Citation: Jingsong Peng, Qunfeng Cheng. Nacre-Inspired Graphene-based Multifunctional Nanocomposites[J]. Acta Physico-Chimica Sinica, ;2022, 38(5): 200500. doi: 10.3866/PKU.WHXB202005006 shu

Nacre-Inspired Graphene-based Multifunctional Nanocomposites

Jingsong Peng ,
Qunfeng Cheng ^,

School of Chemistry, Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing 100191, China

Corresponding author: Qunfeng Cheng, cheng@buaa.edu.cn
Received Date: 5 May 2020
Revised Date: 10 July 2020
Accepted Date: 10 July 2020
Available Online: 14 July 2020
Fund Project: the National Natural Science Foundation of China 51522301the National Natural Science Foundation of China 51961130388the National Natural Science Foundation of China 21875010the National Natural Science Foundation of China 21273017the National Natural Science Foundation of China 51103004the Newton Advanced Fellowship NAF\R1\191235the Beijing Natural Science Foundation, China JQ19006the 111 Project, China B14009the Fundamental Research Funds for the Central Universities, China YWF-19-BJ-J-8

Graphene is a 2D nanocomposite that has been gaining popularity in the research community in recent years. It is light weight with high tensile strength and excellent electrical conductivity. While graphene nanosheets are typically assembled into macroscopic nanocomposites, their beneficial properties may degrade from the aggregation of nanosheets owing to the weak interfacial interactions caused by random orientation and many other obstacles. Thus, finding an effective way to assemble the graphene nanosheets while not impacting its intrinsic properties is challenging. In nature, live organisms have always assembled numerous nanomaterials into high-performance nanocomposites. For example, nacre is composed of aragonite nanoplatelets and biopolymers such as protein and chitin. The aragonite nanoplatelets with a 95% volume fraction are stacked into a layered structure and "glued" together by biopolymers based on the "brick-and-mortar" architecture. The fracture toughness is 3000 times higher than natural aragonite minerals owing to the "extrinsic toughening mechanism" from the crack deflection and bridging in the "brick-and-mortar" architecture. We propose a nacre-inspired layered structure in graphene-based nanocomposites with two complementary strategies: constructing nacre-like and inverse nacre-like structures. This paper first introduces the structure and toughening mechanism of nacre and clarify the advantages of a bioinspired strategies. Then, some of the recent work on nacre-inspired graphene-based multifunctional nanocomposites is discussed. To construct the nacre-like structure, we fabricated graphene-based fibers and membranes with graphene as the main component. The nacre-like graphene-based nanocomposites have excellent tensile strength and toughness due to the synergistic effects from interfacial interactions and building blocks. It also demonstrated high electrical conductivity, which makes it suitable for electromagnetic interference shielding or supercapacitors. We also fabricated inverse nacre-like graphene-based nanocomposites with a small amount of graphene. The inverse nacre-like graphene-based nanocomposites has a layered structure and exhibited the "extrinsic toughening mechanism" seen in nacre. Consequently, the inverse nacre-like graphene-based nanocomposites possesses high fracture toughness that pushes the limit of "mixing rule". With the addition of graphene, the inverse nacre-like nanocomposites are suitable for use in many applications such as electrical conductivity, electrical heating, temperature measurement and many other functions. Finally, our study summarizes the strategies to overcome the obstacles we encountered during the assembly process to construct both the nacre-like and inverse nacre-like structures that were based on graphene. Some of the challenges we encountered include the small sample size, the quality of graphene nanosheets and developing hierarchical assembly techniques. The upcoming trends in nacre-inspired graphene-based multifunctional nanocomposites will also be discussed.
- Nacre,
- Bioinspiration,
- Graphene,
- Multifunction,
- Nanocomposite
1. [1]
  Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183. doi: 10.1038/nmat1849 doi: 10.1038/nmat1849
2. [2]
  Lee, C.; Wei, X.; Kysar, J. W.; Hone, J. Science 2008, 321, 385. doi: 10.1126/science.1157996 doi: 10.1126/science.1157996
3. [3]
  Berger, C.; Song, Z. M.; Li, X. B.; Wu, X. S.; Brown, N.; Naud, C.; Mayou, D.; Li, T. B.; Hass, J.; Marchenkov, A. N.; et al. Science 2006, 312, 1191. doi: 10.1126/science.1125925 doi: 10.1126/science.1125925
4. [4]
  Huang, C.; Cheng, Q. Compos. Sci. Technol. 2017, 150, 141. doi: 10.1016/j.compscitech.2017.07.021 doi: 10.1016/j.compscitech.2017.07.021
5. [5]
  Wan, S.; Peng, J.; Jiang, L.; Cheng, Q. Adv. Mater. 2016, 28, 7862. doi: 10.1002/adma.201601934 doi: 10.1002/adma.201601934
6. [6]
  Wegst, U. G.; Bai, H.; Saiz, E.; Tomsia, A. P.; Ritchie, R. O. Nat. Mater. 2015, 14, 23. doi: 10.1038/nmat4089 doi: 10.1038/nmat4089
7. [7]
  Barthelat, F.; Yin, Z.; Buehler, M. J. Nat. Rev. Mater. 2016, 1, 16007. doi: 10.1038/natrevmats.2016.7 doi: 10.1038/natrevmats.2016.7
8. [8]
  Espinosa, H. D.; Rim, J. E.; Barthelat, F.; Buehler, M. J. Prog. Mater. Sci. 2009, 54, 1059. doi: 10.1016/j.pmatsci.2009.05.001 doi: 10.1016/j.pmatsci.2009.05.001
9. [9]
  Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S. Nature 2007, 448, 457. doi: 10.1038/nature06016 doi: 10.1038/nature06016
10. [10]
  Keten, S.; Buehler, M. J. Nano Lett. 2008, 8, 743. doi: 10.1021/nl0731670 doi: 10.1021/nl0731670
11. [11]
  Park, S.; Lee, K. S.; Bozoklu, G.; Cai, W.; Nguyen, S. T.; Ruoff, R. S. ACS Nano 2008, 2, 572. doi: 10.1021/nn700349a doi: 10.1021/nn700349a
12. [12]
  Xu, Y.; Bai, H.; Lu, G.; Li, C.; Shi, G. J. Am. Chem. Soc. 2008, 130, 5856. doi: 10.1021/ja800745y doi: 10.1021/ja800745y
13. [13]
  Putz, K. W.; Compton, O. C.; Palmeri, M. J.; Nguyen, S. T.; Brinson, L. C. Adv. Funct. Mater. 2010, 20, 3322. doi: 10.1002/adfm.201000723 doi: 10.1002/adfm.201000723
14. [14]
  Li, Y. Q.; Yu, T.; Yang, T. Y.; Zheng, L. X.; Liao, K. Adv. Mater. 2012, 24, 3426. doi: 10.1002/adma.201200452 doi: 10.1002/adma.201200452
15. [15]
  Hu, K.; Tolentino, L. S.; Kulkarni, D. D.; Ye, C.; Kumar, S.; Tsukruk, V. V. Angew. Chem. Int. Ed. 2013, 52, 13784. doi: 10.1002/anie.201307830 doi: 10.1002/anie.201307830
16. [16]
  Xu, Z.; Sun, H.; Zhao, X.; Gao, C. Adv. Mater. 2013, 25, 188. doi: 10.1002/adma.201203448 doi: 10.1002/adma.201203448
17. [17]
  Yeh, C. N.; Raidongia, K.; Shao, J.; Yang, Q. H.; Huang, J. Nat. Chem. 2014, 7, 166. doi: 10.1038/nchem.2145 doi: 10.1038/nchem.2145
18. [18]
  Zhang, M.; Huang, L.; Chen, J.; Li, C.; Shi, G. Adv. Mater. 2014, 26, 7588. doi: 10.1002/adma.201403322 doi: 10.1002/adma.201403322
19. [19]
  Wang, J.; Qiao, J.; Wang, J.; Zhu, Y.; Jiang, L. ACS Appl. Mater. Interfaces 2015, 7, 9281. doi: 10.1021/acsami.5b02194 doi: 10.1021/acsami.5b02194
20. [20]
  Xin, G.; Yao, T.; Sun, H.; Scott, S. M.; Shao, D.; Wang, G.; Lian, J. Science 2015, 349, 1083. doi: 10.1126/science.aaa6502 doi: 10.1126/science.aaa6502
21. [21]
  Georgakilas, V.; Tiwari, J. N.; Kemp, K. C.; Perman, J. A.; Bourlinos, A. B.; Kim, K. S.; Zboril, R. Chem. Rev. 2016, 116, 5464. doi: 10.1021/acs.chemrev.5b00620 doi: 10.1021/acs.chemrev.5b00620
22. [22]
  Xiong, R.; Hu, K.; Grant, A. M.; Ma, R.; Xu, W.; Lu, C.; Zhang, X.; Tsukruk, V. V. Adv. Mater. 2016, 28, 1501. doi: 10.1002/adma.201504438 doi: 10.1002/adma.201504438
23. [23]
  Ye, S.; Chen, B.; Hu, D.; Liu, C.; Feng, J. ChemNanoMat 2016, 2, 816. doi: 10.1002/cnma.201600127 doi: 10.1002/cnma.201600127
24. [24]
  Zhao, H.; Yue, Y.; Zhang, Y.; Li, L.; Guo, L. Adv. Mater. 2016, 28, 2037. doi: 10.1002/adma.201505511 doi: 10.1002/adma.201505511
25. [25]
  He, G.; Xu, M.; Zhao, J.; Jiang, S.; Wang, S.; Li, Z.; He, X.; Huang, T.; Cao, M.; Wu, H.; et al. Adv. Mater. 2017, 29, 1605898. doi: 10.1002/adma.201605898 doi: 10.1002/adma.201605898
26. [26]
  Xin, G.; Zhu, W.; Deng, Y.; Cheng, J.; Zhang, L. T.; Chung, A. J.; De, S.; Lian, J. Nat. Nanotechnol. 2019, 14, 168. doi: 10.1038/s41565-018-0330-9 doi: 10.1038/s41565-018-0330-9
27. [27]
  Li, P.; Yang, M.; Liu, Y.; Qin, H.; Liu, J.; Xu, Z.; Liu, Y.; Meng, F.; Lin, J.; Wang, F.; et al. Nat. Commun. 2020, 11, 2645. doi: 10.1038/s41467-020-16494-0 doi: 10.1038/s41467-020-16494-0
28. [28]
  Wan, S.; Cheng, Q. Adv. Funct. Mater. 2017, 27, 1703459. doi: 10.1002/adfm.201703459 doi: 10.1002/adfm.201703459
29. [29]
  Zhang, Y.; Gong, S.; Zhang, Q.; Ming, P.; Wan, S.; Peng, J.; Jiang, L.; Cheng, Q. Chem. Soc. Rev. 2016, 45, 2378. doi: 10.1039/c5cs00258c doi: 10.1039/c5cs00258c
30. [30]
  Xu, Z.; Gao, C. Nat. Commun. 2011, 2, 571. doi: 10.1038/ncomms1583 doi: 10.1038/ncomms1583
31. [31]
  Zhang, Y.; Li, Y.; Ming, P.; Zhang, Q.; Liu, T.; Jiang, L.; Cheng, Q. Adv. Mater. 2016, 28, 2834. doi: 10.1002/adma.201506074 doi: 10.1002/adma.201506074
32. [32]
  Zhang, Y.; Peng, J.; Li, M.; Saiz, E.; Wolf, S. E.; Cheng, Q. ACS Nano 2018, 12, 8901. doi: 10.1021/acsnano.8b04322 doi: 10.1021/acsnano.8b04322
33. [33]
  Wang, X.; Peng, J.; Zhang, Y.; Li, M.; Saiz, E.; Tomsia, A. P.; Cheng, Q. ACS Nano 2018, 12, 12638. doi: 10.1021/acsnano.8b07392 doi: 10.1021/acsnano.8b07392
34. [34]
  Cheng, Y. R.; Peng, J. S.; Xu, H. J.; Cheng, Q. F. Adv. Funct. Mater. 2018, 28, 1800924. doi: 10.1002/adfm.201800924 doi: 10.1002/adfm.201800924
35. [35]
  Wan, S.; Zhang, Q.; Zhou, X.; Li, D.; Ji, B.; Jiang, L.; Cheng, Q. ACS Nano 2017, 11, 7074. doi: 10.1021/acsnano.7b02706 doi: 10.1021/acsnano.7b02706
36. [36]
  Akbari, A.; Cunning, B. V.; Joshi, S. R.; Wang, C.; Camacho-Mojica, D. C.; Chatterjee, S.; Modepalli, V.; Cahoon, C.; Bielawski, C. W.; Bakharev, P.; et al. Matter 2020, 2, 1198. doi: 10.1016/j.matt.2020.02.014 doi: 10.1016/j.matt.2020.02.014
37. [37]
  Wan, S.; Li, Y.; Mu, J.; Aliev, A. E.; Fang, S.; Kotov, N. A.; Jiang, L.; Cheng, Q.; Baughman, R. H. Proc. Natl. Acad. Sci. USA 2018, 115, 5359. doi: 10.1073/pnas.1719111115 doi: 10.1073/pnas.1719111115
38. [38]
  Zhou, T.; Ni, H.; Wang, Y.; Wu, C.; Zhang, H.; Zhang, J.; Tomsia, A. P.; Jiang, L.; Cheng, Q. Proc. Natl. Acad. Sci. USA 2020, 117, 8727. doi: 10.1073/pnas.1916610117 doi: 10.1073/pnas.1916610117
39. [39]
  Cui, W.; Li, M.; Liu, J.; Wang, B.; Zhang, C.; Jiang, L.; Cheng, Q. ACS Nano 2014, 8, 9511. doi: 10.1021/nn503755c doi: 10.1021/nn503755c
40. [40]
  Wan, S. J.; Peng, J. S.; Li, Y. C.; Hu, H.; Jiang, L.; Cheng, Q. F. ACS Nano 2015, 9, 9830. doi: 10.1021/acsnano.5b02902 doi: 10.1021/acsnano.5b02902
41. [41]
  Degtyar, E.; Harrington, M. J.; Politi, Y.; Fratzl, P. Angew. Chem. Int. Ed. 2014, 53, 12026. doi: 10.1002/anie.201404272 doi: 10.1002/anie.201404272
42. [42]
  Huang, X.; Zeng, Z.; Zhang, H. Chem. Soc. Rev. 2013, 42, 1934. doi: 10.1039/c2cs35387c doi: 10.1039/c2cs35387c
43. [43]
  Liu, Y.; Rodrigues, J. N. B.; Luo, Y. Z.; Li, L.; Carvalho, A.; Yang, M.; Laksono, E.; Lu, J.; Bao, Y.; Xu, H.; et al. Nat. Nanotechnol. 2018, 13, 828. doi: 10.1038/s41565-018-0178-z doi: 10.1038/s41565-018-0178-z
44. [44]
  Dong, X.; Fu, D.; Fang, W.; Shi, Y.; Chen, P.; Li, L. J. Small 2009, 5, 1422. doi: 10.1002/smll.200801711 doi: 10.1002/smll.200801711
45. [45]
  Das, B.; Voggu, R.; Rout, C. S.; Rao, C. N. Chem. Commun. 2008, 5155. doi: 10.1039/b808955h doi: 10.1039/b808955h
46. [46]
  Su, Y. H.; Wu, Y. K.; Tu, S. L.; Chang, S. J. Appl. Phys. Lett. 2011, 99, 163102. doi: 10.1063/1.3653284 doi: 10.1063/1.3653284
47. [47]
  Ni, H.; Xu, F.; Tomsia, A. P.; Saiz, E.; Jiang, L.; Cheng, Q. ACS Appl. Mater. Interfaces 2017, 9, 24987. doi: 10.1021/acsami.7b07748 doi: 10.1021/acsami.7b07748
48. [48]
  Gong, S.; Cui, W.; Zhang, Q.; Cao, A.; Jiang, L.; Cheng, Q. ACS Nano 2015, 9, 11568. doi: 10.1021/acsnano.5b05252 doi: 10.1021/acsnano.5b05252
49. [49]
  Wan, S.; Li, Y.; Peng, J.; Hu, H.; Cheng, Q.; Jiang, L. ACS Nano 2015, 9, 708. doi: 10.1021/nn506148w doi: 10.1021/nn506148w
50. [50]
  Wang, J.; Cheng, Q.; Lin, L.; Jiang, L. ACS Nano 2014, 8, 2739. doi: 10.1021/nn406428n doi: 10.1021/nn406428n
51. [51]
  Wan, S.; Xu, F.; Jiang, L.; Cheng, Q. Adv. Funct. Mater. 2017, 27, 1605636. doi: 10.1002/adfm.201605636 doi: 10.1002/adfm.201605636
52. [52]
  Cheng, Q.; Wu, M.; Li, M.; Jiang, L.; Tang, Z. Angew. Chem. Int. Ed. 2013, 52, 3750. doi: 10.1002/anie.201210166 doi: 10.1002/anie.201210166
53. [53]
  Song, P.; Xu, Z.; Wu, Y.; Cheng, Q.; Guo, Q.; Wang, H. Carbon 2017, 111, 807. doi: 10.1016/j.carbon.2016.10.067 doi: 10.1016/j.carbon.2016.10.067
54. [54]
  Gong, S.; Jiang, L.; Cheng, Q. J. Mater. Chem. A 2016, 4, 17073. doi: 10.1039/c6ta06893f doi: 10.1039/c6ta06893f
55. [55]
  Gong, S.; Zhang, Q.; Wang, R.; Jiang, L.; Cheng, Q. J. Mater. Chem. A 2017, 5, 16386. doi: 10.1039/c7ta03535g doi: 10.1039/c7ta03535g
56. [56]
  Ming, P.; Song, Z.; Gong, S.; Zhang, Y.; Duan, J.; Zhang, Q.; Jiang, L.; Cheng, Q. J. Mater. Chem. A 2015, 3, 21194. doi: 10.1039/c5ta05742f doi: 10.1039/c5ta05742f
57. [57]
  Gong, S.; Wu, M.; Jiang, L.; Cheng, Q. Mater. Res. Express 2016, 3, 075002. doi: 10.1088/2053-1591/3/7/075002 doi: 10.1088/2053-1591/3/7/075002
58. [58]
  Wan, S.; Hu, H.; Peng, J.; Li, Y.; Fan, Y.; Jiang, L.; Cheng, Q. Nanoscale 2016, 8, 5649. doi: 10.1039/c6nr00562d doi: 10.1039/c6nr00562d
59. [59]
  Zhang, Q.; Wan, S.; Jiang, L.; Cheng, Q. Sci. China: Technol. Sci. 2017, 60, 758. doi: 10.1007/s11431-016-0529-3 doi: 10.1007/s11431-016-0529-3
60. [60]
  Wan, S.; Chen, Y.; Wang, Y.; Li, G.; Wang, G.; Liu, L.; Zhang, J.; Liu, Y.; Xu, Z.; Tomsia, A. P. Matter 2019, 1, 389. doi: 10.1016/j.matt.2019.04.006 doi: 10.1016/j.matt.2019.04.006
61. [61]
  Kumar, A.; Sharma, K.; Dixit, A. R. J. Mater. Sci. 2018, 54, 5992. doi: 10.1007/s10853-018-03244-3 doi: 10.1007/s10853-018-03244-3
62. [62]
  Domun, N.; Hadavinia, H.; Zhang, T.; Sainsbury, T.; Liaghat, G. H.; Vahid, S. Nanoscale 2015, 7, 10294. doi: 10.1039/c5nr01354b doi: 10.1039/c5nr01354b
63. [63]
  Chandrasekaran, S.; Sato, N.; Tölle, F.; Mülhaupt, R.; Fiedler, B.; Schulte, K. Compos. Sci. Technol. 2014, 97, 90. doi: 10.1016/j.compscitech.2014.03.014 doi: 10.1016/j.compscitech.2014.03.014
64. [64]
  Deville, S.; Saiz, E.; Nalla, R. K.; Tomsia, A. P. Science 2006, 311, 515. doi: 10.1126/science.1120937 doi: 10.1126/science.1120937
65. [65]
  Munch, E.; Launey, M. E.; Alsem, D. H.; Saiz, E.; Tomsia, A. P.; Ritchie, R. O. Science 2008, 322, 1516. doi: 10.1126/science.1164865 doi: 10.1126/science.1164865
66. [66]
  Bouville, F.; Maire, E.; Meille, S.; Van de Moortele, B.; Stevenson, A. J.; Deville, S. Nat. Mater. 2014, 13, 508. doi: 10.1038/nmat3915 doi: 10.1038/nmat3915
67. [67]
  Bai, H.; Chen, Y.; Delattre, B.; Tomsia, A. P.; Ritchie, R. O. Sci. Adv. 2015, 1, e1500849. doi: 10.1126/sciadv.1500849 doi: 10.1126/sciadv.1500849
68. [68]
  Qiu, L.; Liu, J. Z.; Chang, S. L.; Wu, Y.; Li, D. Nat. Commun. 2012, 3, 1241. doi: 10.1038/ncomms2251 doi: 10.1038/ncomms2251
69. [69]
  Gao, H. L.; Zhu, Y. B.; Mao, L. B.; Wang, F. C.; Luo, X. S.; Liu, Y. Y.; Lu, Y.; Pan, Z.; Ge, J.; Shen, W.; et al. Nat. Commun. 2016, 7, 12920. doi: 10.1038/ncomms12920 doi: 10.1038/ncomms12920
70. [70]
  Picot, O. T.; Rocha, V. G.; Ferraro, C.; Ni, N.; D'Elia, E.; Meille, S.; Chevalier, J.; Saunders, T.; Peijs, T.; Reece, M. J.; et al. Nat. Commun. 2017, 8, 14425. doi: 10.1038/ncomms14425 doi: 10.1038/ncomms14425
71. [71]
  Si, Y.; Wang, X.; Dou, L.; Yu, J.; Ding, B. Sci. Adv. 2018, 4, eaas8925. doi: 10.1126/sciadv.aas8925 doi: 10.1126/sciadv.aas8925
72. [72]
  Ferraro, C.; Garcia-Tuñon, E.; Rocha, V. G.; Barg, S.; Fariñas, M. D.; Alvarez-Arenas, T. E. G.; Sernicola, G.; Giuliani, F.; Saiz, E. Adv. Funct. Mater. 2016, 26, 1636. doi: 10.1002/adfm.201504051 doi: 10.1002/adfm.201504051
73. [73]
  Zhang, H.; Cooper, A. I. Adv. Mater. 2007, 19, 1529. doi: 10.1002/adma.200700154 doi: 10.1002/adma.200700154
74. [74]
  Riblett, B. W.; Francis, N. L.; Wheatley, M. A.; Wegst, U. G. K. Adv. Funct. Mater. 2012, 22, 4920. doi: 10.1002/adfm.201201323 doi: 10.1002/adfm.201201323
75. [75]
  Peng, J.; Huang, C.; Cao, C.; Saiz, E.; Du, Y.; Dou, S.; Tomsia, A. P.; Wagner, H. D.; Jiang, L.; Cheng, Q. Matter 2019, 2, 220. doi: 10.1016/j.matt.2019.08.013 doi: 10.1016/j.matt.2019.08.013
76. [76]
  Huang, C.; Peng, J.; Wan, S.; Du, Y.; Dou, S.; Wagner, H. D.; Tomsia, A. P.; Jiang, L.; Cheng, Q. Angew. Chem. Int. Ed. 2019, 58, 7636. doi: 10.1002/anie.201902410 doi: 10.1002/anie.201902410
77. [77]
  Huang, C.; Peng, J.; Cheng, Y.; Zhao, Q.; Du, Y.; Dou, S.; Tomsia, A. P.; Wagner, H. D.; Jiang, L.; Cheng, Q. J. Mater. Chem. A 2019, 7, 2787. doi: 10.1039/c8ta10725d doi: 10.1039/c8ta10725d
78. [78]
  Zhang, J.; Wang, L. N.; Chen, X. F.; Wang, Y. F.; Niu, C. Y.; Wu, L. X.; Tang, Z. Y. Acta Phys. -Chim. Sin. 2020, 36, 1912002. doi: 10.3866/PKU.WHXB201912002
79. [79]
  Li, K. X.; Zhang, T. L.; Li, H. Z.; Li, M. Z.; Song, Y. L. Acta Phys. -Chim. Sin. 2020, 36, 1911057. doi: 10.3866/PKU.WHXB201911057
80. [80]
  Chen, Z. L.; Gao, P.; Liu, Z. F. Acta Phys. -Chim. Sin. 2020, 36, 1907004. doi: 10.3866/PKU.WHXB201907004
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2. [2]
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  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
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沈阳化工大学材料科学与工程学院沈阳 110142