Citation: CHEN Cheng-Cheng, ZHANG Ning, LIU Yong-Chang, WANG Yi-Jing, CHEN Jun. In-situ Preparation of Na₂Ti₃O₇ Nanosheets as High-Performance Anodes for Sodium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 349-355. doi: 10.3866/PKU.WHXB201512073 shu

In-situ Preparation of Na₂Ti₃O₇ Nanosheets as High-Performance Anodes for Sodium Ion Batteries

1.
1 Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
2.
2 Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, P. R. China

Corresponding author: CHEN Jun,
Received Date: 6 November 2015
Available Online: 7 December 2015
Fund Project: 国家自然科学基金(51231003,21231005) (51231003,21231005)教育部重点科技项目(B12015,113016A,ACET-13-0296)资助 (B12015,113016A,ACET-13-0296)

We report on the in-situ preparation of Na₂Ti₃O₇ nanosheets and their application as highperformance anode material for sodium ion batteries. Nanosheets with interconnected micro-nano architectures are prepared by simply engraving commercial titanium foils. Furthermore, the foils can be used directly as electrodes without redundant conductive additives or binders. The electrode material exhibits excellent electrochemical performance with reversible capacity of 175 mAh·g^-1 at 50 mA·g^-1 and 120 mAh·g^-1 at 2000 mA·g^-1 after 3000 cycles (capacity retention of 96.5%). The superior electrochemical performance of Na₂Ti₃O₇ nanosheets results from the short ion/electron diffusion pathway of the twodimensional architecture and the good conductive capability of the binder-free structure. The anode of the binder-free Na₂Ti₃O₇ nanosheets effectively overcomes poor ion/electron conductivity, the main drawback of Na₂Ti₃O₇ electrodes, and is promising for rechargeable sodium ion batteries.
- Na₂Ti₃O₇,
- Nanosheet,
- Binder-free,
- Anode material,
- Sodium ion battery
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In-situ Preparation of Na₂Ti₃O₇ Nanosheets as High-Performance Anodes for Sodium Ion Batteries