Citation: Sun Shangcong, Zhang Xuya, Liu Xianlong, Pan Lun, Zhang Xiangwen, Zou Jijun. Design and Construction of Cocatalysts for Photocatalytic Water Splitting[J]. Acta Physico-Chimica Sinica, ;2020, 36(3): 190500. doi: 10.3866/PKU.WHXB201905007 shu

Design and Construction of Cocatalysts for Photocatalytic Water Splitting

Sun Shangcong ^1,2,† ,
Zhang Xuya ^1,2,† ,
Liu Xianlong ¹ ,
Pan Lun ^1,2 ,
Zhang Xiangwen ^1,2 ,
Zou Jijun ^1,2,,

1.
Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China
2.
Collaborative Innovative Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China

Corresponding author: Zou Jijun, jj_zou@tju.edu.cn
Received Date: 2 May 2019
Revised Date: 25 May 2019
Accepted Date: 3 June 2019
Available Online: 5 March 2019
Fund Project: The project was supported by National Natural Science Foundation of China 21506156The project was supported by National Natural Science Foundation of China (21676193, 51661145026, 21506156)The project was supported by National Natural Science Foundation of China 21676193The project was supported by National Natural Science Foundation of China 51661145026

Converting solar light into chemical energy is currently a hot topic for addressing the worldwide energy and environmental crises. However, the utilization of solar energy greatly suffers from its low energy flow density and discontinuous space-time distribution, which are essential for a reasonable energy conversion strategy toward effective storage and utilization. To this end, photocatalytic water splitting is a promising method for utilizing solar light to produce environmentally friendly hydrogen energy; yet, the efficiency needs to be improved. Generally, such processes can be divided into three elementary steps: light absorption, charge separation and migration, and surface redox reaction. The overall performance is determined by the cumulative efficiencies of the above three steps. The construction of cocatalysts is among the extensive efforts taken to improve the solar conversion efficiency. First, the cocatalysts possess higher work function than the semiconductors, and the photogenerated electrons migrate from semiconductor to cocatalysts, thereby promoting the charge separation. Second, cocatalysts usually lower the activation energy and provide abundant surface reactive sites. Particularly, the addition of cocatalysts can remarkably accelerate the four-electron transfer O₂ evolution kinetics, which usually requires much higher overpotential and is often considered as the bottleneck for water splitting. Third, cocatalysts can timely remove the photogenerated charges from the surface of the semiconductor and subsequently inhibit the photocorrosion and improve the stability of the photocatalysts. Moreover, the cocatalysts also retard the backward recombination of H₂ and O₂. In general, cocatalysts for water splitting can be classified into three categories: H₂ evolution cocatalysts, O₂ evolution cocatalysts, and dual cocatalysts. The H₂ evolution cocatalysts mainly contain noble metals such as Pt, Au, and other transition metals such as Co, Ni, and Cu and their phosphides or sulfides, which are capable of trapping electrons and promoting proton reduction. The O₂ evolution cocatalysts are often noble metal oxides and transition metal (hydro)oxides and corresponding phosphates, which are always efficient in adsorbing and dissociating water molecules. To realize the overall water splitting, H₂ evolution cocatalysts and O₂ evolution cocatalysts are often integrated on one photocatalyst, which results in the so-called dual cocatalyst system. Furthermore, the performance of cocatalysts can be improved by modulating the loading amount, morphology, particle size, etc. In addition, composites such as Pt/Ni(OH)₂ cocatalyst can not only provide both H₂ and O₂ evolution sites but also accelerate the intrinsic surface redox kinetics by promoting H₂O activation, thus being much more active than the conventional dual cocatalyst system. This review summarizes the important role and design principle of cocatalysts in photocatalytic systems. The construction and functional mechanism of H₂ evolution cocatalyst, O₂ evolution cocatalyst, and dual cocatalysts in overall water splitting photocatalysts are discussed in detail, and the design strategy of new cocatalysts toward water activation is proposed.
- Photocatalytic water splitting,
- Cocatalyst,
- Charge separation,
- Water molecular activation
1. [1]
  Fu, C. F.; Wu, X. J.; Yang, J. L. Adv. Mater. 2018, 30, 1802106. doi: 10.1002/adma.201802106 doi: 10.1002/adma.201802106
2. [2]
  Wu, W.; Jiang, C. Z.; Roy, V. A. L. Nanoscale 2015, 7, 38. doi: 10.1039/c4nr04244a doi: 10.1039/c4nr04244a
3. [3]
  Kong, D.; Zheng, Y.; Kobielusz, M.; Wang, Y.; Bai, Z.; Macyk, W.; Wang, X.; Tang, J. Mater. Today 2018, 21, 897. doi: 10.1016/j.mattod.2018.04.009 doi: 10.1016/j.mattod.2018.04.009
4. [4]
  Zhou, P.; Yu, J. G.; Jaroniec, M. Adv. Mater. 2014, 26, 4920. doi: 10.1002/chin.201439243 doi: 10.1002/chin.201439243
5. [5]
  Maeda, K. J. Photochem. Photobiol. C 2011, 12, 237. doi: 10.1016/j.jphotochemrev.2011.07.001 doi: 10.1016/j.jphotochemrev.2011.07.001
6. [6]
  Chen, X. B.; Shen, S. H.; Guo, L. J.; Mao, S. S. Chem. Rev. 2010, 110, 6503. doi: 10.1021/cr1001645 doi: 10.1021/cr1001645
7. [7]
  Marzo, L.; Pagire, S. K.; Reiser, O.; Konig, B. Angew. Chem. Int. Ed. 2018, 57, 10034. doi: 10.1002/anie.201709766 doi: 10.1002/anie.201709766
8. [8]
  Inoue, Y. Energy Environ. Sci. 2009, 2, 364. doi: 10.1039/b816677n doi: 10.1039/b816677n
9. [9]
  Wang, Z.; Li, C.; Domen, K. Chem. Soc. Rev. 2019, 48, 2109. doi: 10.1039/c8cs00542g doi: 10.1039/c8cs00542g
10. [10]
  Wu, L. Z.; Chen, B.; Li, Z. J.; Tung, C. H. Acc. Chem. Res. 2014, 47, 2177. doi: 10.1021/ar500140r doi: 10.1021/ar500140r
11. [11]
  Gong, C.; Xiang, S. W.; Zhang, Z. Y.; Sun, L.; Ye, C. Q.; Lin, C. J. Acta Phys. -Chim. Sin. 2019, 35, 616. doi: 10.3866/PKU.WHXB201805082
12. [12]
  Huang, Z. F.; Zou, J.-J.; Pan, L.; Wang, S. B.; Zhang, X. W.; Wang, L. Appl. Catal. B: Environ. 2014, 147, 167. doi: 10.1016/j.apcatb.2013.08.038 doi: 10.1016/j.apcatb.2013.08.038
13. [13]
  Pan, L.; Zou, J. -J.; Zhang, X. W.; Wang, L. J. Am. Chem. Soc. 2011, 133, 10000. doi: 10.1021/ja2035927 doi: 10.1021/ja2035927
14. [14]
  Huang, Z. F.; Song, J. -J.; Pan, L.; Wang, Z. M.; Zhang, X. Q.; Zou, J. -J.; Mi, W. B.; Zhang, X. W.; Wang, L. Nano Energy 2015, 12, 646. doi: 10.1016/j.nanoen.2015.01.043 doi: 10.1016/j.nanoen.2015.01.043
15. [15]
  Tong, H.; Ouyang, S. X.; Bi, Y. P.; Umezawa, N.; Oshikiri, M.; Ye, J. H. Adv. Mater. 2012, 24, 229. doi: 10.1002/adma.201102752 doi: 10.1002/adma.201102752
16. [16]
  Low, J. X.; Jiang, C.; Cheng, B.; Wageh, S.; Al-Ghamdi, A. A.; Yu, J. G. Small Methods 2017, 1, 1700080. doi: 10.1002/smtd.201700080 doi: 10.1002/smtd.201700080
17. [17]
  Fan, K.; Jin, Z. L.; Yang, H.; Liu, D. D.; Hu, H. Y.; Bi, Y. P. Sci. Rep. 2017, 7, 7710. doi: 10.1038/s41598-017-08163-y doi: 10.1038/s41598-017-08163-y
18. [18]
  Hisatomi, T.; Kubota, J.; Domen, K. Chem. Soc. Rev. 2014, 43, 7520. doi: 10.1039/c3cs60378d doi: 10.1039/c3cs60378d
19. [19]
  Wang, H. L.; Zhang, L. S.; Chen, Z. G.; Hu, J. Q.; Li, S. J.; Wang, Z. H.; Liu, J. S.; Wang, X. C. Chem. Soc. Rev. 2014, 43, 5234. doi: 10.1039/c4cs00126e doi: 10.1039/c4cs00126e
20. [20]
  Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0 doi: 10.1038/238037a0
21. [21]
  Li, X.; Yu, J. G.; Low, J. X.; Fang, Y. P.; Xiao, J.; Chen, X. B. J. Mater. Chem. A 2015, 3, 2485. doi: 10.1039/c4ta04461d doi: 10.1039/c4ta04461d
22. [22]
  Moniz, S. J. A.; Shevlin, S. A.; Martin, D. J.; Guo, Z. X.; Tang, J. W. Energy Environ. Sci. 2015, 8, 731. doi: 10.1039/c4ee03271c doi: 10.1039/c4ee03271c
23. [23]
  Low, J. X.; Yu, J. G.; Jaroniec, M.; Wageh, S.; Al-Ghamdi, A. A. Adv. Mater. 2017, 29, 1601694. doi: 10.1002/adma.201601694 doi: 10.1002/adma.201601694
24. [24]
  Huang, J. H.; Shang, Q. C.; Huang, Y. Y.; Tang, F. M.; Zhang, Q.; Liu, Q. H.; Jiang, S.; Hu, F. C.; Liu, W.; Luo, Y.; et al. Angew. Chem. Int. Ed. 2016, 55, 2137. doi: 10.1002/anie.201510642
25. [25]
  Gao, Y. J.; Li, X. B.; Wu, H. L.; Meng, S. L.; Fan, X. B.; Huang, M. Y.; Guo, Q.; Tung, C. H.; Wu, L. Z. Adv. Funct. Mater. 2018, 28, 1801769. doi: 10.1002/adfm.201801769 doi: 10.1002/adfm.201801769
26. [26]
  Martin, D. J.; Qiu, K. P.; Shevlin, S. A.; Handoko, A. D.; Chen, X. W.; Guo, Z. X.; Tang, J. W. Angew. Chem. Int. Ed. 2014, 53, 9240. doi: 10.1002/anie.201403375 doi: 10.1002/anie.201403375
27. [27]
  Shi, R.; Ye, H. F.; Liang, F.; Wang, Z.; Li, K.; Weng, Y. X.; Lin, Z. S.; Fu, W. F.; Che, C. M.; Chen, Y. Adv. Mater. 2017, 30, 1705941. doi: 10.1002/adma.201705941 doi: 10.1002/adma.201705941
28. [28]
  Ning, X. F.; Zhen, W. L.; Wu, Y. Q.; Lu, G. X. Appl. Catal. B: Environ. 2018, 226, 373. doi: 10.1016/j.apcatb.2017.12.067 doi: 10.1016/j.apcatb.2017.12.067
29. [29]
  Wang, M.; Zhen, W. L.; Tian, B.; Ma, J. T.; Lu, G. X. Appl. Catal. B: Environ. 2018, 236, 240. doi: 10.1016/j.apcatb.2018.05.031 doi: 10.1016/j.apcatb.2018.05.031
30. [30]
  Li, Y. H.; Xing, J.; Chen, Z. J.; Li, Z.; Tian, F.; Zheng, L. R.; Wang, H. F.; Hu, P.; Zhao, H. J.; Yang, H. G. Nat. Commun. 2013, 4, 2500. doi: 10.1038/ncomms3500 doi: 10.1038/ncomms3500
31. [31]
  Chen, S. S.; Takata, T.; Domen, K. Nat. Rev. Mater. 2017, 2, 17050. doi: 10.1038/natrevmats.2017.50 doi: 10.1038/natrevmats.2017.50
32. [32]
  Qi, J.; Zhang, W.; Cao, R. Adv. Energy Mater. 2018, 8, 1701620. doi: 10.1002/aenm.201701620 doi: 10.1002/aenm.201701620
33. [33]
  Xu, X. T.; Pan, L.; Zhang, X. W.; Wang, L.; Zou, J.-J. Adv. Sci. 2019, 6, 1801505. doi: 10.1002/advs.201801505 doi: 10.1002/advs.201801505
34. [34]
  Yang, J. H.; Wang, D. G.; Han, H. X.; Li, C. Acc. Chem. Res. 2013, 46, 1900. doi: 10.1021/ar300227e doi: 10.1021/ar300227e
35. [35]
  Al Azri, Z. H. N.; Al-Oufi, M.; Chan, A.; Waterhouse, G. I. N.; Idriss, H. ACS Catal. 2019, 9, 3946. doi: 10.1021/acscatal.8b05070 doi: 10.1021/acscatal.8b05070
36. [36]
  Lu, X.; Han, Y.; Lu, T. Acta Phys. -Chim. Sin. 2018, 34, 1014. doi: 10.3866/PKU.WHXB201801171
37. [37]
  Zhang, Z.; Yates, J. T. Chem. Rev. 2012, 112, 5520. doi: 10.1021/cr3000626 doi: 10.1021/cr3000626
38. [38]
  Zhang, G. G.; Lan, Z. A.; Wang, X. C. Chem. Sci. 2017, 8, 5261. doi: 10.1039/c7sc01747b doi: 10.1039/c7sc01747b
39. [39]
  Guan, J. Q.; Duan, Z. Y.; Zhang, F. X.; Kelly, S. D.; Si, R.; Dupuis, M.; Huang, Q. G.; Chen, J. Q.; Tang, C. H.; Li, C. Nat. Catal. 2018, 1, 870. doi: 10.1038/s41929-018-0158-6 doi: 10.1038/s41929-018-0158-6
40. [40]
  Ran, J. R.; Zhang, J.; Yu, J. G.; Jaroniec, M.; Qiao, S. Z. Chem. Soc. Rev. 2014, 43, 7787. doi: 10.1039/c3cs60425j doi: 10.1039/c3cs60425j
41. [41]
  Subbaraman, R.; Tripkovic, D.; Strmcnik, D.; Chang, K. C.; Uchimura, M.; Paulikas, A. P.; Stamenkovic, V.; Markovic, N. M. Science 2011, 334, 1256. doi: 10.1126/science.1211934 doi: 10.1126/science.1211934
42. [42]
  Wang, L.; Zhu, Y. H.; Zeng, Z. H.; Lin, C.; Giroux, M.; Jiang, L.; Han, Y.; Greeley, J.; Wang, C.; Jin, J. Nano Energy 2017, 31, 456. doi: 10.1016/j.nanoen.2016.11.048 doi: 10.1016/j.nanoen.2016.11.048
43. [43]
  Tahir, M.; Pan, L.; Idrees, F.; Zhang, X. W.; Wang, L.; Zou, J. -J.; Wang, Z. L. Nano Energy 2017, 37, 136. doi: 10.1016/j.nanoen.2017.05.022 doi: 10.1016/j.nanoen.2017.05.022
44. [44]
  Mahmood, N.; Yao, Y. D.; Zhang, J. W.; Pan, L.; Zhang, X. W.; Zou, J. -J. Adv. Sci. 2018, 5, 1700464. doi: 10.1002/advs.201700464 doi: 10.1002/advs.201700464
45. [45]
  Huang, Z. F.; Song, J. J.; Li, K.; Tahir, M.; Wang, Y. T.; Pan, L.; Wang, L.; Zhang, X. W.; Zou, J. -J. J. Am. Chem. Soc. 2016, 138, 1359. doi: 10.1021/jacs.5b11986 doi: 10.1021/jacs.5b11986
46. [46]
  Zhang, R. R.; Zhang, Y. C.; Pan, L.; Shen, G. Q.; Mahmood, N.; Ma, Y. H.; Shi, Y.; Jia, W. Y.; Wang, L.; Zhang, X. W.; et al. ACS Catal. 2018, 8, 3803. doi: 10.1021/acscatal.8b01046
47. [47]
  Lin, Z.; Shen, L. F.; Qu, X. M.; Zhang, J. M.; Jiang, Y. X.; Sun, S. G. Acta Phys. -Chim. Sin. 2019, 35, 523. doi: 10.3866/PKU.WHXB201806191
48. [48]
  Luo, P.; Sun, F.; Deng, J.; Xu, H. T.; Zhang, H. J.; Wang, Y. Acta Phys. -Chim. Sin. 2018, 34, 1397. doi: 10.3866/PKU.WHXB201804022
49. [49]
  Han, G. Q.; Jin, Y. H.; Burgess, R. A.; Dickenson, N. E.; Cao, X. M.; Sun, Y. J. J. Am. Chem. Soc. 2017, 139, 15584. doi: 10.1021/jacs.7b08657 doi: 10.1021/jacs.7b08657
50. [50]
  Zhao, Q.; Sun, J.; Li, S. C.; Huang, C. P.; Yao, W. F.; Chen, W.; Zeng, T.; Wu, Q.; Xu, Q. J. ACS Catal. 2018, 8, 11863. doi: 10.1021/acscatal.8b03737 doi: 10.1021/acscatal.8b03737
51. [51]
  Zhang, K.; Ran, J. R.; Zhu, B. C.; Ju, H. X.; Yu, J. G.; Song, L.; Qiao, S. Z. Small 2018, 14, 1801705. doi: 10.1002/smll.201801705 doi: 10.1002/smll.201801705
52. [52]
  Lin, H. Y.; Yang, H. C.; Wang, W. L. Catal. Today 2011, 174, 106. doi: 10.1016/j.cattod.2011.01.052 doi: 10.1016/j.cattod.2011.01.052
53. [53]
  Liu, J. N.; Jia, Q. H.; Long, J. L.; Wang, X. X.; Gao, Z. W.; Gu, Q. Appl. Catal. B: Environ. 2018, 222, 35. doi: 10.1016/j.apcatb.2017.09.073 doi: 10.1016/j.apcatb.2017.09.073
54. [54]
  Xu, Y.; Gong, Y. Y.; Ren, H.; Liu, W. B.; Li, C.; Liu, X. J.; Niu, L. Y. J. Alloys Compd. 2017, 735, 2551. doi: 10.1016/j.jallcom.2017.11.388 doi: 10.1016/j.jallcom.2017.11.388
55. [55]
  Foo, W. J.; Zhang, C.; Ho, G. W. Nanoscale 2013, 5, 759. doi: 10.1039/c2nr33004k doi: 10.1039/c2nr33004k
56. [56]
  Wang, X. J.; Tian, X.; Sun, Y. J.; Zhu, J. Y.; Li, F. T.; Mu, H. Y.; Zhao, J. Nanoscale 2018, 10, 12315. doi: 10.1039/c8nr03846e doi: 10.1039/c8nr03846e
57. [57]
  Wang, P. F.; Zhan, S. H.; Wang, H. T.; Xia, Y. G.; Hou, Q. L.; Zhou, Q. X.; Li, Y.; Kumar, R. R. Appl. Catal. B: Environ. 2018, 230, 210. doi: 10.1016/j.apcatb.2018.02.043 doi: 10.1016/j.apcatb.2018.02.043
58. [58]
  Chen, Y. B.; Qin, Z. X. Catal. Sci. Technol. 2016, 6, 8212. doi: 10.1039/c6cy01653g doi: 10.1039/c6cy01653g
59. [59]
  Indra, A.; Acharjya, A.; Menezes, P. W.; Merschjann, C.; Hollmann, D.; Schwarze, M.; Aktas, M.; Friedrich, A.; Lochbrunner, S.; Thomas, A.; et al. Angew. Chem. Int. Ed. 2017, 56, 1653. doi: 10.1002/anie.201611605
60. [60]
  Kumar, D. P.; Choi, J.; Hong, S.; Reddy, D. A.; Lee, S.; Kim, T. K. ACS Sustain. Chem. Eng. 2016, 4, 7158. doi: 10.1021/acssuschemeng.6b02032 doi: 10.1021/acssuschemeng.6b02032
61. [61]
  Yin, L. S.; Hai, X.; Chang, K.; Ichihara, F.; Ye, J. H. Small 2018, 14, 1704153. doi: 10.1002/smll.201704153 doi: 10.1002/smll.201704153
62. [62]
  Garcia-Esparza, A. T.; Cha, D.; Ou, Y. W.; Kubota, J.; Domen, K.; Takanabe, K. ChemSusChem 2013, 6, 168. doi: 10.1002/cssc.201200780 doi: 10.1002/cssc.201200780
63. [63]
  Nurlaela, E.; Wang, H.; Shinagawa, T.; Flanagan, S.; Ould-Chikh, S.; Qureshi, M.; Mics, Z.; Sautet, P.; Le Bahers, T.; Cánovas, E.; et al. ACS Catal. 2016, 6, 4117. doi: 10.1021/acscatal.6b00508
64. [64]
  Li, M.; Bai, L.; Wu, S. J.; Wen, X. D.; Guan, J. Q. ChemSusChem 2018, 11, 1722. doi: 10.1002/cssc.201800489 doi: 10.1002/cssc.201800489
65. [65]
  Zhang, H. Y.; Tian, W. J.; Zhou, L.; Sun, H. Q.; Tade, M.; Wang, S. B. Appl. Catal. B: Environ. 2017, 223, 2. doi: 10.1016/j.apcatb.2017.03.028 doi: 10.1016/j.apcatb.2017.03.028
66. [66]
  Zhang, G. G.; Zang, S. H.; Wang, X. C. ACS Catal. 2015, 5, 941. doi: 10.1021/cs502002u doi: 10.1021/cs502002u
67. [67]
  Zhang, L. Z.; Yang, C.; Xi, Z. L.; Wang, X. C. Appl. Catal. B: Environ. 2018, 224, 886. doi: 10.1016/j.apcatb.2017.11.023 doi: 10.1016/j.apcatb.2017.11.023
68. [68]
  Yoshinaga, T.; Saruyama, M.; Xiong, A.; Ham, Y.; Kuang, Y. B.; Niishiro, R.; Akiyama, S.; Sakamoto, M.; Hisatomi, T.; Domen, K.; et al. Nanoscale 2018, 10, UNSP10420. doi: 10.1039/c8nr00377g
69. [69]
  Ye, C.; Li, J. X.; Li, Z. J.; Li, X. B.; Fan, X. B.; Zhang, L. P.; Chen, B.; Tung, C. H.; Wu, L. Z. ACS Catal. 2015, 5, 6973. doi: 10.1021/acscatal.5b02185 doi: 10.1021/acscatal.5b02185
70. [70]
  Wang, D. E.; Li, R. G.; Zhu, J.; Shi, J. Y.; Han, J. F.; Zong, X.; Li, C. J. Phys. Chem. C 2012, 116, 5082. doi: 10.1021/jp210584b doi: 10.1021/jp210584b
71. [71]
  Yan, H. J.; Yang, J. H.; Ma, G. J.; Wu, G. P.; Zong, X.; Lei, Z. B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266, 165. doi: 10.1016/j.jcat.2009.06.024 doi: 10.1016/j.jcat.2009.06.024
72. [72]
  Maeda, K.; Xiong, A. K.; Yoshinaga, T.; Ikeda, T.; Sakamoto, N.; Hisatomi, T.; Takashima, M.; Lu, D. L.; Kanehara, M.; Setoyama, T.; et al. Angew. Chem. Int. Ed. 2010, 49, 4096. doi: 10.1002/anie.201001259 doi: 10.1002/anie.201001259
73. [73]
  Maeda, K.; Lu, D. L.; Domen, K. Chemistry 2013, 19, 4986. doi: 10.1002/chem.201300158 doi: 10.1002/chem.201300158
74. [74]
  Chen, S. S.; Qi, Y.; Hisatomi, T.; Ding, Q.; Asai, T.; Li, Z.; Ma, S. S. K.; Zhang, F. X.; Domen, K.; Li, C. Angew. Chem. Int. Ed. 2015, 54, 8498. doi: 10.1002/anie.201502686 doi: 10.1002/anie.201502686
75. [75]
  Wang, Q.; Hisatomi, T.; Jia, Q. X.; Tokudome, H.; Zhong, M.; Wang, C. Z.; Pan, Z. H.; Takata, T.; Nakabayashi, M.; Shibata, N.; et al. Nat. Mater. 2016, 15, 611. doi: 10.1038/nmat4589
76. [76]
  Lin, L. H.; Yu, Z. Y.; Wang, X. C. Angew. Chem. Int. Ed. 2018, 58, 6164. doi: 10.1002/anie.201809897 doi: 10.1002/anie.201809897
77. [77]
  Niu, W. H.; Yang, Y. ACS Energy Lett. 2018, 3, 2796. doi: 10.1021/acsenergylett.8b01594 doi: 10.1021/acsenergylett.8b01594
78. [78]
  Zhang, J. W.; Gong, S.; Mahmood, N.; Pan, L.; Zhang, X. W.; Zou, J. -J. Appl. Catal. B: Environ. 2018, 221, 9. doi: 10.1016/j.apcatb.2017.09.003 doi: 10.1016/j.apcatb.2017.09.003
79. [79]
  Zheng, Y.; Lin, L. H.; Wang, B.; Wang, X. C. Angew. Chem. Int. Ed. 2015, 54, 12868. doi: 10.1002/anie.201501788 doi: 10.1002/anie.201501788
80. [80]
  Pan, Z. M.; Zhang, G. G.; Wang, X. C. Angew. Chem. Int. Ed. 2019. doi: 10.1002/anie.201902634 doi: 10.1002/anie.201902634
81. [81]
  Huang, Z. F.; Song, J. J.; Wang, X.; Pan, L.; Li, K.; Zhang, X. W.; Wang, L.; Zou, J. -J. Nano Energy 2017, 40, 308. doi: 10.1016/j.nanoen.2017.08.032 doi: 10.1016/j.nanoen.2017.08.032
82. [82]
  Zheng, Y.; Yu, Z. H.; Ou, H. H.; Asiri, A. M.; Chen, Y. L.; Wang, X. C. Adv. Funct. Mater. 2018, 28, 1705407. doi: 10.1002/adfm.201705407 doi: 10.1002/adfm.201705407
83. [83]
  Liu, N. Y.; Han, M. M.; Sun, Y.; Zhu, C.; Zhou, Y. J.; Zhang, Y. L.; Huang, H.; Kremnican, V.; Liu, Y.; Lifshitz, Y.; et al. Energy Environ. Sci. 2018, 11, 1841. doi: 10.1039/c7ee03459h
84. [84]
  Zhang, G. G.; Lan, Z. A.; Lin, L. H.; Lin, S.; Wang, X. C. Chem. Sci. 2016, 7, 3062. doi: 10.1039/c5sc04572j doi: 10.1039/c5sc04572j
85. [85]
  Pan, Z. M.; Zheng, Y.; Guo, F. S.; Niu, P. P.; Wang, X. C. ChemSusChem 2017, 10, 87. doi: 10.1002/cssc.201600850 doi: 10.1002/cssc.201600850
86. [86]
  Zheng, D. D.; Cao, X. N.; Wang, X. C. Angew. Chem. Int. Ed. 2016, 55, 11512. doi: 10.1002/anie.201606102 doi: 10.1002/anie.201606102
87. [87]
  Sun, S. C.; Zhang, Y. C.; Shen, G. Q.; Wang, Y. T.; Liu, X. L.; Duan, Z. W.; Pan, L.; Zhang, X. W.; Zou, J. -J. Appl. Catal. B: Environ. 2019, 243, 253. doi: 10.1016/j.apcatb.2018.10.051 doi: 10.1016/j.apcatb.2018.10.051
1. [1]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
2. [2]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
3. [3]
  Ruiyun Liu , Ping Wang , Xuefei Wang , Feng Chen , Huogen Yu . Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100137-0. doi: 10.1016/j.actphy.2025.100137
4. [4]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
5. [5]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
6. [6]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046
7. [7]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
8. [8]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 2309047-0. doi: 10.3866/PKU.WHXB202309047
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
10. [10]
  Jiaqi Yang , Xuqiang Hao , Jiejie Jing , Yuqiang Hao , Zhiliang Jin . 3D/2D ReSe₂/ZnCdS S-scheme photocatalyst with efficient interfacial charge separation for optimized hydrogen production. Acta Physico-Chimica Sinica, 2025, 41(10): 100131-0. doi: 10.1016/j.actphy.2025.100131
11. [11]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-0. doi: 10.3866/PKU.WHXB202405005
12. [12]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
13. [13]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
14. [14]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
15. [15]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
16. [16]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
17. [17]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
18. [18]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
19. [19]
  Jia Zhou . Constructing Potential Energy Surface of Water Molecule by Quantum Chemistry and Machine Learning: Introduction to a Comprehensive Computational Chemistry Experiment. University Chemistry, 2024, 39(3): 351-358. doi: 10.3866/PKU.DXHX202309060
20. [20]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

Get Citation

PDF

XML

Metrics

PDF Downloads(16)
Abstract views(1149)
HTML views(237)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142