Citation: ZHU Qing-Gong, SUN Xiao-Fu, KANG Xin-Chen, MA Jun, QIAN Qing-Li, HAN Bu-Xing. Cu₂S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO₂ to Formic Acid[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 261-266. doi: 10.3866/PKU.WHXB201512101 shu

Cu₂S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO₂ to Formic Acid

1.
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: HAN Bu-Xing,
Received Date: 24 October 2015
Available Online: 10 December 2015
Fund Project: 国家自然科学基金(21403253,21533011,21321063)资助项目 (21403253,21533011,21321063)

The electrocatalytic reduction of CO₂ to HCOOH is an interesting topic and the efficiency usually depends strongly on the materials of the electrodes. Herein, nanostructured Cu₂S on Cu-foam was prepared by electro-deposition method and characterized by means of scanning electron microscope (SEM) and X-ray diffraction (XRD). The Cu₂S/Cu-foam electrode was used for the first time in the electrocatalytic reduction of CO₂ to HCOOH, and acetonitrile (MeCN) with 0.5 mol·L^-1 1-butyl-3- methylimidazolium tetrafluoroborate (BmimBF4) was used as the electrolyte. It was demonstrated that the electrolysis system was very efficient for the electrochemical reaction, and faradaic efficiency of HCOOH (FE_HCOOH) and reduction current density could reach 85% and 5.3 mA·cm^-2, respectively.
- Copper(I) sulfide,
- Copper foam,
- Formic acid,
- Electrochemistry,
- CO₂ reduction
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Cu2S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO2 to Formic Acid

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Cu₂S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO₂ to Formic Acid