Citation: KONG Wei-Wei, GUO Shuang, ZHANG Yong-Min, LIU Xue-Feng. Redox-Responsive Interfacial Properties of Se-Containing Sulfobetaine Surfactant[J]. Acta Physico-Chimica Sinica, ;2017, 33(6): 1205-1213. doi: 10.3866/PKU.WHXB201702222 shu

Redox-Responsive Interfacial Properties of Se-Containing Sulfobetaine Surfactant

School of Chemical & Materials Engineering, Key Laboratory of Food Colloids and Biotechnology Ministry of Education, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 27 December 2016
Revised Date: 22 February 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (21503094, 21673103), MOE & SAFEA for the 111 Project (B13025), Fundamental Research Funds for the Central Universities, China (JUSRP 51507), Natural Science Foundation of Jiangsu Province, China (BK20150128) and Qinglan Project of Jiangsu Province, China.

Because of good biocompatibility using Se atom as the redox-responsive group has aroused considerable attention. However, only a few efforts have been devoted to Se-containing surfactant, especially for smart control of interfacial properties. This paper focuses on the redox-responsive behaviors of molecular structure, Krafft temperature, Surface/interfacial tension, foaming and emulsification of Se-containing zwitterionic surfactant, benzylselanyl-undecyl-dimethyl ammonium propane sulfonate (BSeUSB). The results show that after oxidization with a trace of H₂O₂ (≤0.056% of total mass), reduced form BSeUSB with one hydrophilic head and one hydrophobic tail transformed to Bola-type oxidized form BSeUSB-Ox due to the presence of a new hydrophilic group (selenoxide). And thus Krafft temperature decreased from (23.5±0.5)℃ to less than 0℃. The surface/interfacial tension at 5.00 mmol·L^-1 increased from 45.15, 5.52 mN·m^-1 to 61.63, 18.38 mN·m^-1, respectively. Macroscopically, reduced form BSeUSB has good foaming and emulsification properties, while the foaming and emulsification abilities of oxidized form BSeUSB-Ox almost disappeared. Interestingly the molecular structure and the solution properties re-turned the initial states after reduction with a trace of Na₂SO₃ (≤0.060% of total mass). In a word, by the addition trace amounts of H₂O₂ and Na₂SO₃ alternately, we have achieved the smart control of the interfacial properties of the surfactant.
- Redox-responsive,
- Se-containing surfactant,
- Betaine,
- Interfacial property,
- Foam,
- Emulsion
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