Citation: XU Jiale, HU Lei, WANG Lu, DENG Jinxia, CHEN Jun, XING Xianran. Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions[J]. Acta Physico-Chimica Sinica, ;2018, 34(4): 339-343. doi: 10.3866/PKU.WHXB201709081 shu

Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions

Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, P. R. China

Corresponding author: CHEN Jun, Junchen@ustb.edu.cn
Received Date: 9 August 2017
Revised Date: 6 September 2017
Accepted Date: 7 September 2017
Available Online: 8 April 2017
Fund Project: the National Natural Science Foundation of China 21231001the Fundamental Research Funds for the Central Universities, China FRF-TP-14-012C1the National Natural Science Foundation of China 91422301The project was supported by the National Natural Science Foundation of China (91422301, 21231001) and the Fundamental Research Funds for the Central Universities, China (FRF-TP-14-012C1)

Most materials expand on heating and contract on cooling. In the recent years, however, some compounds have been found to exhibit abnormal negative thermal expansion (NTE) behavior; this presents an opportunity to adjust the coefficient of thermal expansion (CTE) of such materials. It is especially important to obtain controllable thermal expansion in isotropic compounds. Herein, we report the preparation, crystal structure, and controllable thermal expansion in double ReO₃-type (Fe_1-xNi_x)ZrF₆ solid solutions. (Fe_1-xNi_x)ZrF₆ exhibits full range solubility. A controllable thermal expansion of (Fe_1-xNi_x)ZrF₆ could be achieved by the chemical substitution of Ni²⁺ for Fe²⁺ over a wide range of CTE from −3.24 × 10⁻⁶ to +18.23 × 10⁻⁶ K⁻¹ (300–675 K). In particular, zero thermal expansion was obtained for the composition (Fe_0.5Ni_0.5)ZrF₆. As a kind of typical framework structure, the transverse thermal vibrations of fluorine atoms are expected to play a critical role in the thermal expansion behavior of double-ReO₃ compounds. This study presents a potential method to tune the thermal expansion of NTE (negative thermal expansion) families which have an open framework structure.
- Solid solution,
- Fluorides,
- ReO₃,
- Controllable thermal expansion,
- Zero thermal expansion
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Controllable Thermal Expansion and Crystal Structure of (Fe1-xNix)ZrF6 Solid Solutions

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Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions