Citation: YANG Kun, YAO Qi-Lu, LU Zhang-Hui, KANG Zhi-Bing, CHEN Xiang-Shu. Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane[J]. Acta Physico-Chimica Sinica, ;2017, 33(5): 993-1000. doi: 10.3866/PKU.WHXB201702087 shu

Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane

1.
Jiangxi Inorganic Membrane Materials Engineering Research Centre, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2.
School of Aeronautical Manufacture Engineering, Nanchang Hangkong University, Nanchang 330036, P. R. China

Received Date: 15 December 2016
Revised Date: 21 January 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (21463012), Young Scientist Foundation of Jiangxi Province, China (20133BCB23011), and“Gan-po talent 555”Project of Jiangxi Province, China.

Noble-metal-free CuMo nanoparticles (NPs) without surfactant or support have been facilely prepared using NaBH₄ as a reducing agent. The as-prepared CuMo nanocatalysts were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), X-ray photoelectron spectroscopy (XPS), and Brunauer-Emmett-Teller (BET) surface area measurements, and used as catalysts for the hydrolysis of ammonia borane (AB, NH₃BH₃) at room temperature. The as-synthesized Cu_0.9Mo_0.1 NPs exhibited a high activity towards the hydrolysis of AB with a turnover frequency (TOF) of 14.9 min^-1, a higher value than that reported for Cu catalysts. Our synthesis is not limited to CuMo NPs alone, but can easily be extended to CuW (3.6 min^-1), CuCr (2 min^-1), NiMo (55.6 min^-1), and CoMo (21.7 min^-1) NPs, providing a general approach to Cu-M (M = Mo, W, Cr) and TM-Mo (TM = Cu, Ni, Co) NPs as a series of novel catalysts for the hydrolysis of AB. The enhanced activity of bimetallic NPs may be attributed to the synergistic effects of the Cu-M NPs induced by the strain and ligand effects.
- Copper,
- Ammonia borane,
- Hydrolysis,
- Hydrogen energy,
- Nanoparticle
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
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