Citation: Pan Zhiming, Liu Minghui, Niu Pingping, Guo Fangsong, Fu Xianzhi, Wang Xinchen. Photocatalytic CO₂ Reduction Using Ni₂P Nanosheets[J]. Acta Physico-Chimica Sinica, ;2020, 36(1): 190601. doi: 10.3866/PKU.WHXB201906014 shu

Photocatalytic CO₂ Reduction Using Ni₂P Nanosheets

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China

Corresponding author: Wang Xinchen, xcwang@fzu.edu.cn
Received Date: 4 June 2019
Revised Date: 5 July 2019
Accepted Date: 11 July 2019
Available Online: 19 January 2019
Fund Project: the National Key Technology R&D Program of China 2018YFA0209301The project was supported by the National Key Technology R&D Program of China (2018YFA0209301), the Chang Jiang Scholars Program of China (T2016147), the National Natural Science Foundation of China (21425309, 21761132002, 21861130353) and the 111 Project, China (D16008)the Chang Jiang Scholars Program of China T2016147the National Natural Science Foundation of China 21425309the National Natural Science Foundation of China 21861130353the National Natural Science Foundation of China 21761132002111 Project, China D16008

Artificial photosynthesis is an ideal method for solar-to-chemical energy conversion, wherein solar energy is stored in the form of chemical bonds of solar fuels. In particular, the photocatalytic reduction of CO₂ has attracted considerable attention due to its dual benefits of fossil fuel production and CO₂ pollution reduction. However, CO₂ is a comparatively stable molecule and its photoreduction is thermodynamically and kinetically challenging. Thus, the photocatalytic efficiency of CO₂ reduction is far below the level of industrial applications. Therefore, development of low-cost cocatalysts is crucial for significantly decreasing the activation energy of CO₂ to achieving efficient photocatalytic CO₂ reduction. Herein, we have reported the use of a Ni₂P material that can serve as a robust cocatalyst by cooperating with a photosensitizer for the photoconversion of CO₂. An effective strategy for engineering Ni₂P in an ultrathin layered structure has been proposed to improve the CO₂ adsorption capability and decrease the CO₂ activation energy, resulting in efficient CO₂ reduction. A series of physicochemical characterizations including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and atomic force microscopy (AFM) were used to demonstrate the successful preparation of ultrathin Ni₂P nanosheets. The XRD and XPS results confirm the successful synthesis of Ni₂P from Ni(OH)₂ by a low temperature phosphidation process. According to the TEM images, the prepared Ni₂P nanosheets exhibit a 2D and near-transparent sheet-like structure, suggesting their ultrathin thickness. The AFM images further demonstrated this result and also showed that the height of the Ni₂P nanosheets is ca 1.5 nm. The photoluminescence (PL) spectroscopy results revealed that the Ni₂P material could efficiently promote the separation of the photogenerated electrons and holes in [Ru(bpy)₃]Cl₂·6H₂O. More importantly, the Ni₂P nanosheets could more efficiently promote the charge transfer and charge separation rate of [Ru(bpy)₃]Cl₂·6H₂O compared with the Ni₂P particles. In addition, the electrochemical experiments revealed that the Ni₂P nanosheets, with their high active surface area and charge conductivity, can provide more active centers for CO₂ conversion and accelerate the interfacial reaction dynamics. These results strongly suggest that the Ni₂P nanosheets are a promising material for photocatalytic CO₂ reduction, and can achieve a CO generation rate of 64.8 μmol·h^-1, which is 4.4 times higher than that of the Ni₂P particles. In addition, the XRD and XPS measurements of the used Ni₂P nanosheets after the six cycles of the photocatalytic CO₂ reduction reaction demonstrated their high stability. Overall, this study offers a new function for the 2D transition-metal phosphide catalysts in photocatalytic CO₂ reduction.
- Photocatalysis,
- Nanosheet,
- Ni₂P,
- CO₂ reduction,
- CO
1. [1]
  Asadi, M.; Kim, K.; Liu, C.; Addepalli, A. V.; Abbasi, P.; Yasaei, P.; Phillips, P.; Behranginia, A.; Cerrato, J. M.; Haasch, R.; et al. Science 2016, 353, 467. doi: 10.1126/science.aaf4767 doi: 10.1126/science.aaf4767
2. [2]
  Wang, S.; Wang, X. Angew. Chem. Int. Ed. 2016, 55, 2308. doi: 10.1002/anie.201507145 doi: 10.1002/anie.201507145
3. [3]
  Qin, J.; Wang, S.; Ren, H.; Hou, Y.; Wang, X. Appl. Catal. B 2015, 179, 1. doi: 10.1016/j.apcatb.2015.05.005 doi: 10.1016/j.apcatb.2015.05.005
4. [4]
  Wang, Y.; Zhang, Z.; Zhang, L.; Luo, Z.; Shen, J.; Lin, H.; Long, J.; Wu, J. C. S.; Fu, X.; Wang, X.; et al. J. Am. Chem. Soc. 2018, 140, 14595. doi: 10.1021/jacs.8b09344 doi: 10.1021/jacs.8b09344
5. [5]
  Pan, Z.; Zheng, Y.; Guo, F.; Niu, P.; Wang, X. ChemSusChem 2017, 10, 87. doi: 10.1002/cssc.201600850 doi: 10.1002/cssc.201600850
6. [6]
  Liang, F.; Lindberg, P.; Lindblad, P. Sustain. Energy Fuels 2018, 2, 2583. doi: 10.1039/C8SE00281A doi: 10.1039/C8SE00281A
7. [7]
  Pan, Z.; Zhang, G.; Wang, X. Angew. Chem. Int. Ed. 2019, 58, 7102, 7102. doi: 10.1002/anie.201902634
8. [8]
  Lan, Z. A.; Wang, X. C. Acta Phys. -Chim. Sin. 2017, 33, 457. doi: 10.3866/PKU.WHXB201701061
9. [9]
  Kuriki, R.; Sekizawa, K.; Ishitani, O.; Maeda, K. Angew. Chem. Int. Ed. 2015, 54, 2406. doi: 10.1002/anie.201411170 doi: 10.1002/anie.201411170
10. [10]
  Wu, L. Y.; Mu, Y. F.; Guo, X. X.; Zhang, W.; Zhang, Z. M.; Zhang, M.; Lu, T. B. Angew. Chem. Int. Ed. 2019, 58, 9491. doi: 10.1002/anie.201904537 doi: 10.1002/anie.201904537
11. [11]
  Zhai, Q.; Xie, S.; Fan, W.; Zhang, Q.; Wang, Y.; Deng, W.; Wang, Y. Angew. Chem. Int. Ed. 2013, 52, 5776. doi: 10.1002/anie.201301473 doi: 10.1002/anie.201301473
12. [12]
  Shown, I.; Samireddi, S.; Chang, Y. C.; Putikam, R.; Chang, P. H.; Sabbah, A.; Fu, F. Y.; Chen, W. F.; Wu, C. I.; Yu, T. Y.; et al. Nat. Commun. 2018, 9, 169. doi: 10.1038/s41467-017-02547-4 doi: 10.1038/s41467-017-02547-4
13. [13]
  Qin, J.; Wang, S.; Wang, X. Appl. Catal. B 2017, 209, 476. doi: 10.1016/j.apcatb.2017.03.018 doi: 10.1016/j.apcatb.2017.03.018
14. [14]
  Kuriki, R.; Matsunaga, H.; Nakashima, T.; Wada, K.; Yamakata, A.; Ishitani, O.; Maeda, K. J. Am. Chem. Soc. 2016, 138, 5159. doi: 10.1021/jacs.6b01997 doi: 10.1021/jacs.6b01997
15. [15]
  Kang, Q.; Wang, T.; Li, P.; Liu, L.; Chang, K.; Li, M.; Ye, J. Angew. Chem. 2015, 127, 855. doi: 10.1002/ange.201409183 doi: 10.1002/ange.201409183
16. [16]
  Cometto, C.; Kuriki, R.; Chen, L.; Maeda, K.; Lau, T. C.; Ishitani, O.; Robert, M. J. Am. Chem. Soc. 2018, 140, 7437. doi: 10.1021/jacs.8b04007 doi: 10.1021/jacs.8b04007
17. [17]
  Pei, Z.; Li, H.; Huang, Y.; Xue, Q.; Huang, Y.; Zhu, M.; Wang, Z.; Zhi, C. Energy Environ. Sci. 2017, 10, 742. doi: 10.1039/C6EE03265F doi: 10.1039/C6EE03265F
18. [18]
  Wang, S.; Guan, B. Y.; Lou, X. W. Energy Environ. Sci. 2018, 11, 306. doi: 10.1039/C7EE02934A doi: 10.1039/C7EE02934A
19. [19]
  Zheng, Y.; Lin, L.; Ye, X.; Guo, F.; Wang, X. Angew. Chem. Int. Ed. 2014, 53, 11926. doi: 10.1002/anie.201407319 doi: 10.1002/anie.201407319
20. [20]
  Wang, S.; Wang, X. Appl. Catal. B 2015, 162, 494. doi: 10.1016/j.apcatb.2014.07.026 doi: 10.1016/j.apcatb.2014.07.026
21. [21]
  Kuriki, R.; Yamamoto, M.; Higuchi, K.; Yamamoto, Y.; Akatsuka, M.; Lu, D.; Yagi, S.; Yoshida, T.; Ishitani, O.; Maeda, K. Angew. Chem. Int. Ed. 2017, 56, 4867. doi: 10.1002/anie.201701627 doi: 10.1002/anie.201701627
22. [22]
  Ouyang, T.; Wang, H. J.; Huang, H. H.; Wang, J. W.; Guo, S.; Liu, W. J.; Zhong, D. C.; Lu, T. B. Angew. Chem. Int. Ed. 2018, 57, 16480. doi: 10.1002/anie.201811010 doi: 10.1002/anie.201811010
23. [23]
  Ouyang, T.; Huang, H. H.; Wang, J. W.; Zhong, D. C.; Lu, T. B. Angew. Chem. Int. Ed. 2017, 56, 738. doi: 10.1002/anie.201610607 doi: 10.1002/anie.201610607
24. [24]
  Wang, S.; Wang, X. Angew. Chem. Int. Ed. 2015, 55, 2308. doi: 10.1002/anie.201507145 doi: 10.1002/anie.201507145
25. [25]
  Fu, J.; Zhu, B.; Jiang, C.; Cheng, B.; You, W.; Yu, J. Small 2017, 13, 1603938. doi: 10.1002/smll.201603938 doi: 10.1002/smll.201603938
26. [26]
  Apaydin, D. H.; Portenkirchner, E.; Jintanalert, P.; Strauss, M.; Luangchaiyaporn, J.; Sariciftci, N. S.; Thamyongkit, P. Sustain. Energy Fuels 2018, 2, 2747. doi: 10.1039/C8SE00422F doi: 10.1039/C8SE00422F
27. [27]
  Yang, Y.; Ajmal, S.; Zheng, X.; Zhang, L. Sustain. Energy Fuels 2018, 2, 510. doi: 10.1039/C7SE00371D doi: 10.1039/C7SE00371D
28. [28]
  Carenco, S.; Portehault, D.; Boissière, C.; Mézailles, N.; Sanchez, C. Adv. Mater. 2014, 26, 371. doi: 10.1002/adma.201303198 doi: 10.1002/adma.201303198
29. [29]
  Shi, Y.; Zhang, B. Chem. Soc. Rev. 2016, 45, 1529. doi: 10.1039/C5CS00434A doi: 10.1039/C5CS00434A
30. [30]
  Liu, Q.; Tian, J.; Cui, W.; Jiang, P.; Cheng, N.; Asiri, A. M.; Sun, X. Angew. Chem. 2014, 126, 6828. doi: 10.1002/ange.201404161 doi: 10.1002/ange.201404161
31. [31]
  Tian, J.; Liu, Q.; Asiri, A. M.; Sun, X. J. Am. Chem. Soc. 2014, 136, 7587. doi: 10.1021/ja503372r doi: 10.1021/ja503372r
32. [32]
  Li, D.; Baydoun, H.; Verani, C. N.; Brock, S. L. J. Am. Chem. Soc. 2016, 138, 4006. doi: 10.1021/jacs.6b01543 doi: 10.1021/jacs.6b01543
33. [33]
  Yu, X. Y.; Feng, Y.; Guan, B.; Lou, X. W.; Paik, U. Energy Environ. Sci. 2016, 9, 1246. doi: 10.1039/C6EE00100A doi: 10.1039/C6EE00100A
34. [34]
  Stern, L. A.; Feng, L.; Song, F.; Hu, X. Energy Environ. Sci. 2015, 8, 2347. doi: 10.1039/C5EE01155H doi: 10.1039/C5EE01155H
35. [35]
  Pan, Z.; Niu, P.; Hou, Y.; Fang, Y.; Liu, M.; Wang, X. ChemSusChem 2019, 12, 1911. doi: 10.1002/cssc.201801691 doi: 10.1002/cssc.201801691
36. [36]
  Indra, A.; Acharjya, A.; Menezes, P. W.; Merschjann, C.; Hollmann, D.; Schwarze, M.; Aktas, M.; Friedrich, A.; Lochbrunner, S.; Thomas, A.; et al. Angew. Chem. Int. Ed. 2017, 56, 1653. doi: 10.1002/anie.201611605 doi: 10.1002/anie.201611605
37. [37]
  Sun, Z.; Zheng, H.; Li, J.; Du, P. Energy Environ. Sci. 2015, 8, 2668. doi: 10.1039/C5EE01310K doi: 10.1039/C5EE01310K
38. [38]
  Sun, X.; Lu, L.; Zhu, Q.; Wu, C.; Yang, D.; Chen, C.; Han, B. Angew. Chem. Int. Ed. 2018, 57, 2427. doi: 10.1002/anie.201712221 doi: 10.1002/anie.201712221
39. [39]
  Calvinho, K. U. D.; Laursen, A. B.; Yap, K. M. K.; Goetjen, T. A.; Hwang, S.; Murali, N.; Mejia-Sosa, B.; Lubarski, A.; Teeluck, K. M.; Hall, E. S.; et al. Energy Environ. Sci. 2018, 11, 2550. doi: 10.1039/C8EE00936H doi: 10.1039/C8EE00936H
40. [40]
  Fu, Z. C.; Xu, R. C.; Moore, J. T.; Liang, F.; Nie, X. C.; Mi, C.; Mo, J.; Xu, Y.; Xu, Q. Q.; Yang, Z.; et al. Chem. Eur. J. 2018, 24, 4273. doi: 10.1002/chem.201800335 doi: 10.1002/chem.201800335
41. [41]
  Wang, S.; Guan, B. Y.; Lu, Y.; Lou, X. W. D. J. Am. Chem. Soc. 2017, 139, 17305. doi: 10.1021/jacs.7b10733 doi: 10.1021/jacs.7b10733
42. [42]
  Wang, S.; Guan, B. Y.; Lou, X. W. D. J. Am. Chem. Soc. 2018, 140, 5037. doi: 10.1021/jacs.8b02200 doi: 10.1021/jacs.8b02200
43. [43]
  Chen, Y.; Jia, G.; Hu, Y.; Fan, G.; Tsang, Y. H.; Li, Z.; Zou, Z. Sustain. Energy Fuels 2017, 1, 1875. doi: 10.1039/C7SE00344G doi: 10.1039/C7SE00344G
44. [44]
  Li, F.; Chen, L.; Knowles, G. P.; MacFarlane, D. R.; Zhang, J. Angew. Chem. Int. Ed. 2017, 56, 505. doi: 10.1002/anie.201608279 doi: 10.1002/anie.201608279
45. [45]
  Tu, W.; Zhou, Y.; Liu, Q.; Tian, Z.; Gao, J.; Chen, X.; Zhang, H.; Liu, J.; Zou, Z. Adv. Funct. Mater. 2012, 22, 1215. doi: 10.1002/adfm.201102566 doi: 10.1002/adfm.201102566
46. [46]
  Cao, S.; Shen, B.; Tong, T.; Fu, J.; Yu, J. Adv. Funct. Mater. 2018, 28, 1800136. doi: 10.1002/adfm.201800136 doi: 10.1002/adfm.201800136
47. [47]
  Ou, H.; Lin, L.; Zheng, Y.; Yang, P.; Fang, Y.; Wang, X. Adv. Mater. 2017, 29, 1700008. doi: 10.1002/adma.201700008 doi: 10.1002/adma.201700008
48. [48]
  Pu, Z.; Wei, S.; Chen, Z.; Mu, S. Appl. Catal. B 2016, 196, 193. doi: 10.1016/j.apcatb.2016.05.027 doi: 10.1016/j.apcatb.2016.05.027
49. [49]
  Gao, C.; Meng, Q.; Zhao, K.; Yin, H.; Wang, D.; Guo, J.; Zhao, S.; Chang, L.; He, M.; Li, Q.; et al. Adv. Mater. 2016, 28, 6485. doi: 10.1002/adma.201601387 doi: 10.1002/adma.201601387
50. [50]
  Jiang, J.; Zhao, K.; Xiao, X.; Zhang, L. J. Am. Chem. Soc. 2012, 134, 4473. doi: 10.1021/ja210484t doi: 10.1021/ja210484t
51. [51]
  Yu, J.; Low, J.; Xiao, W.; Zhou, P.; Jaroniec, M. J. Am. Chem. Soc. 2014, 136, 8839. doi: 10.1021/ja5044787 doi: 10.1021/ja5044787
52. [52]
  Jia, J.; Qian, C.; Dong, Y.; Li, Y. F.; Wang, H.; Ghoussoub, M.; Butler, K. T.; Walsh, A.; Ozin, G. A. Chem. Soc. Rev. 2017, 46, 4631. doi: 10.1039/C7CS00026J doi: 10.1039/C7CS00026J
53. [53]
  Li, F.; Xue, M.; Li, J.; Ma, X.; Chen, L.; Zhang, X.; MacFarlane, D. R.; Jie, Z. Angew. Chem. Int. Ed. 2017, 56, 14718. doi: 10.1002/anie.201710038 doi: 10.1002/anie.201710038
54. [54]
  Zhao, Y.; Chen, G.; Bian, T.; Zhou, C.; Waterhouse, G. I. N.; Wu, L. Z.; Tung, C. H.; Smith, L. J.; O'Hare, D.; Zhang, T. Adv. Mater. 2015, 27, 7824. doi: 10.1002/adma.201503730 doi: 10.1002/adma.201503730
55. [55]
  Yao, T.; Liu, L.; Xiao, C.; Zhang, X.; Liu, Q.; Wei, S.; Xie, Y. Angew. Chem. Int. Ed. 2013, 52, 7554. doi: 10.1002/anie.201302891 doi: 10.1002/anie.201302891
56. [56]
  Popczun, E. J.; McKone, J. R.; Read, C. G.; Biacchi, A. J.; Wiltrout, A. M.; Lewis, N. S.; Schaak, R. E. J. Am. Chem. Soc. 2013, 135, 9267. doi: 10.1021/ja403440e doi: 10.1021/ja403440e
57. [57]
  Tang, C.; Zhang, R.; Lu, W.; Wang, Z.; Liu, D.; Hao, S; Du, G.; Asiri, A.M.; Sun, X. Angew. Chem. Int. Ed. 2017, 56, 842. doi: 10.1002/anie.201608899 doi: 10.1002/anie.201608899
58. [58]
  Bai, Y.; Zhang, H.; Li, X.; Liu, L.; Xu, H.; Qiu, H.; Wang, Y. Nanoscale 2015, 7, 1446. doi: 10.1039/C4NR05862C doi: 10.1039/C4NR05862C
59. [59]
  Wang, S.; Wang, X. Appl. Catal. B 2015, 162, 494. doi: 10.1016/j.apcatb.2014.07.026 doi: 10.1016/j.apcatb.2014.07.026
60. [60]
  Chen, Y.; Wang, B.; Lin, S.; Zhang, Y.; Wang, X. J. Phys. Chem. C 2014, 118, 29981. doi: 10.1021/jp510187c doi: 10.1021/jp510187c
61. [61]
  Wang, S.; Hou, Y.; Wang, X. ACS Appl. Mater. Interfaces 2015, 7, 4327. doi: 10.1021/am508766s doi: 10.1021/am508766s
1. [1]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
2. [2]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
3. [3]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
4. [4]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
5. [5]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
6. [6]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
7. [7]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
8. [8]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
9. [9]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
10. [10]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
11. [11]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
12. [12]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
13. [13]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
14. [14]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
15. [15]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
16. [16]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
17. [17]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
18. [18]
  Hao Lv , Zhi Li , Peng Yin , Ping Wan , Mingshan Zhu . Recent progress on non-metallic carbon nitride for the photosynthesis of H₂O₂: Mechanism, modification and in-situ applications. Chinese Chemical Letters, 2025, 36(1): 110457-. doi: 10.1016/j.cclet.2024.110457
19. [19]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
20. [20]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(387)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic CO2 Reduction Using Ni2P Nanosheets

Metrics

通讯作者: 陈斌, bchen63@163.com

Photocatalytic CO₂ Reduction Using Ni₂P Nanosheets