Citation: Yang Shijie, Xu Xiangqun, Cheng Xinbing, Wang Xinmeng, Chen Jinxiu, Xiao Ye, Yuan Hong, Liu He, Chen Aibing, Zhu Wancheng, Huang Jiaqi, Zhang Qiang. Columnar Lithium Metal Deposits: the Role of Non-Aqueous Electrolyte Additive[J]. Acta Physico-Chimica Sinica, ;2021, 37(1): 200705. doi: 10.3866/PKU.WHXB202007058 shu

Columnar Lithium Metal Deposits: the Role of Non-Aqueous Electrolyte Additive

Yang Shijie ^1,3 ,
Xu Xiangqun ² ,
Cheng Xinbing ^2,, ,
Wang Xinmeng ^2,4 ,
Chen Jinxiu ^2,5 ,
Xiao Ye ^1,3 ,
Yuan Hong ^1,3,, ,
Liu He ^1,3 ,
Chen Aibing ⁴ ,
Zhu Wancheng ⁵ ,
Huang Jiaqi ^1,3 ,
Zhang Qiang ²

1.
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China
2.
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
3.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
4.
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
5.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong Province, China

Corresponding author: Cheng Xinbing, cxb12@mails.tsinghua.edu.cn Yuan Hong, yuanhong@bit.edu.cn
Received Date: 23 July 2020
Revised Date: 21 August 2020
Accepted Date: 31 August 2020
Available Online: 4 September 2020
Fund Project: the National Natural Science Foundation of China 21808124The project was supported by the National Key Research and Development Program of China (2016YFA0202500, 2016YFA0200102), the National Natural Science Foundation of China (21805161, 21808124, U1932220)the National Natural Science Foundation of China U1932220the National Key Research and Development Program of China 2016YFA0200102the National Key Research and Development Program of China 2016YFA0202500the National Natural Science Foundation of China 21805161

With the booming growth market of electric vehicles and portable electronics, high-energy-density rechargeable lithium ion batteries are being extensively used to advance high-end devices. Lithium-ion batteries with graphite anodes approach the ceiling in energy density, but they cannot satisfy the current demand. Among the next-generation electrodes, lithium metal anodes are strong candidates because of their high theoretical capacity and the most negative electrochemical potential. However, lithium metal batteries have been abandoned because of their poor safety resulting from the growth of lithium dendrites during lithium deposition. Although several strategies have been proposed to suppress the generation of lithium dendrites as well as the side reactions between active lithium and the electrolyte, lithium metal anodes have not been practically applied so far. Various studies have been conducted on the factors influencing lithium deposition, with the aim of understanding the growth behavior of lithium dendrites. The electrolyte plays a crucial role in the performance of the working Li metal anode. In this study, a unique battery system is proposed to realize columnar lithium deposition, which is convenient for obtaining the length and diameter of lithium deposits. The influence of different electrolytes on lithium deposition was investigated by comparing the length-diameter (L/D) ratio of the lithium deposits in two kinds of electrolytes (1.0 mol·L^-1 LiPF₆-ethylene carbonate/diethyl carbonate (EC/DEC, 1 : 1 by volume) and 1.0 mol·L^-1 LiPF₆-5% (volume fraction) fluoroethylene carbonate (FEC)-EC/DEC (1 : 1 by volume)). The morphology of the lithium deposits was strongly affected by the electrolyte composition. In the electrolyte with the FEC additive, the diameter of columnar lithium increased from 0.3-0.6 μm to 0.7-1.3 μm, while the L/D ratio decreased from 12.5 to 5.6. The small L/D ratio can reduce the reactive area between the lithium metal anode and the electrolyte, which is beneficial for achieving high lithium utilization and a long lifespan. To probe the origin of this influence, the surface chemistry of the cycled lithium metal anode was investigated by X-ray photoelectron spectroscopy. The FEC additive can increase the proportion of lithium fluoride (LiF) in the solid electrolyte interphase, which is conducive for the rapid diffusion of lithium ions. As a result, fewer nucleation sites are formed, providing more space for the growth of lithium cores with a large diameter. Therefore, the addition of FEC leads to a decrease in the L/D ratio of columnar lithium.
- Lithium metal battery,
- Columnar lithium,
- Electrolyte,
- Lithium fluoride,
- Length-diameter ratio
1. [1]
  Chen, X. R.; Yao, Y. X.; Yan, C.; Zhang, R.; Cheng, X. B.; Zhang, Q. Angew. Chem. Int. Ed. 2020, 132, 7817. doi: 10.1002/ange.202000375 doi: 10.1002/ange.202000375
2. [2]
  Fan, Y.; Wang, T.; Legut, D.; Zhang, Q. J. Energy Chem. 2019, 39, 160. doi: 10.1016/j.jechem.2019.01.021 doi: 10.1016/j.jechem.2019.01.021
3. [3]
  Liu, H.; Cheng, X. B.; Huang, J. Q.; Yuan, H.; Lu, Y.; Yan, C.; Zhu, G. L.; Xu, R.; Zhao, C. Z.; Hou, L. P.; et al. ACS Energy Lett. 2020, 5, 833. doi: 10.1021/acsenergylett.9b02660 doi: 10.1021/acsenergylett.9b02660
4. [4]
  Qiao, Y.; Li, Q.; Cheng, X. B.; Liu, F. X.; Yang, Y.; Lu, Z. S.; Zhao, J.; Wu, J. W.; Liu, H.; Yang, S. T.; et al. ACS Appl. Mater. Interfaces 2020, 12, 5767. doi: 10.1021/acsami.9b18315 doi: 10.1021/acsami.9b18315
5. [5]
  Shen, Y.; Zhang, Y.; Han, S.; Wang, J.; Peng, Z.; Chen, L. Joule 2018, 2, 1674. doi: 10.1016/j.joule.2018.06.021 doi: 10.1016/j.joule.2018.06.021
6. [6]
  Feng, Y. Q.; Zheng, Z. J.; Wang, C. Y.; Yin, Y. X.; Ye, H.; Cao, F. F.; Guo, Y. G. Nano Energy 2020, 73, 104731. doi: 10.1016/j.nanoen.2020.104731 doi: 10.1016/j.nanoen.2020.104731
7. [7]
  Wan, J.; Xie, J.; Kong, X.; Liu, Z.; Liu, K.; Shi, F.; Pei, A.; Chen, H.; Chen, W.; Chen, J.; et al. Nat. Nanotechnol. 2019, 14, 705. doi: 10.1038/s41565-019-0465-3 doi: 10.1038/s41565-019-0465-3
8. [8]
  Ma, Y. Y.; Chen, D.; Yang, Q. L.; Yin, Y. X.; Bai, X. P.; Zhen, S. Y.; Fan, C.; Sun, K. N. J. Energy Chem. 2020, 42, 49. doi: 10.1016/j.jechem.2019.06.008 doi: 10.1016/j.jechem.2019.06.008
9. [9]
  Liu, Y.; Zheng, L.; Gu, W.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2021, 37, 2004058. doi: 10.3866/PKU.WHXB202004058
10. [10]
  Liang, Y.; Zhao, C. Z.; Yuan, H.; Chen, Y.; Zhang, W.; Huang, J. Q.; Yu, D.; Liu, Y.; Titirici, M. M.; Chueh, Y. L.; et al. InfoMat. 2019, 1, 6. doi: 10.1002/inf2.12000 doi: 10.1002/inf2.12000
11. [11]
  Kong, L.; Yan, C.; Huang, J. Q.; Zhao, M. Q.; Titirici, M. M.; Xiang, R.; Zhang, Q. Energy Environ. Mater. 2018, 1, 100. doi: 10.1002/eem2.12012 doi: 10.1002/eem2.12012
12. [12]
  Yan, C.; Cheng, X. B.; Tian, Y.; Chen, X.; Zhang, X. Q.; Li, W. J.; Huang, J. Q.; Zhang, Q. Adv. Mater. 2018, 30, 1707629. doi: 10.1002/adma.201707629 doi: 10.1002/adma.201707629
13. [13]
  Shi, P.; Li, T.; Zhang, R.; Shen, X.; Cheng, X. B.; Xu, R.; Huang, J. Q.; Chen, X. R.; Liu, H.; Zhang, Q. Adv. Mater. 2019, 31, 1807131. doi: 10.1002/adma.201807131 doi: 10.1002/adma.201807131
14. [14]
  Xu, R.; Xiao, Y.; Zhang, R.; Cheng, X. B.; Zhao, C. Z.; Zhang, X. Q.; Yan, C.; Zhang, Q.; Huang, J. Q. Adv. Mater. 2019, 31, 1808392. doi: 10.1002/adma.201808392 doi: 10.1002/adma.201808392
15. [15]
  Tong, B.; Chen, X.; Chen, L.; Zhou, Z.; Peng, Z. ACS Appl. Energy Mater. 2018, 1, 4426. doi: 10.1021/acsaem.8b00821 doi: 10.1021/acsaem.8b00821
16. [16]
  Ye, H.; Zhang, Y.; Yin, Y. X.; Cao, F. F.; Guo, Y. G. ACS Cent. Sci. 2020, 6, 661. doi: 10.1021/acscentsci.0c00351 doi: 10.1021/acscentsci.0c00351
17. [17]
  Zhang, W.; Wu, Q.; Huang, J.; Fan, L.; Shen, Z.; He, Y.; Feng, Q.; Zhu, G.; Lu, Y. Adv. Mater. 2020, 32, 2001740. doi: 10.1002/adma.202001740 doi: 10.1002/adma.202001740
18. [18]
  Guo, F.; Chen, P.; Kang, T.; Wang, Y. L.; Liu, C. H.; Shen, Y. B.; Lu, W.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1365. doi: 10.3866/PKU.WHXB201903008
19. [19]
  Yue, X. Y.; Ma, C.; Bao, J.; Yang, S. Y.; Chen, D.; Wu, X. J.; Zhou, Y. N. Acta Phys. -Chim. Sin. 2021, 37, 2005012. doi: 10.3866/PKU.WHXB202005012
20. [20]
  Wang, G.; Xiong, X.; Xie, D.; Fu, X.; Ma, X.; Li, Y.; Liu, Y.; Lin, Z.; Yang, C.; Liu, M. Energy Storage Mater. 2019, 23, 701. doi: 10.1016/j.ensm.2019.02.026 doi: 10.1016/j.ensm.2019.02.026
21. [21]
  Zhang, R.; Shen, X.; Cheng, X. B.; Zhang, Q. Energy Storage Mater. 2019, 23, 556. doi: 10.1016/j.ensm.2019.03.029 doi: 10.1016/j.ensm.2019.03.029
22. [22]
  Shi, P.; Cheng, X. B.; Li, T.; Zhang, R.; Liu, H.; Yan, C.; Zhang, X. Q.; Huang, J. Q.; Zhang, Q. Adv. Mater. 2019, 31, 1902785. doi: 10.1002/adma.201902785 doi: 10.1002/adma.201902785
23. [23]
  Niu, C.; Lee, H.; Chen, S.; Li, Q.; Du, J.; Xu, W.; Zhang, J. G.; Whittingham, M. S.; Xiao, J.; Liu, J. Nat. Energy 2019, 4, 551. doi: 10.1038/s41560-019-0390-6 doi: 10.1038/s41560-019-0390-6
24. [24]
  Hobold, G. M.; Khurram, A.; Gallant, B. M. Chem. Mater. 2020, 32, 2341. doi: 10.1021/acs.chemmater.9b04550 doi: 10.1021/acs.chemmater.9b04550
25. [25]
  Chen, Y.; Luo, Y.; Zhang, H.; Qu, C.; Zhang, H.; Li, X. Small Methods 2019, 3, 1800551. doi: 10.1002/smtd.201800551 doi: 10.1002/smtd.201800551
26. [26]
  Yao, Y. X.; Zhang, X. Q.; Li, B. Q.; Yan, C.; Chen, P. Y.; Huang, J. Q.; Zhang, Q. InfoMat 2020, 2, 379. doi: 10.1002/inf2.12046 doi: 10.1002/inf2.12046
27. [27]
  Fan, H.; Gao, C.; Jiang, H.; Dong, Q.; Hong, B.; Lai, Y. J. Energy Chem. 2020, 49, 59. doi: 10.1016/j.jechem.2020.01.013 doi: 10.1016/j.jechem.2020.01.013
28. [28]
  Liu, H.; Cheng, X. B.; Huang, J. Q.; Kaskel, S.; Chou, S.; Park, H. S.; Zhang, Q. ACS Mater. Lett. 2019, 1, 217. doi: 10.1021/acsmaterialslett.9b00118 doi: 10.1021/acsmaterialslett.9b00118
29. [29]
  Zhang, X. Q.; Cheng, X. B.; Chen, X.; Yan, C.; Zhang, Q. Adv. Funct. Mater. 2017, 27, 1605989. doi: 10.1002/adfm.201605989 doi: 10.1002/adfm.201605989
30. [30]
  Chen, W. J.; Zhao, C. X.; Li, B. Q.; Jin, Q.; Zhang, X. Q.; Yuan, T. Q.; Zhang, X.; Jin, Z.; Kaskel, S.; Zhang, Q. Energy Environ. Mater. 2020, 3, 160. doi: 10.1002/eem2.12073 doi: 10.1002/eem2.12073
31. [31]
  He, Y.; Zhang, Y.; Yu, P.; Ding, F.; Li, X.; Wang, Z.; Lv, Z.; Wang, X.; Liu, Z.; Huang, X. J. Energy Chem. 2020, 45, 1. doi: 10.1016/j.jechem.2019.09.033 doi: 10.1016/j.jechem.2019.09.033
32. [32]
  Chen, J. X.; Zhang, X. Q.; Li, B. Q.; Wang, X. M.; Shi, P.; Zhu, W. C.; Chen, A. B.; Jin, Z. H.; Xiang, R.; Huang, J. Q.; Zhang, Q. J. Energy Chem. 2020, 47, 128. doi: 10.1016/j.jechem.2019.11.024 doi: 10.1016/j.jechem.2019.11.024
33. [33]
  Yang, Q. L.; Li, W. L.; Dong, C.; Ma, Y. Y.; Yin, Y. X.; Wu, Q. B.; Xu, Z. T.; Ma, W.; Fan, C.; Sun, K. N. J. Energy Chem. 2020, 42, 83. doi: 10.1016/j.jechem.2019.06.012 doi: 10.1016/j.jechem.2019.06.012
34. [34]
  Li, C.; Liu, S.; Shi, C.; Liang, G.; Lu, Z.; Fu, R.; Wu, D. Nat. Commun. 2019, 10, 1363. doi: 10.1038/s41467-019-09211-z doi: 10.1038/s41467-019-09211-z
35. [35]
  Wei, Z.; Ren, Y.; Sokolowski, J.; Zhu, X.; Wu, G. InfoMat 2020, 2, 483. doi: 10.1002/inf2.12097 doi: 10.1002/inf2.12097
36. [36]
  Liu, H.; Chen, X.; Cheng, X. B.; Li, B. Q.; Zhang, R.; Wang, B.; Chen, X.; Zhang, Q. Small Methods 2019, 3, 1800354. doi: 10.1002/smtd.201800354 doi: 10.1002/smtd.201800354
37. [37]
  Shen, X.; Cheng, X.; Shi, P.; Huang, J.; Zhang, X.; Yan, C.; Li, T.; Zhang, Q. J. Energy Chem. 2019, 37, 29. doi: 10.1016/j.jechem.2018.11.016 doi: 10.1016/j.jechem.2018.11.016
38. [38]
  Shang, Y.; Chu, T.; Shi, B.; Fu, K. Energy Environ. Mater. 2020. doi: 10.1002/eem2.12099 doi: 10.1002/eem2.12099
39. [39]
  Lu, D.; Shao, Y.; Lozano, T.; Bennett, W. D.; Graff, G. L.; Polzin, B.; Zhang, J.; Engelhard, M. H.; Saenz, N. T.; Henderson, W. A.; et al. Adv. Energy Mater. 2015, 5, 1702322. doi: 10.1002/aenm.201400993 doi: 10.1002/aenm.201400993
40. [40]
  Wood, K. N.; Kazyak, E.; Chadwick, A. F.; Chen, K. H.; Zhang, J. G.; Thornton, K.; Dasgupta, N. P. ACS Cent. Sci. 2016, 2, 790. doi: 10.1021/acscentsci.6b00260 doi: 10.1021/acscentsci.6b00260
41. [41]
  Yin, X.; Tang, W.; Jung, I. D.; Phua, K. C.; Adams, S.; Lee, S. W.; Zheng, G. W. Nano Energy 2018, 50, 659. doi: 10.1016/j.nanoen.2018.06.003 doi: 10.1016/j.nanoen.2018.06.003
42. [42]
  Yan, K.; Wang, J.; Zhao, S.; Zhou, D.; Sun, B.; Cui, Y.; Wang, G. Angew. Chem. Int. Ed. 2019, 58, 11364. doi: 10.1002/anie.201905251 doi: 10.1002/anie.201905251
43. [43]
  Rodriguez, R.; Loeffler, K. E.; Edison, R. A.; Stephens, R. M.; Dolocan, A.; Heller, A.; Mullins, C. B. ACS Appl. Energy Mater. 2018, 1, 5830. doi: 10.1021/acsaem.8b01194 doi: 10.1021/acsaem.8b01194
44. [44]
  Zhang, Y.; Qian, J.; Xu, W.; Russell, S. M.; Chen, X.; Nasybulin, E.; Bhattacharya, P.; Engelhard, M. H.; Mei, D.; Cao, R.; et al. Nano Lett. 2014, 14, 6889. doi: 10.1021/nl5039117 doi: 10.1021/nl5039117
45. [45]
  Zhang, X. Q.; Chen, X.; Xu, R.; Cheng, X. B.; Peng, H. J.; Zhang, R.; Huang, J. Q.; Zhang, Q. Angew. Chem. Int. Ed. 2017, 56, 14207. doi: 10.1002/anie.201707093 doi: 10.1002/anie.201707093
46. [46]
  Qian, J.; Xu, W.; Bhattacharya, P.; Engelhard, M.; Henderson, W. A.; Zhang, Y.; Zhang, J. G. Nano Energy 2015, 15, 135. doi: 10.1016/j.nanoen.2015.04.009 doi: 10.1016/j.nanoen.2015.04.009
47. [47]
  Cheng, X. B.; Zhao, M. Q.; Chen, C.; Pentecost, A.; Maleski, K.; Mathis, T.; Zhang, X. Q.; Zhang, Q.; Jiang, J.; Gogotsi, Y. Nat. Commun. 2017, 8, 336. doi: 10.1038/s41467-017-00519-2 doi: 10.1038/s41467-017-00519-2
48. [48]
  Michan, A. L.; Parimalam, B. S.; Leskes, M.; Kerber, R. N.; Yoon, T.; Grey, C. P.; Lucht, B. L. Chem. Mater. 2016, 28, 8149. doi: 10.1021/acs.chemmater.6b02282 doi: 10.1021/acs.chemmater.6b02282
49. [49]
  Nie, M.; Demeaux, J.; Young, B. T.; Heskett, D. R.; Chen, Y.; Bose, A.; Woicik, J. C.; Lucht, B. L. J. Electrochem. Soc. 2015, 162, A7008. doi: 10.1149/2.0021513jes doi: 10.1149/2.0021513jes
50. [50]
  Heine, J.; Hilbig, P.; Qi, X.; Niehoff, P.; Winter, M.; Bieker, P. J. Electrochem. Soc. 2015, 162, A1094. doi: 10.1149/2.0011507jes doi: 10.1149/2.0011507jes
51. [51]
  Jurng, S.; Brown, Z. L.; Kim, J.; Lucht, B. L. Energy Environ. Sci. 2018, 11, 2600. doi: 10.1039/c8ee00364e doi: 10.1039/c8ee00364e
52. [52]
  Ko, J.; Yoon, Y. S. Ceram. Int. 2019, 45, 30. doi: 10.1016/j.ceramint.2018.09.287 doi: 10.1016/j.ceramint.2018.09.287
53. [53]
  Lang, J.; Long, Y.; Qu, J.; Luo, X.; Wei, H.; Huang, K.; Zhang, H.; Qi, L.; Zhang, Q.; Li, Z.; Wu, H. Energy Storage Mater. 2019, 16, 85. doi: 10.1016/j.ensm.2018.04.024 doi: 10.1016/j.ensm.2018.04.024
54. [54]
  Shin, H.; Park, J.; Han, S.; Sastry, A. M.; Lu, W. J. Power Sources 2015, 277, 169. doi: 10.1016/j.jpowsour.2014.11.120 doi: 10.1016/j.jpowsour.2014.11.120
55. [55]
  Jones, J.; Anouti, M.; Caillon-Caravanier, M.; Willmann, P.; Lemordant, D. Fluid Phase Equilib. 2009, 285, 62. doi: 10.1016/j.fluid.2009.07.020 doi: 10.1016/j.fluid.2009.07.020
56. [56]
  He, M.; Guo, R.; Hobold, G. M.; Gao, H.; Gallant, B. M. Proc. Natl. Acad. Sci. U.S.A. 2020, 117, 73. doi: 10.1073/pnas.1911017116 doi: 10.1073/pnas.1911017116
57. [57]
  Yang, G.; Li, Y.; Liu, S.; Zhang, S.; Wang, Z.; Chen, L. Energy Storage Mater. 2019, 23, 350. doi: 10.1016/j.ensm.2019.04.041 doi: 10.1016/j.ensm.2019.04.041
58. [58]
  Lee, Y.; Lee, T. K.; Kim, S.; Lee, J.; Ahn, Y.; Kim, K.; Ma, H.; Park, G.; Lee, S. M.; Kwak, S. K.; Choi, N. S. Nano Energy 2020, 67, 104309. doi: 10.1016/j.nanoen.2019.104309 doi: 10.1016/j.nanoen.2019.104309
1. [1]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
2. [2]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
3. [3]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
4. [4]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
5. [5]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
6. [6]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
9. [9]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
10. [10]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
11. [11]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
12. [12]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
13. [13]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
14. [14]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
15. [15]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
16. [16]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
17. [17]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
18. [18]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
19. [19]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
20. [20]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1679)
HTML views(389)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142