Citation: YIN Hongyao, YU Yue, LI Zongcheng, ZHANG Ganghong, FENG Yujun. Smart Honeycomb-Patterned Porous Films: Fabrications, Responsive Properties, and Applications[J]. Acta Physico-Chimica Sinica, ;2019, 35(12): 1341-1356. doi: 10.3866/PKU.WHXB201904042 shu

Smart Honeycomb-Patterned Porous Films: Fabrications, Responsive Properties, and Applications

Polymer Research Institute, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, P. R. China

Corresponding author: YIN Hongyao, hyyin@scu.edu.cn FENG Yujun, yjfeng@scu.edu.cn
Received Date: 10 April 2019
Revised Date: 14 May 2019
Accepted Date: 15 May 2019
Available Online: 22 December 2019
Fund Project: The project was supported by the China Postdoctoral Science Foundation (2017M623029)the China Postdoctoral Science Foundation 2017M623029

Honeycomb-patterned porous films are polymer films with regular pore arrays on their surfaces. Since the pioneering work of François et al. in 1994, in which they used the breath figure (BF) technique to prepare honeycomb films, these highly ordered porous films have been attracting increasing interest in the past decades. Researchers are interested in the well-ordered pore arrays as they show great potential for use in many areas including superhydrophobic materials, photoelectric materials, tissue engineering, biomedicine, gas sensors, micro-reactors, to name just a few. Previous studies in this area have mainly focused on the preparation of porous films with regular microstructures and the effect of polymer architecture and casting conditions (such as temperature, relative humidity, and solvents) on the morphology. During the past two decades, considerable work has been devoted to identifying the mechanism of generation of well-ordered pore arrays during the BF process. Although the exact mechanism of film formation remains unclear, highly ordered honeycomb films can be produced from various polymers or polymer blends. In other words, currently, preparation of honeycomb films is not a major challenge. More recent studies in this area have concentrated on fabricating smart honeycomb films with reversible surface morphologies and/or properties. These smart films possess not only the properties of ordinary honeycomb films but also unique "on-off" switching functions. The research on stimuli-responsive smart honeycomb films is quite interesting in terms of both fundamental research and practical applications. Theoretically, the different scales and regular pore arrays provide an ideal model for studying the surface properties of porous materials under external stimulation, which is helpful in designing structured surfaces with desirable properties. From an application perspective, the "on-off" switching behavior imparts the films with additional functions that show high potential in a wide range of applications such as cell adhesion and controlled release, protein adsorption and separation, controlled drug release, etc. Thus far, honeycomb films with stimuli-responsive reversible surface morphologies, wettability, and fluorescence spectra have been developed, and the stimulus triggers have been mainly concentrated on temperature, pH, light, solvents, and gases. The main focus of this study is to describe the recent advances in smart honeycomb films, including fabrication strategies, triggers, "on-off" switching mechanisms, responsive behaviors, and related applications. Moreover, special attention is given to discussing the advantages and disadvantages of smart honeycomb films based on different triggers and design of smart honeycomb film systems with improved response properties. This study also discusses the challenges that concern the future development of smart honeycomb films and suggests several means of addressing those challenges.
- Ordered porous film,
- Breath figure,
- Stimuli-responsiveness,
- Wettability,
- Morphology
1. [1]
  Widawski, G.; Rawiso, M.; François, B. Nature 1994, 369, 387. doi: 10.1038/369387a0
2. [2]
  Stenzel, M. H. Aust. J. Chem. 2002, 55, 239. doi: 10.1071/CH02056 doi: 10.1071/CH02056
3. [3]
  Hernandez-Guerrero, M.; Stenzel, M. H. Polym. Chem. 2012, 3, 563. doi: 10.1039/C1PY00219H doi: 10.1039/C1PY00219H
4. [4]
  Li, Z. G.; Ma, X. Y.; Hong, Q.; Guan, X. H. Acta Phys. -Chim. Sin. 2015, 31, 393. doi: 10.3866/PKU.WHXB201412261
5. [5]
  Escalé, P.; Rubatat, L.; Billon, L.; Save, M. Eur. Polym. J. 2012, 48, 1001. doi: 10.1016/j.eurpolymj.2012.03.001 doi: 10.1016/j.eurpolymj.2012.03.001
6. [6]
  Feng, X. J.; Jiang, L. Adv. Mater. 2006, 18, 3063. doi: 10.1002/adma.200501961 doi: 10.1002/adma.200501961
7. [7]
  Li, Z.; Ma, X.; Kong, Q.; Zang, D.; Guan, X.; Ren, X. J. Phys. Chem. C 2016, 120, 18659. doi: 10.1021/acs.jpcc.6b06186 doi: 10.1021/acs.jpcc.6b06186
8. [8]
  Chen, S.; Lu, X.; Hu, Y.; Lu, Q. Biomater. Sci. 2015, 3, 85. doi: 10.1039/C4BM00233D doi: 10.1039/C4BM00233D
9. [9]
  Bui, V. T.; Thuy, L. T.; Tran, Q. C.; Nguyen, V. T.; Dao, V. D.; Choi, J. S.; Choi, H. S. Chem. Eng. J. 2017, 320, 561. doi: 10.1016/j.cej.2017.03.086 doi: 10.1016/j.cej.2017.03.086
10. [10]
  Zhu, Y.; Sheng, R.; Luo, T.; Li, H.; Sun, J.; Chen, S.; Sun, W.; Cao, A. ACS Appl. Mater. Interfaces 2011, 3, 2487. doi: 10.1021/am200371c doi: 10.1021/am200371c
11. [11]
  Bui, V. T.; Thuy, L. L.; Choi, J. S.; Choi, H. S. J. Colloid Interface Sci. 2018, 513, 161. doi: 10.1016/j.jcis.2017.11.024 doi: 10.1016/j.jcis.2017.11.024
12. [12]
  Yao, B.; Zhu, Q.; Yao, L.; Hao, J. Appl. Surf. Sci. 2015, 332, 287. doi: 10.1016/j.apsusc.2015.01.170 doi: 10.1016/j.apsusc.2015.01.170
13. [13]
  Martínez-Campos, E.; Elzein, T.; Bejjani, A.; García-Granda, M. J.; Santos-Coquillat, A.; Ramos, V.; Muñoz-Bonilla, A.; Rodríguez-Hernández, J. ACS Appl. Mater. Interfaces 2016, 8, 6344. doi: 10.1021/acsami.5b12832 doi: 10.1021/acsami.5b12832
14. [14]
  Tu, Z.; Tang, H.; Shen, X. ACS Appl. Mater. Interfaces 2014, 6, 12931. doi: 10.1021/am502871t doi: 10.1021/am502871t
15. [15]
  Wu, X.; Wang, S. ACS Appl. Mater. Interfaces 2012, 4, 4966. doi: 10.1021/am301334s doi: 10.1021/am301334s
16. [16]
  Zhao, Y.; Shang, Q.; Yu, J.; Zhang, Y.; Liu, S. ACS Appl. Mater. Interfaces 2015, 7, 11783. doi: 10.1021/acsami.5b03254 doi: 10.1021/acsami.5b03254
17. [17]
  Chen, S.; Gao, S.; Jing, J.; Lu, Q. Adv. Healthcare Mater. 2018, 7, 1701043. doi: 10.1002/adhm.201701043 doi: 10.1002/adhm.201701043
18. [18]
  Zhang, H.; Liu, Y.; Luo, T.; Zhao, Q.; Cui, K.; Huang, J.; Jiang, T.; Ma, Z. Polym. Chem. 2018, 9, 3922. doi: 10.1039/C8PY00732B doi: 10.1039/C8PY00732B
19. [19]
  Gao, F.; Wang, W.; Li, X.; Li, L.; Lin, J.; Lin, S. J. Colloid Interface Sci. 2016, 468, 70. doi: 10.1016/j.jcis.2016.01.035 doi: 10.1016/j.jcis.2016.01.035
20. [20]
  Yabu, H.; Shimomura, M. Chem. Mater. 2005, 17, 5231. doi: 10.1021/cm051281i doi: 10.1021/cm051281i
21. [21]
  Ting, W. H.; Chen, C. C.; Dai, S. A.; Suen, S. Y.; Yang, I. K.; Liu, Y. L.; Chen, F. M. C.; Jeng, R. J. J. Mater. Chem. 2009, 19, 4819. doi: 10.1039/B900468H doi: 10.1039/B900468H
22. [22]
  Yu, X.; Zhong, Q. Z.; Yang, H. C.; Wan, L. S.; Xu, Z. K. J. Phys. Chem. C 2015, 119, 3667. doi: 10.1021/jp513001k doi: 10.1021/jp513001k
23. [23]
  Yabu, H.; Takebayashi, M.; Tanaka, M.; Shimomura, M. Langmuir 2005, 21, 3235. doi: 10.1021/la050013w doi: 10.1021/la050013w
24. [24]
  Fang, X.; Men, X.; Chen, H.; Zhang, Y. M.; Sun, H.; Yin, S.; Qin, W. J. Colloid Interface Sci. 2018, 512, 1. doi: 10.1016/j.jcis.2017.10.007 doi: 10.1016/j.jcis.2017.10.007
25. [25]
  Geping, Z.; Hongxia, Z.; Mengjun, C.; Hongguang, L.; Ye, Y.; Tiantai, M.; Jingcheng, H. Chem. -Eur. J. 2017, 23, 7278. doi: 10.1002/chem.201605651 doi: 10.1002/chem.201605651
26. [26]
  Liu, C.; Gao, C.; Yan, D. Angew. Chem. Int. Ed. 2007, 46, 4128. doi: 10.1002/anie.200604429 doi: 10.1002/anie.200604429
27. [27]
  Bertrand, A.; Dumur, F.; Mruczkiewicz, M.; Perrin, M.; Lartigau-Dagron, C.; Bousquet, A.; Vignau, L.; Billon, L.; Fasquel, S. Org. Electron. 2018, 52, 222. doi: 10.1016/j.orgel.2017.10.022 doi: 10.1016/j.orgel.2017.10.022
28. [28]
  Zhu, C.; Tian, L.; Liao, J.; Zhang, X.; Gu, Z. Adv. Funct. Mater. 2018, 28, 1803194. doi: 10.1002/adfm.201803194 doi: 10.1002/adfm.201803194
29. [29]
  Li, L.; Zhong, Y.; Ma, C.; Li, J.; Chen, C.; Zhang, A.; Tang, D.; Xie, S.; Ma, Z. Chem. Mater. 2009, 21, 4977. doi: 10.1021/cm902357m doi: 10.1021/cm902357m
30. [30]
  Lu, Y.; Ren, Y.; Wang, L.; Wang, X.; Li, C. Polymer 2009, 50, 2035. doi: 10.1016/j.polymer.2009.02.026 doi: 10.1016/j.polymer.2009.02.026
31. [31]
  Wang, Z.; Zhang, L.; Liu, J.; Jiang, H.; Li, C. Nanoscale 2018, 10, 10691. doi: 10.1039/C8NR01495G doi: 10.1039/C8NR01495G
32. [32]
  Wang, Y.; Zhou, W.; Kang, Q.; Chen, J.; Li, Y.; Feng, X.; Wang, D.; Ma, Y.; Huang, W. ACS Appl. Mater. Interfaces 2018, 10, 27001. doi: 10.1021/acsami.8b06710 doi: 10.1021/acsami.8b06710
33. [33]
  Lin, F. W.; Xu, X. L.; Wan, L. S.; Wu, J.; Xu, Z. K. RSC Adv. 2015, 5, 30472. doi: 10.1039/C5RA01605C doi: 10.1039/C5RA01605C
34. [34]
  Mao, Y.; Mei, Z.; Wen, J.; Li, G.; Tian, Y.; Zhou, B.; Tian, Y. Sens. Actuators B 2018, 257, 944. doi: 10.1016/j.snb.2017.11.042 doi: 10.1016/j.snb.2017.11.042
35. [35]
  Cao, T. T.; Modigunta, J. K. R.; Male, U.; Huh, D. S. Adv. Mater. Interfaces 2018, 5, 1801174. doi: 10.1002/admi.201801174 doi: 10.1002/admi.201801174
36. [36]
  Wan, L. S.; Lv, J.; Ke, B. B.; Xu, Z. K. ACS Appl. Mater. Interfaces 2010, 2, 3759. doi: 10.1021/am1009277 doi: 10.1021/am1009277
37. [37]
  Zhou, H. J.; Yang, G. W.; Zhang, Y. Y.; Xu, Z. K.; Wu, G. P. ACS Nano 2018, 12, 11471. doi: 10.1021/acsnano.8b06521 doi: 10.1021/acsnano.8b06521
38. [38]
  Wan, L. S.; Li, J. W.; Ke, B. B.; Xu, Z. K. J. Am. Chem. Soc. 2012, 134, 95. doi: 10.1021/ja2092745 doi: 10.1021/ja2092745
39. [39]
  Zhang, C.; Wang, X.; Min, K.; Lee, D.; Wei, C.; Schulhauser, H.; Gao, H. Macromol. Rapid. Commun. 2014, 35, 221. doi: 10.1002/marc.201300581 doi: 10.1002/marc.201300581
40. [40]
  Yin, H. Y.; Feng, Y. J.; Billon, L. Chem. -Eur. J. 2018, 24, 425. doi: 10.1002/chem.201704369 doi: 10.1002/chem.201704369
41. [41]
  Wu, B. H.; Wu, L. W.; Gao, K.; Chen, S. H.; Xu, Z. K.; Wan, L. S. J. Phys. Chem. C 2018, 122, 3926. doi: 10.1021/acs.jpcc.7b12286 doi: 10.1021/acs.jpcc.7b12286
42. [42]
  Zhang, L.; Chen, L.; Liu, S. X.; Gong, J.; Tang, Q.; Su, Z. M. Dalton Trans. 2018, 47, 105. doi: 10.1039/C7DT03201C doi: 10.1039/C7DT03201C
43. [43]
  Benoot, N.; Marcasuzaa, P.; Pessoni, L.; Chasvised, S.; Reynaud, S.; Bousquet, A.; Billon, L. Soft Matter 2018, 14, 4874. doi: 10.1039/C8SM00137E doi: 10.1039/C8SM00137E
44. [44]
  Ji, E.; Pellerin, V.; Ehrenfeld, F.; Laffore, A.; Bousquet, A.; Billon, L. Chem. Commun. 2017, 53, 1876. doi: 10.1039/C6CC09898C doi: 10.1039/C6CC09898C
45. [45]
  Wu, B. H.; Zhang, C.; Zheng, N.; Wu, L. W.; Xu, Z. K.; Wan, L. S. ACS Appl. Mater. Interfaces 2019, 1, 47. doi: 10.1021/acsapm.8b00031 doi: 10.1021/acsapm.8b00031
46. [46]
  Yin, H. Y; Bulteau, A. L.; Feng, Y. J.; Billon, L. Adv. Mater. Interfaces 2016, 3, 1500623. doi: 10.1002/admi.201500623 doi: 10.1002/admi.201500623
47. [47]
  Bunz, U. H. F. Adv. Mater. 2006, 18, 973. doi: 10.1002/adma.200501131 doi: 10.1002/adma.200501131
48. [48]
  Bai, H.; Du, C.; Zhang, A.; Li, L. Angew. Chem. Int. Ed. 2013, 52, 12240. doi: 10.1002/anie.201303594 doi: 10.1002/anie.201303594
49. [49]
  Zhang, A.; Bai, H.; Li, L. Chem. Rev. 2015, 115, 9801. doi: 10.1021/acs.chemrev.5b00069 doi: 10.1021/acs.chemrev.5b00069
50. [50]
  Wan, L. S.; Zhu, L. W.; Ou, Y.; Xu, Z. K. Chem. Commun. 2014, 50, 4024. doi: 10.1039/C3CC49826C doi: 10.1039/C3CC49826C
51. [51]
  Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Prog. Polym. Sci. 2014, 39, 510. doi: 10.1016/j.progpolymsci.2013.08.006 doi: 10.1016/j.progpolymsci.2013.08.006
52. [52]
  Escale, P.; Save, M.; Billon, L.; Ruokolainen, J.; Rubatat, L. Soft Matter 2016, 12, 790. doi: 10.1039/C5SM01774B doi: 10.1039/C5SM01774B
53. [53]
  Escale, P.; Save, M.; Lapp, A.; Rubatat, L.; Billon, L. Soft Matter 2010, 6, 3202. doi: 10.1039/C0SM00029A doi: 10.1039/C0SM00029A
54. [54]
  Ghannam, L.; Manguian, M.; François, J.; Billon, L. Soft Matter 2007, 3, 1492. doi: 10.1039/B710282H doi: 10.1039/B710282H
55. [55]
  De Leon, A. S.; Malhotra, S.; Molina, M.; Calderon, M.; Munoz-Bonilla, A.; Rodriguez-Hernandez, J. Polym. Chem. 2016, 7, 4112. doi: 10.1039/C6PY00601A doi: 10.1039/C6PY00601A
56. [56]
  Zhang, Z.; Hughes, T. C.; Gurr, P. A.; Blencowe, A.; Uddin, H.; Hao, X.; Qiao, G. G. Polymer 2013, 54, 4446. doi: 10.1016/j.polymer.2013.06.033 doi: 10.1016/j.polymer.2013.06.033
57. [57]
  Wu, B. H.; Zhu, L. W.; Ou, Y.; Tang, W.; Wan, L. S.; Xu, Z. K. J. Phys. Chem. C 2015, 119, 1971. doi: 10.1021/jp5119212 doi: 10.1021/jp5119212
58. [58]
  Fei, B.; Lu, D. L.; Shen, Q. J. Adhes. Sci. Technol. 2018, 32, 1027. doi: 10.1080/01694243.2017.1393918 doi: 10.1080/01694243.2017.1393918
59. [59]
  Yabu, H.; Hirai, Y.; Kojima, M.; Shimomura, M. Chem. Mater. 2009, 21, 1787. doi: 10.1021/cm803476m doi: 10.1021/cm803476m
60. [60]
  Fukuhira, Y.; Yabu, H.; Ijiro, K.; Shimomura, M. Soft Matter 2009, 5, 2037. doi: 10.1039/B821183C doi: 10.1039/B821183C
61. [61]
  Cui, L.; Li, B.; Han, Y. Langmuir 2007, 23, 3349. doi: 10.1021/la061769d doi: 10.1021/la061769d
62. [62]
  Cheng, C. X.; Tian, Y.; Shi, Y. Q.; Tang, R. P.; Xi, F. Langmuir 2005, 21, 6576. doi: 10.1021/la050187d doi: 10.1021/la050187d
63. [63]
  Xu, W. Z.; Kadla, J. F. Langmuir 2012, 29, 727. doi: 10.1021/la303835e doi: 10.1021/la303835e
64. [64]
  Jang, J. H.; Orbán, M.; Wang, S.; Huh, D. S. Phys. Chem. Chem. Phys. 2014, 16, 25296. doi: 10.1039/C4CP03083D doi: 10.1039/C4CP03083D
65. [65]
  Chen, S.; Lu, X.; Zhu, D.; Lu, Q. Soft Matter 2015, 11, 7420. doi: 10.1039/C5SM01769F doi: 10.1039/C5SM01769F
66. [66]
  Min, E. H.; Ting, S. R. S.; Billon, L.; Stenzel, M. H. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 3440. doi: 10.1002/pola.24129 doi: 10.1002/pola.24129
67. [67]
  Hernandez-Guerrero, M.; Min, E.; Barner-Kowollik, C.; Muller, A. H. E.; Stenzel, M. H. J. Mater. Chem. 2008, 18, 4718. doi: 10.1039/B807495J doi: 10.1039/B807495J
68. [68]
  Pan, Y. V.; Wesley, R. A.; Luginbuhl, R.; Denton, D. D.; Ratner, B. D. Biomacromolecules 2001, 2, 32. doi: 10.1021/bm0000642 doi: 10.1021/bm0000642
69. [69]
  Hirvonen, S. P.; Rossi, T.; Karesoja, M.; Karjalainen, E.; Tenhu, H. Colloid. Polym. Sci. 2015, 293, 2957. doi: 10.1007/s00396-015-3693-6 doi: 10.1007/s00396-015-3693-6
70. [70]
  Nykänen, A.; Hirvonen, S. P.; Tenhu, H.; Mezzenga, R.; Ruokolainen, J. Polym. Int. 2014, 63, 37. doi: 10.1002/pi.4559 doi: 10.1002/pi.4559
71. [71]
  Zhou, Y.; Huang, J.; Sun, W.; Ju, Y.; Yang, P.; Ding, L.; Chen, Z. R.; Kornfield, J. A. ACS Appl. Mater. Interfaces 2017, 9, 4177. doi: 10.1021/acsami.6b13525 doi: 10.1021/acsami.6b13525
72. [72]
  Wang, C.; Mao, Y.; Wang, D.; Qu, Q.; Yang, G.; Hu, X. J. Mater. Chem. 2008, 18, 683. doi: 10.1039/B715520D doi: 10.1039/B715520D
73. [73]
  Escale, P.; Van Camp, W.; Du Prez, F.; Rubatat, L.; Billon, L.; Save, M. Polym. Chem. 2013, 4, 4710. doi: 10.1039/C3PY00643C doi: 10.1039/C3PY00643C
74. [74]
  Escalé, P.; Rubatat, L.; Derail, C.; Save, M.; Billon, L. Macromol. Rapid. Comm. 2011, 32, 1072. doi: 10.1002/marc.201100296 doi: 10.1002/marc.201100296
75. [75]
  Marcasuzaa, P.; Pearson, S.; Bosson, K.; Pessoni, L.; Dupin, J. C.; Billon, L. Chem. Commun. 2018, 54, 13068. doi: 10.1039/C8CC05333B doi: 10.1039/C8CC05333B
76. [76]
  Yin, H. Y.; Feng, Y. J.; Liu, H. B.; Mu, M.; Fei, C. H. Langmuir 2014, 30, 9911. doi: 10.1021/la501461n doi: 10.1021/la501461n
77. [77]
  Jochum, F. D.; Theato, P. Chem. Soc. Rev. 2013, 42, 7468. doi: 10.1039/C2CS35191A doi: 10.1039/C2CS35191A
78. [78]
  Li, L.; Chen, C.; Li, J.; Zhang, A.; Liu, X.; Xu, B.; Gao, S.; Jin, G.; Ma, Z. J. Mater. Chem. 2009, 19, 2789. doi: 10.1039/B820279F doi: 10.1039/B820279F
79. [79]
  Wang, W.; Du, C.; Wang, X.; He, X.; Lin, J.; Li, L.; Lin, S. Angew. Chem. Int. Ed. 2014, 53, 12116. doi: 10.1002/anie.201407230 doi: 10.1002/anie.201407230
80. [80]
  Wei, W.; Dingfeng, S.; Xiao, L.; Yuan, Y.; Jiaping, L.; Aurelia, W.; Jiwoo, Y.; Lin, W. Z.; Won, H. S.; Zhiqun, L.; et al. Angew. Chem. Int. Ed. 2018, 57, 2139. doi: 10.1002/anie.201712100 doi: 10.1002/anie.201712100
81. [81]
  Wang, W.; Yao, Y.; Luo, T.; Chen, L.; Lin, J.; Li, L.; Lin, S. ACS Appl. Mater. Interfaces 2017, 9, 4223. doi: 10.1021/acsami.6b14024 doi: 10.1021/acsami.6b14024
82. [82]
  Wei, W.; Fei, G.; Yuan, Y.; Shaoliang, L. Chin. J. Polym. Sci. 2018, 36, 297. doi: 10.1007/s10118-018-2087-x doi: 10.1007/s10118-018-2087-x
83. [83]
  Xu, Y. Y.; Wang, W.; Chen, J. H.; Lin, S. L. Chin. J. Org. Chem. 2018, 38, 2161. doi: 10.6023/cjoc201803037
84. [84]
  Cui, L.; Xuan, Y.; Li, X.; Ding, Y.; Li, B.; Han, Y. Langmuir 2005, 21, 11696. doi: 10.1021/la051376z doi: 10.1021/la051376z
85. [85]
  Cui, L.; Peng, J.; Ding, Y.; Li, X.; Han, Y. Polymer 2005, 46, 5334. doi: 10.1016/j.polymer.2005.04.018 doi: 10.1016/j.polymer.2005.04.018
86. [86]
  Chen, L.; Liu, R.; Hao, X.; Yan, Q. Angew. Chem. Int. Ed. 2019, 58, 264. doi: 10.1002/anie.201812365 doi: 10.1002/anie.201812365
87. [87]
  Jie, K.; Zhou, Y.; Yao, Y.; Shi, B.; Huang, F. J. Am. Chem. Soc. 2015, 137, 10472. doi: 10.1021/jacs.5b05960 doi: 10.1021/jacs.5b05960
88. [88]
  Yin, H. Y; Liu, H. B.; Wang, W.; Feng, Y. J. Langmuir 2015, 31, 12260. doi: 10.1021/acs.langmuir.5b02831 doi: 10.1021/acs.langmuir.5b02831
89. [89]
  Su, X.; Cunningham, M. F.; Jessop, P. G. Chem. Commun. 2013, 49, 2655. doi: 10.1039/C3cc37816k doi: 10.1039/C3cc37816k
90. [90]
  Jessop, P. G.; Mercer, S. M.; Heldebrant, D. J. Energy Environ. Sci. 2012, 5, 7240. doi: 10.1039/C2ee02912j doi: 10.1039/C2ee02912j
91. [91]
  De León, A. S.; Molina, M.; Wedepohl, S.; Muñoz-Bonilla, A.; Rodríguez-Hernández, J.; Calderón, M. Langmuir 2016, 32, 1854. doi: 10.1021/acs.langmuir.5b04166 doi: 10.1021/acs.langmuir.5b04166
92. [92]
  Heng, L.; Li, J.; Li, M.; Tian, D.; Fan, L. Z.; Jiang, L.; Tang, B. Z. Adv. Funct. Mater. 2014, 24, 7241. doi: 10.1002/adfm.201401342 doi: 10.1002/adfm.201401342
93. [93]
  Yu, X.; Xie, D.; Lan, H.; Li, Y.; Zhen, X.; Ren, J.; Yi, T. J. Mater. Chem. C 2017, 5, 5910. doi: 10.1039/C7TC01331K doi: 10.1039/C7TC01331K
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  .
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沈阳化工大学材料科学与工程学院沈阳 110142

Smart Honeycomb-Patterned Porous Films: Fabrications, Responsive Properties, and Applications

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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