Citation: Tianjie Wang, Yaowei Wang, Yuhui Chen, Jianpeng Liu, Huibing Shi, Limin Guo, Zhiwei Zhao, Chuntai Liu, Zhangquan Peng. Toward Practical Lithium-Air Batteries by Avoiding Negative Effects of CO₂[J]. Acta Physico-Chimica Sinica, ;2022, 38(8): 200907. doi: 10.3866/PKU.WHXB202009071 shu

Toward Practical Lithium-Air Batteries by Avoiding Negative Effects of CO₂

Tianjie Wang ^{1, †} ,
Yaowei Wang ^{1, 2, †} ,
Yuhui Chen ^1,, ,
Jianpeng Liu ² ,
Huibing Shi ² ,
Limin Guo ^3,, ,
Zhiwei Zhao ⁴ ,
Chuntai Liu ⁵ ,
Zhangquan Peng ^{4, 6,,}

1.
State Key Laboratory of Materials-Oriented Chemical Engineering, School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu Province, China
2.
Shandong Chambroad Petrochemicals Co., Ltd., Boxing 256500, Shandong Province, China
3.
College of Environment & Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, China
4.
Laboratory of Spectro-electrochemistry and Li-ion Batteries, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China
5.
College of Materials Science and Engineering, the Key Laboratory of Advanced Materials Processing & Mold of Ministry of Education, Zhengzhou University, Zhengzhou 450002, Henan Province, China
6.
School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, Guangdong Province, China

Author Bio:

Yuhui Chen obtained his Bachelor degree in Fudan University in 2009, and received his Ph.D. degree from University of St Andrews (United Kingdom) in 2014. Later, he worked with Prof. Peter Bruce at the University of Oxford (United Kingdom) on the topic of metal-air batteries. Since 2017, he is the professor at Nanjing Tech University. His research interests include CO₂ electrochemical catalysis and novel batteries such as metal-air batteries

Limin Guo obtained her MSc and Ph.D. degrees from Changchun Institute of Applied Chemistry (CIAC) in 2004 and 2016, respectively. In 2018 she worked as an assistant professor in Jilin Engineering Normal University and promoted to full professor in 2020. Currently she is a professor in the College of Environment & Chemical Engineering of Dalian Jiaotong University. Her research interests include non-aqueous lithium-ion and lithium-air batteries investigated by the in situ electrochemistry techniques

Zhangquan Peng obtained his Bachelor degree in Wuhan University in 1997, and received his MSc and Ph.D. degrees from Changchun Institute of Applied Chemistry (CIAC) in 2000 and 2003, respectively. He continued by working as a postdoctoral researcher at University of Dusseldorf (Germany), University of Aarhus (Denmark) and University of St Andrews (United Kingdom) from 2004 to 2012. From 2012 to 2020, he worked as a principle investigator on the topic of interfacial electrochemistry of various energy storage devices in CIAC. Currently, he is the supervisor of the Laboratory of Advanced Spectro-electrochemistry and Li-ion Batteries, Dalian Institute of Chemical Physics (DICP). His research interests include in situ electrochemistry coupled with theoretical calculation focusing on Li-ion and Li-O₂ batteries
Corresponding author: Yuhui Chen, cheny@njtech.edu.cn Limin Guo, lmguo@ciac.ac.cn Zhangquan Peng, zqpeng@dicp.ac.cn

^†

Received Date: 21 September 2020
Revised Date: 15 October 2020
Accepted Date: 16 October 2020
Available Online: 22 October 2020
Fund Project: the National Key R&D Program of China 2016YFB0100100the National Key R&D Program of China 2018YFB0104400the National Natural Science Foundation of China 21972055the National Natural Science Foundation of China 21825202the National Natural Science Foundation of China 21575135the National Natural Science Foundation of China 21733012the National Natural Science Foundation of China 51773092the National Natural Science Foundation of China 21975124the National Natural Science Foundation of China 21972133the Newton Advanced Fellowships of Royal Society of England NAF/R2/180603

The gradual popularization of new energy technologies has led to rapid development in the field of electric transportation. At present, the demand for high-power density batteries is increasing and next-generation higher-energy battery chemistries aimed at replacing current lithium-ion batteries are emerging. The lithium-air batteries (LABs) are thought to be the ultimate energy conversion and storage system, because of their highest theoretical specific energy compared with other known battery systems. Current LABs are operated with pure O₂ provided by weighty O₂ cylinders instead of the breathing air, and this configuration would greatly undermine LAB's energy density and practicality. However, when the breathing air is used as O₂ feed for LABs, CO₂, as an inevitable impurity therein, usually leads to severe parasitic reactions and can easily deteriorate the performance of LABs. Specifically, Li₂O₂ will react with CO₂ to form Li₂CO₃ on the cathode surface. Compared with the desired discharge product Li₂O₂, the Li₂CO₃ is an insulating solid, which will accumulate and finally passivate the electrode surface leading to the "sudden death" phenomenon of LABs. Moreover, Li₂CO₃ is hard to decompose and a high overpotential is required to charge LABs containing Li₂CO₃ compounds, which not only degrades energy efficiency but also decomposes other battery components (e.g., cathode materials and electrolytes). In recent years, researchers have proposed many strategies to alleviate the negative effects brought about by Li₂CO₃, such as catalyst engineering, electrolyte design, and so on, in which O₂ selective permeable membranes are worth noting. This review summarizes the recent progresses on the understanding of the CO₂-related chemistry and electrochemistry in LABs and describes the various strategies to mitigate and even avoid the negative effects of CO₂. The perspective of CO₂ separation technology using selective permeable membranes/filters in the context of LABs is also discussed.
- Lithium-air battery,
- Reaction mechanism,
- CO₂ separation
1. [1]
  Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
2. [2]
  Yang, S.; He, P.; Zhou, H. Energy Storage Mater. 2018, 13, 29. doi: 10.1016/j.ensm.2017.12.020 doi: 10.1016/j.ensm.2017.12.020
3. [3]
  Imanishi, N.; Yamamoto, O. Mater. Today 2014, 17, 24. doi: 10.1016/j.mattod.2013.12.004 doi: 10.1016/j.mattod.2013.12.004
4. [4]
  Lu, J.; Amine, K. Energies 2013, 6, 6016. doi: 10.3390/en6116016 doi: 10.3390/en6116016
5. [5]
  Yang, Z.; Zhang, W.; Shen, Y.; Yuan, L. X.; Huang, Y. H. Acta Phys. -Chim. Sin. 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
6. [6]
  Etacheri, V.; Marom, R.; Elazari, R.; Salitra, G.; Aurbach, D. Energy Environ. Sci. 2011, 4, 3243. doi: 10.1039/c1ee01598b doi: 10.1039/c1ee01598b
7. [7]
  Li, H.; Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593. doi: 10.1002/adma.200901710 doi: 10.1002/adma.200901710
8. [8]
  Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nat. Mater. 2012, 11, 19. doi: 10.1038/nmat3191 doi: 10.1038/nmat3191
9. [9]
  Xu, J.; Liu, Q.; Yu, Y.; Wang, J.; Yan, J.; Zhang, X. Adv. Mater. 2017, 29, 1606552. doi: 10.1002/adma.201606552 doi: 10.1002/adma.201606552
10. [10]
  Jian, Z.; Liu, P.; Li, F.; He, P.; Guo, X.; Chen, M.; Zhou, H. Angew. Chem. Int. Ed. 2014, 53, 442. doi: 10.1002/anie.201307976 doi: 10.1002/anie.201307976
11. [11]
  Li, C.; Guo, Z.; Yang, B.; Liu, Y.; Wang, Y.; Xia, Y. Angew. Chem. Int. Ed. 2017, 56, 9126. doi: 10.1002/anie.201705017 doi: 10.1002/anie.201705017
12. [12]
  Freunberger, S. A.; Chen, Y.; Peng, Z.; Griffin, J. M.; Hardwick, L. J.; Bardé, F.; Novák, P.; Bruce, P. G. J. Am. Chem. Soc. 2011, 133, 8040. doi: 10.1021/ja2021747 doi: 10.1021/ja2021747
13. [13]
  McCloskey, B. D.; Bethune, D. S.; Shelby, R. M.; Girishkumar, G.; Luntz, A. C. J. Phys. Chem. Lett. 2011, 2, 1161. doi: 10.1021/jz200352v doi: 10.1021/jz200352v
14. [14]
  Peng, Z.; Freunberger, S. A.; Hardwick, L. J.; Chen, Y.; Giordani, V.; Bardé, F.; Novák, P.; Graham, D.; Tarascon, J. M.; Bruce, P. G. Angew. Chem. Int. Ed. 2011, 50, 6351. doi: 10.1002/anie.201100879 doi: 10.1002/anie.201100879
15. [15]
  Débart, A.; Bao, J.; Armstrong, G.; Bruce, P. G. J. Power Sources 2007, 174, 1177. doi: 10.1016/j.jpowsour.2007.06.180 doi: 10.1016/j.jpowsour.2007.06.180
16. [16]
  Giordani, V.; Freunberger, S. A.; Bruce, P. G.; Tarascon, J. M.; Larcher, D. Electrochem. Solid State Lett. 2010, 13, A180. doi: 10.1149/1.3494045 doi: 10.1149/1.3494045
17. [17]
  Lu, Y.; Gasteiger, H. A.; Parent, M. C.; Chiloyan, V.; Shao-Horn, Y. Electrochem. Solid State Lett. 2010, 13, A69. doi: 10.1149/1.3363047 doi: 10.1149/1.3363047
18. [18]
  Aurbach, D. J. Power Sources 2000, 89, 206. doi: 10.1016/S0378-7753(00)00431-6 doi: 10.1016/S0378-7753(00)00431-6
19. [19]
  Cohen, Y. S.; Cohen, Y.; Aurbach, D. J. Phys. Chem. B 2000, 104, 12282. doi: 10.1021/jp002526b doi: 10.1021/jp002526b
20. [20]
  Choi, N. S.; Lee, Y. M.; Cho, K. Y.; Ko, D. H.; Park, J. K. Electrochem. Commun. 2004, 6, 1238. doi: 10.1016/j.elecom.2004.09.023 doi: 10.1016/j.elecom.2004.09.023
21. [21]
  Read, J. J. Electrochem. Soc. 2006, 153, A96. doi: 10.1149/1.2131827 doi: 10.1149/1.2131827
22. [22]
  Qiao, Y.; Deng, H.; He, P.; Zhou, H. Joule 2020, 4, 1445. doi: 10.1016/j.joule.2020.05.012 doi: 10.1016/j.joule.2020.05.012
23. [23]
  Guo, Z.; Dong, X.; Yuan, S.; Wang, Y.; Xia, Y. J. Power Sources 2014, 264, 1. doi: 10.1016/j.jpowsour.2014.04.079 doi: 10.1016/j.jpowsour.2014.04.079
24. [24]
  Meini, S.; Piana, M.; Tsiouvaras, N.; Garsuch, A.; Gasteiger, H. A. Electrochem. Solid State Lett. 2012, 15, A45. doi: 10.1149/2.005204esl doi: 10.1149/2.005204esl
25. [25]
  Li, F.; Wu, S.; Li, D.; Zhang, T.; He, P.; Yamada, A.; Zhou, H. Nat. Commun. 2015, 6, 7. doi: 10.1038/ncomms8843 doi: 10.1038/ncomms8843
26. [26]
  Shui, J.; Okasinski, J. S.; Kenesei, P.; Dobbs, H. A.; Zhao, D.; Almer, J. D.; Liu, D. Nat. Commun. 2013, 4, 2255. doi: 10.1038/ncomms3255 doi: 10.1038/ncomms3255
27. [27]
  Shen, X.; Liu, H.; Cheng, X.; Yan, C.; Huang, J. Energy Storage Mater. 2018, 12, 161. doi: 10.1016/j.ensm.2017.12.002 doi: 10.1016/j.ensm.2017.12.002
28. [28]
  Amici, J.; Francia, C.; Zeng, J.; Bodoardo, S.; Penazzi, N. J. Appl. Electrochem. 2016, 46, 617. doi: 10.1007/s10800-016-0951-3 doi: 10.1007/s10800-016-0951-3
29. [29]
  Xie, M.; Huang, Z.; Lin, X.; Li, Y.; Huang, Z.; Yuan, L.; Shen, Y.; Huang, Y. Energy Storage Mater. 2019, 20, 307. doi: 10.1016/j.ensm.2018.11.023 doi: 10.1016/j.ensm.2018.11.023
30. [30]
  Xu, S.; Lau, S.; Archer, L. A. Inorg. Chem. Front. 2015, 2, 1070. doi: 10.1039/c5qi00169b doi: 10.1039/c5qi00169b
31. [31]
  Wadhawan, J. D.; Welford, P. J.; Maisonhaute, E.; Climent, V.; Lawrence, N. S.; Compton, R. G.; McPeak, H. B.; Hahn, C. E. W. J. Phys. Chem. B 2001, 105, 10659. doi: 10.1021/jp012160i doi: 10.1021/jp012160i
32. [32]
  Albertus, P.; Girishkumar, G.; McCloskey, B.; Sánchez-Carrera, R. S.; Kozinsky, B.; Christensen, J.; Luntz, A. C. J. Electrochem. Soc. 2011, 158, A343. doi: 10.1149/1.3527055 doi: 10.1149/1.3527055
33. [33]
  Yang, S.; He, P.; Zhou, H. Energy Environ. Sci. 2016, 9, 1650. doi: 10.1039/c6ee00004e doi: 10.1039/c6ee00004e
34. [34]
  Farooqui, U. R.; Ahmad, A. L.; Hamid, N. A. Renew. Sust. Energ. Rev. 2017, 77, 1114. doi: 10.1016/j.rser.2016.11.220 doi: 10.1016/j.rser.2016.11.220
35. [35]
  Dias, A. M. A.; Freire, M.; Coutinho, J. A. P.; Marrucho, I. M. Fluid Phase Equilibr. 2004, 222, 325. doi: 10.1016/j.fluid.2004.06.037 doi: 10.1016/j.fluid.2004.06.037
36. [36]
  Liu, L.; Guo, H.; Fu, L.; Chou, S.; Thiele, S.; Wu, Y.; Wang, J. Small 2019, 15, 1903854. doi: 10.1002/smll.201903854 doi: 10.1002/smll.201903854
37. [37]
  Jiang, X.; Li, S. W.; He, S. S.; Bai, Y. P.; Shao, L. J. Mater. Chem. A. 2018, 6, 15064. doi: 10.1039/c8ta03872d doi: 10.1039/c8ta03872d
38. [38]
  Guo, X. Y.; Qiao, Z. H.; Liu, D. H.; Zhong, C. L. J. Mater. Chem. A. 2019, 7, 24738. doi: 10.1039/c9ta09012f doi: 10.1039/c9ta09012f
39. [39]
  Gong, J. H.; Wang, C. H.; Bian, Z. J.; Yang, L.; Hu, J.; Liu, H. L. Acta Phys. -Chim. Sin. 2015, 31, 1963. doi: 10.3866/PKU.WHXB201508282
40. [40]
  Ottakam Thotiyl, M. M.; Freunberger, S. A.; Peng, Z.; Bruce, P. G. J. Am. Chem. Soc. 2013, 135, 494. doi: 10.1021/ja310258x doi: 10.1021/ja310258x
41. [41]
  Zhang, T.; Zhou, H. Nat. Commun. 2013, 4, 1817. doi: 10.1038/ncomms2855 doi: 10.1038/ncomms2855
42. [42]
  Dean, J. A. Mater. Manuf. Process. 1990, 5, 687. doi: 10.1080/10426919008953291 doi: 10.1080/10426919008953291
43. [43]
  Takechi, K.; Shiga, T.; Asaoka, T. Chem. Comm. 2011, 47, 3463. doi: 10.1039/c0cc05176d doi: 10.1039/c0cc05176d
44. [44]
  Gowda, S. R.; Brunet, A.; Wallraff, G. M.; McCloskey, B. D. J. Phys. Chem. Lett. 2013, 4, 276. doi: 10.1021/jz301902h doi: 10.1021/jz301902h
45. [45]
  Mekonnen, Y. S.; Knudsen, K. B.; Mýrdal, J. S. G.; Younesi, R.; Højberg, J.; Hjelm, J.; Norby, P.; Vegge, T. J. Chem. Phys. 2014, 140, 121101. doi: 10.1063/1.4869212 doi: 10.1063/1.4869212
46. [46]
  Lim, H. K.; Lim, H. D.; Park, K. Y.; Seo, D. H.; Gwon, H.; Hong, J.; Goddard Ⅲ, W. A.; Kim, H.; Kang, K. J. Am. Chem. Soc. 2013, 135, 9733. doi: 10.1021/ja4016765 doi: 10.1021/ja4016765
47. [47]
  Yin, W.; Grimaud, A.; Lepoivre, F.; Yang, C.; Tarascon, J. M. J. Phys. Chem. Lett. 2017, 8, 214. doi: 10.1021/acs.jpclett.6b02610 doi: 10.1021/acs.jpclett.6b02610
48. [48]
  Zhao, Z.; Su, Y.; Peng, Z. J. Phys. Chem. Lett. 2019, 10, 322. doi: 10.1021/acs.jpclett.8b03272 doi: 10.1021/acs.jpclett.8b03272
49. [49]
  Albertus, P.; Viswanathan, V.; Christensen, J. F.; Kozinsky, B.; Sanchez-carrera, R.; Iohmann, T. High Specific-Energy Li/O₂-CO₂ Battery. US Patent, US12/907205, 2012.
50. [50]
  Yang, S.; Qiao, Y.; He, P.; Liu, Y.; Cheng, Z.; Zhu, J.; Zhou, H. Energy Environ. Sci. 2017, 10, 972. doi: 10.1039/c6ee03770d doi: 10.1039/c6ee03770d
51. [51]
  Qiao, Y.; Yi, J.; Wu, S.; Liu, Y.; Yang, S.; He, P.; Zhou, H. Joule 2017, 1, 359. doi: 10.1016/j.joule.2017.07.001 doi: 10.1016/j.joule.2017.07.001
52. [52]
  Mahne, N.; Renfrew, S. E.; McCloskey, B. D.; Freunberger, S. A. Angew. Chem. Int. Ed. 2018, 57, 5529. doi: 10.1002/anie.201802277 doi: 10.1002/anie.201802277
53. [53]
  Baek, K.; Jeon, W. C.; Woo, S.; Kim, J. C.; Lee, J. G.; An, K.; Kwak, S. K.; Kang, S. J. Nat. Commun. 2020, 11, 456. doi: 10.1038/s41467-019-14121-1 doi: 10.1038/s41467-019-14121-1
54. [54]
  Li, C.; Guo, Z.; Yang, B.; Liu, Y.; Wang, Y.; Xia, Y. Angew. Chem. Int. Ed. 2017, 56, 9126. doi: 10.1002/anie.201705017 doi: 10.1002/anie.201705017
55. [55]
  Qiao, Y.; Yi, J.; Guo, S.; Sun, Y.; Wu, S.; Liu, X.; Yang, S.; He, P.; Zhou, H. Energy Environ. Sci. 2018, 11, 1211. doi: 10.1039/c7ee03341a doi: 10.1039/c7ee03341a
56. [56]
  Wang, X.; Wang, C.; Xie, Z.; Zhang, X.; Chen, Y.; Wu, D.; Zhou, Z. Chem. Electro. Chem. 2017, 4, 2145. doi: 10.1002/celc.201700539 doi: 10.1002/celc.201700539
57. [57]
  Liu, Z.; Zhang, Y.; Jia, C.; Wan, H.; Peng, Z.; Bi, Y.; Liu, Y.; Peng, Z.; Wang, Q.; Li, H.; Wang, D.; Zhang, J. Nano Energy 2017, 36, 390. doi: 10.1016/j.nanoen.2017.04.049 doi: 10.1016/j.nanoen.2017.04.049
58. [58]
  Hong, M.; Choi, H. C.; Byon, H. R. Chem. Mater. 2015, 27, 2234. doi: 10.1021/acs.chemmater.5b00488 doi: 10.1021/acs.chemmater.5b00488
59. [59]
  Fan, L.; Tang, D.; Wang, D.; Wang, Z.; Chen, L. Nano Res. 2016, 9, 3903. doi: 10.1007/s12274-016-1259-7 doi: 10.1007/s12274-016-1259-7
60. [60]
  Song, S.; Xu, W.; Zheng, J.; Luo, L.; Engelhard, M. H.; Bowden, M. E.; Liu, B.; Wang, C. M.; Zhang, J. G. Nano Lett. 2017, 17, 1417. doi: 10.1021/acs.nanolett.6b04371 doi: 10.1021/acs.nanolett.6b04371
61. [61]
  Bie, S.; Du, M.; He, W.; Zhang, H.; Yu, Z.; Liu, J.; Liu, M.; Yan, W.; Zhou, L.; Zou, Z. ACS Appl. Mater. Interfaces 2019, 11, 5146. doi: 10.1021/acsami.8b20573 doi: 10.1021/acsami.8b20573
62. [62]
  Zhang, P.; Zhang, J.; Sheng, T.; Lu, Y.; Yin, Z.; Li, Y.; Peng, X.; Zhou, Y.; Li, J.; Wu, Y.; et al. ACS Catal. 2019, 10, 1640. doi: 10.1021/acscatal.9b04138 doi: 10.1021/acscatal.9b04138
63. [63]
  Zhang, J.; Xu, W.; Li, X.; Liu, W. J. Electrochem. Soc. 2010, 157, A940. doi: 10.1149/1.3430093 doi: 10.1149/1.3430093
64. [64]
  Zhao, D.; Timmons, D. J.; Yuan, D.; Zhou, H. Acc. Chem. Res. 2011, 44, 123. doi: 10.1021/ar100112y doi: 10.1021/ar100112y
65. [65]
  Liu, J.; Thallapally, P. K.; McGrail, B. P.; Brown, D. R.; Liu, J. Chem. Soc. Rev. 2012, 41, 2308. doi: 10.1039/c1cs15221a doi: 10.1039/c1cs15221a
66. [66]
  Ma, X. J.; Chai, Y. T.; Li, P.; Wang, B. Acc. Chem. Res. 2019, 52, 1461. doi: 10.1021/acs.accounts.9b00113 doi: 10.1021/acs.accounts.9b00113
67. [67]
  Cheng, L.; Liu, G. P.; Jin, W. Q. Acta Phys. -Chim. Sin. 2019, 35, 1090. doi: 10.3866/PKU.WHXB201810059
68. [68]
  Cao, L.; Lv, F.; Liu, Y.; Wang, W.; Huo, Y.; Fu, X.; Sun, R.; Lu, Z. Chem. Commun. 2015, 51, 4364. doi: 10.1039/c4cc09281c doi: 10.1039/c4cc09281c
69. [69]
  Heydari-Gorji, A.; Belmabkhout, Y.; Sayari, A. Langmuir 2011, 27, 12411. doi: 10.1021/la202972t doi: 10.1021/la202972t
70. [70]
  Wang, X.; Chen, L.; Guo, Q. Chem. Eng. J. 2015, 260, 573. doi: 10.1016/j.cej.2014.08.107 doi: 10.1016/j.cej.2014.08.107
71. [71]
  Khatri, R. A.; Chuang, S. S. C.; Soong, Y.; Gray, M. Energy Fuels 2006, 20, 1514. doi: 10.1021/ef050402y doi: 10.1021/ef050402y
72. [72]
  Wurzbacher, J. A.; Gebald, C.; Piatkowski, N.; Steinfeld, A. Environ. Sci Technol. 2012, 46, 9191. doi: 10.1021/es301953k doi: 10.1021/es301953k
73. [73]
  Chen, Z.; Deng, S.; Wei, H.; Wang, B.; Huang, J.; Yu, G. ACS Appl. Mater. Interfaces 2013, 5, 6937. doi: 10.1021/am400661b doi: 10.1021/am400661b
74. [74]
  Sujan, A. R.; Pang, S. H.; Zhu, G.; Jones, C. W.; Lively, R. P. ACS Sustain. Chem. Eng. 2019, 7, 5264. doi: 10.1021/acssuschemeng.8b06203 doi: 10.1021/acssuschemeng.8b06203
75. [75]
  Bacsik, Z.; Ahlsten, N.; Ziadi, A.; Zhao, G.; Garcia-Bennett, A. E.; Martín-Matute, B.; Hedin, N. Langmuir 2011, 27, 11118. doi: 10.1021/la202033p doi: 10.1021/la202033p
76. [76]
  Babel, S.; Kurniawan, T. A. J. Hazard. Mater. 2003, 97, 219. doi: 10.1016/S0304-3894(02)00263-7 doi: 10.1016/S0304-3894(02)00263-7
77. [77]
  Chue, K. T.; Kim, J. N.; Yoo, Y. J.; Cho, S. H.; Yang, R. T. Ind. Eng. Chem. Res. 1995, 34, 591. doi: 10.1021/ie00041a020 doi: 10.1021/ie00041a020
78. [78]
  Merel, J.; Clausse, M.; Meunier, F. Ind. Eng. Chem. Res. 2008, 47, 209. doi: 10.1021/ie071012x doi: 10.1021/ie071012x
79. [79]
  Chou, C.; Chen, C. Sep. Purif. Technol. 2004, 39, 51. doi: 10.1016/j.seppur.2003.12.009 doi: 10.1016/j.seppur.2003.12.009
80. [80]
  Mérel, J.; Clausse, M.; Meunier, F. Environ. Prog. 2006, 25, 327. doi: 10.1002/ep.10166 doi: 10.1002/ep.10166
81. [81]
  Song, Z.; Dong, Q.; Xu, W. L.; Zhou, F.; Liang, X.; Yu, M. ACS Appl. Mater. Interfaces 2018, 10, 769. doi: 10.1021/acsami.7b16574 doi: 10.1021/acsami.7b16574
1. [1]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
2. [2]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
3. [3]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
4. [4]
  Pin Cui , Ying Tang , Jie Yu , Zhen Yang , Shouhua Yang , Boqin Li , Gang Wang , Huan Pang , Feng Yu . Bimetallic ZnFe–NC prepared using microchannel reactor for oxygen reduction reaction and mechanism research. Chinese Chemical Letters, 2025, 36(9): 110303-. doi: 10.1016/j.cclet.2024.110303
5. [5]
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6. [6]
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7. [7]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
8. [8]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
9. [9]
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10. [10]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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Toward Practical Lithium-Air Batteries by Avoiding Negative Effects of CO2

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Toward Practical Lithium-Air Batteries by Avoiding Negative Effects of CO₂