Citation:
LIU Zi-Yu, LIAO Qi, JIN Zhi-Qiang, ZHANG Lei, ZHANG Lu. Effect of Electrolytes on the Interfacial Behavior of Nonionic-Anionic Surfactant Solutions Using Molecular Dynamics Simulations[J]. Acta Physico-Chimica Sinica,
;2016, 32(5): 1168-1174.
doi:
10.3866/PKU.WHXB201602186
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The effect of electrolytes on the interfacial behavior of nonionic-anionic surfactant solutions is studied using molecular dynamics (MD) simulations. The z-dependent surfactant density, radial distribution, coordination number, spatial distribution function, and mean-squared displacement are used to analyze the interaction of electrolytes and surfactants. Based on our simulated results, the three counter ions Na+, Ca2+, and Mg2+ have an effect on the hydration shell structure. On a micro level, the binding strength of the Na2+ counter ion is less than Ca2+, which is less than Mg2+, and this simulated result is consistent with the experimental results. The diffusion results can explain the interfacial tension (IFT) equilibrium time and have a significant effect on the optimal mixture method.
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