Citation: HE Rong-An, CAO Shao-Wen, YU Jia-Guo. Recent Advances in Morphology Control and Surface Modification of Bi-Based Photocatalysts[J]. Acta Physico-Chimica Sinica, ;2016, 32(12): 2841-2870. doi: 10.3866/PKU.WHXB201611021 shu

Recent Advances in Morphology Control and Surface Modification of Bi-Based Photocatalysts

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China;
2.
Hunan Province Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha 410022, P. R. China

Received Date: 16 September 2016
Revised Date: 1 November 2016

Fund Project: The project was supported by the National Key Basic Research Program of China (973) (2013CB632402) and the National Natural Science Foundation of China (51272199, 51320105001, 51372190, 21433007, 21407115).

Bi-based semiconductor photocatalysts are important visible-light-driven photocatalysts. However, the photocatalytic performance of bulk bismuth-containing compounds remains unsatisfactory. Many investigations indicate that morphology control and surface modification are effective methods for improving the photocatalytic activity of these compounds. Herein, we review recent advances in this field, including ultrathin nanoplate fabrication, facet ratio control, hierarchical and hollow architecture construction, functional group and quantum-sized nanoparticle modification, surface defect regulation, and in situ formation of metal bismuth and bismuth compounds. The characteristics and advantages of these modification methods are introduced. In addition, mechanisms for improving light absorption, separation, and utilization of excited carriers are discussed. Trends in the development of Bi-based photocatalysts using morphology control and surface modification, as well as the challenges involved, are also analyzed and summarized.
- Bi-based compound,
- Photocatalysis,
- Morphology control,
- Surface modification
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沈阳化工大学材料科学与工程学院沈阳 110142