Citation: Shi Haodong, Li Yaguang, Lu Pengfei, Wu Zhong-Shuai. Single-Atom Cobalt Coordinated to Oxygen Sites on Graphene for Stable Lithium Metal Anodes[J]. Acta Physico-Chimica Sinica, ;2021, 37(11): 200803. doi: 10.3866/PKU.WHXB202008033 shu

Single-Atom Cobalt Coordinated to Oxygen Sites on Graphene for Stable Lithium Metal Anodes

Shi Haodong ^1,2,3 ,
Li Yaguang ^1,2 ,
Lu Pengfei ^1,2 ,
Wu Zhong-Shuai ^1,2,,

1.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China
2.
Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Wu Zhong-Shuai, wuzs@dicp.ac.cn
Received Date: 13 August 2020
Revised Date: 8 September 2020
Accepted Date: 8 September 2020
Available Online: 14 September 2020
Fund Project: Dalian Institute Of Chemical Physics DICP ZZBS201708Dalian Institute Of Chemical Physics and Qingdao Institute of Biomass Energy and Bioprocess Technology DICP&QIBEBT UN201702the Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS DNL180308The project was supported by the National Key R@D Program of China (2016YBF0100100), the National Natural Science Foundation of China (51872283, 21805273), the Liaoning BaiQianWan Talents Program, Liaoning Revitalization Talents Program (XLYC1807153), the Natural Science Foundation of Liaoning Province (20180510038), Dalian Institute Of Chemical Physics (DICP ZZBS201708, DICP ZZBS201802, DICP I202032), Dalian Institute Of Chemical Physics and Qingdao Institute of Biomass Energy and Bioprocess Technology (DICP&QIBEBT UN201702), and the Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS (DNL180310, DNL180308, DNL201912, DNL201915)Dalian Institute Of Chemical Physics DICP I202032the National Natural Science Foundation of China 51872283the Natural Science Foundation of Liaoning Province 20180510038the Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS DNL180310Dalian Institute Of Chemical Physics DICP ZZBS201802the Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS DNL201912the National Natural Science Foundation of China 21805273the Liaoning BaiQianWan Talents Program, Liaoning Revitalization Talents Program XLYC1807153the National Key R@D Program of China 2016YBF0100100the Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS DNL201915

Lithium (Li)-based batteries are the dominant energy source for consumer electronics, grid storage, and electrified transportation. However, the development of batteries based on graphite anodes is hindered by their limited energy density. With its ultrahigh theoretical capacity (3860 mAh∙g⁻¹), low redox potential (−3.04 V), and satisfactorily low density (0.54 g∙cm⁻³), Li metal is the most promising anode for next-generation high-energy-density batteries. Unfortunately, the limited cycling life and safety issues raised by dendrite growth, unstable solid electrolyte interphase, and "dead Li" have inhibited their practical use. An effective strategy is to develop a suitable lithiophilic matrix for regulating initial Li nucleation behavior and controlling subsequent Li growth. Herein, single-atom cobalt coordinated to oxygen sites on graphene (Co-O-G SA) is demonstrated as a Li plating substrate to efficiently regulate Li metal nucleation and growth. Owing to its dense and more uniform lithiophilic sites than single-atom cobalt coordinated to nitrogen sites on graphene (Co-N-G SA), high electronic conductivity, and high specific surface area (519 m²∙g⁻¹), Co-O-G SA could significantly reduce the local current density and promote the reversibility of Li plating and stripping. As a result, the Co-O-G SA based Li anodes exhibited a high Coulombic efficiency of 99.9% at a current density of 1 mA∙cm⁻² with a capacity of 1 mAh∙cm⁻², and excellent rate capability (high current density of 8 mA∙cm⁻²). Even at a high plating capacity of 6 mAh∙cm⁻², the Co-O-G SA electrode could stably cycle for an ultralong lifespan of 1300 h. In the symmetric battery, the Co-O-G SA based Li anode (Co-O-G SA/Li) possessed a stable voltage profile of 18 mV for 780 h at 1 mA∙cm⁻², and even at a high current density of 3 mA∙cm⁻², its overpotential maintained a small hysteresis of approximately 24 mV for > 550 h. Density functional theory calculations showed that the surface of Co-O-G SA had a stronger interaction with Li atoms with a larger binding energy, −3.1 eV, than that of Co-N-G SA (−2.5 eV), leading to a uniform distribution of metallic Li on the Co-O-G SA surface. More importantly, when matched with a sulfur cathode, the resulting Co-O-G SA/lithium sulfur full batteries exhibited a high capacity of 1002 mAh∙g⁻¹, improved kinetics with a small polarization of 191 mV, and an ultralow capacity decay rate of 0.036% per cycle for 1000 cycles at 0.5C (1C = 1675 mA∙g⁻¹) with a steady Coulombic efficiency of nearly 100%. Therefore, this work provides novel insights into the coordination environment of single atoms for the chemistry of Li metal anodes for high-energy-density batteries.
- Single atom,
- Coordination environment,
- Lithiophilic site,
- Li dendrite,
- High-energy-density lithium battery
1. [1]
  Kang, K.; Meng, Y. S.; Bréger, J.; Grey, C. P.; Ceder, G. Science 2006, 311, 977. doi: 10.1126/science.1122152 doi: 10.1126/science.1122152
2. [2]
  Choi, J. W.; Aurbach, D. Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13 doi: 10.1038/natrevmats.2016.13
3. [3]
  Goodenough, J. B.; Kim, Y. Chem. Mater.2010, 22, 587. doi: 10.1021/cm901452z doi: 10.1021/cm901452z
4. [4]
  Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a doi: 10.1038/451652a
5. [5]
  Shi, H.; Zhang, C. J.; Lu, P.; Dong, Y.; Wen, P.; Wu, Z. S. ACS Nano 2019, 13, 14308. doi: 10.1021/acsnano.0c03042 doi: 10.1021/acsnano.0c03042
6. [6]
  Shi, H.; Qin, J.; Huang, K.; Lu, P.; Zhang, C.; Dong, Y.; Ye, M.; Liu, Z.; Wu, Z. S. Angew. Chem. Int. Ed. 2020, 59, 12147. doi: 10.1002/anie.202004284 doi: 10.1002/anie.202004284
7. [7]
  Cheng, X. B.; Zhang, R.; Zhao, C. Z.; Zhang, Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115 doi: 10.1021/acs.chemrev.7b00115
8. [8]
  Xu, X.; Wang, S.; Wang, H.; Hu, C.; Jin, Y.; Liu, J.; Yan, H. J. Am. Chem. Soc. 2018, 27, 513. doi: 10.1016/j.jechem.2017.11.010 doi: 10.1016/j.jechem.2017.11.010
9. [9]
  Chen, S.; Niu, C.; Lee, H.; Li, Q.; Yu, L.; Xu, W.; Zhang, J. G.; Dufek, E. J.; Whittingham, M. S.; Meng, S. Joule 2019, 3, 1094. doi: 10.1016/j.joule.2019.02.004 doi: 10.1016/j.joule.2019.02.004
10. [10]
  Ran, Q.; Sun, T.; Han, C.; Zhang, H.; Yan, J.; Wang, J. Acta Phys. -Chim. Sin. 2020, 36, 1912068. doi: 10.3866/PKU.WHXB201912068
11. [11]
  Ding, F.; Xu, W.; Graff, G. L.; Zhang, J.; Sushko, M. L.; Chen, X.; Shao, Y.; Engelhard, M. H.; Nie, Z.; Xiao, J.; et al. J. Am. Chem. Soc. 2013, 135, 4450. doi: 10.1021/ja312241y doi: 10.1021/ja312241y
12. [12]
  Wang, G.; Xiong, X.; Xie, D.; Fu, X.; Ma, X.; Li, Y.; Liu, Y.; Lin, Z.; Yang, C.; Liu, M. Energy Storage Mater. 2019, 23, 701. doi: 10.1016/j.ensm.2019.02.026 doi: 10.1016/j.ensm.2019.02.026
13. [13]
  Zhao, C. Z.; Duan, H.; Huang, J. Q.; Zhang, J.; Zhang, Q.; Guo, Y. G.; Wan, L. J. Sci. China Chem. 2019, 62, 1286. doi: 10.1007/s11426-019-9519-9 doi: 10.1007/s11426-019-9519-9
14. [14]
  Jin, F., Li. J.; Hu, C. J.; Dong, H. C.; Chen, P.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1399. doi: 10.3866/PKU.WHXB201904085
15. [15]
  Zhu, G.; Zhao, C.; Yuan, H.; Nan, H.; Zhao, B.; Hou, L.; He, C.; Liu, Q.; Huang, J. Acta Phys. -Chim. Sin. 2021, 37, 2005003. doi: 10.3866/PKU.WHXB202005003
16. [16]
  Zhang, H.; Liao, X.; Guan, Y.; Xiang, Y.; Li, M.; Zhang, W.; Zhu, X.; Ming, H.; Lu, L.; Qiu, J.; et al. Nat. Commun. 2018, 9, 3729. doi: 10.1038/s41467-018-06126-z doi: 10.1038/s41467-018-06126-z
17. [17]
  Zhang, C.; Lyu, R.; Lv, W.; Li, H.; Jiang, W.; Li, J.; Gu, S.; Zhou, G.; Huang, Z.; Zhang, Y.; et al. Adv. Mater. 2019, 31, e1904991. doi: 10.1002/adma.201904991 doi: 10.1002/adma.201904991
18. [18]
  Ni, S.; Tan, S.; An, Q.; Mai, L. J. Energy Chem. 2020, 44, 73. doi: 10.1016/j.jechem.2019.09.031 doi: 10.1016/j.jechem.2019.09.031
19. [19]
  Zhang, R.; Chen, X. R.; Chen, X.; Cheng, X. B.; Zhang, X. Q.; Yan, C.; Zhang, Q. Angew. Chem. Int. Ed. 2017, 56, 7764. doi: 10.1002/ange.201702099 doi: 10.1002/ange.201702099
20. [20]
  Shi, H.; Yue, M.; Zhang, C. J.; Dong, Y.; Lu, P.; Zheng, S.; Huang, H.; Chen, J.; Wen, P.; Xu, Z.; et al. ACS Nano 2020, 14, 8678. doi: 10.1021/acsnano.0c03042 doi: 10.1021/acsnano.0c03042
21. [21]
  Zhang, J. Q.; Zhao, Y. F.; Guo, X.; Chen, C.; Dong, C. L.; Liu, R. S.; Han, C. P.; Li, Y. D.; Gogotsi, Y.; Wang, G. X. Nat. Catal. 2018, 1, 985. doi: 10.1038/s41929-018-0195-1 doi: 10.1038/s41929-018-0195-1
22. [22]
  Zhang, J. Q.; Zhao, Y. F.; Chen, C.; Huang, Y. C.; Dong, C. L.; Chen, C. J.; Liu, R. S.; Wang, C. Y.; Yan, K, ; Li, Y. D.; et al. J. Am. Chem. Soc. 2019, 141, 20118. doi: 10.1021/jacs.9b09352 doi: 10.1021/jacs.9b09352
23. [23]
  Zhao, D.; Chen, Z.; Yang, W. J.; Liu, S. J.; Zhang, X.; Yu, Y.; Cheong, W. C.; Zheng, L. R.; Ren, F. Q.; Ying, G. B.; et al. J. Am. Chem. Soc. 2019, 141, 4086. doi: 10.1021/jacs.8b13579 doi: 10.1021/jacs.8b13579
24. [24]
  Xu, K.; Zhu, M.; Wu, X.; Liang, J.; Liu, Y.; Zhang, T.; Zhu, Y.; Qian, Y. Energy Storage Mater. 2019, 23, 587. doi: 10.1016/j.ensm.2019.03.025 doi: 10.1016/j.ensm.2019.03.025
25. [25]
  Zhai, P.; Wang, T.; Yang, W.; Cui, S.; Zhang, P.; Nie, A.; Zhang, Q.; Gong, Y. Adv. Energy Mater. 2019, 9, 1804019. doi: 10.1002/aenm.201804019 doi: 10.1002/aenm.201804019
26. [26]
  Gu, J.; Zhu, Q.; Shi, Y.; Chen, H.; Zhang, D.; Du, Z.; Yang, S. ACS Nano 2020, 14, 891. doi: 10.1021/acsnano.9b08141 doi: 10.1021/acsnano.9b08141
27. [27]
  Zheng, J.; Engelhard, M. H.; Mei, D.; Jiao, S.; Polzin, B. J.; Zhang, J. G.; Xu, W. Nat. Energy 2017, 2, 17012. doi: 10.1038/nenergy.2017.12 doi: 10.1038/nenergy.2017.12
28. [28]
  Li, Y.; Wu, Z. S.; Lu, P.; Wang, X.; Liu, W.; Liu, Z.; Ma, J.; Ren, W.; Jiang, Z.; Bao, X. Adv. Sci. 2020, 7, 1903089. doi: 10.1002/advs.201903089 doi: 10.1002/advs.201903089
29. [29]
  Xu, Y.; Zhang, W.; Li, Y.; Lu, P.; Wu, Z. S. J. Energy Chem. 2020, 43, 52. doi: 10.1016/j.jechem.2019.08.006 doi: 10.1016/j.jechem.2019.08.006
30. [30]
  Delley, B. J. Chem. Phys. 2000, 113, 7756. doi: 10.1063/1.1316015 doi: 10.1063/1.1316015
31. [31]
  White, J.; Bird, D. Phys. Rev. B 1994, 50, 4954. doi: 10.1103/PhysRevB.50.4954 doi: 10.1103/PhysRevB.50.4954
32. [32]
  Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865. doi: 10.1103/PhysRevLett.77.3865 doi: 10.1103/PhysRevLett.77.3865
33. [33]
  Monkhorst, H. J.; Pack, J. D. Phys. Rev. B 1976, 13, 5188. doi: 10.1103/PhysRevB.13.5188 doi: 10.1103/PhysRevB.13.5188
34. [34]
  Cui, J.; Yao, S.; Ihsan-Ul-Haq, M.; Wu, J.; Kim, J. K. Adv. Energy Mater. 2019, 9, 1802777. doi: 10.1002/aenm.201802777 doi: 10.1002/aenm.201802777
35. [35]
  Sun, W.; Du, L.; Tan, Q.; Zhou, J.; Hu, Y.; Du, C.; Gao, Y.; Yin, G. ACS Appl. Mater. Interfaces 2019, 11, 41258. doi: 10.1021/acsami.9b11830 doi: 10.1021/acsami.9b11830
36. [36]
  Yang, L.; Shi, L.; Wang, D.; Lv, Y.; Cao, D. Nano Energy 2018, 50, 691. doi: 10.1016/j.nanoen.2018.06.023 doi: 10.1016/j.nanoen.2018.06.023
37. [37]
  Cheng, X. B.; Yan, C.; Peng, H. J.; Huang, J. Q.; Yang, S. T.; Zhang, Q. Energy Storage Mater. 2018, 10, 199. doi: 10.1016/j.ensm.2017.03.008 doi: 10.1016/j.ensm.2017.03.008
38. [38]
  Liu, K.; Li, Z.; Xie, W.; Li, J.; Rao, D.; Shao, M.; Zhang, B.; Wei, M. Energy Storage Mater. 2018, 15, 308. doi: 10.1016/j.ensm.2018.05.025 doi: 10.1016/j.ensm.2018.05.025
39. [39]
  Deng, W.; Zhu, W.; Zhou, X.; Liu, Z. Energy Storage Mater. 2018, 15, 266. doi: 10.1016/j.ensm.2018.05.005 doi: 10.1016/j.ensm.2018.05.005
40. [40]
  Chen, W.; Salvatierra, R. V.; Ren, M.; Chen, J.; Stanford, M. G.; Tour, J. M. Adv. Mater. 2020, 2002850. doi: 10.1002/adma.202002850
41. [41]
  Zhang, R.; Chen, X.; Shen, X.; Zhang, X. Q.; Chen, X. R.; Cheng, X. B.; Yan, C.; Zhao, C. Z.; Zhang, Q. Joule 2018, 2, 764. doi: 10.1016/j.joule.2018.02.001 doi: 10.1016/j.joule.2018.02.001
42. [42]
  Chen, X.; Chen, X. R.; Hou, T. Z.; Li, B. Q.; Cheng, X. B.; Zhang, R.; Zhang, Q. Sci. Adv. 2019, 5, eaau7728. doi: 10.1126/sciadv.aau7728 doi: 10.1126/sciadv.aau7728
43. [43]
  Yin, Y. X.; Xin, S.; Guo, Y. G.; Wan, L. J. Angew. Chem. Int. Ed. 2013, 52, 13186. doi: 10.1002/anie.201304762 doi: 10.1002/anie.201304762
44. [44]
  Shi, H.; Zhao, X.; Wu, Z. S.; Dong, Y.; Lu, P.; Chen, J.; Ren, W.; Cheng, H. M.; Bao, X. Nano Energy 2019, 60, 743. doi: 10.1016/j.nanoen.2019.04.006 doi: 10.1016/j.nanoen.2019.04.006
45. [45]
  Shi, H.; Dong, Y.; Zhou, F.; Chen, J.; Wu, Z. S. J. Phys.: Energy 2018, 1, 015002. doi: 10.1088/2515-7655/aadef6 doi: 10.1088/2515-7655/aadef6
1. [1]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
2. [2]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
3. [3]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
4. [4]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
5. [5]
  Junchen Peng , Xue Yin , Dandan Dong , Zhongyuan Guo , Qinqin Wang , Minmin Liu , Fei He , Bin Dai , Chaofeng Huang . Promotion effect of epoxy group neighboring single-atom Cu site on acetylene hydrochlorination. Chinese Chemical Letters, 2024, 35(6): 109508-. doi: 10.1016/j.cclet.2024.109508
6. [6]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
7. [7]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
8. [8]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
9. [9]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
10. [10]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
11. [11]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
12. [12]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
13. [13]
  Zeyu Jiang , Yadi Wang , Changwei Chen , Chi He . Progress and challenge of functional single-atom catalysts for the catalytic oxidation of volatile organic compounds. Chinese Chemical Letters, 2024, 35(9): 109400-. doi: 10.1016/j.cclet.2023.109400
14. [14]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
15. [15]
  Tao Wei , Jiahao Lu , Pan Zhang , Qi Zhang , Guang Yang , Ruizhi Yang , Daifen Chen , Qian Wang , Yongfu Tang . An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity. Chinese Chemical Letters, 2024, 35(8): 109122-. doi: 10.1016/j.cclet.2023.109122
16. [16]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
17. [17]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
18. [18]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
19. [19]
  Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
20. [20]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715

Get Citation

PDF

XML

Metrics

PDF Downloads(39)
Abstract views(1392)
HTML views(293)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142