Citation: YI Yanhui, WANG Xunxun, WANG Li, YAN Jinhui, ZHANG Jialiang, GUO Hongchen. Plasma-Triggered CH₃OH/NH₃ Coupling Reaction for Synthesis of Nitrile Compounds[J]. Acta Physico-Chimica Sinica, ;2018, 34(3): 247-255. doi: 10.3866/PKU.WHXB201708171 shu

Plasma-Triggered CH₃OH/NH₃ Coupling Reaction for Synthesis of Nitrile Compounds

YI Yanhui ^1,, ,
WANG Xunxun ¹ ,
WANG Li ¹ ,
YAN Jinhui ¹ ,
ZHANG Jialiang ² ,
GUO Hongchen ^1,,

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China
2.
School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Corresponding author: YI Yanhui, yiyanhui@dlut.edu.cn GUO Hongchen, hongchenguo@163.com
Received Date: 22 June 2017
Revised Date: 8 August 2017
Accepted Date: 10 August 2017
Available Online: 17 March 2017
Fund Project: The project was supported by the Natural Science Foundation of China 21503032The project was supported by the Natural Science Foundation of China (21503032) and China Postdoctoral Science Foundation (2015M580220, 2016T90217)China Postdoctoral Science Foundation 2016T90217China Postdoctoral Science Foundation 2015M580220

Nitriles are very important for the synthesis of fine chemicals and medicines. However, many nitriles are not widely available, as their synthesis processes pose a serious risk to the environment. Herein, we report that a spontaneous CH₃OH/NH₃ coupling reaction can directly synthesize N, N-dimethyl cyanamide[(CH₃)₂NCN], amino acetonitrile [NH₂CH₂CN], and N, N-dimethyl amino acetonitrile [(CH₃)₂NCH₂CN], when a mixture of methanol and ammonia is transferred into the plasma state via a dielectric barrier discharge. The effects of the plasma reactor configuration, discharge conditions, reaction conditions, and packing materials on the methanol conversion as well as the product selectivity were systematically investigated. Experimental results indicate that, under optimized conditions, a nitrile compound selectivity of 22.1% with a methanol conversion of 51.5% could be achieved. Analysis by optical emission spectroscopy indicates that the C≡N species in CH₃OH/NH₃ plasma could be a key reactive intermediate aiding in the synthesis of nitrile compounds. The CH₃OH/NH₃ plasma coupling reaction process is an environment-friendly methodology for the synthesis of (CH₃)₂NCN, NH₂CH₂CN, and (CH₃)₂NCH₂CN, and is a potential novel pathway for the synthesis of fine chemicals like methanol and ammonia.
- DBD plasma,
- Methanol,
- Ammonia,
- Coupling reaction,
- Nitrile compounds
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Plasma-Triggered CH₃OH/NH₃ Coupling Reaction for Synthesis of Nitrile Compounds