal.6b00590 doi: 10.1021/acscatal.6b00590
43. [43]
  Heyl, D.; Kreyenschulte, C.; Kondratenko, V. A.; Bentrup, U.; Kondratenko, E. V.; Bruckner, A. ChemSusChem 2019, 12, 651. doi: 10.1002/cssc.201801937 doi: 10.1002/cssc.201801937
44. [44]
  Greenhalgh, M. D.; Thomas, S. P. J. Am. Chem. Soc. 2012, 134, 11900. doi: 10.1021/ja3045053 doi: 10.1021/ja3045053
45. [45]
  Gaydou, M.; Moragas, T.; Julia-Hernandez, F.; Martin, R. J. Am. Chem. Soc. 2017, 139, 12161. doi: 10.1021/jacs.7b07637 doi: 10.1021/jacs.7b07637
46. [46]
  Gui, Y. Y.; Hu, N.; Chen, X. W.; Liao, L. L.; Ju, T.; Ye, J. H.; Zhang, Z.; Li, J.; Yu, D. G. J. Am. Chem. Soc. 2017, 139, 17011. doi: 10.1021/jacs.7b10149 doi: 10.1021/jacs.7b10149
47. [47]
  Wu, X. F.; Zheng, F. Top Curr. Chem. 2017, 375, 4. doi: 10.1007/s41061-016-0091-6 doi: 10.1007/s41061-016-0091-6
48. [48]
  Ostapowicz, T. G.; Schmitz, M.; Krystof, M.; Klankermayer, J.; Leitner, W. Angew. Chem. Int. Ed. 2013, 52, 12119. doi: 10.1002/anie.201304529 doi: 10.1002/anie.201304529
49. [49]
  Wang, Y.; Qian, Q.; Zhang, J.; Bediako, B. B. A.; Wang, Z.; Liu, H.; Han, B. Nat. Commun. 2019, 10, 5395. doi: 10.1038/s41467-019-13463-0 doi: 10.1038/s41467-019-13463-0
50. [50]
  Pugh, R. I.; Pringle, P. G.; Drent, E. Chem. Commun. 2001, 1476. doi: 10.1039/b103754b doi: 10.1039/b103754b
51. [51]
  Jimenez Rodriguez, C.; Foster, D. F.; Eastham, G. R.; Cole-Hamilton, D. J. Chem. Commun. 2004, 1720. doi: 10.1039/b404783d doi: 10.1039/b404783d
52. [52]
  Konrad, T. M.; Fuentes, J. A.; Slawin, A. M. Z.; Clarke, M. L. Angew. Chem. Int. Ed. 2010, 49, 9197. doi: 10.1002/anie.201004415 doi: 10.1002/anie.201004415
53. [53]
  Wu, L.; Liu, Q.; Fleischer, I.; Jackstell, R.; Beller, M. Nat. Commun. 2014, 5, 3091. doi: 10.1038/ncomms4091 doi: 10.1038/ncomms4091
54. [54]
  Zhang, X.; Shen, C.; Xia, C.; Tian, X.; He, L. Green Chem. 2018, 20, 5533. doi: 10.1039/c8gc02289e doi: 10.1039/c8gc02289e
55. [55]
  Zhang, Y.; Dai, X.; Wang, H.; Shi, F. Acta Phys. -Chim. Sin. 2018, 34, 845. doi: 10.3866/PKU.WHXB201701081
56. [56]
  Li, R.; Zhao, Y.; Wang, H.; Xiang, J.; Wu, Y.; Yu, B., Han, B.; Liu, Z. Chem. Sci. 2019, 10, 9822. doi: 10.1039/c9sc03242h doi: 10.1039/c9sc03242h
57. [57]
  Srivastava, V. K.; Eilbracht, P. Catal. Commun. 2009, 10, 1791. doi: 10.1016/j.catcom.2009.05.019 doi: 10.1016/j.catcom.2009.05.019
58. [58]
  Ali, M.; Gual, A.; Ebeling, G.; Dupont, J. ChemSusChem. 2016, 9, 2129. doi: 10.1002/cssc.201600385 doi: 10.1002/cssc.201600385
59. [59]
  Ren, X.; Zheng, Z.; Zhang, L.; Wang, Z.; Xia, C.; Ding, K. Angew. Chem. Int. Ed. 2017, 56, 310. doi: 10.1002/anie.201608628 doi: 10.1002/anie.201608628
60. [60]
  Xie, Z.; Xu, Y.; Xie, M.; Chen, X.; Lee, J. H.; Stavitski, E.; Kattel, S.; Chen, J. G. Nat. Commun. 2020, 11, 1887. doi: 10.1038/s41467-020-15849-x doi: 10.1038/s41467-020-15849-x
61. [61]
  Kantlehner, W. Eur. J. Org. Chem. 2003, 2003, 2530. doi: 10.1002/ejoc.200200653 doi: 10.1002/ejoc.200200653
62. [62]
  Crawford, L. P.; Richardson, S. K. General and Synthetic Methods; Royal Society of Chemistry Publ: London, UK, 1994; p. 37. doi: 10.1039/9781847556288-00037
63. [63]
  Sergeev, A. G.; Spannenberg, A.; Beller, M. J. Am. Chem. Soc. 2008, 130, 15549. doi: 10.1021/ja804997z doi: 10.1021/ja804997z
64. [64]
  Natte, K.; Dumrath, A.; Neumann, H.; Beller, M. Angew. Chem. Int. Ed. 2014, 53, 10090. doi: 10.1002/anie.201404833 doi: 10.1002/anie.201404833
65. [65]
  Sun, G.; Lv, X.; Zhang, Y.; Lei, M.; Hu, L. Org. Lett. 2017, 19, 4235. doi: 10.1021/acs.orglett.7b01882 doi: 10.1021/acs.orglett.7b01882
66. [66]
  Yu, B.; Zhao, Y.; Zhang, H.; Xu, J.; Hao, L.; Gao, X.; Liu, Z. Chem. Commun. 2014, 50, 2330. doi: 10.1039/c3cc49365b doi: 10.1039/c3cc49365b
67. [67]
  Yu, B.; Yang, Z.; Zhao, Y.; Hao, L.; Zhang, H.; Gao, X.; Han, B.; Liu, Z. Chem 2016, 22, 1097. doi: 10.1002/chem.201504320 doi: 10.1002/chem.201504320
68. [68]
  Liu, Z.; Yang, Z.; Yu, B.; Yu, X.; Zhang, H.; Zhao, Y.; Yang, P.; Liu, Z. Org. Lett. 2018, 20, 5130. doi: 10.1021/acs.orglett.8b02027 doi: 10.1021/acs.orglett.8b02027
69. [69]
  Shao, Z.; Liu, X.; Zhang, S.; Wang, H.; Sun, Y. Acta Phys. -Chim. Sin. 2021, 37, 1911053. doi: 10.3866/PKU.WHXB201911053
70. [70]
  Maitlis, P.; Haynes, A.; Sunley, G. J.; Howard, M. J. J. Chem. Soc. Dalton. 1996, 11, 2187. doi: 10.1039/dt9960002187 doi: 10.1039/dt9960002187
71. [71]
  Budiman, A. W.; Nam, J. S.; Park, J. H.; Mukti, R. I.; Chang, T. S.; Bae, J. W.; Choi, M. J. Catal. Surv. Asia 2016, 20, 173. doi: 10.1007/s10563-016-9215-9 doi: 10.1007/s10563-016-9215-9
72. [72]
  Peng, J. -B.; Wu, F. -P.; Wu, X. -F. Chem. Rev. 2018, 119, 2090. doi: 10.1021/acs.chemrev.8b00068 doi: 10.1021/acs.chemrev.8b00068
73. [73]
  Li, J.; Wang, L.; Cao, Y.; Zhang, C.; He, P.; Li, H. Chin. J. Chem. Eng. 2018, 26, 2266. doi: 10.1016/j.cjche.2018.07.008 doi: 10.1016/j.cjche.2018.07.008
74. [74]
  Chen, C.; Yan, X.; Liu, S.; Wu, Y.; Wan, Q.; Sun, X.; Zhu, Q.; Liu, H.; Ma, J.; Zheng, L.; et al. Angew. Chem. Int. Ed. 2020, 59, 16459. doi: 10.1002/anie.202006847 doi: 10.1002/anie.202006847
75. [75]
  Prieto, G. ChemSusChem2016, 10, 1056. doi: 10.1002/cssc.v10.6 doi: 10.1002/cssc.v10.6
76. [76]
  Luk, H. T.; Mondelli, C.; Ferre, D. C.; Stewart, J. A.; Perez-Ramirez, J. Chem. Soc. Rev. 2017, 46, 1358. doi: 10.1039/c6cs00324a doi: 10.1039/c6cs00324a
77. [77]
  Wu, J. F.; Yu, S. M.; Wang, W. D.; Fan, Y. X.; Bai, S.; Zhang, C. W.; Gao, Q.; Huang, J.; Wang, W. J. Am. Chem. Soc. 2013, 135, 13567. doi: 10.1021/ja406978q doi: 10.1021/ja406978q
78. [78]
  Fukuoka, A.; Gotoh, N.; Kobayashi, N.; Hirano, M.; Komiya, S. Chem. Lett. 1995, 24, 567. doi: 10.1246/cl.1995.567 doi: 10.1246/cl.1995.567
79. [79]
  Qian, Q.; Zhang, J.; Cui, M.; Han, B. Nat. Commun. 2016, 7, 11481. doi: 10.1038/ncomms11481 doi: 10.1038/ncomms11481
80. [80]
  Cui, M.; Qian, Q.; Zhang, J.; Chen, C.; Han, B. Green Chem. 2017, 19, 3558. doi: 10.1039/c7gc01391d doi: 10.1039/c7gc01391d
81. [81]
  Wang, H.; Zhao, Y.; Ke, Z.; Yu, B.; Li, R.; Wu, Y.; Wang, Z.; Han, J.; Liu, Z. Chem. Commun. 2019, 55, 3069. doi: 10.1039/c9cc00819e doi: 10.1039/c9cc00819e
82. [82]
  Shen, X.; Meng, Q.; Dong, M.; Xiang, J.; Li, S.; Liu, H.; Han, B. ChemSusChem 2019, 12, 5149. doi: 10.1002/cssc.201902404 doi: 10.1002/cssc.201902404
83. [83]
  Gao, Y.; Liu, S.; Zhao, Z.; Tao, H.; Sun, Z. Acta Phys. -Chim. Sin. 2018, 34, 858. doi: 10.3866/PKU.WHXB201802061
84. [84]
  Schmitz, M.; Erken, C.; Ohligschlöger, A.; Schnoor, J. K.; Westhues, N. F.; Klankermayer, J.; Leitner, W.; Liauw, M. A. Chem. Ing. Tech. 2018, 90, 1476. doi: 10.1002/cite.201800053 doi: 10.1002/cite.201800053
85. [85]
  Wang, H.; Zhao, Y.; Wu, Y.; Li, R.; Zhang, H.; Yu, B.; Zhang, F.; Xiang, J.; Wang, Z.; Liu, Z. ChemSusChem. 2019, 12, 4390. doi: 10.1002/cssc.201901820 doi: 10.1002/cssc.201901820
86. [86]
  Zhang, S.; Liu, X.; Shao, Z.; Wang, H.; Sun, Y. J. Catal. 2020, 382, 86. doi: 10.1016/j.jcat.2019.11.038 doi: 10.1016/j.jcat.2019.11.038
87. [87]
  Tominaga, K.; Sasaki, Y.; Watanabe, T.; Saito, M. Advances in Chemical Conversions for Mitigating Carbon Dioxide. In Studies in Surface Science and Catalysis; Inui, T., Anpo, M., Izui, K., Yanagida, S., Yamaguchi, T. Eds.; Elsevier Science Publ: Amsterdam, Japan, 1998; Vol. 114, pp. 495–498.
88. [88]
  Zhang, J.; Qian, Q.; Cui, M.; Chen, C.; Liu, S.; Han, B. Green Chem. 2017, 19, 4396. doi: 10.1039/c7gc01887h doi: 10.1039/c7gc01887h
89. [89]
  Qian, Q.; Cui, M.; Zhang, J.; Xiang, J.; Song, J.; Yang, G.; Han, B. Green Chem. 2018, 20, 206. doi: 10.1039/c7gc02807e doi: 10.1039/c7gc02807e
90. [90]
  Asare Bediako, B. B.; Qian, Q.; Zhang, J.; Wang, Y.; Shen, X.; Shi, J.; Cui, M.; Yang, G.; Wang, Z.; Tong, S.; et al. Green Chem. 2019, 21, 4152. doi: 10.1039/c9gc01185d doi: 10.1039/c9gc01185d
91. [91]
  Wang, Y.; Zhang, J.; Qian, Q.; Asare Bediako, B. B.; Cui, M.; Yang, G.; Yan, J.; Han, B. Green Chem. 2019, 21, 589. doi: 10.1039/c8gc03320j doi: 10.1039/c8gc03320j
92. [92]
  Zhang, J.; Qian, Q.; Wang, Y.; Asare Bediako, B. B.; Yan, J.; Han, B. Chem Sci. 2019, 10, 10640. doi: 10.1039/c9sc03386f doi: 10.1039/c9sc03386f
1. [1]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
2. [2]
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Research Progress Regarding Transition Metal-Catalyzed Carbonylations with CO2/H2

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通讯作者: 陈斌, bchen63@163.com

Research Progress Regarding Transition Metal-Catalyzed Carbonylations with CO₂/H₂