Citation: SHI Ji-Fu, HUANG Qi-Zhang, WAN Qing-Cui, XU Xue-Qing, LI Chun-Sheng, XU Gang. Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 822-827. doi: 10.3866/PKU.WHXB201602262 shu

Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells

SHI Ji-Fu ¹ ,
HUANG Qi-Zhang ^1,2 ,
WAN Qing-Cui ¹ ,
XU Xue-Qing ^1,, ,
LI Chun-Sheng ^3,, ,
XU Gang ^1,,

1.
1. Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2.
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3.
3. College of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, Hebei Province, P. R. China

Corresponding author: XU Xue-Qing, LI Chun-Sheng, XU Gang,
Received Date: 22 January 2016
Available Online: 25 February 2016
Fund Project: 国家自然科学基金(21103194, 51506205) (21103194, 51506205) 广东省科技计划(2014A010106018, 2013A011401011) (2014A010106018, 2013A011401011) 粤港合作项目(2014B050505015) (2014B050505015) 广东省特支计划(2014TQ01N610) (2014TQ01N610) 中国科学院广州能源研究所所长创新基金(y307p81001) (y307p81001)广东省太阳能光热先端材料工程技术研究中心建设项目(2014B090904071)资助 (2014B090904071)

We report the preparation and application of a 1-methyl-3-propylimidazolium sulfide-based ionic liquid electrolyte for quantum-dot-sensitized solar cells. By optimizing the concentrations of S and Na₂S, a considerable conductivity of 12.96 mS·cm^-1 is achieved at 25℃. Differential scanning calorimetry indicates that the glass transition temperature of the electrolyte is-85℃. The quantum-dot-sensitized solar cell assembled with this ionic liquid electrolyte displays a high energy conversion efficiency (η) of 3.03% at 25℃, which is comparable to the efficiency of quantum-dot-sensitized solar cells using a water-based polysulfide electrolyte (η= 3.34%). Due to the favorable thermal properties of this ionic liquid electrolyte (lower glass transition temperature and nonvolatility at higher temperatures), the quantum-dot-sensitized solar cell maintains satisfactory η even at-20℃ (η= 2.32%) and 80℃ (η= 1.90%), which is superior to the cell using the water-based polysulfide electrolyte.
- Quantum-dot-sensitized solar cell,
- Ionic liquid electrolyte,
- 1-Methyl-3-propylimidazolium sulfide,
- Application temperature,
- Efficiency
1. [1]
  (1) Mathew, S.; Yella, A.; Gao, P.; Humphry-Baker, R.; Curchod, B. F.; Ashari-Astani, N.; Tavernelli, I.; Rothlisberger, U.; Nazeeruddin, M. K.; Grätzel, M. Nat. Chem. 2014, 6 (3), 242. doi: 10.1038/nchem.1861
2. [2]
  (2) Moia, D.; Leijtens, T.; Noel, N.; Snaith, H. J.; Nelson, J.; Barnes, P. R. F. Adv. Mater. 2015, 27 (39), 5889. doi: 10.1002/ adma. 201501919
3. [3]
  (3) Tian, J.; Lv, L.; Fei, C.;Wang, Y.; Liu, X.; Cao, G. J. Mater. Chem. A 2014, 2 (46), 19653. doi: 10.1039/C4TA04534C
4. [4]
  (4) Wang, S. M.; Dong, W.W.; Fang, X. D.; Deng, Z. H.; Shao, J. Z.; Hu, L. H.; Zhu, J. Acta Phys. -Chim. Sin. 2014, 30 (5), 873. [王时茂, 董伟伟, 方晓东, 邓赞红, 邵景珍, 胡林华, 朱俊. 物理化学学报, 2014, 30 (5), 873.] doi: 10.3866/PKU. WHXB201403042
5. [5]
  (5) Du, J.; Meng, X.; Zhao, K.; Li, Y.; Zhong, X. J. Mater. Chem. A 2015, 3 (33), 17091. doi: 10.1039/C5TA04758G
6. [6]
  (6) Bai, S. L.; Lu, W. H.; Li, D. Q.; Li, X. N.; Fang, Y. Y.; Lin, Y. Acta Phys. -Chim. Sin. 2014, 30 (6), 1107. [白守礼, 陆文虎, 李殿卿, 李晓宁, 方艳艳, 林原. 物理化学学报, 2014, 30 (6), 1107.] doi: 10.3866/PKU.WHXB201404111
7. [7]
  (7) Wei, H. Y.;Wang, G. S.;Wu, H. J.; Luo, Y. H.; Li, D. M.; Meng, Q. B. Acta Phys. -Chim. Sin. 2016, 32 (1), 201. [卫会云, 王国帅, 吴会觉, 罗艳红, 李冬梅, 孟庆波. 物理化学学报, 2016, 32 (1), 201.] doi: 10.3866/PKU.WHXB201512031
8. [8]
  (8) Feng, W. L.; Li, Y.; Du, J.;Wang, W.; Zhong, X. H. J. Mater. Chem. A 2016, 4 (4), 1461-1468. doi: 10.1039/C5TA08209A
9. [9]
  (9) Sung, S. D.; Lim, I.; Kang, P.; Lee, C.; Lee, W. I. Chem. Commun. 2013, 49 (54), 6054. doi: 10.1039/c3cc40754c
10. [10]
  (10) Wang, Q.Y.; Chen, C.; Liu, W.; Gao, S. M.;Yang, X. C. J. Nanopart. Res. 2016, 18 (1). doi: 10.1007/s11051-015-3314-9
11. [11]
  (11) Lee, Y. L.; Chang, C. H. J. Power Sources 2008, 185 (1), 584. doi: 10.1016/j.jpowsour.2008.07.014
12. [12]
  (12) Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Nazeeruddin, M. K.; Sekiguchi, T.; Grätzel, M. Nat. Mat. 2003, 2 (6), 402. doi: 10.1038/nmat904
13. [13]
  (13) Bai, Y.; Cao, Y.; Zhang, J.;Wang, M.; Li, R.;Wang, P.; Zakeeruddin, S. M.; Grätzel, M. Nat. Mat. 2008, 7 (8), 626. doi: 10.1038/nmat2224
14. [14]
  (14) Wang, H.; Xu, X. Q.; Shi, J. F.; Xu, G. Acta Phys. -Chim. Sin. 2013, 29 (3), 525. [王海, 徐雪青, 史继富, 徐刚. 物理化学学报, 2013, 29 (3), 525.] doi: 10.3866/PKU.WHXB201301091
15. [15]
  (15) Lee, H.;Wang, M.; Chen, P.; Gamelin, D. R.; Zakeeruddin, S. M.; Grätzel, M.; Nazeeruddin, M. K. Nano Lett. 2009, 9 (12), 4221. doi: 10.1021/nl902438d
16. [16]
  (16) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. Acta Phys. -Chim. Sin. 2012, 28 (4), 857. [史继富, 樊烨, 徐雪青, 徐刚, 陈丽华. 物理化学学报, 2012, 28 (4), 857.] doi: 10.3866/PKU.WHXB201202204
17. [17]
  (17) Wu, J.; Hao, S.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Li, P.; Yin, S.; Sato, T. J. Am. Chem. Soc. 2008, 130 (35), 11568. doi: 10.1021/ja802158q
18. [18]
  (18) Jovanovski, V.; González-Pedro, V.; Giménez, S.; Azaceta, E.; Cabañero, G. N.; Grande, H.; Tena-Zaera, R.; Mora-Seró, I. N.; Bisquert, J. J. Am. Chem. Soc. 2011, 133 (50), 20156. doi: 10.1021/ja2096865
19. [19]
  (19) Abbott, A. P.; Boothby, D.; Capper, G.; Davies, D. L.; Rasheed, R. K. J. Am. Chem. Soc. 2004, 126 (29), 9142. doi: 10.1021/ja048266j
20. [20]
  (20) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. ChemPhysChem 2005, 6 (7), 1324. doi: 10.1002/cphc.200500094
21. [21]
  (21) Shi, J.; Chen, J.; Li, Y.; Zhu, Y.; Xu, G.; Xu, J. J. Power Sources 2015, 282, 51. doi: 10.1016/j.jpowsour.2015.02.022
22. [22]
  (22) Hagfeldt, A.; Boschloo, G.; Sun, L.; Kloo, L.; Pettersson, H. Chem. Rev. 2010, 110 (11), 6595. doi: 10.1021/cr900356p
23. [23]
  (23) Huo, Z. P.; Tao, L.;Wang, S. M.;Wei, J. F.; Zhu, J.; Dong, W. W.; Liu, F.; Chen, S. H.; Zhang, B.; Dai, S. Y. J. Power Sources 2015, 284, 582. doi: 10.1016/j.jpowsour.2015.03.049
24. [24]
  (24) Farooq, W. A.; Fatehmulla, A.; Aslam, M.; Atif, M.; Ali, S. M.; Yakuphanoglu, F.; Yahia, I. S. J. Nanoelectron. Optoe. 2014, 9 (5), 671. doi: 10.1166/jno.2014.1653
25. [25]
  (25) Chen, J.; Lei, W.; Deng, W. Q. Nanoscale 2011, 3 (2), 674. doi: 10.1039/C0NR00591F
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