Citation: HIGAKI Tatsuya, JIN Rongchao. Structural Evolution Patterns of FCC-Type Gold Nanoclusters[J]. Acta Physico-Chimica Sinica, ;2018, 34(7): 755-761. doi: 10.3866/PKU.WHXB201801191 shu

Structural Evolution Patterns of FCC-Type Gold Nanoclusters

HIGAKI Tatsuya ,
JIN Rongchao ^,

Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States

Author Bio:
Rongchao Jin is currently a Professor of Chemistry at Carnegie Mellon University. He received his Ph.D. from Northwestern University in 2003. After three years of postdoctoral research at the University of Chicago, he joined the chemistry faculty of Carnegie Mellon University in 2006 and was promoted to Associate Professor in 2012 and Full Professor in 2015. His current research interests are atomically precise nanoparticles, nano-optics, and catalysis
Corresponding author: JIN Rongchao, rongchao@andrew.cmu.edu
Received Date: 9 November 2017
Revised Date: 12 January 2018
Accepted Date: 12 January 2018
Available Online: 19 July 2018
Fund Project: the U.S. National Science Foundation DMREF-0903225The project was supported by the Air Force Office of Scientific Research (FA9550-15-1-0154) and the U.S. National Science Foundation (DMREF-0903225)The project was supported by the Air Force Office of Scientific Research FA9550-15-1-0154

Recent progress in the research of atomically-precise metal nanoclusters has identified a series of exceptionally stable nanoclusters with specific chemical compositions. Structural determination on such "magic size" nanoclusters revealed a variety of unique structures such as decahedron, icosahedron, as well as hexagonal close packing (hcp) and body-centered cubic (bcc) packing arrangements in gold nanoclusters, which are largely different from the face-centered cubic (fcc) structure in conventional gold nanoparticles. The characteristic geometrical structures enable the nanoclusters to exhibit interesting properties, and these properties are in close correlation with their atomic structures according to the recent studies. Experimental and theoretical analyses have been applied in the structural identification aiming to clarify the universal principle in the structural evolution of nanoclusters. In this mini-review, we summarize recent studies on periodic structural evolution of fcc-based gold nanoclusters protected by thiolates. A series of nanoclusters exhibit one-dimensional growth along the [001] direction in a layer-by-layer manner from Au₂₈(TBBT)₂₀ to Au₃₆(TBBT)₂₄, Au₄₄(TBBT)₂₈, and to Au₅₂(TBBT)₃₂ (TBBT: 4-tert-butylbenzenethiolate). The optical properties of these nanoclusters also evolve periodically based on steady-state and ultrafast spectroscopy. In addition, two-dimensional growth from Au₄₄(TBBT)₂₈ toward both [100] and [010] directions leads to the Au₉₂(TBBT)₄₄ nanocluster, and the recently reported Au₅₂(PET)₃₂ (PET: 2-phenylethanethiol) also follows this growth pattern with partial removal of the layer. Theoretical predictions of relevant fcc nanoclusters include Au₆₀(SCH₃)₃₆, Au₆₈(SCH₃)₄₀, Au₇₆(SCH₃)₄₄, etc, for the continuation of 1D growth pattern, as well as Au₆₈(SR)₃₆ mediating the 2D growth pattern from Au₄₄(TBBT)₂₈ to Au₉₂(TBBT)₄₄. Overall, this mini-review provides guidelines on the rules of structural evolution of fcc gold nanoclusters based on 1D, 2D and 3D growth patterns.
- Gold,
- Nanoclusters,
- Thiolate,
- Face-centered-cubic,
- Layer-by-layer growth
1. [1]
  Jin, R.; Zhou, M.; Zeng, C.; Chen, Y. Chem. Rev. 2016, 116, 10346. doi: 10.1021/acs.chemrev.5b00703 doi: 10.1021/acs.chemrev.5b00703
2. [2]
  Tsukuda, T.; Häkkinen, H. Protected Metal Clusters: From Fundamentals to Applications, 1st ed.; Elsevier, B. V.: Amsterdam, The Netherlands, 2015.
3. [3]
  Goswami, N.; Yao, Q.; Chen, T.; Xie, J. Coord. Chem. Rev. 2016, 329, 1. doi: 10.1016/j.ccr.2016.09.001 doi: 10.1016/j.ccr.2016.09.001
4. [4]
  Kurashige, W.; Niihori, Y.; Sharma, S.; Negishi, Y. Coord. Chem. Rev. 2016, 320–321, 238. doi: 10.1016/j.ccr.2016.02.013 doi: 10.1016/j.ccr.2016.02.013
5. [5]
  Lei, Z.; Wan, X. K.; Yuan, S. F.; Wang, J. Q.; Wang, Q. M. Dalton Trans. 2017, 46, 3427. doi: 10.1039/c6dt04763g doi: 10.1039/c6dt04763g
6. [6]
  Xu, W. W.; Zhu, B.; Zeng, X. C.; Gao, Y. Nat. Commun. 2016, 7, 13574. doi: 10.1038/ncomms13574 doi: 10.1038/ncomms13574
7. [7]
  Jiang, D. E Nanoscale 2013, 5, 7149. doi: 10.1039/c3nr34192e doi: 10.1039/c3nr34192e
8. [8]
  Fernando, A.; Weerawardene, K. L. D. M.; Karimova, N. V.; Aikens, C. M. Chem. Rev. 2015, 115, 6112. doi: 10.1021/cr500506r doi: 10.1021/cr500506r
9. [9]
  Ghosh, A.; Ghosh, D.; Khatun, E.; Chakraborty, P.; Pradeep, T. Nanoscale 2017, 9, 1068. doi: 10.1039/c6nr07692k doi: 10.1039/c6nr07692k
10. [10]
  Higaki, T.; Liu, C.; Chen, Y.; Zhao, S.; Zeng, C.; Jin, R.; Wang, S.; Rosi, N. L.; Jin, R. J. Phys. Chem. Lett. 2017, 8, 866. doi:10.1021/acs.jpclett.6b03061 doi: 10.1021/acs.jpclett.6b03061
11. [11]
  Wan, X. K.; Guan, Z. J.; Wang, Q. M. Angew. Chem. Int. Ed. 2017, 56, 11494. doi: 10.1002/anie.201706021 doi: 10.1002/anie.201706021
12. [12]
  Teo, B. K.; Yang, H.; Yan, J.; Zheng, N. Inorg. Chem. 2017, 56, 11470. doi: 10.1021/acs.inorgchem.7b00427 doi: 10.1021/acs.inorgchem.7b00427
13. [13]
  Yamazoe, S.; Matsuo, S.; Muramatsu, S.; Takano, S.; Nitta, K.; Tsukuda, T. Inorg. Chem.2017, 56, 8319. doi: 10.1021/acs.inorgchem.7b00973 doi: 10.1021/acs.inorgchem.7b00973
14. [14]
  Zou, X.; Jin, S.; Du, W.; Li, Y.; Li, P.; Wang, S.; Zhu, M. Nanoscale 2017, 9, 16800. doi: 10.1039/C7NR06338E doi: 10.1039/C7NR06338E
15. [15]
  Higaki, T.; Kitazawa, H.; Yamazoe, S.; Tsukuda, T. Nanoscale 2016, 8, 11371. doi: 10.1039/c6nr01460g doi: 10.1039/c6nr01460g
16. [16]
  Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430. doi: 10.1126/science.1148624 doi: 10.1126/science.1148624
17. [17]
  Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc.2008, 130, 5883. doi: 10.1021/ja801173r doi: 10.1021/ja801173r
18. [18]
  Heaven, M. W.; Dass, A.; White, P. S.; Holt, K. M.; Murray, R. W. J. Am. Chem. Soc. 2008, 130, 3754. doi: 10.1021/ja800561b doi: 10.1021/ja800561b
19. [19]
  Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. J. Am. Chem. Soc. 2010, 132, 8280. doi: 10.1021/ja103592z doi: 10.1021/ja103592z
20. [20]
  Zeng, C.; Chen, Y.; Kirschbaum, K.; Lambright, K. L.; Jin, R. Science 2016, 354, 1580. doi: 10.1126/science.aak9750 doi: 10.1126/science.aak9750
21. [21]
  Huang, L.; Yan, J. Z.; Ren, L. T.; Teo, B. K.; Zheng, N. F. Dalton Trans. 2017, 46, 1757. doi: 10.1039/c6dt04419k doi: 10.1039/c6dt04419k
22. [22]
  Yuan, S. F.; Li, P.; Tang, Q.; Wan, X. K.; Nan, Z. A.; Jiang, D. E; Wang, Q. M. Nanoscale 2017, 9, 11405. doi: 10.1039/c7nr02687k doi: 10.1039/c7nr02687k
23. [23]
  Liao, L. W.; Zhuang, S. L.; Wang, P.; Xu, Y. N.; Yan, N.; Dong, H. W.; Wang, C. M.; Zhao, Y.; Xia, N.; Li, J.; et al. Angew. Chem. Int. Ed.2017, 56, 12644. doi: 10.1002/anie.201707582 doi: 10.1002/anie.201707582
24. [24]
  Gan, Z.; Chen, J.; Wang, J.; Wang, C.; Li, M. B.; Yao, C.; Zhuang, S.; Xu, A.; Li, L.; Wu, Z. Nat. Commun. 2017, 8, 14739. doi:10.1021/acs.jpcc.7b01730 doi: 10.1021/acs.jpcc.7b01730
25. [25]
  Higaki, T.; Liu, C.; Zeng, C.; Jin, R.; Chen, Y.; Rosi, N. L.; Jin, R. Angew. Chem. Int. Ed. 2016, 55, 6694. doi: 10.1002/anie.201601947 doi: 10.1002/anie.201601947
26. [26]
  Liu, C.; Li, T.; Li, G.; Nobusada, K.; Zeng, C.; Pang, G.; Rosi, N. L.; Jin, R. Angew. Chem. Int. Ed. 2015, 54, 9826. doi:10.1002/anie.201502667 doi: 10.1002/anie.201502667
27. [27]
  Zeng, C.; Chen, Y.; Das, A.; Jin, R. J. Phys. Chem. Lett. 2015, 6, 2976. doi: 10.1021/acs.jpclett.5b01150 doi: 10.1021/acs.jpclett.5b01150
28. [28]
  Chen, Y.; Liu, C.; Tang, Q.; Zeng, C.; Higaki, T.; Das, A.; Jiang, D. E.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2016, 138, 1482. doi:10.1021/jacs.5b12094 doi: 10.1021/jacs.5b12094
29. [29]
  Higaki, T.; Liu, C.; Zhou, M.; Luo, T. Y.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2017, 139, 9994. doi: 10.1021/jacs.7b04678 doi: 10.1021/jacs.7b04678
30. [30]
  Higaki, T.; Zeng, C.; Chen, Y.; Hussain, E.; Jin, R. CrystEngComm 2016, 18, 6979. doi: 10.1039/C6CE01325B doi: 10.1039/C6CE01325B
31. [31]
  Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Grönbeck, H.; Häkkinen, H. Proc. Natl. Acad. Sci. USA 2008, 105, 9157. doi:10.1073/pnas.0801001105 doi: 10.1073/pnas.0801001105
32. [32]
  Jin, R.; Liu, C.; Zhao, S.; Das, A.; Xing, H.; Gayathri, C.; Xing, Y.; Rosi, N. L.; Gil, R. R.; Jin, R. ACS Nano 2015, 9, 8530. doi: 10.1021/acsnano.5b03524 doi: 10.1021/acsnano.5b03524
33. [33]
  Zhou, M.; Jin, R.; Sfeir, M. Y.; Chen, Y.; Song, Y.; Jin, R. Proc. Natl. Acad. Sci. USA 2017, 114, E4697. doi: 10.1073/pnas.1704699114 doi: 10.1073/pnas.1704699114
34. [34]
  Zeng, C.; Qian, H.; Li, T.; Li, G.; Rosi, N. L.; Yoon, B.; Barnett, R. N.; Whetten, R. L.; Landman, U.; Jin, R. Angew. Chem. Int. Ed. 2012, 51, 13114. doi: 10.1002/anie.201207098 doi: 10.1002/anie.201207098
35. [35]
  Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 10011. doi: 10.1021/ja404058q doi: 10.1021/ja404058q
36. [36]
  Zeng, C.; Chen, Y.; Iida, K.; Nobusada, K.; Kirschbaum, K.; Lambright, K. J.; Jin, R. J. Am. Chem. Soc.2016, 138, 3950. doi: 10.1021/jacs.5b12747 doi: 10.1021/jacs.5b12747
37. [37]
  Zeng, C.; Chen, Y.; Liu, C.; Nobusada, K.; Rosi, N. L.; Jin, R. Sci. Adv. 2015, 1, e1500425. doi: 10.1126/sciadv.1500425 doi: 10.1126/sciadv.1500425
38. [38]
  Cheng, L.; Yuan, Y.; Zhang, X.; Yang, J.; Angew. Chem. Int. Ed. 2013, 52, 9035. doi: 10.1002/anie.201302926 doi: 10.1002/anie.201302926
39. [39]
  Yang, R.; Chevrier, D. M.; Zeng, C.; Jin, R.; Zhang, P. Can. J. Chem. 2017, 95, 1220. doi: 10.1139/cjc-2017-0169 doi: 10.1139/cjc-2017-0169
40. [40]
  Zhou, M.; Zeng, C.; Sfeir, M. Y.; Cotlet, M.; Iida, K.; Nobusada, K.; Jin, R. J. Phys. Chem. Lett. 2017, 8, 4023. doi: 10.1021/acs.jpclett.7b01597 doi: 10.1021/acs.jpclett.7b01597
41. [41]
  Xu, W. W.; Li, Y.; Gao, Y.; Zeng, X. C. Nanoscale 2016, 8, 7396. doi: 10.1039/C6NR00272B doi: 10.1039/C6NR00272B
42. [42]
  Ma, Z.; Wang, P.; Pei, Y. Nanoscale 2016, 8, 17044. doi: 10.1039/C6NR04998B doi: 10.1039/C6NR04998B
43. [43]
  Takano, S.; Yamazoe, S.; Koyasu, K.; Tsukuda, T. J. Am. Chem. Soc. 2015, 137, 7027. doi: 10.1021/jacs.5b03251 doi: 10.1021/jacs.5b03251
44. [44]
  Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2016, 138, 8710. doi: 10.1021/jacs.6b04835 doi: 10.1021/jacs.6b04835
45. [45]
  Wang, P.; Sun, X.; Liu, X.; Xiong, L.; Ma, Z.; Pei, Y. J. Phys. Chem. Lett. 2017, 8, 1248. doi: 10.1021/acs.jpclett.7b00111 doi: 10.1021/acs.jpclett.7b00111
46. [46]
  Zhuang, S.; Liao, L.; Li, M. B.; Yao, C.; Zhao, Y.; Donga, H.; Li, J.; Deng, H.; Li, L.; Wu, Z. Nanoscale 2017, 9, 14809. doi: 10.1039/c7nr05239a doi: 10.1039/c7nr05239a
47. [47]
  Kwak, K.; Thanthirige, V. D.; Pyo, K.; Lee, D.; Ramakrishna, G. J. Phys. Chem. Lett. 2017, 8, 4898. doi: 10.1021/acs.jpclett.7b01892 doi: 10.1021/acs.jpclett.7b01892
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