Citation: QIN Yu-Cai, GAO Xiong-Hou, SHI Li-Fei, ZHANG Li, DUAN Lin-Hai, SONG Li-Juan. Discrimination of the Mass Transfer Performance of In situ Crystallization FCC Catalysts by the Frequency Response Method[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 527-535. doi: 10.3866/PKU.WHXB201512033 shu

Discrimination of the Mass Transfer Performance of In situ Crystallization FCC Catalysts by the Frequency Response Method

1.
1 Key Laboratory of Petrochemical Catalytic Science and Technology of Liaoning Province, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China;
2.
2 Lanzhou Petrochemical Research Center, Petrochemical Research Institute, Petro China Company Limited, Lanzhou 730060, P. R. China

Corresponding author: GAO Xiong-Hou, SONG Li-Juan,
Received Date: 27 August 2015
Available Online: 2 December 2015
Fund Project: 国家自然科学基金(21076100,21376114) (21076100,21376114)中国石油天然气股份有限公司(10-01A-01-01-01) (10-01A-01-01-01)

Mass transfer behaviors of benzene in an in situ crystallization fluid catalytic cracking (FCC) catalyst were measured and discriminated by the frequency response (FR) method and an intelligent gravimetric analyzer (IGA). The texture properties of the FCC catalysts were analyzed by N₂ adsorption and scanning electron microscope (SEM). By comparison with the mass transfer performance of a semi-synthetic FCC catalyst, as well as a zeolite Y, the results show that the in situ crystallization FCC catalyst has excellent and improved mass transfer behavior over the semi-synthetic FCC catalyst and that it reduces the mass transfer resistance between the interface of zeolite crystal and substrate, which can be attributed to the excellent porous connectivity of the former with the unique accumulation state of the highly dispersed nanosized Y zeolite crystals. It has been demonstrated that the FR technique can be used to measure and distinguish the complex mass transport processes in hierarchical porous catalytic materials.
- Frequency response method,
- In situ crystallization,
- Fluid catalytic cracking catalyst,
- Mass transfer process,
- Porous connectivity
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