Citation: Zihui Mei, Guohong Wang, Suding Yan, Juan Wang. Rapid Microwave-Assisted Synthesis of 2D/1D ZnIn₂S₄/TiO₂ S-Scheme Heterojunction for Catalyzing Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, ;2021, 37(6): 200909. doi: 10.3866/PKU.WHXB202009097 shu

Rapid Microwave-Assisted Synthesis of 2D/1D ZnIn₂S₄/TiO₂ S-Scheme Heterojunction for Catalyzing Photocatalytic Hydrogen Evolution

Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University, Huangshi 435002, Hubei Province, China

Corresponding author: Guohong Wang, wanggh2003@163.com
Received Date: 29 September 2020
Revised Date: 21 October 2020
Accepted Date: 31 October 2020
Available Online: 10 November 2020
Fund Project: the National Natural Science Foundation of China 22075072the National Natural Science Foundation of China 52003079Hubei Provincial Natural Science Foundation of China 2019CFB568

The threat and global concern of energy crises have significantly increased over the last two decades. Because solar light and water are abundant on earth, photocatalytic hydrogen evolution through water splitting has been considered as a promising route to produce green energy. Therefore, semiconductor photocatalysts play a key role in transforming sunlight and water to hydrogen energy. To date, various photocatalysts have been studied. Among them, TiO₂ has been extensively investigated because of its non-toxicity, high chemical stability, controllable morphology, and high photocatalytic activity. In particular, 1D TiO₂ nanofibers (NFs) have attracted increasing attention as effective photocatalysts because of their unique 1D electron transfer pathway, high adsorption capacity, and high photoinduced electron–hole pair transfer capability. However, TiO₂ NFs are considered as an inefficient photocatalyst for the hydrogen evolution reaction (HER) because of their disadvantages such as a large band gap (~3.2 eV) and fast recombination of photoinduced electron–hole pairs. Therefore, the development of a high-performance TiO₂ NF photocatalyst is required for efficient solar light conversion. In recent years, several strategies have been explored to improve the photocatalytic activity of TiO₂ NFs, including coupling with narrow-bandgap semiconductors (such as ZnIn₂S₄). Recently, microwave (MW)-assisted synthesis has been considered as an important strategy for the preparation of photocatalyst semiconductors because of its low cost, environment-friendliness, simplicity, and high reaction rate. Herein, to overcome the above-mentioned limiting properties of TiO₂ NFs, we report a 2D/1D ZnIn₂S₄/TiO₂ S-scheme heterojunction synthesized through a microwave (MW)-assisted process. Herein, the 2D/1D ZnIn₂S₄/TiO₂ S-scheme heterojunction was constructed rapidly by using in situ 2D ZnIn₂S₄nanosheets decorated on 1D TiO₂ NFs. The loading of ZnIn₂S₄ nanoplates on the TiO₂ NFs could be easily controlled by adjusting the molar ratios of ZnIn₂S₄ precursors to TiO₂ NFs. The photocatalytic activity of the as-prepared samples for water splitting under simulated solar light irradiation was assessed. The experimental results showed that the photocatalytic performance of the ZnIn₂S₄/TiO₂ composites was significantly improved, and the obtained ZnIn₂S₄/TiO₂ composites showed increased optical absorption. Under optimal conditions, the highest HER rate of the ZT-0.5 (molar ratio of ZnIn₂S₄/TiO₂= 0.5) sample was 8774 μmol·g^-1·h^-1, which is considerably higher than those of pure TiO₂ NFs (3312 μmol·g^-1·h^-1) and ZnIn₂S₄nanoplates (3114 μmol·g^-1·h^-1) by factors of 2.7 and 2.8, respectively. Based on the experimental data and Mott-Schottky analysis, a possible mechanism for the formation of the S-scheme heterojunction between ZnIn₂S₄ and TiO₂ was proposed to interpret the enhanced HER activity of the ZnIn₂S₄/TiO₂heterojunctionphotocatalysts.
- Microwave-assisted,
- 2D/1D,
- ZnIn₂S₄/TiO₂,
- S-scheme heterojunction,
- Photocatalytic hydrogen evolution
1. [1]
  Zhang, T. M.; Wan, Y. Y.; Xie, H. Y.; Mu, Y.; Du, P. W.; Wang, D.; Wu, X. J.; Ji, H. X.; Wan, L. J. J. Am. Chem. Soc. 2018, 140 (24), 7561. doi: 10.1021/jacs.8b02156 doi: 10.1021/jacs.8b02156
2. [2]
  Meng, A. Y.; Zhang, L. Y.; Cheng, B.; Yu, J. G. Adv. Mater. 2019, 31 (30), 1807660. doi: 10.1002/adma.201807660 doi: 10.1002/adma.201807660
3. [3]
  Di, T. M.; Xu, Q. L.; Ho, W. K.; Tang, H.; Xiang, Q. J.; Yu, J. G. ChemCatChem 2019, 11 (5), 1394. doi: 10.1002/cctc.201802024 doi: 10.1002/cctc.201802024
4. [4]
  Xu, Q. L.; Ma, D. K.; Yang, S. B.; Tian, Z. F.; Cheng, B.; Fan, J. J. Appl. Surf. Sci. 2019, 495, 143555. doi: 10.1016/j.apsusc.2019.143555 doi: 10.1016/j.apsusc.2019.143555
5. [5]
  Sadowski, R.; Wach, A.; Buchalska, M.; Kuśtrowski, P.; Macyk, W. Appl. Surf. Sci. 2019, 475, 710. doi: 10.1016/j.apsusc.2018.12.286 doi: 10.1016/j.apsusc.2018.12.286
6. [6]
  Zhang, C.; Wu, Z. J.; Liu, J. J.; Piao, L. Y. Acta Phys. -Chim. Sin. 2017, 33, 1492. doi: 10.3866/PKU.WHXB201704141
7. [7]
  Ji, Y. C.; Yang, R. Q.; Wang, L. W.; Song, G. X.; Wang, A. Z.; Lv, Y. W.; Gao, M. M.; Zhang, J.; Yu, X. Chem. Eng. J. 2020, 40, 126226. doi: 10.1016/j.cej.2020.126226 doi: 10.1016/j.cej.2020.126226
8. [8]
  Xu, F. Y.; Zhu, B. C.; Cheng, B.; Yu, J. G.; Xu, J. S. Adv. Opt. Mater. 2018, 6 (23), 180911. doi: 10.1002/adom.201800911 doi: 10.1002/adom.201800911
9. [9]
  Wu, J.; Liu, J.; Xia, W.; Ren, Y. Y.; Wang, F. Acta Phys. -Chim. Sin. 2021, 37, 2008043. doi: 10.3866/PKU.WHXB202008043
10. [10]
  Liu, G.; Wang, G. H.; Hu, Z. H.; Su, Y. R.; Zhao, L. Appl. Surf. Sci. 2019, 465, 902. doi: 10.1016/j.apsusc.2018.09.216 doi: 10.1016/j.apsusc.2018.09.216
11. [11]
  Chu, Z. D.; Qiu, L. L.; Chen, Y.; Zhuang, Z. S.; Du, P. F.; Xiong, J. J. Phys. Chem. Solids. 2020, 136, 109138. doi: 10.1016/j.jpcs.2019.109138 doi: 10.1016/j.jpcs.2019.109138
12. [12]
  Liu, Y.; Hao, X. Q.; Hu, H, Q.; Ging, Z. L. Acta Phys. -Chim. Sin. 2021, 37, 2008030. doi: 10.3866/PKU.WHXB202008030
13. [13]
  Li, X. Z.; Yan, X. Y.; Lu, X. W.; Zuo, S. X.; Li, Z. Y.; Yao, C.; Ni, C. Y. J. Catal. 2018, 357, 59. doi: 10.1016/j.jcat.2017.10.024 doi: 10.1016/j.jcat.2017.10.024
14. [14]
  Li, H. F.; Yu, H. T.; Quan, X.; Chen, S.; Zhang, Y. B. ACS Appl. Mater. Interface 2016, 8 (3), 2111. doi: 10.1021/acsami.5b10613 doi: 10.1021/acsami.5b10613
15. [15]
  Shen, J.; Wang, R.; Liu, Q. Q.; Yang, X. F.; Tang, H.; Yang, J. Chin. J. Catal. 2019, 40 (3), 380. doi: 10.1016/S1872-2067(18)63166-3 doi: 10.1016/S1872-2067(18)63166-3
16. [16]
  Pan, J. B.; Shen, S.; Zhou, W.; Tang, J.; Ding, H. Z.; Wang, J. B.; Chen, L.; Au, C. T.; Yin, S. F. Acta Phys. -Chim. Sin. 2020, 36, 1905068. doi: 10.3866/PKU.WHXB201905068
17. [17]
  Huang, J. J.; Du, J. M.; Du, H. W.; Xu, G. S.; Yuan, Y. P. Acta Phys. -Chim. Sin. 2020, 36, 1905056. doi: 10.3866/PKU.WHXB201905056
18. [18]
  Xia, P. F.; Cao, S. W.; Zhu, B. C.; Liu, M. J.; Shi, M. S.; Yu, J. G.; Zhang, Y. F. Angew. Chem. Int. Ed. 2020, 59 (13), 5218. doi: 10.1002/ange.201916012 doi: 10.1002/ange.201916012
19. [19]
  Li, Z. J.; Wang, X. H.; Tian, W. L.; Meng, A. L.; Yang, L. N. ACS Sustain. Chem. Eng. 2019, 7 (24), 20190. doi: 10.1021/acssuschemeng.9b06430 doi: 10.1021/acssuschemeng.9b06430
20. [20]
  He, F.; Meng, A. Y.; Cheng, B.; Ho, W. K.; Yu, J. G. Chin. J. Catal. 2020, 41 (1), 9. doi: 10.1016/S1872-2067(19)63382-6 doi: 10.1016/S1872-2067(19)63382-6
21. [21]
  Luo, J. H.; Lin, Z. X.; Zhao, Y.; Jiang, S. J.; Song, S. Q. Chin. J. Catal. 2020, 41 (1), 122. doi: 10.1016/S1872-2067(19)63490-X doi: 10.1016/S1872-2067(19)63490-X
22. [22]
  Wang, J.; Wang, G. H.; Cheng, B.; Yu, J. G.; Fan, J. J. Chin. J. Catal. 2021, 42 (1), 56. doi: 10.1016/S1872-2067(20)63634-8 doi: 10.1016/S1872-2067(20)63634-8
23. [23]
  Wei, J. X.; Chen, Y. W.; Zhang, H. Y.; Zhuang, Z. Y.; Yu, Y. Chin. J. Catal. 2021, 42 (1), 78. doi: 10.1016/S1872-2067(20)63661-0 doi: 10.1016/S1872-2067(20)63661-0
24. [24]
  Peng, J. J.; Shen, J.; Yu, X. H.; Tang, H.; Zulfiqar; Liu, Q. Q. Chin. J. Catal. 2021, 42 (1), 87. doi: 10.1016/S1872-2067(20)63595-1 doi: 10.1016/S1872-2067(20)63595-1
25. [25]
  Wang, Z. L.; Chen, Y. F.; Zhang, L. Y.; Cheng, B.; Yu, J. G.; Fan, J. J. J. Mater. Sci. Technol. 2020, 56, 143. doi: 10.1016/j.jmst.2020.02.062 doi: 10.1016/j.jmst.2020.02.062
26. [26]
  Li, Z. F.; Wu, Z. H.; He, R. A.; Wan, L.; Zhang, S. Y. J. Mater. Sci. Technol. 2020, 56, 151. doi: 10.1016/j.jmst.2020.02.061 doi: 10.1016/j.jmst.2020.02.061
27. [27]
  Wang, Y. Y.; Wang, K.; Wang, J. L.; Wu, X. Y.; Zhang, G. K. J. Mater. Sci. Technol. 2020, 56, 236. doi: 10.1016/j.jmst.2020.03.039 doi: 10.1016/j.jmst.2020.03.039
28. [28]
  Liu, H.; Yu, D.Q.; Sun, T. B.; Du, H. Y.; Jiang, W. T.; Yaseen, M.; Huang, L. Appl. Surf. Sci. 2019, 473, 855. doi: 10.1016/j.apsusc.2018.12.162 doi: 10.1016/j.apsusc.2018.12.162
29. [29]
  Nasr, M.; Eid, C.; Habchi, R.; Miele, P.; Bechelany, M. ChemSusChem 2018, 11 (18), 3023. doi: 10.1002/cssc.201800874 doi: 10.1002/cssc.201800874
30. [30]
  Chen, W.; Liu, T. Y.; Huang, T.; Liu, X. H.; Yang, X. J. Nanoscale 2016, 8 (6), 3711. doi: 10.1039/c5nr07695a doi: 10.1039/c5nr07695a
31. [31]
  Xia, Y.; Li, Q.; Lv, K. L.; Li, M. Appl. Surf. Sci. 2017, 398, 81. doi: 10.1016/j.apsusc.2016.12.006 doi: 10.1016/j.apsusc.2016.12.006
32. [32]
  Wei, N.; Wu, Y. H.; Wang, M. L.; Sun, W. X.; Li, Z. K.; Ding, L.; Cui, H. Z. Nanotechnology 2018, 30 (4), 045701. doi: 10.1088/1361-6528/aaecc6 doi: 10.1088/1361-6528/aaecc6
33. [33]
  Zhu, Y. J.; Chen, F. Chem. Rev. 2014, 114 (12), 6462. doi: 10.1021/cr400366s doi: 10.1021/cr400366s
34. [34]
  Lin, B.; Li, H.; An, H.; Hao, W. B.; Wei, J. J.; Dai, Y. Z.; Ma, C. S.; Yang, G. D. Appl. Catal. B-Environ. 2018, 220, 542. doi: 10.1016/j.apcatb.2017.08.071 doi: 10.1016/j.apcatb.2017.08.071
35. [35]
  Sing, K. S. Pure Appl. Chem. 1985, 57 (4), 603. doi: 10.1351/pac198254112201 doi: 10.1351/pac198254112201
36. [36]
  Wang, J.; Wang, G. H.; Wang, X.; Su, Y. R.; Tang, H. Carbon 2019, 149, 618. doi: 10.1016/j.carbon.2019.04.088 doi: 10.1016/j.carbon.2019.04.088
37. [37]
  Zhou, X. J.; Shao, C. L.; Li, X. H.; Wang, X. X.; Guo, X. H.; Liu, Y. C. J. Hazard. Mater. 2018, 344, 113. doi: 10.1016/j.jhazmat.2017.10.006 doi: 10.1016/j.jhazmat.2017.10.006
38. [38]
  Cao, S. W.; Shen, B. J.; Tong, T.; Fu, J. W.; Yu, J. G. Adv. Funct. Mater. 2018, 28 (21), 1800136. doi: 10.1002/adfm.201800136 doi: 10.1002/adfm.201800136
39. [39]
  Liu, J. J. J. Phys. Chem. C 2015, 119 (51), 28417. doi: 10.1021/acs.jpcc.5b09092 doi: 10.1021/acs.jpcc.5b09092
40. [40]
  Gao, D. D.; Yuan, R. R.; Fan, J. J.; Hong, X. K.; Yu, H. G. J. Mater. Sci. Technol. 2020, 56, 122. doi: 10.1016/j.jmst.2020.02.031 doi: 10.1016/j.jmst.2020.02.031
41. [41]
  He, R. G.; Liu, H. J.; Liu, H. M.; Xu, D. F.; Zhang, L. Y. J. Mater. Sci. Technol. 2020, 52, 145. doi: 10.1016/j.jmst.2020.03.027 doi: 10.1016/j.jmst.2020.03.027
42. [42]
  Xu, F. Y.; Zhang, J. J.; Zhu, B. C.; Yu, J. G.; Xu, J. S. Appl. Catal. B-Environ. 2018, 230, 194. doi: 10.1016/j.apcatb.2018.02.042 doi: 10.1016/j.apcatb.2018.02.042
43. [43]
  Xu, Q. L.; Zhang, L. Y.; Yu, J. G.; Wageh, S.; Al-Ghamdi, A. A.; Jaroniec, M. Mater. Today 2018, 21 (10), 1042. doi: 10.1016/j.mattod.2018.04.008 doi: 10.1016/j.mattod.2018.04.008
44. [44]
  Xia, Y.; Tian, Z. H.; Heil, T.; Meng, A. Y.; Cheng, B.; Cao, S. W.; Yu, J. G.; Antonietti, M. Joule 2019, 3 (11), 2792. doi: 10.1016/j.joule.2019.08.011 doi: 10.1016/j.joule.2019.08.011
45. [45]
  Ge, H. N.; Xu, F. Y.; Cheng, B.; Yu, J. G.; Ho, W. K. ChemCatChem 2019, 11 (24), 6301. doi: 10.1002/cctc.201901486 doi: 10.1002/cctc.201901486
46. [46]
  Zhang, T.; Low, J. X.; Yu, J. G.; Tyryshkin, A. M.; Mikmekova, E.; Asefa, T. Angew. Chem. Int. Ed. 2020, 59 (35), 15000. doi: 10.1002/anie.202005143 doi: 10.1002/anie.202005143
47. [47]
  Xu, F. Y.; Meng, K.; Cheng, B.; Wang, S. Y.; Xu, J. S.; Yu, J. G. Nat. Commun. 2020, 11, 4613. doi: 10.1038/s41467-020-18350-7 doi: 10.1038/s41467-020-18350-7
48. [48]
  Xu, Q. L.; Zhang, L. Y.; Cheng, B.; Fan, J. J.; Yu, J. G. Chem 2020, 6 (7), 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
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Rapid Microwave-Assisted Synthesis of 2D/1D ZnIn2S4/TiO2 S-Scheme Heterojunction for Catalyzing Photocatalytic Hydrogen Evolution

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通讯作者: 陈斌, bchen63@163.com

Rapid Microwave-Assisted Synthesis of 2D/1D ZnIn₂S₄/TiO₂ S-Scheme Heterojunction for Catalyzing Photocatalytic Hydrogen Evolution