Citation: Zhao Kangning, Li Xiao, Su Dong. High-Entropy Alloy Nanocatalysts for Electrocatalysis[J]. Acta Physico-Chimica Sinica, ;2021, 37(7): 200907. doi: 10.3866/PKU.WHXB202009077 shu

High-Entropy Alloy Nanocatalysts for Electrocatalysis

Zhao Kangning ^† ,
Li Xiao ^† ,
Su Dong ^,

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Su Dong, dongsu@iphy.ac.cn

^†

Received Date: 25 September 2020
Revised Date: 21 October 2020
Accepted Date: 31 October 2020
Available Online: 10 November 2020
Fund Project: The project was supported by the Strategic Priority Research Program (B) (XDB07030200) of Chinese Academy of Sciencesthe Strategic Priority Research Program (B) XDB07030200

The implementation of clean energy techniques, including clean hydrogen generation, use of solar-driven photovoltaic hybrid systems, photochemical heat generation as well as thermoelectric conversion, is crucial for the sustainable development of our society. Among these promising techniques, electrocatalysis has received significant attention for its ability to facilitate clean energy conversion because it promotes a higher rate of reaction and efficiency for the associated chemical transformations. Noble-metal-based electrocatalysts typically show high activity for electrochemical conversion processes. However, their scarcity and high cost limit their applications in electrocatalytic devices. To overcome this limitation, binary catalysts prepared by alloying with transition metals can be used. However, optimization of the activity of the binary catalysts is considerably limited because of the presence of the miscibility gap in the phase diagram of binary alloys. The activity of binary electrocatalysts can be attributed to the adsorption energy of molecules and intermediates on the surface. High-entropy alloys (HEAs), which consist of diverse elements in a single NP, typically exhibit better physical and/or chemical properties than their single-element counterparts, because of their tunable composition and inherent surface complexity. Further, HEAs can improve the performance of binary electrocatalysts because they exhibit a near-continuous distribution of adsorption energy. Recently, HEAs have gained considerable attention for their application in electrocatalytic reactions. This review summarizes recent research advances in HEA nanostructures and their application in the field of electrocatalysis. First, we introduce the concept, structure, and four core effects of HEAs. We believe that this part will provide the basic information about HEAs. Next, we discuss the reported top-down and bottom-up synthesis strategies, emphasizing on the carbothermal shock method, nanodroplet-mediated electrodeposition, fast moving bed pyrolysis, polyol process, and dealloying. Other methods such as combinatorial co-sputtering, ultrashort-pulsed laser ablation, ultrasonication-assisted wet chemistry, and scanning-probe block copolymer lithography are also highlighted. Among these methods, wet chemistry has been reported to be effective for the formation of nano-scale HEAs because it facilitates the concurrent reduction of all metal precursors to form solid-solution alloys. Next, we present the theoretical investigation of HEA nanocatalysts, including their thermodynamics, kinetic stability, and adsorption energy tuning for optimizing their catalytic activity and selectivity. To elucidate the structure–property relationship in HEAs, we summarize the research progress related to electrocatalytic reactions promoted by HEA nanocatalysts, including the oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, methanol oxidation reaction, and CO₂ reduction reaction. Finally, we discuss the challenges and various strategies toward the development of HEAs.
- High-entropy alloy nanostructures,
- Electrocatalysis,
- Single-phase solid solution,
- Adsorption energy,
- Active site
1. [1]
  Turner, J. A. Science 2004, 305, 972. doi: 10.1126/science.1103197 doi: 10.1126/science.1103197
2. [2]
  Lewis, N. S.; Nocera, D. G. Proc. Natl. Acad. Sci. 2006, 103, 15729. doi: 10.1073/pnas.0603395103 doi: 10.1073/pnas.0603395103
3. [3]
  Chu, S.; Majumdar, A. Nature 2012, 488, 294. doi: 10.1038/nature11475 doi: 10.1038/nature11475
4. [4]
  Seh, Z. W.; Kibsgaard, J.; Dickens, C. F.; Chorkendorff, I.; Nørskov, J. K.; Jaramillo, T. F. Science 2017, 355, eaad4998. doi: 10.1126/science.aad4998 doi: 10.1126/science.aad4998
5. [5]
  Nguyen, D. L. T.; Kim, Y.; Hwang, Y. J.; Won, D. H. Carbon Energy 2020, 2, 72. doi: 10.1002/cey2.27 doi: 10.1002/cey2.27
6. [6]
  Ali, A.; Shen, P. K. Carbon Energy 2020, 2, 99. doi: 10.1002/cey2.26 doi: 10.1002/cey2.26
7. [7]
  He, Y.; Liu, J. -C.; Luo, L.; Wang, Y. -G.; Zhu, J.; Du, Y.; Li, J.; Mao, S. X.; Wang, C. Proc. Natl. Acad. Sci. 2018, 115, 7700. doi: 10.1073/pnas.1800262115 doi: 10.1073/pnas.1800262115
8. [8]
  Li, C.; Tan, H.; Lin, J.; Luo, X.; Wang, S.; You, J.; Kang, Y. -M.; Bando, Y.; Yamauchi, Y.; Kim, J. Nano Today 2018, 21, 91. doi: 10.1016/j.nantod.2018.06.005 doi: 10.1016/j.nantod.2018.06.005
9. [9]
  Yu, J.; He, Q.; Yang, G.; Zhou, W.; Shao, Z.; Ni, M. ACS Catal. 2019, 9, 9973. doi: 10.1021/acscatal.9b02457 doi: 10.1021/acscatal.9b02457
10. [10]
  Singh, K.; Tetteh, E. B.; Lee, H. -Y.; Kang, T. -H.; Yu, J. -S. ACS Catal. 2019, 9, 8622. doi: 10.1021/acscatal.9b01420 doi: 10.1021/acscatal.9b01420
11. [11]
  Zhang, C.; Chen, Z.; Lian, Y.; Chen, Y.; Li, Q.; Gu, Y.; Lu, Y.; Deng, Z.; Peng, Y. Acta Phys. -Chim. Sin. 2019, 35, 1404. doi: 10.3866/PKU.WHXB201905030
12. [12]
  Luo, M.; Sun, Y.; Qin, Y.; Li, Y.; Li, C.; Yang, Y.; Xu, N.; Wang, L.; Guo, S. Mater. Today Nano 2018, 1, 29. doi: 10.1016/j.mtnano.2018.04.008 doi: 10.1016/j.mtnano.2018.04.008
13. [13]
  Halawa, M. I.; Lai, J.; Xu, G. Mater. Today Nano 2018, 3, 9. doi: 10.1016/j.mtnano.2018.11.001 doi: 10.1016/j.mtnano.2018.11.001
14. [14]
  Batchelor, T. A. A.; Pedersen, J. K.; Winther, S. H.; Castelli, I. E.; Jacobsen, K. W.; Rossmeisl, J. Joule 2019, 3, 834. doi: 10.1016/. joule.2018.12.015 doi: 10.1016/.joule.2018.12.015
15. [15]
  Wang, S.; Xin, H. Chem 2019, 5, 502. doi: 10.1016/j.chempr.2019.02.015 doi: 10.1016/j.chempr.2019.02.015
16. [16]
  Nellaiappan, S.; Katiyar, N. K.; Kumar, R.; Parui, A.; Malviya, K. D.; Pradeep, K. G.; Singh, A. K.; Sharma, S.; Tiwary, C. S.; Biswas, K. ACS Catal. 2020, 10, 3658. doi: 10.1021/acscatal.9b04302 doi: 10.1021/acscatal.9b04302
17. [17]
  Nørskov, J. K.; Bligaard, T.; Rossmeisl, J.; Christensen, C. H. Nat. Chem. 2009, 1, 37. doi: 10.1038/nchem.121 doi: 10.1038/nchem.121
18. [18]
  Mao, Y.; Chen, J.; Wang, H.; Hu, P. Chin. J. Catal. 2015, 36, 1596. doi: 10.1016/S1872-2067(15)60875-0 doi: 10.1016/S1872-2067(15)60875-0
19. [19]
  Sankar, M.; Dimitratos, N.; Miedziak, P. J.; Wells, P. P.; Kiely, C. J.; Hutchings, G. J. Chem. Soc. Rev. 2012, 41, 8099. doi: 10.1039/C2CS35296F doi: 10.1039/C2CS35296F
20. [20]
  Pickering, H. W.; Wagner, C. J. Electrochem. Soc. 1967, 114, 698. doi: 10.1149/1.2426709/meta doi: 10.1149/1.2426709/meta
21. [21]
  Toshima, N.; Yonezawa, T. New J. Chem. 1998, 22, 1179. doi: 10.1039/A805753B doi: 10.1039/A805753B
22. [22]
  Tao, F.; Grass, M. E.; Zhang, Y.; Butcher, D. R.; Renzas, J. R.; Liu, Z.; Chung, J. Y.; Mun, B. S.; Salmeron, M.; Somorjai, G. A. Science 2008, 322, 932. doi: 10.1126/science.1164170 doi: 10.1126/science.1164170
23. [23]
  Pendergast, A. D.; Glasscott, M. W.; Renault, C.; Dick, J. E. Electrochem. Commun. 2019, 98, 1. doi: 10.1016/j.elecom.2018.11.005 doi: 10.1016/j.elecom.2018.11.005
24. [24]
  Bu, L.; Zhang, N.; Guo, S.; Zhang, X.; Li, J.; Yao, J.; Wu, T.; Lu, G.; Ma, J. -Y.; Su, D.; et al. Science 2016, 354, 1410. doi: 10.1126/science.aah6133 doi: 10.1126/science.aah6133
25. [25]
  Li, Q.; Wu, L.; Wu, G.; Su, D.; Lv, H.; Zhang, S.; Zhu, W.; Casimir, A.; Zhu, H.; Mendoza-Garcia, A.; Sun, S. Nano Lett. 2015, 15, 2468. doi: 10.1021/acs.nanolett.5b00320 doi: 10.1021/acs.nanolett.5b00320
26. [26]
  Zhang, S.; Metin, Ö.; Su, D.; Sun, S. Angew. Chem. Int. Ed. 2013, 52, 3681. doi: 10.1002/anie.201300276 doi: 10.1002/anie.201300276
27. [27]
  Luo, M.; Zhao, Z.; Zhang, Y.; Sun, Y.; Xing, Y.; Lv, F.; Yang, Y.; Zhang, X.; Hwang, S.; Qin, Y.; et al. Nature 2019, 574, 81. doi: 10.1038/s41586-019-1603-7 doi: 10.1038/s41586-019-1603-7
28. [28]
  Hansgen, D. A.; Vlachos, D. G.; Chen, J. G. Nat. Chem. 2010, 2, 484. doi: 10.1038/nchem.626 doi: 10.1038/nchem.626
29. [29]
  Boisen, A.; Dahl, S.; Jacobsen, C. J. H. J. Catal. 2002, 208, 180. doi: 10.1006/jcat.2002.3571 doi: 10.1006/jcat.2002.3571
30. [30]
  Tomboc, G. M.; Kwon, T.; Joo, J.; Lee, K. J. Mater. Chem. A 2020, 8, 14844. doi: 10.1039/D0TA05176D doi: 10.1039/D0TA05176D
31. [31]
  Koo, W. -T.; Millstone, J. E.; Weiss, P. S.; Kim, I. -D. ACS Nano 2020, 14, 6407. doi: 10.1021/acsnano.0c03993 doi: 10.1021/acsnano.0c03993
32. [32]
  Xin, Y.; Li, S.; Qian, Y.; Zhu, W.; Yuan, H.; Jiang, P.; Guo, R.; Wang, L. ACS Catal. 2020, 11280. doi: 10.1021/acscatal.0c03617
33. [33]
  Li, H.; Zhu, H.; Zhang, S.; Zhang, N.; Du, M.; Chai, Y. Small Struct. 2020, doi: 10.1002/sstr.202000033
34. [34]
  Dai, S. ChemSusChem 2020, 13, 1915. doi: 10.1002/cssc.202000448 doi: 10.1002/cssc.202000448
35. [35]
  Xie, P.; Yao, Y.; Huang, Z.; Liu, Z.; Zhang, J.; Li, T.; Wang, G.; Shahbazian-Yassar, R.; Hu, L.; Wang, C. Nat. Commun. 2019, 10, 4011. doi: 10.1073/pnas.1903721117 doi: 10.1073/pnas.1903721117
36. [36]
  Yao, Y.; Liu, Z.; Xie, P.; Huang, Z.; Li, T.; Morris, D.; Finfrock, Z.; Zhou, J.; Jiao, M.; Gao, J.; et al. Sci. Adv. 2020, 6, eaaz0510. doi: 10.1126/sciadv.aaz0510 doi: 10.1126/sciadv.aaz0510
37. [37]
  Yao, Y.; Huang, Z.; Xie, P.; Lacey, S. D.; Jacob, R. J.; Xie, H.; Chen, F.; Nie, A.; Pu, T.; Rehwoldt, M.; et al. Science 2018, 359, 1489. doi: 10.1126/science.aan5412 doi: 10.1126/science.aan5412
38. [38]
  Chen, X.; Si, C.; Gao, Y.; Frenzel, J.; Sun, J.; Eggeler, G.; Zhang, Z. J. Power Sources 2015, 273, 324. doi: 10.1016/j.jpowsour.2014.09.076 doi: 10.1016/j.jpowsour.2014.09.076
39. [39]
  Li, J.; Stein, H. S.; Sliozberg, K.; Liu, J.; Liu, Y.; Sertic, G.; Scanley, E.; Ludwig, A.; Schroers, J.; Schuhmann, W.; et al. J. Mater. Chem. A 2016, 5, 67. doi: 10.1016/S1872-2067(15)60875-0 doi: 10.1016/S1872-2067(15)60875-0
40. [40]
  Li, S.; Tang, X.; Jia, H.; Li, H.; Xie, G.; Liu, X.; Lin, X.; Qiu, H. J. Catal. 2020, 383, 164. doi: 10.1016/j.jcat.2020.01.024 doi: 10.1016/j.jcat.2020.01.024
41. [41]
  Löffler, T.; Meyer, H.; Savan, A.; Wilde, P.; Garzón Manjón, A.; Chen, Y. -T.; Ventosa, E.; Scheu, C.; Ludwig, A.; Schuhmann, W. Adv. Energy Mater. 2018, 8, 1802269. doi: 10.1002/aenm.201802269 doi: 10.1002/aenm.201802269
42. [42]
  Löffler, T.; Savan, A.; Meyer, H.; Meischein, M.; Strotkötter, V.; Ludwig, A.; Schuhmann, W. Angew. Chem. Int. Ed. 2020, 59, 5844. doi: 10.1002/anie.201914666 doi: 10.1002/anie.201914666
43. [43]
  Qiu, H.; Fang, G.; Wen, Y.; Liu, P.; Xie, G.; Liu, X.; Sun, S. J. Mater. Chem. A 2019, 7, 6499. doi: 10.1039/C9TA00505F doi: 10.1039/C9TA00505F
44. [44]
  Jin, Z.; Lv, J.; Jia, H.; Liu, W.; Li, H.; Chen, Z.; Lin, X.; Xie, G.; Liu, X.; Sun, S.; Qiu, H. J. Small 2019, 15, 1904180. doi: 10.1002/smll.201904180 doi: 10.1002/smll.201904180
45. [45]
  Yao, Y.; Huang, Z.; Li, T.; Wang, H.; Liu, Y.; Stein, H. S.; Mao, Y.; Gao, J.; Jiao, M.; Dong, Q.; et al. Proc. Natl. Acad. Sci. 2020, 117, 6316. doi: 10.1073/pnas.1903721117 doi: 10.1073/pnas.1903721117
46. [46]
  Pedersen, J. K.; Batchelor, T. A. A.; Bagger, A.; Rossmeisl, J. ACS Catal. 2020, 10, 2169. doi: 10.1021/acscatal.9b04343 doi: 10.1021/acscatal.9b04343
47. [47]
  Glasscott, M. W.; Pendergast, A. D.; Goines, S.; Bishop, A. R.; Hoang, A. T.; Renault, C.; Dick, J. E. Nat. Commun. 2019, 10, 2650. doi: 10.1038/s41467-019-10303-z doi: 10.1038/s41467-019-10303-z
48. [48]
  Liu, M.; Zhang, Z.; Okejiri, F.; Yang, S.; Zhou, S.; Dai, S. Adv. Mater. Interfaces 2019, 6, 1900015. doi: 10.1002/admi.201900015 doi: 10.1002/admi.201900015
49. [49]
  Waag, F.; Li, Y.; Ziefuß, A. R.; Bertin, E.; Kamp, M.; Duppel, V.; Marzun, G.; Kienle, L.; Barcikowski, S.; Gökce, B. RSC Adv. 2019, 9, 18547. doi: 10.1039/C9RA03254A doi: 10.1039/C9RA03254A
50. [50]
  Cui, X.; Zhang, B.; Zeng, C.; Guo, S. MRS Commun. 2018, 8, 1230. doi: 10.1557/mrc.2018.111 doi: 10.1557/mrc.2018.111
51. [51]
  Dai, W.; Lu, T.; Pan, Y. J. Power Sources 2019, 430, 104. doi: 10.1016/j.jpowsour.2019.05.030 doi: 10.1016/j.jpowsour.2019.05.030
52. [52]
  Huang, K.; Zhang, B.; Wu, J.; Zhang, T.; Peng, D.; Cao, X.; Zhang, Z.; Li, Z.; Huang, Y. J. Mater. Chem. A 2020, 8, 11938. doi: 10.1039/D0TA02125C doi: 10.1039/D0TA02125C
53. [53]
  Qiu, H.; Fang, G.; Gao, J.; Wen, Y.; Lv, J.; Li, H.; Xie, G.; Liu, X.; Sun, S. ACS Mater. Lett. 2019, 1, 526. doi: 10.1021/acsmaterialslett.9b00414 doi: 10.1021/acsmaterialslett.9b00414
54. [54]
  Feng, J.; Chen, D.; Pikhitsa, P. V.; Jung, Y. -H.; Yang, J.; Choi, M. Matter 2020, 3, 1646. doi: 10.1016/j.matt.2020.07.027 doi: 10.1016/j.matt.2020.07.027
55. [55]
  Tsai, C. -F.; Yeh, K. -Y.; Wu, P. -W.; Hsieh, Y. -F.; Lin, P. J. Alloys Compd. 2009, 478, 868. doi: 10.1016/j.jallcom.2008.12.055 doi: 10.1016/j.jallcom.2008.12.055
56. [56]
  Yusenko, K. V.; Riva, S.; Carvalho, P. A.; Yusenko, M. V.; Arnaboldi, S.; Sukhikh, A. S.; Hanfland, M.; Gromilov, S. A. Scr. Mater. 2017, 138, 22. doi: 10.1016/j.scriptamat.2017.05.022 doi: 10.1016/j.scriptamat.2017.05.022
57. [57]
  Katiyar, N. K.; Nellaiappan, S.; Kumar, R.; Malviya, K. D.; Pradeep, K. G.; Singh, A. K.; Sharma, S.; Tiwary, C. S.; Biswas, K. Mater. Today Energy 2020, 16, 100393. doi: 10.1016/j.mtener.2020.100393 doi: 10.1016/j.mtener.2020.100393
58. [58]
  Yeh, J. W.; Chen, S. K.; Lin, S. J.; Gan, J. Y.; Chin, T. S.; Shun, T. T.; Tsau, C. H.; Chang, S. Y. Adv. Eng. Mater. 2004, 6, 299. doi: 10.1002/adem.200300567 doi: 10.1002/adem.200300567
59. [59]
  Cantor, B.; Chang, I. T. H.; Knight, P.; Vincent, A. J. B. Mater. Sci. Eng. A 2004, 375–377, 213. doi: 10.1016/j.msea.2003.10.257
60. [60]
  Yeh, J. -W. JOM 2013, 65, 1759. doi: 10.1007/s11837-013-0761-6 doi: 10.1007/s11837-013-0761-6
61. [61]
  Ruffa, A. R. Phys. Rev. B 1982, 25, 5895. doi: 10.1103/PhysRevB.25.5895 doi: 10.1103/PhysRevB.25.5895
62. [62]
  Zhang, W.; Liaw, P. K.; Zhang, Y. Sci. China Mater. 2018, 61, 2. doi: 10.1007/s40843-017-9195-8 doi: 10.1007/s40843-017-9195-8
63. [63]
  Gludovatz, B.; Hohenwarter, A.; Thurston, K. V. S.; Bei, H.; Wu, Z.; George, E. P.; Ritchie, R. O. Nat. Commun. 2016, 7, 10602. doi: 10.1038/ncomms10602 doi: 10.1038/ncomms10602
64. [64]
  Zhang, Z.; Sheng, H.; Wang, Z.; Gludovatz, B.; Zhang, Z.; George, E. P.; Yu, Q.; Mao, S. X.; Ritchie, R. O. Nat. Commun. 2017, 8, 14390. doi: 10.1038/ncomms14390 doi: 10.1038/ncomms14390
65. [65]
  Ding, J.; Yu, Q.; Asta, M.; Ritchie, R. O. Proc. Natl. Acad. Sci. 2018, 115, 8919. doi: 10.1073/pnas.1808660115 doi: 10.1073/pnas.1808660115
66. [66]
  Zhang, R.; Zhao, S.; Ding, J.; Chong, Y.; Jia, T.; Ophus, C.; Asta, M.; Ritchie, R. O.; Minor, A. M. Nature 2020, 581, 283. doi: 10.1038/s41586-020-2275-z doi: 10.1038/s41586-020-2275-z
67. [67]
  George, E. P.; Raabe, D.; Ritchie, R. O. Nat. Rev. Mater. 2019, 4, 515. doi: 10.1038/s41578-019-0121-4 doi: 10.1038/s41578-019-0121-4
68. [68]
  Ma, D.; Grabowski, B.; Körmann, F.; Neugebauer, J.; Raabe, D. Acta Mater. 2015, 100, 90. doi: 10.1016/j.actamat.2015.08.050 doi: 10.1016/j.actamat.2015.08.050
69. [69]
  Miracle, D. B.; Senkov, O. N. Acta Mater. 2017, 122, 448. doi: 10.1016/j.actamat.2016.08.081 doi: 10.1016/j.actamat.2016.08.081
70. [70]
  Zhang, Y.; Zuo, T. T.; Tang, Z.; Gao, M. C.; Dahmen, K. A.; Liaw, P. K.; Lu, Z. P. Proc. Natl. Acad. Sci. 2014, 61, 1. doi: 10.1016/j.pmatsci.2013.10.001 doi: 10.1016/j.pmatsci.2013.10.001
71. [71]
  Gibbs, J. W. Am. J. Sci. 1878, 16, 441. doi: 10.2475/ajs.s3-16.96.441 doi: 10.2475/ajs.s3-16.96.441
72. [72]
  Yeh, J. -W.; Chang, S. -Y.; Hong, Y. -D.; Chen, S. -K.; Lin, S. -J. Mater. Chem. Phys. 2007, 103, 41. doi: 10.1016/j.matchemphys.2007.01.003 doi: 10.1016/j.matchemphys.2007.01.003
73. [73]
  Guo, W.; Dmowski, W.; Noh, J.; Rack, P. D.; Liaw, P. K.; Egami, T. Metall. Mater. Trans. A-Phys. Metall. Mater. Sci. 2013, 44, 1994. doi: 10.1007/s11661-012-1474-0 doi: 10.1007/s11661-012-1474-0
74. [74]
  Tsai, K. Y.; Tsai, M. H.; Yeh, J. W. Acta Mater. 2013, 61, 4887. doi: 10.1016/j.actamat.2013.04.058 doi: 10.1016/j.actamat.2013.04.058
75. [75]
  Ranganathan, S. Curr. Sci. 2003, 85, 1404.
76. [76]
  Pickering, E. J.; Jones, N. G. Int. Mater. Rev. 2016, 61, 183. doi: 10.1080/09506608.2016.1180020 doi: 10.1080/09506608.2016.1180020
77. [77]
  Pickering, E. J.; Muñoz-Moreno, R.; Stone, H. J.; Jones, N. G. Scr. Mater. 2016, 113, 106. doi: 10.1016/j.scriptamat.2015.10.025 doi: 10.1016/j.scriptamat.2015.10.025
78. [78]
  Laplanche, G.; Berglund, S.; Reinhart, C.; Kostka, A.; Fox, F.; George, E. P. Acta Mater. 2018, 161, 338. doi: 10.1016/j.actamat.2018.09.040 doi: 10.1016/j.actamat.2018.09.040
79. [79]
  Schuh, B.; Mendez-Martin, F.; Völker, B.; George, E. P.; Clemens, H.; Pippan, R.; Hohenwarter, A. Acta Mater. 2015, 96, 258. doi: 10.1016/j.actamat.2015.06.025 doi: 10.1016/j.actamat.2015.06.025
80. [80]
  Otto, F.; Dlouhý, A.; Pradeep, K. G.; Kuběnová, M.; Raabe, D.; Eggeler, G.; George, E. P. Acta Mater. 2016, 112, 40. doi: 10.1016/j.actamat.2016.04.005 doi: 10.1016/j.actamat.2016.04.005
81. [81]
  Sharma, G.; Kumar, D.; Kumar, A.; Al-Muhtaseb, A. a. H.; Pathania, D.; Naushad, M.; Mola, G. T. Mater. Sci. Eng. C 2017, 71, 1216. doi: 10.1016/j.msec.2016.11.002 doi: 10.1016/j.msec.2016.11.002
82. [82]
  Yang, Y.; Lin, Z.; Gao, S.; Su, J.; Lun, Z.; Xia, G.; Chen, J.; Zhang, R.; Chen, Q. ACS Catal. 2017, 7, 469. doi: 10.1021/acscatal.6b02573 doi: 10.1021/acscatal.6b02573
83. [83]
  Gao, S.; Hao, S.; Huang, Z.; Yuan, Y.; Han, S.; Lei, L.; Zhang, X.; Shahbazian-Yassar, R.; Lu, J. Nat. Commun. 2020, 11, 2016. doi: 10.1038/s41467-020-15934-1 doi: 10.1038/s41467-020-15934-1
84. [84]
  Wu, D.; Kusada, K.; Yamamoto, T.; Toriyama, T.; Matsumura, S.; Kawaguchi, S.; Kubota, Y.; Kitagawa, H. J. Am. Chem. Soc. 2020, 142, 13833. doi: 10.1021/jacs.0c04807 doi: 10.1021/jacs.0c04807
85. [85]
  Glasscott, M. W.; Pendergast, A. D.; Dick, J. E. ACS Appl. Nano Mater. 2018, 1, 5702. doi: 10.1021/acsanm.8b01308 doi: 10.1021/acsanm.8b01308
86. [86]
  Glasscott, M. W.; Dick, J. E. ACS Nano 2019, 13, 4572. doi: 10.1021/acsnano.9b00546 doi: 10.1021/acsnano.9b00546
87. [87]
  Glasscott, M. W.; Dick, J. E. Anal. Chem. 2018, 90, 7804. doi: 10.1021/acs.analchem.8b02219 doi: 10.1021/acs.analchem.8b02219
88. [88]
  LaMer, V. K.; Dinegar, R. H. J. Am. Chem. Soc. 1950, 72, 4847. doi: 10.1021/ja01167a001 doi: 10.1021/ja01167a001
89. [89]
  Pound, G. M.; Mer, V. K. L. J. Am. Chem. Soc. 1952, 74, 2323. doi: 10.1021/ja01129a044 doi: 10.1021/ja01129a044
90. [90]
  Jia, Z.; Yang, T.; Sun, L.; Zhao, Y.; Li, W.; Luan, J.; Lyu, F.; Zhang, L. C.; Kruzic, J. J.; Kai, J. J.; et al. Adv. Mater. 2020, 32, 2000385. doi: 10.1002/adma.202000385 doi: 10.1002/adma.202000385
91. [91]
  Chen, P.; Liu, X.; Hedrick, J. L.; Xie, Z.; Wang, S.; Lin, Q. -Y.; Hersam, M. C.; Dravid, V. P.; Mirkin, C. A. Science 2016, 352, 1565. doi: 10.1126/science.aaf8402 doi: 10.1126/science.aaf8402
92. [92]
  Chen, P.; Liu, M.; Du, J. S.; Meckes, B.; Wang, S.; Lin, H.; Dravid, V. P.; Wolverton, C.; Mirkin, C. A. Science 2019, 363, 959. doi: 10.1126/science.aav4302 doi: 10.1126/science.aav4302
93. [93]
  Chen, P.; Du, J. S.; Meckes, B.; Huang, L.; Xie, Z.; Hedrick, J. L.; Dravid, V. P.; Mirkin, C. A. J. Am. Chem. Soc. 2017, 139, 9876. doi: 10.1021/jacs.7b03163 doi: 10.1021/jacs.7b03163
94. [94]
  Xu, X.; Du, Y.; Wang, C.; Guo, Y.; Zou, J.; Zhou, K.; Zeng, Z.; Liu, Y.; Li, L. J. Alloys Compd. 2020, 822, 153642. doi: 10.1016/j.jallcom.2020.153642 doi: 10.1016/j.jallcom.2020.153642
95. [95]
  Calvo-Dahlborg, M.; Brown, S. G. R. J. Alloys Compd. 2017, 724, 353. doi: 10.1016/j.jallcom.2017.07.074 doi: 10.1016/j.jallcom.2017.07.074
96. [96]
  Otto, F.; Yang, Y.; Bei, H.; George, E. P. Acta Mater. 2013, 61, 2628. doi: 10.1016/j.actamat.2013.01.042 doi: 10.1016/j.actamat.2013.01.042
97. [97]
  Masa, J.; Schuhmann, W. J. Solid State Electrochem. 2020, 24, 2181. doi: 10.1007/s10008-020-04757-1 doi: 10.1007/s10008-020-04757-1
98. [98]
  Medford, A. J.; Vojvodic, A.; Hummelshøj, J. S.; Voss, J.; Abild-Pedersen, F.; Studt, F.; Bligaard, T.; Nilsson, A.; Nørskov, J. K. J. Catal. 2015, 328, 36. doi: 10.1016/j.jcat.2014.12.033 doi: 10.1016/j.jcat.2014.12.033
99. [99]
  Torelli, D. A.; Francis, S. A.; Crompton, J. C.; Javier, A.; Thompson, J. R.; Brunschwig, B. S.; Soriaga, M. P.; Lewis, N. S. ACS Catal. 2016, 6, 2100. doi: 10.1021/acscatal.5b02888 doi: 10.1021/acscatal.5b02888
100. [100]
  Wang, S.; Jiang, S. P. Natl. Sci. Rev. 2017, 4, 163. doi: 10.1093/nsr/nww099 doi: 10.1093/nsr/nww099
101. [101]
  Gong, K.; Du, F.; Xia, Z.; Durstock, M.; Dai, L. Science 2009, 323, 760. doi: 10.1126/science.1168049 doi: 10.1126/science.1168049
102. [102]
  Wang, T.; Xie, H.; Chen, M.; D'Aloia, A.; Cho, J.; Wu, G.; Li, Q. Nano Energy 2017, 42, 69. doi: 10.1016/j.nanoen.2017.10.045 doi: 10.1016/j.nanoen.2017.10.045
103. [103]
  Zhao, T.; Hu, Y.; Gong, M.; Lin, R.; Deng, S.; Lu, Y.; Liu, X.; Chen, Y.; Shen, T.; Hu, Y.; et al. Nano Energy 2020, 74, 104877. doi: 10.1016/j.nanoen.2020.104877 doi: 10.1016/j.nanoen.2020.104877
104. [104]
  Qiu, H. J.; Shen, X.; Wang, J. Q.; Hirata, A.; Fujita, T.; Wang, Y.; Chen, M. W. ACS Catal. 2015, 5, 3779. doi: 10.1021/acscatal.5b00073 doi: 10.1021/acscatal.5b00073
105. [105]
  Jia, Q.; Zhao, Z.; Cao, L.; Li, J.; Ghoshal, S.; Davies, V.; Stavitski, E.; Attenkofer, K.; Liu, Z.; Li, M.; et al. Nano Lett. 2018, 18, 798. doi: 10.1021/acs.nanolett.7b04007 doi: 10.1021/acs.nanolett.7b04007
106. [106]
  Shi, Y.; Yang, B.; Liaw, P. Metals 2017, 2, 107. doi: 10.3390/met7020043 doi: 10.3390/met7020043
107. [107]
  Alaneme, K. K.; Bodunrin, M. O.; Oke, S. R. J. Mater. Res. Technol. 2016, 5, 384. doi: 10.1016/j.jmrt.2016.03.004 doi: 10.1016/j.jmrt.2016.03.004
108. [108]
  Chou, Y. L.; Yeh, J. W.; Shih, H. C. Corros. Sci. 2010, 52, 2571. doi: 10.1016/j.corsci.2010.04.004 doi: 10.1016/j.corsci.2010.04.004
109. [109]
  Shi, Y.; Yang, B.; Xie, X.; Brechtl, J.; Dahmen, K. A.; Liaw, P. K. Corros. Sci. 2017, 119, 33. doi: 10.1016/j.corsci.2017.02.019 doi: 10.1016/j.corsci.2017.02.019
110. [110]
  McNicol, B. D.; Rand, D. A. J.; Williams, K. R. J. Power Sources 1999, 83, 15. doi: 10.1016/S0378-7753(99)00244-X doi: 10.1016/S0378-7753(99)00244-X
111. [111]
  Kamarudin, S. K.; Achmad, F.; Daud, W. R. W. Int. J. Hydrog. Energy 2009, 34, 6902. doi: 10.1016/j.ijhydene.2009.06.013 doi: 10.1016/j.ijhydene.2009.06.013
112. [112]
  Tiwari, J. N.; Tiwari, R. N.; Singh, G.; Kim, K. S. Nano Energy 2013, 2, 553. doi: 10.1016/j.nanoen.2013.06.009 doi: 10.1016/j.nanoen.2013.06.009
113. [113]
  Zhuang, L. Carbon Energy 2018, 34, 115. doi: 10.3866/pku.Whxb201707102 doi: 10.3866/pku.Whxb201707102
114. [114]
  Zhou, Y.; Han, N.; Li, Y. Acta Phys. -Chim. Sin. 2020, 36, 2001041. doi: 10.3866/PKU.WHXB202001041
115. [115]
  Wang, S.; Kou, T.; Baker, S. E.; Duoss, E. B.; Li, Y. Mater. Today Nano 2020, 12, 100096. doi: 10.1016/j.mtnano.2020.100096 doi: 10.1016/j.mtnano.2020.100096
116. [116]
  Kang, Y.; Yang, P.; Markovic, N. M.; Stamenkovic, V. R. Nano Today 2016, 11, 587. doi: 10.1016/j.nantod.2016.08.008 doi: 10.1016/j.nantod.2016.08.008
117. [117]
  Chen, Y.; Lai, Z.; Zhang, X.; Fan, Z.; He, Q.; Tan, C.; Zhang, H. Nat. Rev. Chem. 2020, 4, 243. doi: 10.1038/s41570-020-0173-4 doi: 10.1038/s41570-020-0173-4
118. [118]
  Fan, Z.; Zhang, H. Chem. Soc. Rev. 2016, 45, 63. doi: 10.1039/C5CS00467E doi: 10.1039/C5CS00467E
119. [119]
  Xia, Y.; Xiong, Y.; Lim, B.; Skrabalak, S. E. Angew. Chem. Int. Ed. 2009, 48, 60. doi: 10.1002/anie.200802248 doi: 10.1002/anie.200802248
120. [120]
  Tan, C.; Chen, J.; Wu, X. -J.; Zhang, H. Nat. Rev. Mater. 2018, 3, 17089. doi: 10.1038/natrevmats.2017.89 doi: 10.1038/natrevmats.2017.89
121. [121]
  Aslam, U.; Rao, V. G.; Chavez, S.; Linic, S. Nat. Catal. 2018, 1, 656. doi: 10.1038/s41929-018-0138-x doi: 10.1038/s41929-018-0138-x
122. [122]
  Luo, M.; Guo, S. Nat. Rev. Mater. 2017, 2, 17059. doi: 10.1038/natrevmats.2017.59 doi: 10.1038/natrevmats.2017.59
123. [123]
  Hwang, S.; Chen, X.; Zhou, G.; Su, D. Adv. Energy Mater. 2020, 10, 1902105. doi: 10.1002/aenm.201902105 doi: 10.1002/aenm.201902105
124. [124]
  Su, D. Green Energy Environ. 2017, 2, 70. doi: 10.1016/j.gee.2017.02.001 doi: 10.1016/j.gee.2017.02.001
125. [125]
  Gilroy, K. D.; Ruditskiy, A.; Peng, H. -C.; Qin, D.; Xia, Y. Chem. Rev. 2016, 116, 10414. doi: 10.1021/acs.chemrev.6b00211 doi: 10.1021/acs.chemrev.6b00211
126. [126]
  Ge, M.; Su, F.; Zhao, Z.; Su, D. Mater. Today Nano 2020, 11, 100087. doi: 10.1016/j.mtnano.2020.100087 doi: 10.1016/j.mtnano.2020.100087
127. [127]
  Jia, Z.; Yang, T.; Sun, L.; Zhao, Y.; Li, W.; Luan, J.; Lyu, F.; Zhang, L. -C.; Kruzic, J. J.; Kai, J. -J.; et al. Adv. Mater. 2020, 32, 2000385. doi: 10.1002/adma.202000385 doi: 10.1002/adma.202000385
128. [128]
  Anandkumar, M.; Bhattacharya, S.; Deshpande, A. S. RSC Adv. 2019, 9, 26825. doi: 10.1039/C9RA04636D doi: 10.1039/C9RA04636D
129. [129]
  Chen, H.; Lin, W.; Zhang, Z.; Jie, K.; Mullins, D. R.; Sang, X.; Yang, S. -Z.; Jafta, C. J.; Bridges, C. A.; Hu, X.; et al. ACS Mater. Lett. 2019, 1, 83. doi: 10.1021/acsmaterialslett.9b00064 doi: 10.1021/acsmaterialslett.9b00064
130. [130]
  Chen, H.; Jie, K.; Jafta, C. J.; Yang, Z.; Yao, S.; Liu, M.; Zhang, Z.; Liu, J.; Chi, M.; Fu, J.; et al. Appl. Catal. B 2020, 276, 119155. doi: 10.1016/j.apcatb.2020.119155 doi: 10.1016/j.apcatb.2020.119155
131. [131]
  Deng, C.; Wu, P.; Zhu, L.; He, J.; Tao, D.; Lu, L.; He, M.; Hua, M.; Li, H.; Zhu, W. Appl. Mater. Today 2020, 20, 100680. doi: 10.1016/j.apmt.2020.100680 doi: 10.1016/j.apmt.2020.100680
132. [132]
  Okejiri, F.; Zhang, Z.; Liu, J.; Liu, M.; Yang, S.; Dai, S. ChemSusChem 2020, 13, 111. doi: 10.1002/cssc.201902705 doi: 10.1002/cssc.201902705
133. [133]
  Oses, C.; Toher, C.; Curtarolo, S. Nat. Rev. Mater. 2020, 5, 295. doi: 10.1038/s41578-019-0170-8 doi: 10.1038/s41578-019-0170-8
134. [134]
  Wang, T.; Chen, H.; Yang, Z.; Liang, J.; Dai, S. J. Am. Chem. Soc. 2020, 142, 4550. doi: 10.1021/jacs.9b12377 doi: 10.1021/jacs.9b12377
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