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Citation: LIU Jin, MAI Jiang-Quan, LI Shi, REN Zhao-Hui, LI Ming, WU Meng-Jiao, WU Yong-Jun, LU Xin-Hui, LI Xiang, TIAN He, WANG Zong-Rong, HAN Gao-Rong. Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films[J]. Acta Physico-Chimica Sinica, ;2017, 33(6): 1261-1266. doi: 10.3866/PKU.WHXB201702281 shu

Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P(VDF-TrFE) Films

LIU Jin ^1, ,
MAI Jiang-Quan ² ,
LI Shi ¹ ,
REN Zhao-Hui ¹ ,
LI Ming ¹ ,
WU Meng-Jiao ¹ ,
WU Yong-Jun ¹ ,
LU Xin-Hui ² ,
LI Xiang ¹ ,
TIAN He ³ ,
WANG Zong-Rong ¹ ,
HAN Gao-Rong ¹

1.
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Cyrus Tang Center for Sensor Materials and Application, Zhejiang University, Hangzhou 310027, P. R. China;
2.
Department of Physics, Chinese University of Hong Kong, New Territories, Hong Kong 999077, P. R. China;
3.
Center of Electron Microscope, State Key Laboratory of Silicon Material, School of Material Science & Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 15 February 2017
Revised Date: 27 February 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (No.51232006, 51472218), the National 973 Program of China (2015CB654901), Fundamental Research Funds for the Central Universities (No. 2016FZA4005) and RGC of Hong Kong GRF (No. 14303314) and CUHK Direct Grant (No. 4053128).

Ferroelectric polymers are particularly attractive for applications in flexible electronic devices, and controlling its crystalline phase growth is crucial for obtaining optimized ferroelectric properties. Herein we report that a very low introduction (0.2% (w)) of single-domain ferroelectric PbTiO₃ nanoplates can effectively mediate the nucleation and subsequent growth of a crystalline phase within P(VDF-TrFE) (denoted by PVTF), forming highly oriented films and significantly improving the ferroelectric properties due to an alignment of the polarization directions of the polymer and the nanoplates.
- P(VDF-TrFE),
- PbTiO₃,
- Nanoplate,
- Orientation growth,
- Ferroelectricity
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